Published in J Am Chem Soc on September 28, 2005
A stable compound containing a silicon-silicon triple bond. Science (2004) 1.64
Reoperation for recurrent lumbar disc herniation: a study over a 20-year period in a Japanese population. J Orthop Sci (2011) 1.19
(tBu2MeSi)2Sn=Sn(SiMetBu2)2: a distannene with a >Sn=Sn< double bond that is stable both in the solid state and in solution. J Am Chem Soc (2006) 1.14
Induction of autophagy and autophagic cell death in damaged neural tissue after acute spinal cord injury in mice. Spine (Phila Pa 1976) (2011) 1.14
Spinal cord injury induces upregulation of Beclin 1 and promotes autophagic cell death. Neurobiol Dis (2008) 1.09
Toward a silicon version of metathesis: from Schrock-type titanium silylidenes to silatitanacyclobutenes. J Am Chem Soc (2013) 1.03
Novel organometallic reagents: geminal dianionic derivatives of the heavy group 14 elements. Inorg Chem (2011) 1.02
The role of mTOR signaling pathway in spinal cord injury. Cell Cycle (2012) 0.90
Stable cyclic silenes from reaction of disilenides with carboxylic acid chlorides. Angew Chem Int Ed Engl (2007) 0.90
Genetic ablation of transcription repressor Bach1 reduces neural tissue damage and improves locomotor function after spinal cord injury in mice. J Neurotrauma (2009) 0.88
The role of autophagy in spinal cord injury. Autophagy (2009) 0.86
Air-stable disilacyclopropene with a SI=C bond and its conversion to disilacyclopropenylium ion: silicon-carbon hybrid 2pi-electron systems. J Am Chem Soc (2007) 0.86
Cyclotrisilenylium ion: the persilaaromatic compound. J Am Chem Soc (2005) 0.85
Isozyme-specific modes of activation of CTP:phosphorylcholine cytidylyltransferase in Arabidopsis thaliana at low temperature. Plant Cell Physiol (2009) 0.84
A stable Schrock-type hafnium-silylene complex. J Am Chem Soc (2006) 0.84
High-power electrochemical energy storage system employing stable radical pseudocapacitors. Angew Chem Int Ed Engl (2013) 0.84
Aromaticity of group 14 organometallics: experimental aspects. Angew Chem Int Ed Engl (2007) 0.83
Solid-state (29)Si NMR study of RSiSiR: a tool for analyzing the nature of the Si-Si bond. J Am Chem Soc (2006) 0.82
Reactivity of a disilyne RSi identical with SiR (R=SiiPr[CH(SiMe3)2]2) toward pi-bonds: stereospecific addition and a new route to an isolable 1,2-disilabenzene. J Am Chem Soc (2007) 0.82
Sulfur-substituted tetrahedranes. J Am Chem Soc (2011) 0.81
Isolable anion radical of blue disilene (tBu2MeSi)2Si=Si(SiMetBu2)2 formed upon one-electron reduction: synthesis and characterization. J Am Chem Soc (2004) 0.81
An N-heterocyclic carbene-disilyne complex and its reactivity toward ZnCl2. J Am Chem Soc (2010) 0.81
Photoisomerization of perfluoroaryltetrahedranes to perfluoroarylcyclobutadienes. J Am Chem Soc (2011) 0.81
Perfluoroaryltetrahedranes: tetrahedranes with extended sigma-pi conjugation. J Am Chem Soc (2009) 0.81
Tetrakis(trimethylsilyl)tetrahedrane. J Am Chem Soc (2002) 0.80
Isolable silyl and germyl radicals lacking conjugation with pi-bonds: synthesis, characterization, and reactivity. J Am Chem Soc (2002) 0.80
Conversion of a disilenide into a silene: silyl-anion-substituted silene by a sila-Peterson-type reaction from an sp2-type silyl anion. Angew Chem Int Ed Engl (2007) 0.80
