Published in J Am Chem Soc on September 21, 2007
A highly reactive p450 model compound I. J Am Chem Soc (2009) 1.21
Manganese catalysts for C-H activation: an experimental/theoretical study identifies the stereoelectronic factor that controls the switch between hydroxylation and desaturation pathways. J Am Chem Soc (2010) 1.01
Prediction of high-valent iron K-edge absorption spectra by time-dependent density functional theory. Dalton Trans (2011) 0.99
Dramatic influence of an anionic donor on the oxygen-atom transfer reactivity of a Mn(V) -oxo complex. Chemistry (2014) 0.92
Methoxy-derivatization of alkyl chains increases the in vivo efficacy of cationic Mn porphyrins. Synthesis, characterization, SOD-like activity, and SOD-deficient E. coli study of meta Mn(III) N-methoxyalkylpyridylporphyrins. Dalton Trans (2011) 0.91
Oxygen-atom transfer reactivity of axially ligated Mn(V)-oxo complexes: evidence for enhanced electrophilic and nucleophilic pathways. J Am Chem Soc (2014) 0.89
One-electron oxidation of an oxoiron(IV) complex to form an [O═FeV═NR]+ center. Proc Natl Acad Sci U S A (2012) 0.87
Characterization and dioxygen reactivity of a new series of coordinatively unsaturated thiolate-ligated manganese(II) complexes. Inorg Chem (2012) 0.83
Molecular recognition in Mn-catalyzed C-H oxidation. Reaction mechanism and origin of selectivity from a DFT perspective. Dalton Trans (2009) 0.79
Tuning the Relative Stability and Reactivity of Manganese Dioxygen and Peroxo Intermediates via Systematic Ligand Modification. Acc Chem Res (2015) 0.76
Structural elucidation and physicochemical properties of mononuclear Uranyl(VI) complexes incorporating dianionic units. Sci Rep (2016) 0.75
Reactivity and O2 Formation by Mn(IV)- and Mn(V)-Hydroxo Species Stabilized within a Polyfluoroxometalate Framework. J Am Chem Soc (2015) 0.75
Singlet versus Triplet Reactivity in an Mn(V)-Oxo Species: Testing Theoretical Predictions Against Experimental Evidence. J Am Chem Soc (2016) 0.75
Beyond ferryl-mediated hydroxylation: 40 years of the rebound mechanism and C-H activation. J Biol Inorg Chem (2016) 0.75
Mechanism of oxidation reactions catalyzed by cytochrome p450 enzymes. Chem Rev (2004) 4.25
Water-splitting chemistry of photosystem II. Chem Rev (2006) 3.67
Application of Badger's rule to heme and non-heme iron-oxygen bonds: an examination of ferryl protonation states. J Am Chem Soc (2006) 1.61
Chromium- and manganese-salen promoted epoxidation of alkenes. Chem Rev (2005) 1.49
Preparation and properties of a monomeric Mn(IV)-oxo complex. J Am Chem Soc (2006) 1.29
Synthesis, characterization, and reactivities of manganese(V)-oxo porphyrin complexes. J Am Chem Soc (2007) 1.25
Characterization of a dinuclear MnV=O complex and is efficient evolution of O2 in the presence of water. Angew Chem Int Ed Engl (2004) 1.13
Electronic structure and reactivity of isomeric oxo-Mn(V) porphyrins: effects of spin-state crossing and pKa modulation. Inorg Chem (2006) 1.02
Modeling the haloperoxidases: reversible oxygen atom transfer between bromide ion and an oxo-Mn(V) porphyrin. J Inorg Biochem (2007) 0.99
High-valent transition metal corrolazines. J Inorg Biochem (2006) 0.88
17O NMR study of oxo metalloporphyrin complexes: correlation with electronic structure of M=O moiety. J Inorg Biochem (2006) 0.86
Potent metalloporphyrin peroxynitrite decomposition catalyst protects against the development of doxorubicin-induced cardiac dysfunction. Circulation (2003) 2.56
Cu(I) recognition via cation-pi and methionine interactions in CusF. Nat Chem Biol (2007) 2.28
Mycobactin-mediated iron acquisition within macrophages. Nat Chem Biol (2005) 2.09
Role for nitrosative stress in diabetic neuropathy: evidence from studies with a peroxynitrite decomposition catalyst. FASEB J (2004) 1.64
