Palladium-mediated fluorination of arylboronic acids.

PubWeight™: 2.20‹?› | Rank: Top 2%

🔗 View Article (PMID 18604865)

Published in Angew Chem Int Ed Engl on January 01, 2008

Authors

Takeru Furuya1, Hanns Martin Kaiser, Tobias Ritter

Author Affiliations

1: Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, MA 02138, USA.

Articles citing this

Formation of ArF from LPdAr(F): catalytic conversion of aryl triflates to aryl fluorides. Science (2009) 4.13

A fluoride-derived electrophilic late-stage fluorination reagent for PET imaging. Science (2011) 2.84

Catalysis for fluorination and trifluoromethylation. Nature (2011) 2.70

Aryl-CF(3) bond-forming reductive elimination from palladium(IV). J Am Chem Soc (2010) 2.15

Synthesis and reactivity of a mono-sigma-aryl palladium(IV) fluoride complex. J Am Chem Soc (2009) 2.07

Nickel-mediated oxidative fluorination for PET with aqueous [18F] fluoride. J Am Chem Soc (2012) 1.83

Mechanism of C-F reductive elimination from palladium(IV) fluorides. J Am Chem Soc (2010) 1.83

Bimetallic Pd(III) complexes in palladium-catalysed carbon–heteroatom bond formation. Nat Chem (2009) 1.72

Silver-catalyzed late-stage fluorination. J Am Chem Soc (2010) 1.62

Evidence for in situ catalyst modification during the Pd-catalyzed conversion of aryl triflates to aryl fluorides. J Am Chem Soc (2011) 1.47

Bystanding F+ oxidants enable selective reductive elimination from high-valent metal centers in catalysis. Angew Chem Int Ed Engl (2011) 1.39

Copper-mediated fluorination of aryl iodides. J Am Chem Soc (2012) 1.26

An improved catalyst system for the Pd-catalyzed fluorination of (hetero)aryl triflates. Org Lett (2013) 1.24

Deoxyfluorination of phenols. J Am Chem Soc (2011) 1.18

Accelerating palladium-catalyzed C-F bond formation: use of a microflow packed-bed reactor. Angew Chem Int Ed Engl (2011) 1.18

Copper-catalyzed, directing group-assisted fluorination of arene and heteroarene C-H bonds. J Am Chem Soc (2013) 1.13

Gold-catalyzed oxidative coupling reactions with aryltrimethylsilanes. Org Lett (2010) 1.04

Application of palladium-mediated (18)F-fluorination to PET radiotracer development: overcoming hurdles to translation. PLoS One (2013) 1.03

Copper-mediated fluorination of arylboronate esters. Identification of a copper(III) fluoride complex. J Am Chem Soc (2013) 1.01

Steric Crowding Makes Challenging C(sp3)-F Reductive Eliminations Feasible. Organometallics (2011) 1.00

Palladium(III)-catalyzed fluorination of arylboronic acid derivatives. J Am Chem Soc (2013) 0.92

Silver-mediated trifluoromethoxylation of aryl stannanes and arylboronic acids. J Am Chem Soc (2011) 0.91

Bis-N-heterocyclic carbene palladium(IV) tetrachloride complexes: synthesis, reactivity, and mechanisms of direct chlorinations and oxidations of organic substrates. J Am Chem Soc (2011) 0.91

Electrophilic fluorination of cationic Pt-aryl complexes. Chem Commun (Camb) (2011) 0.90

C-F Bond Formation for the Synthesis of Aryl Fluorides. Synthesis (Stuttg) (2010) 0.89

Catalytic enantioselective cyclization and C3-fluorination of polyenes. J Am Chem Soc (2013) 0.88

Late-Stage Fluorination: From Fundamentals to Application. Org Process Res Dev (2014) 0.87

PhenoFluor: Practical Synthesis, New Formulation, and Deoxyfluorination of Heteroaromatics. Org Process Res Dev (2014) 0.86

Intercepting Wacker intermediates with arenes: C-H functionalization and dearomatization. Org Lett (2011) 0.86

Synthesis and reactivity of palladium(II) fluoride complexes containing nitrogen-donor ligands. Dalton Trans (2009) 0.85

Asymmetric palladium-catalyzed directed intermolecular fluoroarylation of styrenes. J Am Chem Soc (2014) 0.83

Studying regioisomer formation in the Pd-catalyzed fluorination of aryl triflates by deuterium labeling. J Am Chem Soc (2014) 0.81

Mechanism of Electrophilic Fluorination with Pd(IV): Fluoride Capture and Subsequent Oxidative Fluoride Transfer(.) Chem Sci (2014) 0.81

A Fluorinated Ligand Enables Room-Temperature and Regioselective Pd-Catalyzed Fluorination of Aryl Triflates and Bromides. J Am Chem Soc (2015) 0.80

Palladium-Catalyzed Enantioselective 1,1-Fluoroarylation of Aminoalkenes. J Am Chem Soc (2015) 0.79

The [F]2-Fluoro-1,3-thiazolyl Moiety - an Easily-Accessible Structural Motif for Prospective Molecular Imaging Radiotracers. Tetrahedron Lett (2010) 0.78

Radiochemistry: Flipping fluoride's reactivity. Nat Chem (2012) 0.77

Articles by these authors

A fluoride-derived electrophilic late-stage fluorination reagent for PET imaging. Science (2011) 2.84

Catalysis for fluorination and trifluoromethylation. Nature (2011) 2.70

Carbon-fluorine reductive elimination from a high-valent palladium fluoride. J Am Chem Soc (2008) 2.22

