| Rank |
Title |
Journal |
Year |
PubWeight™‹?› |
|
1
|
Ligand-directed molecular architectures: self-assembly of two-dimensional rectangular metallacycles and three-dimensional trigonal or tetragonal prisms.
|
J Am Chem Soc
|
2003
|
2.95
|
|
2
|
Self-assembly of trigonal-prismatic metallocages encapsulating BF4- or CuI32- as anionic guests: structures and mechanism of formation.
|
Angew Chem Int Ed Engl
|
2002
|
0.96
|
|
3
|
Isovalent and mixed-valent diruthenium complexes [(acac)2RuII (-bpytz)RuII(acac)2] and [(acac)2RuII(-bpytz)RuIII(acac)2](ClO4) (acac = acetylacetonate and bpytz = 3,6-bis(3,5-dimethylpyrazolyl)-1,2,4,5-tetrazine): synthesis, spectroelectrochemical, and epr investigation .
|
Inorg Chem
|
2004
|
0.91
|
|
4
|
Filling gaps in the series of noninnocent hetero-1,3-diene chelate ligands: ruthenium complexes of redox-active α-azocarbonyl and α-azothiocarbonyl ligands RNNC(R')E, E = O or S.
|
Inorg Chem
|
2012
|
0.89
|
|
5
|
Electronic structure and catalytic aspects of [Ru(tpm)(bqdi)(Cl/H2O)]n, tpm = tris(1-pyrazolyl)methane and bqdi = o-benzoquinonediimine.
|
Dalton Trans
|
2013
|
0.84
|
|
6
|
Metal-induced tautomerization of p- to o-quinone compounds: experimental evidence from CuI and ReI complexes of azophenine and DFT studies.
|
Chemistry
|
2004
|
0.84
|
|
7
|
Acidic iridium hydrides: implications for aerobic and Oppenauer oxidation of alcohols.
|
Chem Commun (Camb)
|
2006
|
0.82
|
|
8
|
Self-assembly of heterobimetallic neutral macrocycles incorporating ferrocene spacer groups: spectroelectrochemical analysis of the double two-electron oxidation of a molecular rectangle.
|
Inorg Chem
|
2005
|
0.81
|
|
9
|
Tetranuclear complexes of [Fe(CO)2(C5H5)]+ with TCNX ligands (TCNX=TCNE, TCNQ, TCNB): intramolecular electron transfer alternatives in compounds (mu4-TCNX)[MLn]4.
|
Inorg Chem
|
2007
|
0.81
|
|
10
|
The metal-NO interaction in the redox systems [Cl5Os(NO)]n-, n = 1-3, and cis-[(bpy)2ClOs(NO)]2+/+: calculations, structural, electrochemical, and spectroscopic results.
|
Inorg Chem
|
2006
|
0.80
|
|
11
|
Enhanced hydroxyl radical production by dihydroxybenzene-driven Fenton reactions: implications for wood biodegradation.
|
J Biol Inorg Chem
|
2007
|
0.80
|
|
12
|
Long-range electronic coupling in various oxidation states of a C4-linked tris(beta-diketonato)ruthenium dimer.
|
Angew Chem Int Ed Engl
|
2003
|
0.79
|
|
13
|
Proof of innocence for the quintessential noninnocent ligand TCNQ in its tetranuclear complex with four [fac-Re(CO)3(bpy)]+ groups: unusually different reactivity of the TCNX ligands (TCNX = TCNE, TCNQ, TCNB).
|
Inorg Chem
|
2003
|
0.79
|
|
14
|
Isomeric ruthenium terpyridine complexes [Ru(trpy)(L)Cl]n+ containing the unsymmetrically bidentate acceptor L=3-amino-6-(3,5-dimethylpyrazol-1-yl)-1,2,4,5-tetrazine. Synthesis, structures, electrochemistry, spectroscopy and DFT calculations.
