Published in J Org Chem on September 04, 2009
Evolution of C-H Bond Functionalization from Methane to Methodology. J Am Chem Soc (2015) 1.18
Catalyst-controlled formal [4 + 3] cycloaddition applied to the total synthesis of (+)-barekoxide and (-)-barekol. J Am Chem Soc (2010) 1.12
Controlling factors for C-H functionalization versus cyclopropanation of dihydronaphthalenes. J Org Chem (2010) 1.03
Strain release in C-H bond activation? Angew Chem Int Ed Engl (2009) 0.98
Rhodium-catalyzed enantioselective cyclopropanation of electron deficient alkenes. Chem Sci (2013) 0.91
Site-selective and stereoselective functionalization of unactivated C-H bonds. Nature (2016) 0.89
Scope and mechanistic analysis of the enantioselective synthesis of allenes by rhodium-catalyzed tandem ylide formation/[2,3]-sigmatropic rearrangement between donor/acceptor carbenoids and propargylic alcohols. J Am Chem Soc (2012) 0.88
Engineering a dirhodium artificial metalloenzyme for selective olefin cyclopropanation. Nat Commun (2015) 0.88
Undirected, Homogeneous C-H Bond Functionalization: Challenges and Opportunities. ACS Cent Sci (2016) 0.84
Enantioselective carbenoid insertion into C(sp(3))-H bonds. Beilstein J Org Chem (2016) 0.82
Synthesis of complex hexacyclic compounds via a tandem Rh(II)-catalyzed double-cyclopropanation/Cope rearrangement/Diels-Alder reaction. Org Lett (2014) 0.75
Enantioselective Dirhodium(II)-Catalyzed Cyclopropanations with Trimethylsilylethyl and Trichloroethyl Aryldiazoacetates. Tetrahedron (2015) 0.75
Dirhodium tetracarboxylate derived from adamantylglycine as a chiral catalyst for carbenoid reactions. Org Lett (2006) 1.48
Asymmetric synthesis of tropanes by rhodium-catalyzed [4 + 3] cycloaddition. J Am Chem Soc (2007) 1.43
Density functional calculations of the 13C NMR chemical shifts in (9,0) single-walled carbon nanotubes. J Am Chem Soc (2004) 1.35
Asymmetric [4 + 3] cycloadditions between vinylcarbenoids and dienes: application to the total synthesis of the natural product (-)-5-epi-vibsanin E. J Am Chem Soc (2009) 1.34
C-H functionalization in organic synthesis. Chem Soc Rev (2011) 1.34
Dirhodium tetracarboxylates derived from adamantylglycine as chiral catalysts for enantioselective C-h aminations. Org Lett (2006) 1.22
The reinforcing efficacy of psychostimulants in rhesus monkeys: the role of pharmacokinetics and pharmacodynamics. J Pharmacol Exp Ther (2003) 1.21
Isotope effects and the nature of selectivity in rhodium-catalyzed cyclopropanations. J Am Chem Soc (2003) 1.17
Asymmetric [4+3] cycloadditions between benzofuranyldiazoacetates and dienes: formal synthesis of (+)-frondosin B. Org Lett (2008) 1.13
Catalyst-controlled formal [4 + 3] cycloaddition applied to the total synthesis of (+)-barekoxide and (-)-barekol. J Am Chem Soc (2010) 1.12
D2-symmetric dirhodium catalyst derived from a 1,2,2-triarylcyclopropanecarboxylate ligand: design, synthesis and application. J Am Chem Soc (2011) 1.08
On the mechanism and selectivity of the combined C-H activation/Cope rearrangement. J Am Chem Soc (2011) 1.07
Rhodium-catalyzed [3 + 2] annulation of indoles. J Am Chem Soc (2010) 1.05
The reinforcing efficacy of the dopamine reuptake inhibitor 2beta-propanoyl-3beta-(4-tolyl)-tropane (PTT) as measured by a progressive-ratio schedule and a choice procedure in rhesus monkeys. J Pharmacol Exp Ther (2002) 1.05
