Published in Chemistry on June 16, 2003
Ruthenium-catalyzed cycloaddition of alkynes and organic azides. J Am Chem Soc (2005) 2.35
Ruthenium-catalyzed azide-alkyne cycloaddition: scope and mechanism. J Am Chem Soc (2008) 1.76
Understanding d(0)-olefin metathesis catalysts: which metal, which ligands? J Am Chem Soc (2007) 1.48
Half-sandwich iridium complexes for homogeneous water-oxidation catalysis. J Am Chem Soc (2010) 1.48
C-H bond activation in transition metal species from a computational perspective. Chem Rev (2010) 1.40
d0 Re-based olefin metathesis catalysts, Re([triple bond]CR)(=CHR)(X)(Y): the key role of X and Y ligands for efficient active sites. J Am Chem Soc (2005) 1.25
Silver(I) complexes in coordination supramolecular system with bulky acridine-based ligands: syntheses, crystal structures, and theoretical investigations on C-H...Ag close interaction. Inorg Chem (2006) 1.23
Palladium-catalyzed amination of aryl mesylates. Angew Chem Int Ed Engl (2008) 1.23
Highly active and robust Cp* iridium complexes for catalytic water oxidation. J Am Chem Soc (2009) 1.21
A facile route to aryl boronates: room-temperature, copper-catalyzed borylation of aryl halides with alkoxy diboron reagents. Angew Chem Int Ed Engl (2009) 1.11
Boryl ligands and their roles in metal-catalysed borylation reactions. Chem Commun (Camb) (2009) 1.06
Easily accessible and highly tunable indolyl phosphine ligands for Suzuki-Miyaura coupling of aryl chlorides. Org Lett (2007) 1.05
A general palladium-catalyzed Suzuki-Miyaura coupling of aryl mesylates. Angew Chem Int Ed Engl (2008) 1.04
DFT studies on the mechanism of allylative dearomatization catalyzed by palladium. J Am Chem Soc (2006) 1.04
Manganese catalysts for C-H activation: an experimental/theoretical study identifies the stereoelectronic factor that controls the switch between hydroxylation and desaturation pathways. J Am Chem Soc (2010) 1.01
Suzuki-Miyaura coupling of aryl tosylates catalyzed by an array of indolyl phosphine-palladium catalysts. J Org Chem (2008) 0.98
A general palladium catalyst system for Suzuki-Miyaura coupling of potassium aryltrifluoroborates and aryl mesylates. J Org Chem (2010) 0.97
Shutting down secondary reaction pathways: the essential role of the pyrrolyl ligand in improving silica supported d(0)-ML4 alkene metathesis catalysts from DFT calculations. J Am Chem Soc (2010) 0.96
Beta-H transfer from the metallacyclobutane: a key step in the deactivation and byproduct formation for the well-defined silica-supported rhenium alkylidene alkene metathesis catalyst. J Am Chem Soc (2008) 0.95
Structural and dynamic properties of propane coordinated to TpRh(CNR) from a confrontation between theory and experiment. Proc Natl Acad Sci U S A (2007) 0.93
An anion-dependent switch in selectivity results from a change of C-H activation mechanism in the reaction of an imidazolium salt with IrH5(PPh3)2. J Am Chem Soc (2005) 0.92
A rational basis for the axial ligand effect in C-H oxidation by [MnO(porphyrin)(X)]+ (X = H2O, OH-, O2-) from a DFT study. Inorg Chem (2008) 0.91
Trans influence of boryl ligands and comparison with C, SI, and SN ligands. Inorg Chem (2005) 0.90
Theoretical aspects of palladium-catalysed carbon-carbon cross-coupling reactions. Chem Soc Rev (2009) 0.89
Rhodium catalysed dehydrogenative borylation of alkenes: vinylboronates via C-H activation. Dalton Trans (2007) 0.89
Reactions of monomeric [1,2,4-(Me3C)3C5H2]2CeH and CO with or without H2: an experimental and computational study. J Am Chem Soc (2007) 0.89
Phosphorescent platinum(II) complexes derived from multifunctional chromophores: synthesis, structures, photophysics, and electroluminescence. Inorg Chem (2006) 0.86
BF3-activated oxidation of alkanes by MnO4 -. J Am Chem Soc (2006) 0.86
Supramolecular interactions between fullerenes and porphyrins. J Am Chem Soc (2003) 0.85
Double geminal C-H activation and reversible alpha-elimination in 2-aminopyridine iridium(III) complexes: the role of hydrides and solvent in flattening the free energy surface. J Am Chem Soc (2004) 0.85
Linear-selective hydroarylation of unactivated terminal and internal olefins with trifluoromethyl-substituted arenes. J Am Chem Soc (2014) 0.84
Spectroscopic and structural characterization of the CyNHC adduct of B2pin2 in solution and in the solid state. J Org Chem (2011) 0.84
