Published in J Am Chem Soc on July 10, 2002
Application of metal coordination chemistry to explore and manipulate cell biology. Chem Rev (2009) 1.56
Selective DNA strand scission with binuclear copper complexes: implications for an active Cu2-O2 species. J Am Chem Soc (2006) 0.90
DNA cleavage studies of mononuclear and dinuclear copper(II) complexes with benzothiazolesulfonamide ligands. J Biol Inorg Chem (2003) 0.83
Mechanistic studies on DNA damage by minor groove binding copper-phenanthroline conjugates. Nucleic Acids Res (2005) 0.82
(Acetonitrile)[bis-(2-pyridylmeth-yl)amine]bis-(perchlorato)copper(II). Acta Crystallogr Sect E Struct Rep Online (2007) 0.75
Investigation and improvement of DNA cleavage models of polyamide + Cu(II) nuclease + OOH- ligands bound to DNA. BMC Struct Biol (2010) 0.75
Oxidant types in copper-dioxygen chemistry: the ligand coordination defines the Cu(n)-O2 structure and subsequent reactivity. J Biol Inorg Chem (2004) 2.36
Synthetic models for heme-copper oxidases. Chem Rev (2004) 1.82
Nitric oxide in biological denitrification: Fe/Cu metalloenzyme and metal complex NO(x) redox chemistry. Chem Rev (2002) 1.81
Copper-dioxygen complex mediated C-H bond oxygenation: relevance for particulate methane monooxygenase (pMMO). Curr Opin Chem Biol (2009) 1.75
A 1:1 copper-dioxygen adduct is an end-on bound superoxo copper(II) complex which undergoes oxygenation reactions with phenols. J Am Chem Soc (2007) 1.54
Reactions of a copper(II) superoxo complex lead to C-H and O-H substrate oxygenation: modeling copper-monooxygenase C-H hydroxylation. Angew Chem Int Ed Engl (2008) 1.43
Synthesis and X-ray absorption spectroscopy structural studies of Cu(I) complexes of histidylhistidine peptides: the predominance of linear 2-coordinate geometry. J Am Chem Soc (2007) 1.40
Heme-copper/dioxygen adduct formation, properties, and reactivity. Acc Chem Res (2007) 1.33
Cupric superoxo-mediated intermolecular C-H activation chemistry. J Am Chem Soc (2011) 1.26
Substrate oxidation by copper-dioxygen adducts: mechanistic considerations. J Am Chem Soc (2005) 1.24
Targeted guanine oxidation by a dinuclear copper(II) complex at single stranded/double stranded DNA junctions. Inorg Chem (2006) 1.22
Structural studies of copper(I) complexes of amyloid-beta peptide fragments: formation of two-coordinate bis(histidine) complexes. Angew Chem Int Ed Engl (2008) 1.17
Contrasting copper-dioxygen chemistry arising from alike tridentate alkyltriamine copper(I) complexes. J Am Chem Soc (2002) 1.16
Heme/non-heme diiron(II) complexes and O2, CO, and NO adducts as reduced and substrate-bound models for the active site of bacterial nitric oxide reductase. J Am Chem Soc (2005) 1.16
Toluene and ethylbenzene aliphatic C-H bond oxidations initiated by a dicopper(II)-mu-1,2-peroxo complex. J Am Chem Soc (2009) 1.16
Resonance raman investigation of equatorial ligand donor effects on the Cu(2)O(2)(2+) core in end-on and side-on mu-peroxo-dicopper(II) and bis-mu-oxo-dicopper(III) complexes. J Am Chem Soc (2003) 1.16
Aryl hydroxylation from a mononuclear copper-hydroperoxo species. J Am Chem Soc (2007) 1.14
A general strategy for target-promoted alkylation in biological systems. Proc Natl Acad Sci U S A (2003) 1.09
A transient product of DNA alkylation can be stabilized by binding localization. J Am Chem Soc (2003) 1.07
Copper-dioxygen adducts and the side-on peroxo dicopper(II)/bis(mu-oxo) dicopper(III) equilibrium: Significant ligand electronic effects. Inorg Chem (2006) 1.07
Substituents on quinone methides strongly modulate formation and stability of their nucleophilic adducts. J Am Chem Soc (2006) 1.06