Sequential C-H functionalization reactions for the enantioselective synthesis of highly functionalized 2,3-dihydrobenzofurans. J Am Chem Soc (2013) 1.04
Controlling factors for C-H functionalization versus cyclopropanation of dihydronaphthalenes. J Org Chem (2010) 1.03
Stereoselective construction of nitrile-substituted cyclopropanes. Chem Commun (Camb) (2008) 1.03
Novel aromatase inhibitors by structure-guided design. J Med Chem (2012) 1.03
Enhancement of cyclopropanation chemistry in the silver-catalyzed reactions of aryldiazoacetates. J Am Chem Soc (2007) 1.03
High Symmetry Dirhodium(II) Paddlewheel Complexes as Chiral Catalysts. Coord Chem Rev (2008) 1.02
Rhodium carbenoid approach for introduction of 4-substituted (Z)-pent-2-enoates into sterically encumbered pyrroles and indoles. Org Lett (2010) 1.01
Rhodium-catalyzed enantioselective vinylogous addition of enol ethers to vinyldiazoacetates. J Am Chem Soc (2012) 1.00
Rh2(S-biTISP)2-catalyzed asymmetric functionalization of indoles and pyrroles with vinylcarbenoids. Org Lett (2012) 1.00
Computationally guided stereocontrol of the combined C-H functionalization/Cope rearrangement. Angew Chem Int Ed Engl (2011) 0.99
One-pot synthesis of highly functionalized pyridines via a rhodium carbenoid induced ring expansion of isoxazoles. J Am Chem Soc (2008) 0.98
Theoretical methods of potential use for studies of inorganic reaction mechanisms. Chem Rev (2005) 0.98
Social dominance in female monkeys: dopamine receptor function and cocaine reinforcement. Biol Psychiatry (2012) 0.97
Combined C-H functionalization/Cope rearrangement with vinyl ethers as a surrogate for the vinylogous Mukaiyama aldol reaction. J Am Chem Soc (2011) 0.97
Enantioselective synthesis of (-)-maoecrystal V by enantiodetermining C-H functionalization. J Am Chem Soc (2014) 0.96
Catalytic asymmetric synthesis of pyrroloindolines via a rhodium(II)-catalyzed annulation of indoles. J Am Chem Soc (2013) 0.96
Mechanistic studies of UV assisted [4 + 2] cycloadditions in synthetic efforts toward vibsanin E. J Am Chem Soc (2007) 0.96
Enantioselective synthesis of trifluoromethyl-substituted cyclopropanes. Org Lett (2007) 0.95
Convenient method for the functionalization of the 4- and 6-positions of the androgen skeleton. Chem Commun (Camb) (2012) 0.93
Alkynoate synthesis through the vinylogous reactivity of rhodium(II) carbenoids. Angew Chem Int Ed Engl (2012) 0.92
Enantioselective reactions of donor/acceptor carbenoids derived from alpha-aryl-alpha-diazoketones. Org Lett (2009) 0.92
Role of sterically demanding chiral dirhodium catalysts in site-selective C-H functionalization of activated primary C-H bonds. J Am Chem Soc (2014) 0.91
Direct spectroscopic characterization of a transitory dirhodium donor-acceptor carbene complex. Science (2013) 0.91
Rhodium-catalyzed enantioselective cyclopropanation of electron deficient alkenes. Chem Sci (2013) 0.91
Investigation into factors influencing stereoselectivity in the reactions of heterocycles with donor-acceptor-substituted rhodium carbenoids. J Org Chem (2006) 0.91
Scope and mechanistic analysis of the enantioselective synthesis of allenes by rhodium-catalyzed tandem ylide formation/[2,3]-sigmatropic rearrangement between donor/acceptor carbenoids and propargylic alcohols. J Am Chem Soc (2012) 0.88
Synthetic and isolation studies related to the marine natural products (+)-elisabethadione and (+)-elisabethamine. J Org Chem (2007) 0.88
