| Rank |
Title |
Journal |
Year |
PubWeight™‹?› |
|
1
|
Evaluating cis-2,6-dimethylpiperidide (cis-DMP) as a base component in lithium-mediated zincation chemistry.
|
Chemistry
|
2013
|
0.95
|
|
2
|
Synthesis of the mixed lithium-potassium-(bis)magnesium N-metallated/N, C-dimetallated amide [Li2K2Mg4[But(Me3Si)N]4[But[Me2(H2C)Si]N]4]: an inverse crown molecule with an atomless cavity.
|
Chem Commun (Camb)
|
2003
|
0.95
|
|
3
|
Selective meta-deprotonation of toluene by using alkali-metal-mediated magnesiation.
|
Angew Chem Int Ed Engl
|
2005
|
0.88
|
|
4
|
Unmasking representative structures of TMP-active Hauser and turbo-Hauser bases.
|
Angew Chem Int Ed Engl
|
2008
|
0.87
|
|
5
|
A structural and computational study of synthetically important alkali-metal/tetramethylpiperidide (TMP) amine solvates.
|
Chemistry
|
2008
|
0.85
|
|
6
|
Transamination chemistry of sodium TMP-zincate: synthesis and crystal structure of a chiral amidozincate.
|
Chem Commun (Camb)
|
2007
|
0.84
|
|
7
|
Alkali-metal-mediated zincation of polycyclic aromatic hydrocarbons: synthesis and structures of mono- and dizincated naphthalenes.
|
Angew Chem Int Ed Engl
|
2006
|
0.82
|
|
8
|
Reactions of (-)-sparteine with alkali metal HMDS complexes: conventional meets the unconventional.
|
Chem Commun (Camb)
|
2009
|
0.81
|
|
9
|
A homologous series of regioselectively tetradeprotonated group 8 metallocenes: new inverse crown ring compounds synthesized via a mixed sodium-magnesium tris(diisopropylamide) synergic base.
|
J Am Chem Soc
|
2004
|
0.81
|
|
10
|
Structurally defined reactions of sodium TMP-zincate with nitrile compounds: synthesis of a salt-like sodium sodiumdizincate and other unexpected ion-pair products.
|
Angew Chem Int Ed Engl
|
2008
|
0.80
|
|
11
|
Alkoxide binding in inverse crown chemistry: rational synthesis of a series of composite alkali metal-magnesium-alkoxide-diisopropylamides.
|
Chem Commun (Camb)
|
2002
|
0.79
|
|
12
|
Structural elucidation of homometallic anthracenolates synthesised via deprotonative metallation of anthrone.
|
Dalton Trans
|
2012
|
0.79
|
|
13
|
Hydride encapsulation in s-block metal inverse crown chemistry.
|
Chem Commun (Camb)
|
2002
|
0.79
|
|
14
|
Synergic synthesis of benzannulated zincabicyclic complexes, alpha-zincated N ylides, through sodium-TMEDA-mediated zincation of a haloarene.
|
Angew Chem Int Ed Engl
|
2009
|
0.78
|
|
15
|
Organometallic polymers assembled from cation-pi interactions: use of ferrocene as a ditopic linker within the homologous series [{(Me3Si)2NM}2.(Cp2Fe)]infinity (M=Na, K, Rb, Cs; Cp=cyclopentadienyl).
|
Chemistry
|
2007
|
0.78
|
|
16
|
Stoichiometrically-controlled reactivity and supramolecular storage of butylmagnesiate anions.
|
Chem Commun (Camb)
|
2005
|
0.77
|
|
17
|
cis-2,6-Dimethylpiperidide: a structural mimic for TMP (2,2,6,6-tetramethylpiperidide) or DA (diisopropylamide)?
|
Dalton Trans
|
2009
|
0.77
|
|
18
|
Mixed lithium amide-lithium halide compounds: unusual halide-deficient amido metal anionic crowns.
|
Angew Chem Int Ed Engl
|
2011
|
0.76
|
|
19
|
Synthesis and structural chemistry of alkali metal tris(HMDS) magnesiates containing chiral diamine donor ligands.