Structure and H(2)-Loss Energies of OsHX(H(2))(CO)L(2) Complexes (L = P(t-Bu)(2)Me, P(i-Pr)(3); X = Cl, I, H): Attempted Correlation of (1)J(H-D), T(1min), and DeltaG(). Inorg Chem (1996) 0.84
The rebound mechanism in catalytic C-H oxidation by MnO(tpp)Cl from DFT studies: electronic nature of the active species. Chem Commun (Camb) (2008) 0.84
Palladium-catalyzed three-component cascade cyclization reaction of bisallenes with propargylic carbonates and organoboronic acids: efficient construction of cis-fused bicyclo[4.3.0]nonenes. Angew Chem Int Ed Engl (2009) 0.84
DFT calculations of d0 M(NR)(CHtBu)(X)(Y) (M = Mo, W; R = CPh3, 2,6-iPr-C6H3; X and Y = CH2tBu, OtBu, OSi(OtBu)3) olefin metathesis catalysts: structural, spectroscopic and electronic properties. Dalton Trans (2006) 0.84
Regioselectivity in the Sonogashira coupling of 4,6-dichloro-2-pyrone. Org Biomol Chem (2006) 0.84
Preferential C-binding versus N-binding in imidazole depends on the metal fragment involved. Inorg Chem (2002) 0.83
Hydrogen-mediated metal-carbon to metal-boron bond conversion in metal-carboranyl complexes. J Am Chem Soc (2008) 0.83
C-F and C-H bond activation of fluorobenzenes and fluoropyridines at transition metal centers: how fluorine tips the scales. Acc Chem Res (2011) 0.83
Palladium-indolylphosphine-catalyzed Hiyama cross-coupling of aryl mesylates. Org Lett (2009) 0.83
Mechanism of silver- and copper-catalyzed decarboxylation reactions of aryl carboxylic acids. Dalton Trans (2011) 0.83
Dynamics of silica-supported catalysts determined by combining solid-state NMR spectroscopy and DFT calculations. J Am Chem Soc (2008) 0.83
Coupling reactions of CO2 with neat epoxides catalyzed by PPN salts to yield cyclic carbonates. J Org Chem (2005) 0.82
Iridium-catalyzed C-H borylation of pyridines. Org Biomol Chem (2014) 0.82
Organocatalytic asymmetric synthesis of 1,1-diarylethanes by transfer hydrogenation. J Am Chem Soc (2014) 0.82
Osmabenzenes from the reactions of HC[triple bond]CCH(OH)C[triple bond]CH with OsX2(PPh3)3 (X = Cl, Br). J Am Chem Soc (2004) 0.82
DFT studies on the mechanism of the diboration of aldehydes catalyzed by copper(I) boryl complexes. J Am Chem Soc (2008) 0.82
Synthesis, Structure, and Reactivity of Anionic sp(2) -sp(3) Diboron Compounds: Readily Accessible Boryl Nucleophiles. Chemistry (2015) 0.82
Copper-mediated reduction of CO2 with pinB-SiMe2Ph via CO2 insertion into a copper-silicon bond. J Am Chem Soc (2011) 0.81
Palladium-catalyzed borylation of aryl mesylates and tosylates and their applications in one-pot sequential Suzuki-Miyaura biaryl synthesis. Chemistry (2011) 0.81
Biscarbene-ruthenium complexes in catalysis: novel stereoselective synthesis of (1E,3E)-1,4-disubstituted-1,3-dienes via head-to-head coupling of terminal alkynes and addition of carboxylic acids. J Am Chem Soc (2003) 0.80
Iridium-catalyzed intermolecular azide-alkyne cycloaddition of internal thioalkynes under mild conditions. Angew Chem Int Ed Engl (2014) 0.80
Palladium-catalyzed cross-coupling of aryl halides using organotitanium nucleophiles. Angew Chem Int Ed Engl (2009) 0.80
Palladium-catalyzed direct arylation of heteroarenes with aryl mesylates. Chemistry (2010) 0.80
Carbon monoxide activation via O-bound CO using decamethylscandocinium-hydridoborate ion pairs. J Am Chem Soc (2012) 0.80
Bis(sulfonylimide)ruthenium(VI) porphyrins: X-ray crystal structure and mechanism of C-H bond amination by density functional theory calculations. Chemistry (2013) 0.79
Synthesis and Characterization of a Metallabenzyne This work was supported by the Hong Kong Research Grant Council and The Hong Kong University of Science and Technology. We thank Professor C. P. Lau for valuable discussions. Angew Chem Int Ed Engl (2001) 0.79
Synthesis and characterization of a metallapyridyne complex. Angew Chem Int Ed Engl (2012) 0.79
cine-Substitution reactions of metallabenzenes: an experimental and computational study. Chemistry (2013) 0.79
Validation of the M-C/H-C bond enthalpy relationship through application of density functional theory. J Am Chem Soc (2006) 0.79
Iridium-catalyzed hydrogenation of N-heterocyclic compounds under mild conditions by an outer-sphere pathway. J Am Chem Soc (2011) 0.79
Molecular recognition in Mn-catalyzed C-H oxidation. Reaction mechanism and origin of selectivity from a DFT perspective. Dalton Trans (2009) 0.79