Oxidative aliphatic C-H fluorination with fluoride ion catalyzed by a manganese porphyrin. Science (2012) 1.62
Effects of FP15, a peroxynitrite decomposition catalyst on cardiac and pulmonary function after cardiopulmonary bypass. Eur J Cardiothorac Surg (2012) 1.48
Definitive evidence for monoanionic binding of 2,3-dihydroxybiphenyl to 2,3-dihydroxybiphenyl 1,2-dioxygenase from UV resonance Raman spectroscopy, UV/Vis absorption spectroscopy, and crystallography. J Am Chem Soc (2002) 1.45
Role of nitrosative stress in early neuropathy and vascular dysfunction in streptozotocin-diabetic rats. Am J Physiol Endocrinol Metab (2007) 1.31
FeNO structure in distal pocket mutants of myoglobin based on resonance Raman spectroscopy. Biochemistry (2003) 1.24
Time-resolved absorption and UV resonance Raman spectra reveal stepwise formation of T quaternary contacts in the allosteric pathway of hemoglobin. J Mol Biol (2004) 1.23
Differential sensing of protein influences by NO and CO vibrations in heme adducts. J Am Chem Soc (2006) 1.23
Modulation of the heme electronic structure and cystathionine beta-synthase activity by second coordination sphere ligands: The role of heme ligand switching in redox regulation. J Inorg Biochem (2009) 1.22
Nitrosative stress and peripheral diabetic neuropathy in leptin-deficient (ob/ob) mice. Exp Neurol (2007) 1.21
A highly reactive p450 model compound I. J Am Chem Soc (2009) 1.21
Radical intermediates in monooxygenase reactions of rieske dioxygenases. J Am Chem Soc (2007) 1.20
Membrane affinity of the amphiphilic marinobactin siderophores. J Am Chem Soc (2002) 1.18
A peroxynitrite decomposition catalyst counteracts sensory neuropathy in streptozotocin-diabetic mice. Eur J Pharmacol (2007) 1.14
Detection and kinetic characterization of a highly reactive heme-thiolate peroxygenase compound I. J Am Chem Soc (2012) 1.12
Enzymatic tailoring of enterobactin alters membrane partitioning and iron acquisition. ACS Chem Biol (2006) 1.09
Revisiting the mechanism of P450 enzymes with the radical clocks norcarane and spiro[2,5]octane. J Am Chem Soc (2002) 1.08
Quantum chemical evaluation of protein control over heme ligation: CO/O2 discrimination in myoglobin. J Phys Chem B (2005) 1.08
Protein dynamics from time resolved UV Raman spectroscopy. Curr Opin Struct Biol (2008) 1.07
Evaluation of the peroxynitrite decomposition catalyst Fe(III) tetra-mesitylporphyrin octasulfonate on peripheral neuropathy in a mouse model of type 1 diabetes. Int J Mol Med (2007) 1.05
Dynamics of carbon monoxide binding to CooA. J Biol Chem (2004) 1.05
Dynamics of carbon monoxide binding to cystathionine beta-synthase. J Biol Chem (2006) 1.05
Modeling of ligation-induced helix/loop displacements in myoglobin: toward an understanding of hemoglobin allostery. J Am Chem Soc (2006) 1.04
A conformational switch to beta-sheet structure in cytochrome c leads to heme exposure. Implications for cardiolipin peroxidation and apoptosis. J Am Chem Soc (2007) 1.03
Spectroscopic studies of the corrinoid/iron-sulfur protein from Moorella thermoacetica. J Am Chem Soc (2006) 1.03
Electronic structure and reactivity of isomeric oxo-Mn(V) porphyrins: effects of spin-state crossing and pKa modulation. Inorg Chem (2006) 1.02
Characterization of two different five-coordinate soluble guanylate cyclase ferrous-nitrosyl complexes. Biochemistry (2008) 1.01
DFT analysis of axial and equatorial effects on heme-CO vibrational modes: applications to CooA and H-NOX heme sensor proteins. Biochemistry (2008) 1.00
Porphyrin distortion during affinity maturation of a ferrochelatase antibody, monitored by Resonance Raman spectroscopy. J Am Chem Soc (2004) 1.00
Peroxynitrite mediates active site tyrosine nitration in manganese superoxide dismutase. Evidence of a role for the carbonate radical anion. J Am Chem Soc (2010) 1.00