|
Dalton Trans
|
2005
|
0.79
|
|
15
|
[Ga9(CMe3)9]*--a persistent cluster radical anion, boron-analogous chemistry with the heavier homologue gallium.
|
Angew Chem Int Ed Engl
|
2003
|
0.79
|
|
16
|
Isolation of neutral mononuclear copper complexes stabilized by two cyclic (alkyl)(amino)carbenes.
|
J Am Chem Soc
|
2014
|
0.79
|
|
17
|
Molecule-bridged mixed-valent intermediates involving the Ru I oxidation state.
|
J Am Chem Soc
|
2004
|
0.78
|
|
18
|
Oxidative perhydroxylation of [closo-B12H12]2- to the stable inorganic cluster redox system [B12(OH)12](2-/*-): experiment and theory.
|
Chemistry
|
2010
|
0.78
|
|
19
|
New ruthenium nitrosyl complexes with tris(1-pyrazolyl)methane (tpm) and 2,2'-bipyridine (bpy) coligands. Structure, spectroscopy, and electrophilic and nucleophilic reactivities of bound nitrosyl.
|
Inorg Chem
|
2006
|
0.78
|
|
20
|
Heterohexanuclear (Cu3Fe3) complexes of substituted hexaazatrinaphthylene (HATN) ligands: twofold BF4(-) association in the solid and stepwise oxidation (3e) or reduction (2e) to spectroelectrochemically characterized species.
|
Chemistry
|
2009
|
0.78
|
|
21
|
Intramolecular valence and spin interaction in meso and rac diastereomers of a p-quinonoid-bridged diruthenium complex.
|
J Am Chem Soc
|
2008
|
0.78
|
|
22
|
(α-Diimine)tricarbonylhalorhenium complexes: the oxidation side.
|
Dalton Trans
|
2011
|
0.78
|
|
23
|
Stabilization of a two-coordinate mononuclear cobalt(0) compound.
|
Chemistry
|
2014
|
0.78
|
|
24
|
Variable Reduction Sequences for Axial (L) and Chelate Ligands (NwedgeN) in Rhenium(I) Complexes [(NwedgeN)Re(CO)(3)(L)](n)().
|
Inorg Chem
|
1998
|
0.77
|
|
25
|
Complex reduction chemistry of (abpy)PtCl2, abpy = 2,2'-azobispyridine: formation of cyclic [(micro,eta2:eta1-abpy)PtCl]2(2+) with a new coordination mode for abpy and a near-infrared ligand-to-ligand intervalence charge transfer absorption of the one-electron reduced state.
|
Inorg Chem
|
2004
|
0.77
|
|
26
|
The semiquinone-ruthenium combination as a remarkably invariant feature in the redox and substitution series [Ru(Q)(n)(acac)(3-n)](m), n = 1-3; m = (-2), -1, 0, +1, (+2); Q = 4,6-Di-tert-butyl-N-phenyl-o-iminobenzoquinone.
|
Inorg Chem
|
2009
|
0.77
|
|
27
|
Redox-rich spin-spin-coupled semiquinoneruthenium dimers with intense near-IR absorption.
|
Inorg Chem
|
2011
|
0.77
|
|
28
|
An odd-electron complex [Ru(k)(NO(m))(Q(n))(terpy)]2+ with two prototypical non-innocent ligands.
|
Angew Chem Int Ed Engl
|
2009
|
0.77
|
|
29
|
Separating innocence and non-innocence of ligands and metals in complexes [(L)Ru(acac)2](n) (n = -1, 0, +1; L = o-iminoquinone or o-iminothioquinone).
|
Inorg Chem
|
2003
|
0.77
|
|
30
|
3,6-bis(2'-pyridyl)pyridazine (L) and its deprotonated form (L - H+)- as ligands for {(acac)2Ru(n+)} or {(bpy)2Ru(m+)}: investigation of mixed valency in [{(acac)2Ru}2(mu-L - H+)]0 and [{(bpy)2Ru}2(mu-L - H+)]4+ by spectroelectrochemistry and EPR.
