Published in Angew Chem Int Ed Engl on July 22, 2013
(BB)-Carboryne Complex of Ruthenium: Synthesis by Double B-H Activation at a Single Metal Center. J Am Chem Soc (2016) 0.78
P-C-Activated Bimetallic Rhodium Xantphos Complexes: Formation and Catalytic Dehydrocoupling of Amine-Boranes. Angew Chem Int Ed Engl (2015) 0.77
Thermal Dehydrogenation of Base-Stabilized B2 H5 (+) Complexes and Its Role in CH Borylation. Angew Chem Int Ed Engl (2015) 0.75
Computational study of the mechanism of cyclometalation by palladium acetate. J Am Chem Soc (2005) 1.68
Coordination chemistry of 4-methyl-2,6,7-trioxa-1-phosphabicyclo[2,2,1]heptane: preparation and characterization of Ru(II) complexes. Inorg Chem (2012) 1.01
Intermolecular alkene and alkyne hydroacylation with beta-S-substituted aldehydes: mechanistic insight into the role of a hemilabile P-O-P ligand. Chemistry (2008) 0.99
Room-temperature C-C bond cleavage of an arene by a metallacarborane. Angew Chem Int Ed Engl (2010) 0.99
Intermolecular hydroacylation: high activity rhodium catalysts containing small-bite-angle diphosphine ligands. J Am Chem Soc (2012) 0.97
Mechanisms of C-H bond activation: rich synergy between computation and experiment. Dalton Trans (2009) 0.94
Rhodium-catalyzed branched-selective alkyne hydroacylation: a ligand-controlled regioselectivity switch. Angew Chem Int Ed Engl (2011) 0.93
Mechanisms of catalyst poisoning in palladium-catalyzed cyanation of haloarenes. remarkably facile C-N bond activation in the [(Ph3P)4Pd]/[Bu4N]+ CN- system. J Am Chem Soc (2008) 0.93
Electrophilic C-H activation at Cp*Ir: ancillary-ligand control of the mechanism of C-H activation. J Am Chem Soc (2006) 0.92
Unprecedented steric deformation of ortho-carborane. Chem Commun (Camb) (2008) 0.91
Transition metal complexes of the chelating phosphine borane ligand Ph2PCH2Ph2P.BH3. Dalton Trans (2004) 0.91
Responses to exercise in the heat related to measures of hypothalamic serotonergic and dopaminergic function. Eur J Appl Physiol (2003) 0.89
Aryl methyl sulfides as substrates for rhodium-catalyzed alkyne carbothiolation: arene functionalization with activating group recycling. J Am Chem Soc (2012) 0.89
Model studies of beta-scission ring-opening reactions of cyclohexyloxy radicals: application to thermal rearrangements of dispiro-1,2,4-trioxanes. Org Lett (2007) 0.89
Synthesis and characterization of a rhodium(I) σ-alkane complex in the solid state. Science (2012) 0.86
A highly reactive rhodium(I)-boryl complex as a useful tool for C-H bond activation and catalytic C-F bond borylation. Angew Chem Int Ed Engl (2010) 0.85
Ligand effects in chromium diphosphine catalysed olefin co-trimerisation and diene trimerisation. Dalton Trans (2009) 0.85
B-H activation at a rhodium(I) center: isolation of a bimetallic complex relevant to the transition-metal-catalyzed dehydrocoupling of amine-boranes. Angew Chem Int Ed Engl (2010) 0.85
Tuning the [L2Rh···H3B·NR3]+ interaction using phosphine bite angle. Demonstration by the catalytic formation of polyaminoboranes. Chem Commun (Camb) (2011) 0.84
Mechanistic studies of the dehydrocoupling and dehydropolymerization of amine-boranes using a [Rh(Xantphos)]⁺ catalyst. J Am Chem Soc (2014) 0.84
Effect of the phosphine steric and electronic profile on the Rh-promoted dehydrocoupling of phosphine-boranes. Inorg Chem (2014) 0.83
Reaction of Cu(I) with dialkyl peroxides: Cu(II)-alkoxides, alkoxy radicals, and catalytic C-H etherification. J Am Chem Soc (2012) 0.83
C-F and C-H bond activation of fluorobenzenes and fluoropyridines at transition metal centers: how fluorine tips the scales. Acc Chem Res (2011) 0.83
A second-generation catalyst for intermolecular hydroacylation of alkenes and alkynes using beta-S-substituted aldehydes: the role of a hemilabile P-O-P ligand. Angew Chem Int Ed Engl (2006) 0.83
Solid-state synthesis and characterization of σ-alkane complexes, [Rh(L2)(η(2),η(2)-C7H12)][BAr(F)4] (L2 = bidentate chelating phosphine). J Am Chem Soc (2015) 0.83
Copper(II) anilides in sp³ C-H amination. J Am Chem Soc (2014) 0.82
A ligand knowledge base for carbenes (LKB-C): maps of ligand space. Dalton Trans (2009) 0.82
C-C sigma complexes of rhodium. Proc Natl Acad Sci U S A (2007) 0.82
