Published in Angew Chem Int Ed Engl on July 02, 2002
Structure validation in chemical crystallography. Acta Crystallogr D Biol Crystallogr (2009) 1216.15
And Hückel was correct after all--a withdrawal and an apology. Angew Chem Int Ed Engl (2002) 0.75
Stable Carbenes. Chem Rev (2000) 4.21
Stable cyclic (alkyl)(amino)carbenes as rigid or flexible, bulky, electron-rich ligands for transition-metal catalysts: a quaternary carbon atom makes the difference. Angew Chem Int Ed Engl (2005) 2.20
Synthesis and characterization of a neutral tricoordinate organoboron isoelectronic with amines. Science (2011) 1.84
Crystallographic evidence for a free silylium ion. Science (2002) 1.82
Synthesis and ligand properties of stable five-membered-ring allenes containing only second-row elements. Angew Chem Int Ed Engl (2008) 1.70
Intramolecular "hydroiminiumation" of alkenes: application to the synthesis of conjugate acids of cyclic alkyl amino carbenes (CAACs). Angew Chem Int Ed Engl (2007) 1.68
A rigid cyclic (alkyl)(amino)carbene ligand leads to isolation of low-coordinate transition-metal complexes. Angew Chem Int Ed Engl (2005) 1.60
Facile splitting of hydrogen and ammonia by nucleophilic activation at a single carbon center. Science (2007) 1.59
Isolation of a C5-deprotonated imidazolium, a crystalline "abnormal" N-heterocyclic carbene. Science (2009) 1.49
Synthesis, reactivity, and ligand properties of a stable alkyl carbene. J Am Chem Soc (2004) 1.47
Isolation of a carbene-stabilized phosphorus mononitride and its radical cation (PN+*). Angew Chem Int Ed Engl (2010) 1.45
Cyclopropenylidenes: from interstellar space to an isolated derivative in the laboratory. Science (2006) 1.43
Stable cyclic carbenes and related species beyond diaminocarbenes. Angew Chem Int Ed Engl (2010) 1.42
Synthesis and structure of a base-stabilized C-phosphino-Si-amino silyne. Angew Chem Int Ed Engl (2010) 1.39
Allene formation by gold catalyzed cross-coupling of masked carbenes and vinylidenes. Proc Natl Acad Sci U S A (2007) 1.37
Synthesis and reactivity of olefin metathesis catalysts bearing cyclic (alkyl)(amino)carbenes. Angew Chem Int Ed Engl (2007) 1.36
CO fixation to stable acyclic and cyclic alkyl amino carbenes: stable amino ketenes with a small HOMO-LUMO gap. Angew Chem Int Ed Engl (2006) 1.28
Capacitive sensing of electrocardiographic potential through cloth from the dorsal surface of the body in a supine position: a preliminary study. IEEE Trans Biomed Eng (2007) 1.28
Homogeneous catalytic hydroamination of alkynes and allenes with ammonia. Angew Chem Int Ed Engl (2008) 1.26
Novel weak coordination to silylium ions: formation of nearly linear Si-H-Si bonds. Chem Commun (Camb) (2006) 1.23
Intramolecular "hydroiminiumation and -amidiniumation" of alkenes: a convenient, flexible, and scalable route to cyclic iminium and imidazolinium salts. J Org Chem (2007) 1.16
Synthesis of a simplified version of stable bulky and rigid cyclic (alkyl)(amino)carbenes, and catalytic activity of the ensuing gold(I) complex in the three-component preparation of 1,2-dihydroquinoline derivatives. J Am Chem Soc (2009) 1.14
Synthesis of an extremely bent acyclic allene (a "carbodicarbene"): a strong donor ligand. Angew Chem Int Ed Engl (2008) 1.14
Amino-aryl-carbenes: alternative ligands for transition metals? J Am Chem Soc (2004) 1.11
Isolation of cyclopropenylidene-lithium adducts: the Weiss-Yoshida reagent. Angew Chem Int Ed Engl (2006) 1.11
Outcomes of fusion surgery for ossification of the posterior longitudinal ligament of the thoracic spine: a multicenter retrospective survey: clinical article. J Neurosurg Spine (2011) 1.11
Five-year follow-up evaluation of surgical treatment for cervical myelopathy caused by ossification of the posterior longitudinal ligament: a prospective comparative study of anterior decompression and fusion with floating method versus laminoplasty. Spine (Phila Pa 1976) (2012) 1.11
Stable singlet carbenes as mimics for transition metal centers. Chem Sci (2011) 1.10
Crystalline 1H-1,2,3-triazol-5-ylidenes: new stable mesoionic carbenes (MICs). Angew Chem Int Ed Engl (2010) 1.09
A stable P-heterocyclic carbene. Angew Chem Int Ed Engl (2005) 1.07
Gold-catalyzed intermolecular Markovnikov hydroamination of allenes with secondary amines. Org Lett (2009) 1.04
Carbene activation of P4 and subsequent derivatization. Angew Chem Int Ed Engl (2007) 1.04