|
Dalton Trans
|
2005
|
0.77
|
|
31
|
Bis(acetylacetonato)ruthenium complexes of noninnocent 1,2-dioxolene ligands: qualitatively different bonding in relation to monoimino and diimino analogues.
|
Chemistry
|
2011
|
0.76
|
|
32
|
Oxidation state analysis of a four-component redox series [Os(pap)2(Q)]n involving two different non-innocent ligands on a redox-active transition metal.
|
Inorg Chem
|
2011
|
0.76
|
|
33
|
Mixed valence aspects of diruthenium complexes [((L)ClRu)2(mu-tppz)]n+ incorporating 2-(2-pyridyl)azoles (L) as ancillary functions and 2,3,5,6-tetrakis(2-pyridyl)pyrazine (Tppz) as bis-tridentate bridging ligand.
|
Inorg Chem
|
2004
|
0.76
|
|
34
|
All-trans-[ClRu(II)(py)4(NC)Ru(II)(py)4(CN)Ru(II)(py)4(NO)](PF6)4: a redox-active 2-donor/1-acceptor system based on the electrophilic {RuNO}6 motif.
|
Inorg Chem
|
2009
|
0.76
|
|
35
|
Spectroelectrochemical evidence for the nitrosyl redox siblings NO+, NO*, and NO- coordinated to a strongly electron-accepting Fe(II) porphyrin: DFT calculations suggest the presence of high-spin states after reduction of the Fe(II)-NO- complex.
|
Chemistry
|
2011
|
0.76
|
|
36
|
Three-spin system with a twist: a bis(semiquinonato)copper complex with a nonplanar configuration at the copper(II) center.
|
Angew Chem Int Ed Engl
|
2005
|
0.76
|
|
37
|
Stabilization of a cobalt-cobalt bond by two cyclic alkyl amino carbenes.
|
J Am Chem Soc
|
2014
|
0.76
|
|
38
|
Synthesis, structure, and electronic properties of RuN6 dinuclear Ru-Hbpp complexes.
|
Inorg Chem
|
2011
|
0.76
|
|
39
|
Pseudo-base formation in the attempted synthesis of a conjugatively coupled bis(nitrosylruthenium) complex and spectroelectrochemistry of bipyrimidine-bridged dinuclear Ru(terpy)X precursor compounds (X = Cl, NO2).
|
Dalton Trans
|
2007
|
0.75
|
|
40
|
Theoretical and experimental evidence for a new kind of spin-coupled singlet species: isomeric mixed-valent complexes bridged by a radical anion ligand.
|
Angew Chem Int Ed Engl
|
2005
|
0.75
|
|
41
|
Sensitivity of a strained C-C single bond to charge transfer: redox activity in mononuclear and dinuclear ruthenium complexes of bis(arylimino)acenaphthene (BIAN) ligands.
|
Inorg Chem
|
2014
|
0.75
|
|
42
|
Tuning of the spin distribution between ligand- and metal-based spin: electron paramagnetic resonance of mixed-ligand molybdenum tris(dithiolene) complex anions.
|
Inorg Chem
|
2011
|
0.75
|
|
43
|
Metal vs ligand reduction in complexes of dipyrido[3,2-a:2',3'-c]phenazine and related ligands with [(C5Me5)ClM]+ (M = Rh or Ir): evidence for potential rather than orbital control in the reductive cleavage of the metal-chloride bond.
|
Inorg Chem
|
2004
|
0.75
|
|
44
|
Strong metal-metal coupling in mixed-valent intermediates [Cl(L)Ru(μ-tppz)Ru(L)Cl]+, L = β-diketonato ligands, tppz = 2,3,5,6-tetrakis(2-pyridyl)pyrazine.
|
Dalton Trans
|
2012
|
0.75
|
|
45
|
Multifrequency EPR study and density functional g-tensor calculations of persistent organorhenium radical complexes.