Selective and efficient cycloisomerization of alkynols catalyzed by a new ruthenium complex with a tetradentate nitrogen-phosphorus mixed ligand. Chemistry (2010) 0.79
Enantioselective synthesis of β,γ-unsaturated α-fluoroesters catalyzed by N-heterocyclic carbenes. Angew Chem Int Ed Engl (2012) 0.79
C-H oxidation by hydroxo manganese(v) porphyrins: a DFT study. Chem Commun (Camb) (2009) 0.79
Imidazolium carboxylates as versatile and selective N-heterocyclic carbene transfer agents: synthesis, mechanism, and applications. J Am Chem Soc (2007) 0.79
Protonation and bromination of an osmabenzyne: reactions leading to the formation of new metallabenzynes. J Am Chem Soc (2003) 0.79
Generation and structural characterization of a gold(III) alkene complex. Angew Chem Int Ed Engl (2013) 0.78
Intermediate-valence tautomerism in decamethylytterbocene complexes of methyl-substituted bipyridines. J Am Chem Soc (2010) 0.78
Remarkably effective phosphanes simply with a PPh2 moiety: application to Pd-catalysed cross-coupling reactions for tetra-ortho-substituted biaryl syntheses. Chemistry (2010) 0.78
Palladium-catalyzed three-component reaction of 2,3-allenyl amines, isocyanates, and organic halides: a diversified assembly of imidazolidinones. Chemistry (2011) 0.78
Importance of palladium-carbon bond energies in direct arylation of polyfluorinated benzenes. Dalton Trans (2010) 0.78
Some structural and electronic properties of MX3 (M = Ln, Sc, Y, Ti+, Zr+, Hf+; X = H, Me, Hal, NH2) from DFT calculations. Faraday Discuss (2003) 0.78
Multifunctional iridium complexes based on carbazole modules as highly efficient electrophosphores. Angew Chem Int Ed Engl (2006) 0.78
Computational study on the reaction mechanism of hydrosilylation of carbonyls catalyzed by high-valent rhenium(V)-di-oxo complexes. J Org Chem (2006) 0.78
Conversion of metallabenzynes into carbene complexes. Angew Chem Int Ed Engl (2011) 0.78
A mild and efficient palladium-catalyzed cyanation of aryl mesylates in water or tBuOH/water. Angew Chem Int Ed Engl (2010) 0.78
A metallanaphthalyne complex from zinc reduction of a vinylcarbyne complex. Angew Chem Int Ed Engl (2007) 0.78
A mild and efficient palladium-catalyzed cyanation of aryl chlorides with K4[Fe(CN)6]. Org Lett (2011) 0.78
Key intermediates of iodine-mediated electrophilic cyclization: isolation and characterization in an osmabenzene system. Angew Chem Int Ed Engl (2013) 0.77
Coordination and insertion of alkenes and alkynes in Au(III) complexes: nature of the intermediates from a computational perspective. Dalton Trans (2016) 0.77
Electrophilic substitution reactions of metallabenzynes. J Am Chem Soc (2011) 0.77
Palladium-catalyzed decarboxylation of allenyl 3-oxoalkanoates: an efficient synthesis of 3,4-allenyl ketones. Org Lett (2011) 0.77
An efficient palladium-benzimidazolyl phosphine complex for the Suzuki-Miyaura coupling of aryl mesylates: facile ligand synthesis and metal complex characterization. Chem Commun (Camb) (2012) 0.77
Synthesis and structure of "16-electron" rhodium(III) catalysts fortransfer hydrogenation of a cyclic imine: mechanistic implications. Chem Commun (Camb) (2009) 0.77
Synthesis of heterobimetallic Ru-Mn complexes and the coupling reactions of epoxides with carbon dioxide catalyzed by these complexes. Chemistry (2006) 0.77
Computational structure-activity relationships in H2 storage: how placement of N atoms affects release temperatures in organic liquid storage materials. Chem Commun (Camb) (2007) 0.77
The lewis acidic ruthenium-complex-catalyzed addition of beta-diketones to alcohols and styrenes is in fact Brønsted acid catalyzed. Chemistry (2007) 0.77
Highly efficient tetradentate ruthenium catalyst for ester reduction: especially for hydrogenation of fatty acid esters. Org Lett (2015) 0.77
Energetics of C-H bond activation of fluorinated aromatic hydrocarbons using a [Tp'Rh(CNneopentyl)] complex. J Am Chem Soc (2009) 0.77
Palladium-catalyzed sonogashira coupling of aryl mesylates and tosylates. Chemistry (2010) 0.77
Ligand substitution in cubic clusters: surprising isolation of the cocrystallization products of Cu8(mu8-Se)[S2P(OEt)2]6 and Cu6[S2P(OEt)2]6. Inorg Chem (2003) 0.77
Exceptional sensitivity of metal-aryl bond energies to ortho-fluorine substituents: influence of the metal, the coordination sphere, and the spectator ligands on M-C/H-C bond energy correlations. J Am Chem Soc (2009) 0.77