Low-energy extracorporeal shock wave therapy promotes vascular endothelial growth factor expression and improves locomotor recovery after spinal cord injury. J Neurosurg (2014) 0.80
Cyclotetrasilenide ion: a reversible redox system of cyclotetrasilenyl cation, radical, and anion. Angew Chem Int Ed Engl (2002) 0.79
The isolable cation radical of disilene: synthesis, characterization, and a reversible one-electron redox system. J Am Chem Soc (2008) 0.79
Tetrasilatetrahedranide: a silicon cage anion. J Am Chem Soc (2003) 0.79
Isolable silylene anion radical: structural characteristics in the solid state and in solution. J Am Chem Soc (2007) 0.79
Tetrakis(di-tert-butylmethylsilyl)distannene and its anion radical. J Am Chem Soc (2004) 0.79
The first silastannene >si=sn<: a new doubly-bonded system of heavier group 14 elements. J Am Chem Soc (2002) 0.78
From tetragermacyclobutene to tetragermacyclobutadiene dianion to tetragermacyclobutadiene transition metal complexes. J Am Chem Soc (2011) 0.78
Heavy ferrocene: a sandwich complex containing Si and Ge atoms. J Am Chem Soc (2007) 0.78
Access to a stable Si2N2 four-membered ring with non-Kekulé singlet biradical character from a disilyne. J Am Chem Soc (2011) 0.78
A chemical trick: how to make a digermene from a disilene, formation of 3delta-1,2,3,4-disiladigermetene. J Am Chem Soc (2003) 0.78
Carbonylation of cyclotrisilenes. Angew Chem Int Ed Engl (2013) 0.78
Reoperation rates after fenestration for lumbar spinal canal stenosis: a 20-year period survival function method analysis. Eur Spine J (2014) 0.78
Comment on "Disproving a silicon analog of an alkyne with the aid of topological analyses of the electronic structure and ab initio molecular dynamics calculations". Chemphyschem (2006) 0.78
Eta(5)-1,2,3-trisilacyclopentadienyl--a ligand for transition metal complexes: rhodium half-sandwich and ruthenium sandwich. J Am Chem Soc (2009) 0.77
The first isolable 1,1-dilithiogermane and its unusual dimeric structure--an effective reagent for the preparation of double-bonded derivatives of group 14 elements. Angew Chem Int Ed Engl (2002) 0.76
An isolable NHC-stabilized silylene radical cation: synthesis and structural characterization. J Am Chem Soc (2012) 0.76
A blue digermene (t-Bu2MeSi)2Ge=Ge(SiMet-Bu2)2. Chem Commun (Camb) (2011) 0.76
[(tBu2MeSi)3Ge]+: an isolable free germyl cation lacking conjugation to pi bonds. Angew Chem Int Ed Engl (2003) 0.75
1,4,5-trigermabicyclo[2.1.0]pent-2-en-5-ylium: the isolable bishomocyclopropenylium ion containing a heavier group 14 element. J Am Chem Soc (2003) 0.75
The cation cluster of heavier group 14 elements: a free germyl cation with trishomoaromaticity. J Am Chem Soc (2002) 0.75
Isolable p- and m-[((t)Bu2MeSi)2Si]2C6H4: disilaquinodimethane vs triplet bis(silyl radical). J Am Chem Soc (2011) 0.75
Cyclobutadiene dianions consisting of heavier group 14 elements: synthesis and characterization. J Am Chem Soc (2004) 0.75
Isolable aryl-substituted silyl radicals: synthesis, characterization, and reactivity. Chemistry (2014) 0.75
A (Tetrasilacyclobutadiene)tricarbonyliron complex [{eta4-(tBu2MeSi)4Si4}Fe(CO)3]: the silicon cousin of pettit's (cyclobutadiene)tricarbonyliron complex [(eta4-H4C4)Fe(CO)3]. Angew Chem Int Ed Engl (2006) 0.75