|
J Am Chem Soc
|
2002
|
0.75
|
|
46
|
Four-center oxidation state combinations and near-infrared absorption in [Ru(pap)(Q)2]n (Q = 3,5-di-tert-butyl-N-aryl-1,2-benzoquinonemonoimine, pap = 2-phenylazopyridine).
|
Chemistry
|
2013
|
0.75
|
|
47
|
C4 cumulene and the corresponding air-stable radical cation and dication.
|
Angew Chem Int Ed Engl
|
2014
|
0.75
|
|
48
|
Probing mixed valence in a new tppz-bridged diruthenium(III,II) complex {(mu-tppz)[Ru(bik)Cl]2}3+ (tppz=2,3,5,6-tetrakis(2-pyridyl)pyrazine, bik=2,2'-bis(1-methylimidazolyl)ketone): EPR silence, intervalence absorption, and nu(CO) line broadening.
|
Inorg Chem
|
2007
|
0.75
|
|
49
|
Synthesis and characterization of Lewis base stabilized mono- and di-organo aluminum radicals.
|
Chem Commun (Camb)
|
2017
|
0.75
|
|
50
|
Replacement of 2,2'-bipyridine by 1,4-diazabutadiene acceptor ligands: why the bathochromic shift for [(N empty set N)IrCl(C5Me5)]+ complexes but the hypsochromic shift for (N empty set N)Ir(C5Me5)?
|
Inorg Chem
|
2003
|
0.75
|
|
51
|
Variable coordination of redox-active TCNB in discrete and polymeric ferrocenylcopper(I) complexes: structures and spectroelectrochemical behaviour.
|
Dalton Trans
|
2013
|
0.75
|
|
52
|
Correlated coordination and redox activity of a hemilabile noninnocent ligand in nickel complexes.
|
Chemistry
|
2014
|
0.75
|
|
53
|
Singlet diradical complexes of ruthenium and osmium: geometrical and electronic structures and their unexpected changes on oxidation.
|
Inorg Chem
|
2008
|
0.75
|
|
54
|
9-Oxidophenalenone: a noninnocent β-diketonate ligand?
|
Inorg Chem
|
2012
|
0.75
|
|
55
|
Variable noninnocence of substituted azobis(phenylcyanamido)diruthenium complexes.
|
Inorg Chem
|
2015
|
0.75
|
|
56
|
1,4,7,10-tetraazacyclododecane metal complexes as potent promoters of phosphodiester hydrolysis under physiological conditions.
|
Inorg Chem
|
2008
|
0.75
|
|
57
|
1H NMR, electron paramagnetic resonance, and density functional theory study of dinuclear pentaammineruthenium dicyanamidobenzene complexes.
|
Inorg Chem
|
2012
|
0.75
|
|
58
|
Metal-induced reductive ring opening of 1,2,4,5-tetrazines: three resulting coordination alternatives, including the new non-innocent 1,2-diiminohydrazido(2-) bridging ligand system.
|
Inorg Chem
|
2006
|
0.75
|
|
59
|
Formation of trichlorosilyl-substituted carbon-centered stable radicals through the use of π-accepting carbenes.
|
Angew Chem Int Ed Engl
|
2013
|
0.75
|
|
60
|
Sensitivity of the valence structure in diruthenium complexes as a function of terminal and bridging ligands.
|
Inorg Chem
|
2014
|
0.75
|
|
61
|
Reversibly reducible cis-dichloroplatinum(II) and cis-dichloropalladium(II) complexes of bis(1-methylimidazol-2-yl)glyoxal.
|
Inorg Chem
|
2007
|
0.75
|
|
62
|
Correspondence of Ru(III) Ru(II) and Ru(IV) Ru(III) mixed valent states in a small dinuclear complex.
|
Chemistry
|
2012
|
0.75
|
|
63
|
Varying electronic structural forms of ruthenium complexes of non-innocent 9,10-phenanthrenequinonoid ligands.