Cyclic (alkyl)(amino)carbenes (CAACs): stable carbenes on the rise. Acc Chem Res (2014) 1.02
31P NMR chemical shifts of carbene-phosphinidene adducts as an indicator of the π-accepting properties of carbenes. Angew Chem Int Ed Engl (2013) 1.01
Synthesis of carbenes through substitution reactions at a carbene center. Science (2003) 1.00
Kinetic Selectivity of Olefin Metathesis Catalysts Bearing Cyclic (Alkyl)(Amino)Carbenes. Organometallics (2008) 0.99
Risk factors for early reconstruction failure of multilevel cervical corpectomy with dynamic plate fixation. Spine (Phila Pa 1976) (2011) 0.99
Structural basis of the versatile DNA recognition ability of the methyl-CpG binding domain of methyl-CpG binding domain protein 4. J Biol Chem (2013) 0.99
NHC-mediated aggregation of P4: isolation of a P12 cluster. J Am Chem Soc (2007) 0.98
Hybrid grafting using bone marrow aspirate combined with porous β-tricalcium phosphate and trephine bone for lumbar posterolateral spinal fusion: a prospective, comparative study versus local bone grafting. Spine (Phila Pa 1976) (2012) 0.98
Mono- and diaminocarbenes from chloroiminium and -amidinium salts: synthesis of metal-free bis(dimethylamino)carbene. J Am Chem Soc (2004) 0.97
Vascular endothelial growth factor (VEGF)-induced angiogenesis in herniated disc resorption. J Orthop Res (2002) 0.97
Nonmetal-mediated fragmentation of P4: isolation of P1 and P2 bis(carbene) adducts. Angew Chem Int Ed Engl (2009) 0.97
Middle-term results of a prospective comparative study of anterior decompression with fusion and posterior decompression with laminoplasty for the treatment of cervical spondylotic myelopathy. Spine (Phila Pa 1976) (2011) 0.96
Exploring the reactivity of white phosphorus with electrophilic carbenes: synthesis of a P4 cage and P8 clusters. Chem Commun (Camb) (2013) 0.96
Readily available onio-substituted methyleneiminium salts: single precursors for a variety of aminocarbenes. Angew Chem Int Ed Engl (2004) 0.96
A New Synthetic Method for the Preparation of Protonated-NHCs and Related Compounds. J Organomet Chem (2006) 0.96
Serendipitous discovery of the catalytic hydroammoniumation and methylamination of alkynes. Angew Chem Int Ed Engl (2010) 0.96
Neurological complications of cervical laminoplasty for patients with ossification of the posterior longitudinal ligament-a multi-institutional retrospective study. Spine (Phila Pa 1976) (2011) 0.95
Isolation of crystalline carbene-stabilized P(2)-radical cations and P(2)-dications. Nat Chem (2010) 0.95
Exocyclic delocalization at the expense of aromaticity in 3,5-bis(pi-donor) substituted pyrazolium ions and corresponding cyclic bent allenes. J Am Chem Soc (2009) 0.93
Stable Bis(diisopropylamino)cyclopropenylidene (BAC) as Ligand for Transition Metal Complexes. J Organomet Chem (2008) 0.93
Strong conductance variation in conformationally constrained oligosilane tunnel junctions. J Phys Chem A (2009) 0.93
A prospective comparative study of 2 minimally invasive decompression procedures for lumbar spinal canal stenosis: unilateral laminotomy for bilateral decompression (ULBD) versus muscle-preserving interlaminar decompression (MILD). Spine (Phila Pa 1976) (2014) 0.93
Prescription profiles for pharmacological treatment of Japanese inpatients with schizophrenia: comparison between 2007 and 2009. Hum Psychopharmacol (2012) 0.92
Phosphide delivery to a cyclotrisilene. Angew Chem Int Ed Engl (2014) 0.91
Cyclic (Alkyl)(amino)carbene Gold(I) complexes: A Synthetic and Structural Investigation. J Organomet Chem (2008) 0.91
Vertical and nonvertical participation by sulfur, selenium, and tellurium. Chemistry (2002) 0.91
A tricyclic aromatic isomer of hexasilabenzene. Science (2010) 0.91
Simultaneous inference of biological networks of multiple species from genome-wide data and evolutionary information: a semi-supervised approach. Bioinformatics (2009) 0.91
A Brief Survey of our Contribution to Stable Carbene Chemistry. Organometallics (2011) 0.90
Stable cyclic silenes from reaction of disilenides with carboxylic acid chlorides. Angew Chem Int Ed Engl (2007) 0.90
Stable non-push-pull phosphanylcarbenes: NMR spectroscopic characterization of a methylcarbene. Angew Chem Int Ed Engl (2002) 0.90
Chemistry. Soluble allotropes of main-group elements. Science (2008) 0.90
