A variety of spin-crossover behaviors depending on the counter anion: two-dimensional complexes constructed by NH...Cl- hydrogen bonds, [FeIIH3LMe]Cl.X (X = PF6 -, AsF6 -, SbF6 -, CF3SO3 -; H3L(Me) = Tris[2-{[(2-methylimidazol-4-yl)methylidene]amino}ethyl]amine).

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Published in Chemistry on June 02, 2006

Authors

Masahiro Yamada1, Hiroaki Hagiwara, Haruna Torigoe, Naohide Matsumoto, Masaaki Kojima, Françoise Dahan, Jean-Pierre Tuchagues, Nazzareno Re, Seiichiro Iijima

Author Affiliations

1: Department of Chemistry, Faculty of Science, Kumamoto University, Kurokami 2-39-1, Kumamoto 860-8555, Japan. naohide@aster.sci.kumamoto-u.ac.jp

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