|
Dalton Trans
|
2013
|
0.75
|
|
64
|
Asymmetrical diruthenium complex bridged by a redox-active ligand.
|
Inorg Chem
|
2012
|
0.75
|
|
65
|
[(mu-L)[RuII(acac)2]2]n, n= 2+, +, 0, -, 2-, with L = 3,3',4,4'-tetraimino-3,3',4,4'-tetrahydrobiphenyl. EPR-supported assignment of NIR absorptions for the paramagnetic intermediates.
|
Dalton Trans
|
2004
|
0.75
|
|
66
|
Selenol nitrosation and Se-nitrososelenol homolysis: a reaction path with possible biochemical implications.
|
Angew Chem Int Ed Engl
|
2004
|
0.75
|
|
67
|
Mixed-valent metals bridged by a radical ligand: fact or fiction based on structure-oxidation state correlations.
|
J Am Chem Soc
|
2008
|
0.75
|
|
68
|
Reduction and protonation of Mo(IV) imido complexes with depe coligands: generation and reactivity of a S = 1/2 Mo(III) alkylnitrene intermediate.
|
Inorg Chem
|
2013
|
0.75
|
|
69
|
2,5-Dioxido-1,4-benzoquinonediimine (H2L2-), a hydrogen-bonding noninnocent bridging ligand related to aminated topaquinone: different oxidation state distributions in complexes [{(bpy)2Ru}2(mu-H2L)]n (n=0,+,2+,3+,4+) and [{(acac)2Ru}2(mu-H2L)]m (m=2-,-,0,+,2+).
|
Chemistry
|
2005
|
0.75
|
|
70
|
Complex series [Ru(tpy)(dpk)(X)]n+ (tpy = 2,2':6',2''-terpyridine; dpk = 2,2'-dipyridyl ketone; X = Cl-, CH3CN, NO2(-), NO+, NO*, NO-): substitution and electron transfer, structure, and spectroscopy.
|
Inorg Chem
|
2005
|
0.75
|
|
71
|
Reduced and excited states of the intermediates (alpha-diimine)(C5R5)Rh in hydride transfer catalysis schemes: EPR and resonance Raman spectroscopy, and comparative DFT calculations of Co, Rh and Ir analogues.
|
Dalton Trans
|
2004
|
0.75
|
|
72
|
Synthesis and characterisation of the persistent radical [BCl2(bipy)]*.
|
Chem Commun (Camb)
|
2010
|
0.75
|
|
73
|
Structural basis for unusually long wavelength charge transfer transitions in complexes [MCl(ECH(2)CH(2)NMe(2))(PR(3))] (E = Te, Se; M = Pt, Pd): experimental results and TD-DFT calculations.
|
Inorg Chem
|
2002
|
0.75
|
|
74
|
A Route to Base Coordinate Silicon Difluoride and the Silicon Trifluoride Radical.
|
Chemistry
|
2017
|
0.75
|
|
75
|
What a difference ancillary thienyl makes: unexpected additional stabilization of the diruthenium(III,II) but not the diosmium(III,II) mixed-valent state in tetrazine ligand-bridged complexes.
|
Inorg Chem
|
2003
|
0.75
|
|
76
|
Establishing the chelating alpha-azocarbonyl function in pi-acceptor ligands.
|
Angew Chem Int Ed Engl
|
2008
|
0.75
|
|
77
|
2,2'-Dipyridylketone (dpk) as ancillary acceptor and reporter ligand in complexes [(dpk)(Cl)Ru(mu-tppz)Ru(Cl)(dpk)]n+ where tppz = 2,3,5,6-tetrakis(2-pyridyl)pyrazine.
|
Inorg Chem
|
2006
|
0.75
|
|
78
|
High-frequency EPR study of reduced diruthenium and dirhenium polypyridine complexes based on the 1,2,4,5-tetrazine radical bridge.