Spectroscopy and bonding in side-on and end-on Cu2(S2) cores: comparison to peroxide analogues. J Am Chem Soc (2003) 1.06
Crystal structure of iodotyrosine deiodinase, a novel flavoprotein responsible for iodide salvage in thyroid glands. J Biol Chem (2009) 1.05
Iodotyrosine deiodinase is the first mammalian member of the NADH oxidase/flavin reductase superfamily. J Biol Chem (2005) 1.05
Bioinspired heme, heme/nonheme diiron, heme/copper, and inorganic NOx chemistry: *NO((g)) oxidation, peroxynitrite-metal chemistry, and *NO((g)) reductive coupling. Inorg Chem (2010) 1.04
Copper-hydroperoxo-mediated N-debenzylation chemistry mimicking aspects of copper monooxygenases. Inorg Chem (2008) 1.04
The rate of O2 and CO binding to a copper complex, determined by a "flash-and-trap" technique, exceeds that for hemes. J Am Chem Soc (2003) 1.04
Spectroscopic and computational studies of an end-on bound superoxo-Cu(II) complex: geometric and electronic factors that determine the ground state. Inorg Chem (2010) 1.04
Copper(I) complex O(2)-reactivity with a N(3)S thioether ligand: a copper-dioxygen adduct including sulfur ligation, ligand oxygenation, and comparisons with all nitrogen ligand analogues. Inorg Chem (2007) 1.03
Mono-, bi-, and trinuclear CuII-Cl containing products based on the tris(2-pyridylmethyl)amine chelate derived from copper(I) complex dechlorination reactions of chloroform. Inorg Chem (2004) 1.02
Reactivity studies on Fe(III)-(O2(2-))-Cu(II) compounds: influence of the ligand architecture and copper ligand denticity. Inorg Chem (2007) 1.01
Heme-copper-dioxygen complexes: toward understanding ligand-environmental effects on the coordination geometry, electronic structure, and reactivity. Inorg Chem (2010) 1.01
Hydrogen Peroxide as a Sustainable Energy Carrier: Electrocatalytic Production of Hydrogen Peroxide and the Fuel Cell. Electrochim Acta (2012) 1.01
Mononuclear copper complex-catalyzed four-electron reduction of oxygen. J Am Chem Soc (2010) 1.00
Tuning copper-dioxygen reactivity and exogenous substrate oxidations via alterations in ligand electronics. J Am Chem Soc (2003) 0.99
X-ray absorption spectroscopic and theoretical studies on (L)2[Cu2(S2)n]2+ complexes: disulfide versus disulfide(*1-) bonding. J Am Chem Soc (2007) 0.98
Reaction of elemental sulfur with a copper(I) complex forming a trans-mu-1,2 end-on disulfide complex: new directions in copper-sulfur chemistry. J Am Chem Soc (2003) 0.98
Synthesis and spectroscopy of micro-oxo (O(2)(-))-bridged heme/non-heme diiron complexes: models for the active site of nitric oxide reductase. Inorg Chem (2004) 0.98
Kinetics and thermodynamics of formation and electron-transfer reactions of Cu-O2 and Cu2-O2 complexes. Coord Chem Rev (2012) 0.98
Copper dioxygen adducts: formation of bis(mu-oxo)dicopper(III) versus (mu-1,2)Peroxodicopper(II) complexes with small changes in one pyridyl-ligand substituent. Inorg Chem (2008) 0.97
Homogeneous catalytic O2 reduction to water by a cytochrome c oxidase model with trapping of intermediates and mechanistic insights. Proc Natl Acad Sci U S A (2011) 0.97
Time-dependent evolution of adducts formed between deoxynucleosides and a model quinone methide. Chem Res Toxicol (2005) 0.97
Excess electron transfer from an internally conjugated aromatic amine to 5-bromo-2'-deoxyuridine in DNA. J Am Chem Soc (2003) 0.96
Copper(I)/O2 chemistry with imidazole containing tripodal tetradentate ligands leading to mu-1,2-peroxo-dicopper(II) species. Inorg Chem (2009) 0.96
Sulfur donor atom effects on copper(I)/O(2) chemistry with thioanisole containing tetradentate N(3)S ligand leading to μ-1,2-peroxo-dicopper(II) species. Inorg Chem (2010) 0.96