Modeling the haloperoxidases: reversible oxygen atom transfer between bromide ion and an oxo-Mn(V) porphyrin. J Inorg Biochem (2007) 0.99
Reversible heme-dependent regulation of human cystathionine β-synthase by a flavoprotein oxidoreductase. Biochemistry (2011) 0.99
Vibrational and electronic couplings in ultraviolet resonance Raman spectra of cyclic peptides. Biophys Chem (2003) 0.99
Intermediacy of poly(L-proline) II and beta-strand conformations in poly(L-lysine) beta-sheet formation probed by temperature-jump/UV resonance Raman spectroscopy. Biochemistry (2006) 0.99
Porphyrin distortion from resonance Raman intensities of out-of-plane modes: Computation and modeling of N-methylmesoporphyrin, a ferrochelatase transition state analog. J Phys Chem A (2005) 0.99
Late stage benzylic C-H fluorination with [¹⁸F]fluoride for PET imaging. J Am Chem Soc (2014) 0.98
Antidiabetic Activity of Vinca rosea Extracts in Alloxan-Induced Diabetic Rats. Int J Endocrinol (2010) 0.98
Heme regulation of human cystathionine beta-synthase activity: insights from fluorescence and Raman spectroscopy. J Am Chem Soc (2009) 0.98
The peroxynitrite decomposition catalyst FP15 improves ageing-associated cardiac and vascular dysfunction. Mech Ageing Dev (2006) 0.98
The use of routine monitoring and evaluation systems to assess a referral model of family planning and HIV service integration in Nigeria. AIDS (2009) 0.97
Activation mechanism of the CO sensor CooA. Mutational and resonance Raman spectroscopic studies. J Biol Chem (2003) 0.97
Early events in apomyoglobin unfolding probed by laser T-jump/UV resonance Raman spectroscopy. Biochemistry (2005) 0.97
A "push-pull" mechanism for heterolytic o-o bond cleavage in hydroperoxo manganese porphyrins. Inorg Chem (2010) 0.97
Cytochrome c causes pore formation in cardiolipin-containing membranes. Proc Natl Acad Sci U S A (2013) 0.97
Manganese porphyrins catalyze selective C-H bond halogenations. J Am Chem Soc (2010) 0.96
Profiling mechanisms of alkane hydroxylase activity in vivo using the diagnostic substrate norcarane. Chem Biol (2007) 0.96
Selective hydroxylation of alkanes by an extracellular fungal peroxygenase. FEBS J (2011) 0.95
Manganese-catalyzed oxidative benzylic C-H fluorination by fluoride ions. Angew Chem Int Ed Engl (2013) 0.95
Molecular probes of the mechanism of cytochrome P450. Oxygen traps a substrate radical intermediate. Arch Biochem Biophys (2010) 0.95
Hemoglobin site-mutants reveal dynamical role of interhelical H-bonds in the allosteric pathway: time-resolved UV resonance Raman evidence for intra-dimer coupling. J Mol Biol (2004) 0.94
Single vesicle observations of the cardiolipin-cytochrome C interaction: induction of membrane morphology changes. Langmuir (2011) 0.94
Tunable kHz deep ultraviolet (193-210 nm) laser for Raman application. Appl Spectrosc (2005) 0.94
Mechanisms of peroxynitrite interactions with heme proteins. Inorg Chem (2010) 0.93
Temperature-jump apparatus with Raman detection based on a solid-state tunable (1.80-2.05 microm) kHz optical parametric oscillator laser. Appl Spectrosc (2006) 0.93
Part II: beneficial effects of the peroxynitrite decomposition catalyst FP15 in murine models of arthritis and colitis. Mol Med (2002) 0.93
New light on NO bonding in Fe(III) heme proteins from resonance Raman spectroscopy and DFT modeling. J Am Chem Soc (2010) 0.93
Driving force for oxygen-atom transfer by heme-thiolate enzymes. Angew Chem Int Ed Engl (2013) 0.92
Paediatric pelvic ring fractures and associated injuries. Injury (2010) 0.92
Heme displacement mechanism of CooA activation: mutational and Raman spectroscopic evidence. J Biol Chem (2006) 0.91
The diagnostic substrate bicyclohexane reveals a radical mechanism for bacterial cytochrome P450 in whole cells. Angew Chem Int Ed Engl (2006) 0.91