|
Dalton Trans
|
2004
|
0.75
|
|
79
|
Reductive approach to mixed valency (n = 1-) in the pyrazine ligand-bridged [(acac)2Ru(μ-L(2-))Ru(acac)2](n) (L(2-) = 2,5-pyrazine-dicarboxylate) through experiment and theory.
|
Inorg Chem
|
2011
|
0.75
|
|
80
|
Experimental and DFT evidence for the fractional non-innocence of a β-diketonate ligand.
|
Chemistry
|
2012
|
0.75
|
|
81
|
A diruthenium complex of a "Nindigo" ligand.
|
Inorg Chem
|
2013
|
0.75
|
|
82
|
Multinuclear NMR study of some organoplatinum complexes containing multifunctional azines as chelating ligands.
|
Magn Reson Chem
|
2004
|
0.75
|
|
83
|
A structurally characterised redox pair involving an indigo radical: indigo based redox activity in complexes with one or two [Ru(bpy)2] fragments.
|
Dalton Trans
|
2017
|
0.75
|
|
84
|
Conjugation length dependent ground and excited state electronic behavior in oligothienyl ru complexes.
|
Inorg Chem
|
2006
|
0.75
|
|
85
|
The triruthenium complex [[(acac)2Ru(II)]3(L)] containing a conjugated diquinoxaline[2,3-a:2',3'-c]phenazine (L) bridge and acetylacetonate (acac) as ancillary ligands. Synthesis, spectroelectrochemical and EPR investigation.
|
Dalton Trans
|
2004
|
0.75
|
|
86
|
Tellurium(0) as a ligand: synthesis and characterization of 2-pyridyltellurolates of platinum(II) and structures of [Pt{2-Te-3-(R)C5H3N}2Te(PR'3)] (R = H or Me).
|
Inorg Chem
|
2010
|
0.75
|
|
87
|
Synthesis and characterization of a triphenyl-substituted radical and an unprecedented formation of a carbene-functionalized quinodimethane.
|
Chemistry
|
2014
|
0.75
|
|
88
|
Charged, but found "not guilty": innocence of the suspect bridging ligands [RO(O)CNNC(O)OR]2- = L2- in [(acac)2Ru(μ-L)Ru(acac)2]n, n = +,0,-,2-.
|
Inorg Chem
|
2012
|
0.75
|
|
89
|
Stabilizing the elusive ortho-quinone/copper(I) oxidation state combination through pi/pi interaction in an isolated complex.
|
J Am Chem Soc
|
2008
|
0.75
|
|
90
|
2,3-Bis(1-methylimidazol-2-yl)quinoxaline (bmiq), a new ligand with decoupled electron transfer and metal coordination sites: the very different redox behaviour of isoelectronic complexes with [PtCl2] and [AuCl2]+.
|
Dalton Trans
|
2011
|
0.75
|
|
91
|
Towards new organometallic wires: tetraruthenium complexes bridged by phenylenevinylene and vinylpyridine ligands.
|
Chemistry
|
2007
|
0.75
|
|
92
|
Low-valent cobalt complexes with three different pi acceptor ligands: experimental and DFT studies of the reduced and the low-lying excited states of (R-DAB)Co(NO)(CO), R-DAB = substituted 1,4-diaza-1,4-butadiene.
|
Inorg Chem
|
2003
|
0.75
|
|
93
|
Formation, reactivity, and photorelease of metal bound nitrosyl in [Ru(trpy)(L)(NO)](n+) (trpy = 2,2':6',2''-terpyridine, L = 2-phenylimidazo[4,5-f]1,10-phenanthroline).
|
Inorg Chem
|
2008
|
0.75
|
|
94
|
A five-center redox system: molecular coupling of two noninnocent imino-o-benzoquinonato-ruthenium functions through a pi acceptor bridge.