Transient azomethine-ylides from a stable amino-carbene and an aldiminium salt. J Org Chem (2003) 0.90
Protonolysis of a ruthenium-carbene bond and applications in olefin metathesis. J Am Chem Soc (2011) 0.90
Isolation of neutral mono- and dinuclear gold complexes of cyclic (alkyl)(amino)carbenes. Angew Chem Int Ed Engl (2013) 0.89
Stable (amino)(phosphino)carbenes: difunctional molecules. J Am Chem Soc (2002) 0.89
Stable (aryl)(phosphino)carbenes: new ligands for transition metals. J Am Chem Soc (2002) 0.89
(Phosphino)(aryl)carbenes: effect of aryl substituents on their stabilization mode. J Am Chem Soc (2003) 0.89
Nucleophilic silylenoid character of stable phosphonium sila-ylides. Chemistry (2010) 0.89
Deprotonation of a borohydride: synthesis of a carbene-stabilized boryl anion. Angew Chem Int Ed Engl (2013) 0.88
Synthesis of Highly Stable 1,3-Diaryl-1H-1,2,3-triazol-5-ylidenes and their Applications in Ruthenium-Catalyzed Olefin Metathesis. Organometallics (2011) 0.88
An efficient synthetic route to stable bis(carbene)borylenes [(L1)(L2)BH]. Chem Commun (Camb) (2014) 0.87
Experimental studies on the effects of recombinant human matrix metalloproteinases on herniated disc tissues--how to facilitate the natural resorption process of herniated discs. J Orthop Res (2005) 0.87
Synthesis of transient and stable C-amino phosphorus ylides and their fragmentation into transient and stable carbenes. J Am Chem Soc (2006) 0.87
Persistent (amino)(silyl)carbenes. J Am Chem Soc (2005) 0.87
Synthesis of 4- and 4,5-functionalized imidazol-2-ylidenes from a single 4,5-unsubstituted imidazol-2-ylidene. J Am Chem Soc (2010) 0.87
Dural closure for the treatment of superficial siderosis. J Neurosurg Spine (2013) 0.87
Synthesis and reactivity of a CAAC-aminoborylene adduct: a hetero-allene or an organoboron isoelectronic with singlet carbenes. Angew Chem Int Ed Engl (2014) 0.87
Two-coordinate Fe⁰ and Co⁰ complexes supported by cyclic (alkyl)(amino)carbenes. Angew Chem Int Ed Engl (2014) 0.87
Potential role for matrix metalloproteinase-3 in gastric ulcer healing. Digestion (2009) 0.87
Carbene-Stabilized Main Group Radicals and Radical Ions. Chem Sci (2013) 0.86
Borylene complexes (BH)L2 and nitrogen cation complexes (N+)L2: isoelectronic homologues of carbones CL2. Chemistry (2012) 0.86
Shape anisotropy induces rotations in optically trapped red blood cells. J Biomed Opt (2010) 0.86
Singlet diradicals: from transition states to crystalline compounds. Science (2002) 0.86
Respiratory chain analysis of Zymomonas mobilis mutants producing high levels of ethanol. Appl Environ Microbiol (2012) 0.85
Warning thresholds on the basis of origin of amplitude changes in transcranial electrical motor-evoked potential monitoring for cervical compression myelopathy. Spine (Phila Pa 1976) (2012) 0.85
Bis(1,2,3-triazol-5-ylidenes) (i-bitz) as Stable 1,4-Bidentate Ligands Based on Mesoionic Carbenes (MICs). Organometallics (2011) 0.85
NHC-stabilized silagermenylidene: a heavier analogue of vinylidene. Angew Chem Int Ed Engl (2013) 0.85
Increase in paravertebral muscle activity in lumbar kyphosis patients by surface electromyography compared with lumbar spinal canal stenosis patients and healthy volunteers. J Spinal Disord Tech (2012) 0.85
Carbenes introduction. Chem Rev (2009) 0.84
Stable optically pure phosphino(silyl)carbenes: reagents for highly enantioselective cyclopropanation reactions. Chemistry (2004) 0.84
NHC-coordinated silagermenylidene functionalized in allylic position and its behaviour as a ligand. Dalton Trans (2014) 0.84
Reversible base coordination to a disilene. Angew Chem Int Ed Engl (2012) 0.83
Effects of Vitrectomy on Recurrent Macular Edema due to Branch Retinal Vein Occlusion after Intravitreal Injection of Bevacizumab. J Ophthalmol (2013) 0.83
N-heterocyclic carbene coordinated neutral and cationic heavier cyclopropylidenes. Angew Chem Int Ed Engl (2014) 0.83
New synthetic routes to C-amino phosphorus ylides and their subsequent fragmentation into carbenes and phosphines. Chem Asian J (2006) 0.83
Gold-catalyzed hydroamination of alkynes and allenes with parent hydrazine. Angew Chem Int Ed Engl (2011) 0.83
Perioperative complications of anterior cervical decompression with fusion in patients with ossification of the posterior longitudinal ligament: a retrospective, multi-institutional study. J Orthop Sci (2012) 0.82