A bis-acetonitrile two-coordinate copper(I) complex: synthesis and characterization of highly soluble B(C(6)F(5))(4)(-) salts of [Cu(MeCN)(2)](+) and [Cu(MeCN)(4)](+). Inorg Chem (2002) 0.95
Distinguishing rate-limiting electron versus H-atom transfers in Cu2O2-mediated oxidative N-dealkylations: application of inter- versus intramolecular kinetic isotope effects. J Am Chem Soc (2003) 0.95
A mammalian reductive deiodinase has broad power to dehalogenate chlorinated and brominated substrates. J Am Chem Soc (2009) 0.95
Superoxo, mu-peroxo, and mu-oxo complexes from heme/O2 and heme-Cu/O2 reactivity: copper ligand influences in cytochrome c oxidase models. Proc Natl Acad Sci U S A (2003) 0.94
Mechanistic insights into the oxidation of substituted phenols via hydrogen atom abstraction by a cupric-superoxo complex. J Am Chem Soc (2014) 0.93
Reductive electron injection into duplex DNA by aromatic amines. J Am Chem Soc (2004) 0.93
Spectroscopic elucidation of a new heme/copper dioxygen structure type: implications for O···O bond rupture in cytochrome c oxidase. Angew Chem Int Ed Engl (2011) 0.93
CO and O2 binding to pseudo-tetradentate ligand-copper(I) complexes with a variable N-donor moiety: kinetic/thermodynamic investigation reveals ligand-induced changes in reaction mechanism. J Am Chem Soc (2010) 0.93
A peroxynitrite complex of copper: formation from a copper-nitrosyl complex, transformation to nitrite and exogenous phenol oxidative coupling or nitration. J Biol Inorg Chem (2009) 0.92
Coordination chemistry and reactivity of a cupric hydroperoxide species featuring a proximal H-bonding substituent. Inorg Chem (2012) 0.92
Copper(II)-hydroperoxo complex induced oxidative N-dealkylation chemistry. J Am Chem Soc (2007) 0.92
Dynamic cross-linking is retained in duplex DNA after multiple exchange of strands. Angew Chem Int Ed Engl (2010) 0.92
Chromium(IV)-peroxo complex formation and its nitric oxide dioxygenase reactivity. J Am Chem Soc (2012) 0.92
Heme/O2/*NO nitric oxide dioxygenase (NOD) reactivity: phenolic nitration via a putative heme-peroxynitrite intermediate. J Am Chem Soc (2009) 0.92
Electronic structure of a low-spin heme/Cu peroxide complex: spin-state and spin-topology contributions to reactivity. Inorg Chem (2011) 0.91
Flavoprotein iodotyrosine deiodinase functions without cysteine residues. Chembiochem (2008) 0.91
Reaction of a copper-dioxygen complex with nitrogen monoxide (*NO) leads to a copper(II)-peroxynitrite species. J Am Chem Soc (2008) 0.91
Immortalizing a transient electrophile for DNA cross-linking. Angew Chem Int Ed Engl (2008) 0.90
Solvent effects on the conversion of dicopper(II) micro-eta(2):eta(2)-peroxo to bis-micro-oxo dicopper(III) complexes: direct probing of the solvent interaction. Inorg Chem (2004) 0.90
Carbon monoxide coordination and reversible photodissociation in copper(I) pyridylalkylamine compounds. Inorg Chem (2007) 0.90
Selective DNA strand scission with binuclear copper complexes: implications for an active Cu2-O2 species. J Am Chem Soc (2006) 0.90
Copper-Carbon Bonds in Mechanistic and Structural Probing of Proteins as well as in Situations where Copper is a Catalytic or Receptor Site. Met Ions Life Sci (2009) 0.90
A N3S(thioether)-ligated Cu(II)-superoxo with enhanced reactivity. J Am Chem Soc (2015) 0.89
Dioxygen reactivity of copper and heme-copper complexes possessing an imidazole-phenol cross-link. Inorg Chem (2005) 0.89
Correlation of the electronic and geometric structures in mononuclear copper(II) superoxide complexes. Inorg Chem (2013) 0.89