|
J Am Chem Soc
|
2009
|
0.75
|
|
95
|
Valence structures of the diastereomeric complexes meso- and rac-[Ru(2)(acac)(4)(mu-Q)](n) (n = 2-, 1-, 0, 1+, 2+) with the multiple quinonoid bridging ligand Q = 1,2,4,5-tetraimino-3,6-diketocyclohexane.
|
Dalton Trans
|
2009
|
0.75
|
|
96
|
Spectroelectrochemistry and DFT analysis of a new {RuNO}n redox system with multifrequency EPR suggesting conformational isomerism in the {RuNO}7 state.
|
Inorg Chem
|
2007
|
0.75
|
|
97
|
Redox properties of ruthenium nitrosyl porphyrin complexes with different axial ligation: structural, spectroelectrochemical (IR, UV-visible, and EPR), and theoretical studies.
|
Inorg Chem
|
2008
|
0.75
|
|
98
|
Discovering more non-innocence: triazenido versus triazenyl radical ligand function, and a comment on [NO2]n as a "suspect" ligand.
|
Angew Chem Int Ed Engl
|
2013
|
0.75
|
|
99
|
Uncommon cis configuration of a metal-metal bridging noninnocent Nindigo ligand.
|
Inorg Chem
|
2014
|
0.75
|
|
100
|
A new coordination mode of the photometric reagent glyoxalbis(2-hydroxyanil) (H2gbha): bis-bidentate bridging by gbha2- in the redox series [(mu-gbha)[Ru(acac)2]2]n (n = -2, -1, 0, +1, +2), including a radical-bridged diruthenium(III) and a Ru(III)/Ru(IV) intermediate.
|
Inorg Chem
|
2005
|
0.75
|
|
101
|
Ancillary ligand determination of the spin location in both oxidised and reduced forms of diruthenium complexes bridged by bis-bidentate 1,4-bis(2-phenolato)-1,4-diazabutadiene.
|
Dalton Trans
|
2007
|
0.75
|
|
102
|
Valence-state alternatives in diastereoisomeric complexes [(acac)2Ru(mu-QL)Ru(acac)2]n (QL2- = 1,4-dioxido-9,10-anthraquinone,n = +2, +1, 0, -1, -2).
|
Inorg Chem
|
2008
|
0.75
|
|
103
|
Sensitive oxidation state ambivalence in unsymmetrical three-center (M/Q/M) systems [(acac)2 Ru(mu-Q)Ru(acac)2](n), Q = 1,10-phenanthroline-5,6-dione or 1,10-phenanthroline-5,6-diimine (n = +, 0, -, 2-).
|
Inorg Chem
|
2005
|
0.75
|
|
104
|
The intricate paramagnetic state of [Os(Q)2(bpy)]+, Q = 4,6-di-tert-butyl-o-iminobenzoquinone.
|
Dalton Trans
|
2012
|
0.75
|
|
105
|
Ruthenium complexes with vinyl, styryl, and vinylpyrenyl ligands: a case of non-innocence in organometallic chemistry.
|
J Am Chem Soc
|
2007
|
0.75
|
|
106
|
Controlling metal-ligand-metal oxidation state combinations by ancillary ligand (L) variation in the redox systems [L2Ru(mu-boptz)RuL2]n, boptz = 3,6-bis(2-oxidophenyl)-1,2,4,5-tetrazine, and L = acetylacetonate, 2,2'-bipyridine, or 2-phenylazopyridine.
|
Chemistry
|
2005
|
0.75
|
|
107
|
A series of metal complexes with the non-innocent N,N'-bis(pentafluorophenyl)-o-phenylenediamido ligand: twisted geometry for tuning the electronic structure.
|
Dalton Trans
|
2008
|
0.75
|
|
108
|
Solar cell sensitizer models [Ru(bpy-R)2(NCS)2] probed by spectroelectrochemistry.
|
Inorg Chem
|
2012
|
0.75
|
|
109
|
Valence-state analysis through spectroelectrochemistry in a series of quinonoid-bridged diruthenium complexes [(acac)(2)Ru(mu-L)Ru(acac)(2)](n) (n=+2, +1, 0, -1, -2).