Probing soluble guanylate cyclase activation by CO and YC-1 using resonance Raman spectroscopy. Biochemistry (2010) 0.91
Comparison and contrasts between the active site PKs of Mn-superoxide dismutase and those of Fe-superoxide dismutase. J Am Chem Soc (2002) 0.91
Dissolving efficacy of different organic solvents on gutta-percha and resilon root canal obturating materials at different immersion time intervals. J Conserv Dent (2012) 0.91
Prevalence of Impacted Molar Teeth among Saudi Population in Asir Region, Saudi Arabia - A Retrospective Study of 3 Years. J Int Oral Health (2013) 0.90
Reaction mechanisms of non-heme diiron hydroxylases characterized in whole cells. J Inorg Biochem (2005) 0.89
Investigation of an unnatural amino acid for use as a resonance Raman probe: Detection limits, solvent and temperature dependence of the νC≡N band of 4-cyanophenylalanine. J Raman Spectrosc (2008) 0.89
Remarkable aliphatic hydroxylation by the diiron enzyme toluene 4-monooxygenase in reactions with radical or cation diagnostic probes norcarane, 1,1-dimethylcyclopropane, and 1,1-diethylcyclopropane. Biochemistry (2004) 0.89
Multicopper oxidase involvement in both Mn(II) and Mn(III) oxidation during bacterial formation of MnO(2). J Biol Inorg Chem (2012) 0.89
Membrane dynamics of the amphiphilic siderophore, acinetoferrin. J Am Chem Soc (2005) 0.89
Spectroscopic studies of the anaerobic enzyme-substrate complex of catechol 1,2-dioxygenase. J Am Chem Soc (2005) 0.88
Dynamics of allostery in hemoglobin: roles of the penultimate tyrosine H bonds. J Mol Biol (2005) 0.88
Mechanism of the CO-sensing heme protein CooA: new insights from the truncated heme domain and UVRR spectroscopy. J Inorg Biochem (2007) 0.88
Fast catalytic hydroxylation of hydrocarbons with ruthenium porphyrins. Inorg Chem (2006) 0.88
The molecular biogeochemistry of manganese(II) oxidation. Biochem Soc Trans (2012) 0.87
Enthalpic and entropic stages in alpha-helical peptide unfolding, from laser T-jump/UV Raman spectroscopy. J Am Chem Soc (2007) 0.87
Peroxynitrite and protein nitration in the pathogenesis of diabetic peripheral neuropathy. Diabetes Metab Res Rev (2014) 0.86
UV Raman monitoring of histidine protonation and H-(2)H exchange in plastocyanin. J Inorg Biochem (2002) 0.85
Alkane-oxidizing metalloenzymes in the carbon cycle. Metallomics (2011) 0.85
Anti-Markovnikov hydrofunctionalization of olefins mediated by rhodium-porphyrin complexes. Angew Chem Int Ed Engl (2004) 0.85
Efficient water oxidation catalyzed by homogeneous cationic cobalt porphyrins with critical roles for the buffer base. Proc Natl Acad Sci U S A (2013) 0.85
Catalytic generation of chlorine dioxide from chlorite using a water-soluble manganese porphyrin. Angew Chem Int Ed Engl (2010) 0.85
Role of ligand bending in the photodissociation of O2 vs CO-heme: a time-dependent density functional study. J Am Chem Soc (2003) 0.84
Direct detection of the oxygen rebound intermediates, ferryl Mb and NO2, in the reaction of metmyoglobin with peroxynitrite. J Am Chem Soc (2009) 0.84
Ferryl protonation in oxoiron(IV) porphyrins and its role in oxygen transfer. J Am Chem Soc (2015) 0.84
Cage escape competes with geminate recombination during alkane hydroxylation by the diiron oxygenase AlkB. Angew Chem Int Ed Engl (2008) 0.84
Hepatoprotective evaluation of Anogeissus latifolia: in vitro and in vivo studies. World J Gastroenterol (2009) 0.83
Heme reactivity is uncoupled from quaternary structure in gel-encapsulated hemoglobin: a resonance Raman spectroscopic study. J Am Chem Soc (2012) 0.83
Mechanistic studies of an unusual epoxide-forming elimination of a beta-hydroxyalkyl rhodium porphyrin. Chem Commun (Camb) (2005) 0.83
Differential control of heme reactivity in alpha and beta subunits of hemoglobin: a combined Raman spectroscopic and computational study. J Am Chem Soc (2014) 0.83