Synthesis, electronic structure, and magnetism of [Ni(6-Mes)2]+: a two-coordinate nickel(I) complex stabilized by bulky N-heterocyclic carbenes. J Am Chem Soc (2013) 0.81
Stable fluorophosphines: predicted and realized ligands for catalysis. Angew Chem Int Ed Engl (2011) 0.81
C-H functionalization reactivity of a nickel-imide. J Am Chem Soc (2012) 0.81
The conformations of 13-vertex ML2C2B10 metallacarboranes: experimental and computational studies. J Am Chem Soc (2007) 0.81
Development of a generic mechanism for the dehydrocoupling of amine-boranes: a stoichiometric, catalytic, and kinetic study of H3B·NMe2H using the [Rh(PCy3)2]+ fragment. J Am Chem Soc (2012) 0.81
A rhodium complex with one Rh...C-C and one Rh...H-C agostic bond. Angew Chem Int Ed Engl (2006) 0.80
Dehydrocoupling of dimethylamine borane catalyzed by Rh(PCy3)2H2Cl. Inorg Chem (2013) 0.80
Amine-borane sigma-complexes of rhodium. relevance to the catalytic dehydrogenation of amine-boranes. J Am Chem Soc (2008) 0.80
On the prebiotic potential of reduced oxidation state phosphorus: the H-phosphinate-pyruvate system. Chem Commun (Camb) (2010) 0.80
C-C activation in the solid state in an organometallic σ-complex. J Am Chem Soc (2011) 0.80
Computational and synthetic studies on the cyclometallation reaction of dimethylbenzylamine with [IrCl2Cp*]2: role of the chelating base. Dalton Trans (2009) 0.80
[PtMe(iPr3P)2]+: a Pt(II) complex with an agostic interaction that undergoes C-H activation. Chem Commun (Camb) (2004) 0.79
Rhodium-catalysed linear-selective alkyne hydroacylation. Chem Commun (Camb) (2012) 0.79
Traceless chelation-controlled rhodium-catalyzed intermolecular alkene and alkyne hydroacylation. Chemistry (2013) 0.79
Catching the first oligomerization event in the catalytic formation of polyaminoboranes: H3B·NMeHBH2·NMeH2 bound to iridium. J Am Chem Soc (2011) 0.79
Structure, reactivity, and computational studies of a novel ruthenium hydrogen sulfide dihydride complex. Inorg Chem (2003) 0.79
Bis(phosphine)boronium salts. Synthesis, structures and coordination chemistry. Dalton Trans (2013) 0.78
C-C and C-H bond activation reactions in N-heterocyclic carbene complexes of ruthenium. J Am Chem Soc (2002) 0.78
Redox-mediated reactions of vinylferrocene: toward redox auxiliaries. Dalton Trans (2016) 0.78
Fluxionality of [(Ph3P)3Rh(X)]: the extreme case of X = CF3. J Am Chem Soc (2009) 0.78
Intermediates in the Rh-catalysed dehydrocoupling of phosphine-borane. Chem Commun (Camb) (2012) 0.78
Computational study of the double C-Cl bond activation of dichloromethane and phosphine alkylation at [CoCl(PR3)3]. Dalton Trans (2013) 0.78
Cationic rhodium mono-phosphine fragments partnered with carborane monoanions [closo-CB11H6X6]- (X = H, Br). Synthesis, structures and reactivity with alkenes. Dalton Trans (2007) 0.78
Activation of an alkyl C-H bond geminal to an agostic interaction: an unusual mode of base-induced C-H activation. J Am Chem Soc (2009) 0.77
Organometallic reactivity: the role of metal-ligand bond energies from a computational perspective. Dalton Trans (2011) 0.77
Bis(sigma-amine-borane) complexes: an unusual binding mode at a transition-metal center. Angew Chem Int Ed Engl (2009) 0.77
Chiral palladacycles based on resorcinol monophosphite ligands: the role of the meta-hydroxyl in ligand C-H activation and catalysis. Dalton Trans (2011) 0.77
A combined experimental and computational study of fluxional processes in sigma amine-borane complexes of rhodium and iridium. Dalton Trans (2013) 0.77
C-Cl activation of the weakly coordinating anion [B(3,5-Cl2C6H3)4]- at a Rh(I) centre in solution and the solid-state. Dalton Trans (2013) 0.77
Computational studies on the mechanism of the gold(I)-catalysed rearrangement of cyclopropenes. Org Biomol Chem (2012) 0.77
High hydride count rhodium octahedra, [Rh6(PR3)6H12][BArF4]2: synthesis, structures, and reversible hydrogen uptake under mild conditions. J Am Chem Soc (2006) 0.77
Intramolecular C-C agostic complexes: C-C sigma interactions by another name. Chem Soc Rev (2013) 0.76
Intramolecular alkyl phosphine dehydrogenation in cationic rhodium complexes of tris(cyclopentylphosphine). Chemistry (2008) 0.76