|
Dalton Trans
|
2011
|
0.76
|
|
20
|
Isolation and characterisation of the mixed-metal alkyl amide [(TMEDA)Na(mu-Bu)(mu-TMP)Mg(TMP)], an unexpected chelate-trapped intermediate in the formation of inverse crowns.
|
Chem Commun (Camb)
|
2004
|
0.76
|
|
21
|
catena-Poly[sodium-μ2-(N,N,N',N'-tetra-methyl-ethane-1,2-diamine)-κ(2) N:N'-sodium-bis-[μ2-bis-(trimethyl-sil-yl)aza-nido-κ(2) N:N]].
|
Acta Crystallogr Sect E Struct Rep Online
|
2012
|
0.75
|
|
22
|
Meta-metallation of N,N-dimethylaniline: Contrasting direct sodium-mediated zincation with indirect sodiation-dialkylzinc co-complexation.
|
Beilstein J Org Chem
|
2011
|
0.75
|
|
23
|
Dehydromethylation of alkali metal salts of the utility amide 2,2,6,6-tetramethylpiperidide (TMP).
|
Chem Commun (Camb)
|
2014
|
0.75
|
|
24
|
Solid state and solution studies of lithium tris(n-butyl)magnesiates stabilised by Lewis donors.
|
Dalton Trans
|
2015
|
0.75
|
|
25
|
Optimisation of a lithium magnesiate for use in the non-cryogenic asymmetric deprotonation of prochiral ketones.
|
Dalton Trans
|
2013
|
0.75
|
|
26
|
Sodium-mediated magnesiation of thiophene and tetrahydrothiophene: structural contrasts with furan and tetrahydrofuran.
|
Chemistry
|
2010
|
0.75
|
|
27
|
Hexameric Mg-O stacks with six THF-solvated sodium amide appendages: "super" variants of inverse crown ethers generated by cleavage of THF.
|
Angew Chem Int Ed Engl
|
2002
|
0.75
|
|
28
|
Isolation and characterisation of a (-)-sparteine coordinated mixed alkyl/amido sodium magnesiate, a chiral variant of an important utility ate base.
|
Dalton Trans
|
2008
|
0.75
|
|
29
|
Synthetic and reactivity studies of hetero-tri-anionic sodium zincates.
|
Dalton Trans
|
2015
|
0.75
|
|
30
|
Single electron transfer (SET) activity of the dialkyl-amido sodium zincate [(TMEDA)·Na(μ-TMP)(μ-tBu)Zn(tBu)] towards TEMPO and chalcone.
|
Chem Commun (Camb)
|
2011
|
0.75
|
|
31
|
Synthetic and structural investigations of alkali metal diamine bis(phenolate) complexes.
|
Dalton Trans
|
2008
|
0.75
|
|
32
|
A polymeric solvent-free variant of a hydridomagnesium inverse crown.
|
Acta Crystallogr C
|
2006
|
0.75
|
|
33
|
Structural elaboration of the surprising ortho-zincation of benzyl methyl ether.
|
Chem Commun (Camb)
|
2010
|
0.75
|
|
34
|
Structural variations within group 1 (Li-Cs)+ (2,2,6,6-tetramethyl-1-piperidinyloxy)- complexes made via metallic reduction of the nitroxyl radical.
|
Inorg Chem
|
2009
|
0.75
|
|
35
|
Building an extended inverse crown motif via alkali-metal-mediated alpha-magnesiation of furan.
|
Chem Commun (Camb)
|
2006
|
0.75
|
|
36
|
Remote functionalisation via sodium alkylamidozincate intermediates: access to unusual fluorenone and pyridyl ketone reactivity patterns.
|
Chem Commun (Camb)
|
2011
|
0.75
|
|
37
|
Synthesis and structure of a molecular barium Aminebis(phenolate) and its application as an initiator for ring-opening polymerization of cyclic esters.
|
Inorg Chem
|
2007
|
0.75
|