Changing selectivity of DNA oxidation from deoxyribose to Guanine by ligand design and a new binuclear copper complex. J Am Chem Soc (2005) 0.89
Electron-transfer reduction of dinuclear copper peroxo and bis-μ-oxo complexes leading to the catalytic four-electron reduction of dioxygen to water. Chemistry (2012) 0.88
Heme-copper assembly mediated reductive coupling of nitrogen monoxide (*NO). J Am Chem Soc (2009) 0.88
Reductive coupling of nitrogen monoxide (*NO) facilitated by heme/copper complexes. Inorg Chem (2010) 0.88
Stepwise protonation and electron-transfer reduction of a primary copper-dioxygen adduct. J Am Chem Soc (2013) 0.87
Synthesis, characterization, and laser flash photolysis reactivity of a carbonmonoxy heme complex. Inorg Chem (2003) 0.87
Computational study of the activated O(H) state in the catalytic mechanism of cytochrome c oxidase. Proc Natl Acad Sci U S A (2013) 0.86
A "naked" Fe(III)-(O₂²⁻)-Cu(II) species allows for structural and spectroscopic tuning of low-spin heme-peroxo-Cu complexes. J Am Chem Soc (2015) 0.86
Heme/Cu/O2 reactivity: change in FeIII-(O2 2-)-CuII unit peroxo binding geometry effected by tridentate copper chelation. J Am Chem Soc (2004) 0.86
Bioinorganic chemistry: Model offers intermediate insight. Nature (2010) 0.86
Synthesis and characterization of reduced heme and heme/copper carbonmonoxy species. Inorg Chem (2003) 0.86
Thioether sulfur oxygenation from O2 or H2O2 reactivity of copper complexes with tridentate N2Sthioether ligands. Inorg Chem (2006) 0.86
Exogenous nitrile substrate hydroxylation by a new dicopper-hydroperoxide complex. J Am Chem Soc (2005) 0.86
Use of a boroxazolidone complex of 3-iodo-L-tyrosine for palladium-catalyzed cross-coupling. J Org Chem (2003) 0.85
Heme-copper/dioxygen adduct formation relevant to cytochrome c oxidase: spectroscopic characterization of [(6L)FeIII-(O2(2-))-CuII]+. J Biol Inorg Chem (2004) 0.85
Amine oxidative N-dealkylation via cupric hydroperoxide Cu-OOH homolytic cleavage followed by site-specific fenton chemistry. J Am Chem Soc (2015) 0.85
A molecular pinwheel multicopper(I) cluster, [(L(S-))6Cu(I)13(S2-)2]3+ with mu4-sulfido, mu3-thiolato and nitrogen ligands. Chem Commun (Camb) (2005) 0.85
One is lonely and three is a crowd: two coppers are for methane oxidation. Angew Chem Int Ed Engl (2010) 0.85
Reactions of a chromium(III)-superoxo complex and nitric oxide that lead to the formation of chromium(IV)-oxo and chromium(III)-nitrito complexes. J Am Chem Soc (2013) 0.85
Copper(I)/S(8) reversible reactions leading to an end-on bound dicopper(II) disulfide complex: nucleophilic reactivity and analogies to copper-dioxygen chemistry. J Am Chem Soc (2007) 0.85
Tuning of the copper-thioether bond in tetradentate N₃S(thioether) ligands; O-O bond reductive cleavage via a [Cu(II)₂(μ-1,2-peroxo)]²⁺/[Cu(III)₂(μ-oxo)₂]²⁺ equilibrium. J Am Chem Soc (2014) 0.85
Heme/copper assembly mediated nitrite and nitric oxide interconversion. J Am Chem Soc (2012) 0.84
Iodotyrosine deiodinase: a unique flavoprotein present in organisms of diverse phyla. Mol Biosyst (2014) 0.84
Observation of a Cu(II)(2) (μ-1,2-peroxo)/Cu(III)(2) (μ-oxo)(2) equilibrium and its implications for copper-dioxygen reactivity. Angew Chem Int Ed Engl (2014) 0.84
Geometric and electronic structure of the heme-peroxo-copper complex [(F8TPP)FeIII-(O22-)-CuII(TMPA)](ClO4). J Am Chem Soc (2005) 0.84
Expression of a soluble form of iodotyrosine deiodinase for active site characterization by engineering the native membrane protein from Mus musculus. Protein Sci (2012) 0.84
Dioxygen reactivity of a copper(I) complex with a N3S thioether chelate; peroxo-dicopper(II) formation including sulfur-ligation. Inorg Chem (2006) 0.84