Holding onto lots of hydrogen: a 12-hydride rhodium cluster that reversibly adds two molecules of H2. Angew Chem Int Ed Engl (2005) 0.76
[Ir(PCy3)2(H)2(H2B-NMe2)]+ as a latent source of aminoborane: probing the role of metal in the dehydrocoupling of H3B⋅NMe2H and retrodimerisation of [H2BNMe2]2. Chemistry (2011) 0.76
Monomeric and oligomeric amine-borane sigma-complexes of rhodium. intermediates in the catalytic dehydrogenation of amine-boranes. J Am Chem Soc (2009) 0.76
Amino-borane oligomers bound to a Rh(I) metal fragment. Chem Commun (Camb) (2010) 0.76
Amine- and dimeric amino-borane complexes of the {Rh(P(i)Pr3)2}+ fragment and their relevance to the transition-metal-mediated dehydrocoupling of amine-boranes. Inorg Chem (2010) 0.76
Dihydrogen complexes of rhodium: [RhH2(H2)x (PR3)2]+ (R = Cy, iPr; x = 1, 2). Inorg Chem (2005) 0.76
Tuning ligand structure in chiral bis(phosphite) and mixed phosphite-phosphinite PCP-palladium pincer complexes. Dalton Trans (2011) 0.76
Phosphine-olefin ligands: a facile dehydrogenative route to catalytically active rhodium complexes. Chem Commun (Camb) (2006) 0.76
Gold(I)-catalysed direct thioetherifications using allylic alcohols: an experimental and computational study. Chemistry (2014) 0.76
Combined experimental and computational investigations of rhodium- and ruthenium-catalyzed C-H functionalization of pyrazoles with alkynes. J Org Chem (2014) 0.76
The role of halogenated carborane monoanions in olefin hydrogenation catalysed by cationic iridium phosphine complexes. Dalton Trans (2006) 0.75
Palladium-catalyzed direct C-H functionalization of benzoquinone. Angew Chem Int Ed Engl (2014) 0.75
Isothiourea-catalysed enantioselective pyrrolizine synthesis: synthetic and computational studies. Org Biomol Chem (2016) 0.75
Combined experimental and computational investigations of rhodium-catalysed C - H functionalisation of pyrazoles with alkenes. Chemistry (2014) 0.75
Cyclopropenylidene carbene ligands in palladium catalysed coupling reactions: carbene ligand rotation and application to the Stille reaction. Dalton Trans (2011) 0.75
Icosahedral metallacarborane/carborane species derived from 1,1'-bis(o-carborane). Dalton Trans (2015) 0.75
Reactivity of the latent 12-electron fragment [Rh(PiBu3)2]+ with aryl bromides: aryl-Br and phosphine ligand C-H activation. Chemistry (2010) 0.75
α-Halo carbonyls enable meta selective primary, secondary and tertiary C-H alkylations by ruthenium catalysis. Org Biomol Chem (2017) 0.75
Silver phosphanes partnered with carborane monoanions: synthesis, structures and use as highly active Lewis acid catalysts in a hetero-Diels-Alder reaction. Chemistry (2002) 0.75
Alkyl dehydrogenation in a Rh(I) complex via an isolated agostic intermediate. Chem Commun (Camb) (2008) 0.75
Hydroboration of an alkene by amine-boranes catalysed by a [Rh(PR3)2]+ fragment. Mechanistic insight and tandem hydroboration/dehydrogenation. Dalton Trans (2011) 0.75
[(PPh(3))Ag(HCB(11)Me(11))]: a complex with intermolecular Ag.H3C interactions. Angew Chem Int Ed Engl (2002) 0.75
Using EPR to follow reversible dihydrogen addition to paramagnetic clusters of high hydride count: [Rh(6)(PCy(3))(6)H(12)](+) and [Rh(6)(PCy(3))(6)H(14)](+). Dalton Trans (2009) 0.75
Bond catastrophes in rhodium complexes: experimental charge-density studies of [Rh(C7H8)(P(t)Bu3)Cl] and [Rh(C7H8)(PCy3)Cl]. Acta Crystallogr B (2010) 0.75
Reversible C-H activation of a P(t)Bu(i)Bu2 ligand to reveal a masked 12 electron [Rh(PR3)2]+ cation. Dalton Trans (2010) 0.75
Experimental charge density study into C-C σ-interactions in a Binor-S rhodium complex. Dalton Trans (2011) 0.75
Large, weakly basic bis(carboranyl)phosphines: an experimental and computational study. Dalton Trans (2017) 0.75
Beyond the icosahedron: the first 13-vertex carborane. Angew Chem Int Ed Engl (2003) 0.75
Dehydrogenation of cyclic thioethers bound to a [Rh(diphosphine)]+ fragment. Dalton Trans (2011) 0.75
[Cp2ZrMe(12-mu-Me-1-closo-CB11HMe10)]: a transition metal complex of a highly-methylated carborane anion. Chem Commun (Camb) (2003) 0.75
Solution and solid-state structure of the anion [Ag(2)[closo-CB(11)H(12)](4)](2-). Inorg Chem (2002) 0.75