Introduction of fluorine and fluorine-containing functional groups. Angew Chem Int Ed Engl (2013) 2.07

Nickel-mediated oxidative fluorination for PET with aqueous [18F] fluoride. J Am Chem Soc (2012) 1.83

Mechanism of C-F reductive elimination from palladium(IV) fluorides. J Am Chem Soc (2010) 1.83

Silver-mediated fluorination of functionalized aryl stannanes. J Am Chem Soc (2009) 1.78

Bimetallic Pd(III) complexes in palladium-catalysed carbon–heteroatom bond formation. Nat Chem (2009) 1.72

Fluorination of boronic acids mediated by silver(I) triflate. Org Lett (2009) 1.70

Silver-catalyzed late-stage fluorination. J Am Chem Soc (2010) 1.62

Iron-catalyzed 1,4-hydroboration of 1,3-dienes. J Am Chem Soc (2009) 1.46

Bimetallic palladium catalysis: direct observation of Pd(III)-Pd(III) intermediates. J Am Chem Soc (2009) 1.45

Carbon-fluorine bond formation. Curr Opin Drug Discov Devel (2008) 1.40

Ruthenium-catalyzed ring-closing metathesis to form tetrasubstituted olefins. Org Lett (2007) 1.39

Iron-catalyzed 1,4-addition of alpha-olefins to dienes. Org Lett (2009) 1.20

Deoxyfluorination of phenols. J Am Chem Soc (2011) 1.18

On the mechanism of palladium-catalyzed aromatic C-H oxidation. J Am Chem Soc (2010) 1.13

A general gold-catalyzed direct oxidative coupling of non-activated arenes. Chem Commun (Camb) (2008) 1.12

Bimetallic redox synergy in oxidative palladium catalysis. Acc Chem Res (2011) 1.09

Modern carbon-fluorine bond forming reactions for aryl fluoride synthesis. Chem Rev (2014) 1.08

Application of palladium-mediated (18)F-fluorination to PET radiotracer development: overcoming hurdles to translation. PLoS One (2013) 1.03

Late-stage fluorination: fancy novelty or useful tool? Angew Chem Int Ed Engl (2015) 1.00

Bimetallic reductive elimination from dinuclear Pd(III) complexes. J Am Chem Soc (2010) 0.95

Silver-mediated fluorination of aryl silanes. Tetrahedron (2011) 0.95

Late-stage deoxyfluorination of alcohols with PhenoFluor. J Am Chem Soc (2013) 0.95

A general copper-catalyzed sulfonylation of arylboronic acids. Org Lett (2007) 0.94

Synthesis and imaging validation of [¹⁸F]MDL100907 enabled by Ni-mediated fluorination. ACS Chem Neurosci (2014) 0.92

Silver-mediated trifluoromethoxylation of aryl stannanes and arylboronic acids. J Am Chem Soc (2011) 0.91

Palladium(III) in Synthesis and Catalysis. Top Organomet Chem (2011) 0.91

The synthesis and one- and two-photon optical properties of dipolar, quadrupolar and octupolar donor-acceptor molecules containing dimesitylboryl groups. Chemistry (2009) 0.91

C-F Bond Formation for the Synthesis of Aryl Fluorides. Synthesis (Stuttg) (2010) 0.89

A strategy for the synthesis of well-defined iron catalysts and application to regioselective diene hydrosilylation. J Am Chem Soc (2010) 0.88

Synthesis and structure of solution-stable one-dimensional palladium wires. Nat Chem (2011) 0.87

A dinuclear palladium catalyst for α-hydroxylation of carbonyls with O2. J Am Chem Soc (2011) 0.86

Connecting binuclear Pd(III) and mononuclear Pd(IV) chemistry by Pd-Pd bond cleavage. J Am Chem Soc (2012) 0.85

Support of academic synthetic chemistry using separation technologies from the pharmaceutical industry. Org Biomol Chem (2014) 0.82

1,2-selective hydrosilylation of conjugated dienes. J Am Chem Soc (2014) 0.81

An in vitro assay for evaluation of small-molecule inhibitors of cholesterol absorption. Angew Chem Int Ed Engl (2004) 0.78

PhenoFluorMix: practical chemoselective deoxyfluorination of phenols. Org Lett (2015) 0.78

Synthesis, crystal structures, linear and nonlinear optical properties, and theoretical studies of (p-R-phenyl)-, (p-R-phenylethynyl)-, and (E)-[2-(p-R-phenyl)ethenyl]dimesitylboranes and related compounds. Chemistry (2006) 0.77

Condensed-phase, halogen-bonded CF3I and C2F5I adducts for perfluoroalkylation reactions. Angew Chem Int Ed Engl (2015) 0.76

Corrigendum: Concerted nucleophilic aromatic substitution with (19)F(-) and (18)F(). Nature (2016) 0.76

Alkyl Aryl Ether Bond Formation with PhenoFluor. Angew Chem Int Ed Engl (2015) 0.76

Catalysis: Fluorination made easier. Nature (2010) 0.75

Late-stage formation of carbon-fluorine bonds. Chem Rec (2014) 0.75

Iron-catalyzed polymerization of isoprene and other 1,3-dienes. Angew Chem Int Ed Engl (2012) 0.75

One-dimensional palladium wires: influence of molecular changes on supramolecular structure. Inorg Chem (2013) 0.75

Hidden and Neglected: Food Poverty in the Global North - The Case of Germany. World Rev Nutr Diet (2016) 0.75