|
Chemistry
|
2008
|
0.75
|
|
110
|
Geometrical and electronic structures of dinuclear complex ions {(mu-bpym)[Cu(EAr3)2]2}2+ with intramolecular "organic sandwich" formation (E = P or As; Ar = Aryl; bpym = 2,2'-bipyrimidine).
|
Inorg Chem
|
2005
|
0.75
|
|
111
|
Formation of racemate and mesocate complexes from an achiral tripodal ligand containing three benzimidazole groups.
|
Inorg Chem
|
2003
|
0.75
|
|
112
|
Effect of metal exchange (Os vs. Ru) and co-ligand variation (Cl(-)vs. acac(-)) on the oxidation state distribution in complexes of an o-phenylenediamido(2(-))/o-quinonediimine redox system.
|
Dalton Trans
|
2009
|
0.75
|
|
113
|
Electronic structure alternatives in nitrosylruthenium complexes.
|
Dalton Trans
|
2010
|
0.75
|
|
114
|
Bidirectional non-innocence of the β-diketonato ligand 9-oxidophenalenone (L-) in [Ru([9]aneS3)(L)(dmso)]n, [9]aneS3 = 1,4,7-trithiacyclononane.
|
Dalton Trans
|
2014
|
0.75
|
|
115
|
Application of a structure/oxidation-state correlation to complexes of bridging azo ligands.
|
Chemistry
|
2012
|
0.75
|
|
116
|
Establishing the NO oxidation state in complexes [Cl(5)(NO)M](n-), M = Ru or Ir, through experiments and DFT calculations.
|
Dalton Trans
|
2004
|
0.75
|
|
117
|
The redox series [M(bpy)2(q)]n+, M = Ru or Os, Q = 3,5-di-tert-butyl-n-phenyl-1,2-benzoquinonemonoimine. Isolation and a complete X and W band EPR study of the semiquinone states (n = 1).
|
Inorg Chem
|
2005
|
0.75
|
|
118
|
Identifying intermediates of sequential electron and hydrogen loss from a dicarbonylcobalt hydride complex.
|
Angew Chem Int Ed Engl
|
2013
|
0.75
|
|
119
|
Non-innocent behaviour of ancillary and bridging ligands in homovalent and mixed-valent ruthenium complexes [A2Ru(mu-L)RuA2]n, A = 2,4-pentanedionato or 2-phenylazopyridine, L(2-) = 2,5-bis(2-oxidophenyl)pyrazine.
|
Dalton Trans
|
2007
|
0.75
|
|
120
|
UV-vis-NIR and EPR characterisation of the redox series [MQ(3)](2+,+,0,-,2-), M = Ru or Os, and Q = o-quinone derivative.
|
Dalton Trans
|
2012
|
0.75
|
|
121
|
Singlet diradical complexes of chromium, molybdenum, and tungsten with azo anion radical ligands from M(CO)6 precursors.
|
Inorg Chem
|
2007
|
0.75
|
|
122
|
Non-innocence of 1,4-dicyanamidobenzene bridging ligands in dinuclear ruthenium complexes.
|
Inorg Chem
|
2013
|
0.75
|
|
123
|
Carboxylate tolerance of the redox-active platform [Ru(mu-tppz)Ru](n), where tppz = 2,3,5,6-tetrakis(2-pyridyl)pyrazine, in the electron-transfer series [(L)ClRu(mu-tppz)RuCl(L)](n), n = 2+, +, 0, -, 2-, with 2-picolinato, quinaldato, and 8-quinolinecarboxylato ligands (L(-)).
|
Inorg Chem
|
2010
|
0.75
|
|
124
|
A tetranuclear organorhenium(i) complex of the 2,3,5,6-tetrafluoro-7,7,8,8-tetracyano-p-quinodimethane radical anion, TCNQF4 (-).
|
Dalton Trans
|
2008
|
0.75
|