An isolable disilyne anion radical and a new route to the disilenide ion upon reduction of a disilyne. J Am Chem Soc (2007) 0.75
1,2-Disilacyclobut-2-enes: donor-free four-membered cyclic silenes from reaction of disilenides with vinylbromides. Chemistry (2008) 0.75
The first bicyclo[1.1.0]butane dianion of heavier group 14 elements. Angew Chem Int Ed Engl (2004) 0.75
Unsymmetrically substituted disilyne Dsi(2)(i)PrSi-Si≡Si-SiNpDsi(2) (Np = CH(2)(t)Bu): synthesis and characterization. J Am Chem Soc (2010) 0.75
Addition of amines and hydroborane to the disilyne RSi[triple bond]SiR (R = Si(i)Pr[CH(SiMe3)2]2) giving amino- and boryl-substituted disilenes. J Am Chem Soc (2010) 0.75
Tri-tert-butylsilylsilylenes with alkali metal substituents ((t)Bu3Si)SiM (M = Li, K): electronically and sterically accessible triplet ground states. J Am Chem Soc (2007) 0.75
2,4-Disila-1-germatricyclo[2.1.0.0(2,5)]pentane: a new type of cage compound of group 14 elements with an extremely long Ge-C bridge bond and an "Umbrella"-type configuration of a Ge atom. J Am Chem Soc (2002) 0.75
Stable mononuclear radical anions of heavier group 13 elements: [(tBu2MeSi)3E.-].[K+(2.2.2-Cryptand)] (E = Al, Ga). J Am Chem Soc (2005) 0.75
Tetrasilacyclobutadiene ((t)Bu(2)MeSi)(4)Si(4): a new ligand for transition-metal complexes. J Am Chem Soc (2005) 0.75
Reactivity of the disilyne RSi[triple bond]SiR (R = Si(i)Pr[CH(SiMe3)2]2) toward silylcyanide: two pathways to form the bis-adduct [RSiSiR(CNSiMe3)2] with some silaketenimine character and a 1,4-diaza-2,3-disilabenzene analogue. J Am Chem Soc (2008) 0.75
[A case report: small cell carcinoma transformed from transitional cell carcinoma of the urinary bladder]. Hinyokika Kiyo (2006) 0.75
Photochemical isomerization of 1,2,5-trisilabicyclo[3.2.0]hepta-3,6-diene to 1,4,7-trisilabicyclo[2.2.1]hepta-2,5-diene. Chem Commun (Camb) (2003) 0.75
Nearly planar nonsolvated monomeric silyl- and germyllithiums as a result of an intramolecular CH-Li agostic interaction. J Am Chem Soc (2002) 0.75
SiGe2 and Ge3: cyclic digermenes that undergo unexpected ring-expansion reactions. Angew Chem Int Ed Engl (2005) 0.75
Si3C2-rings: from a nonconjugated trisilacyclopentadiene to an aromatic trisilacyclopentadienide and cyclic disilenide. J Am Chem Soc (2009) 0.75
1,3-Disila-2-gallata- and -indataallenic Anions [>SiMSi<]-.Li+ (M = Ga, In): compounds featuring double bonds between elements of groups 13 and 14. J Am Chem Soc (2004) 0.75
Interplay of EnE'3-nC valence isomers (E, E' = Si, Ge): bicyclo[1.1.0]butanes with very short bridging bonds and their isomerization to alkyl-substituted cyclopropenes. J Am Chem Soc (2007) 0.75
Hexakis(trimethylsilyl)tetrahedranyltetrahedrane. Angew Chem Int Ed Engl (2005) 0.75
A stable silaborene: synthesis and characterization. J Am Chem Soc (2006) 0.75
Bis(tri-tert-butylsilyl)silylene: triplet ground state silylene. J Am Chem Soc (2003) 0.75
A new disilene with π-accepting groups from the reaction of disilyne RSi≡SiR (R = Si(i)Pr[CH(SiMe3)2]) with isocyanides. J Am Chem Soc (2012) 0.75
Stable silyl, germyl, and stannyl cations, radicals, and anions: heavy versions of carbocations, carbon radicals, and carbanions. Acc Chem Res (2007) 0.75