Enantioselective synthesis of 2-arylbicyclo[1.1.0]butane carboxylates. Org Lett (2013) 0.88
2,2,2-Trichloroethyl aryldiazoacetates as robust reagents for the enantioselective C-H functionalization of methyl ethers. J Am Chem Soc (2014) 0.88
Quasiparticle spectra from a nonempirical optimally tuned range-separated hybrid density functional. Phys Rev Lett (2012) 0.88
Rhodium-catalyzed conversion of furans to highly functionalized pyrroles. J Am Chem Soc (2013) 0.87
Role of ortho-substituents on rhodium-catalyzed asymmetric synthesis of β-lactones by intramolecular C-H insertions of aryldiazoacetates. Org Lett (2014) 0.87
Enantioselective C-C bond formation by rhodium-catalyzed tandem ylide formation/[2,3]-sigmatropic rearrangement between donor/acceptor carbenoids and allylic alcohols. J Am Chem Soc (2010) 0.87
Solid-state chlorine NMR of group IV transition metal organometallic complexes. J Am Chem Soc (2009) 0.86
Acid/base-triggered switching of circularly polarized luminescence and electronic circular dichroism in organic and organometallic helicenes. Chemistry (2014) 0.86
Asymmetric Synthesis of Highly Functionalized Cyclopentanes by a Rhodium- and Scandium-Catalyzed Five-Step Domino Sequence. Chem Sci (2011) 0.86
Thermally induced cycloadditions of donor/acceptor carbenes. Org Lett (2011) 0.86
Conversion of cyclic ketones to 2,3-fused pyrroles and substituted indoles. J Am Chem Soc (2013) 0.85
Rh2(R-TPCP)4-catalyzed enantioselective [3+2]-cycloaddition between nitrones and vinyldiazoacetates. J Am Chem Soc (2013) 0.85
Highly enantioselective Rh2(S-DOSP)4-catalyzed cyclopropenation of alkynes with styryldiazoacetates. J Am Chem Soc (2010) 0.85
Efficient route to 4H-1,3-oxazines through ring expansion of isoxazoles by rhodium carbenoids. Tetrahedron (2008) 0.85
Expanding the scope of donor/acceptor carbenes to N-phthalimido donor groups: diastereoselective synthesis of 1-cyclopropane α-amino acids. Org Lett (2012) 0.84
Assembly of pi-conjugated phosphole azahelicene derivatives into chiral coordination complexes: an experimental and theoretical study. Chemistry (2010) 0.84
Enantioselective Gold(I)-catalyzed vinylogous [3 + 2] cycloaddition between vinyldiazoacetates and enol ethers. J Am Chem Soc (2013) 0.84
Highly stereoselective C-C bond formation by rhodium-catalyzed tandem ylide formation/[2,3]-sigmatropic rearrangement between donor/acceptor carbenoids and chiral allylic alcohols. J Am Chem Soc (2012) 0.83
Calculation of the vibrationally resolved, circularly polarized luminescence of d-camphorquinone and (S,S)-trans-beta-hydrindanone. Chemphyschem (2010) 0.83
A quantum chemical approach to the design of chiral negative index materials. Opt Express (2007) 0.83
Reversal of the regiochemistry in the rhodium-catalyzed [4+3] cycloaddition between vinyldiazoacetates and dienes. Angew Chem Int Ed Engl (2014) 0.83
Rhodium-catalyzed tandem cyclopropanation/Cope rearrangement of 4-alkenyl-1-sulfonyl-1,2,3-triazoles with dienes. Angew Chem Int Ed Engl (2013) 0.82
Metal carbene-promoted sequential transformations for the enantioselective synthesis of highly functionalized cycloheptadienes. J Am Chem Soc (2005) 0.82
Gold(I)-catalyzed asymmetric cyclopropenation of internal alkynes. J Am Chem Soc (2012) 0.82
From hetero- to homochiral bis(metallahelicene)s based on a Pt(III)-Pt(III) bonded scaffold: isomerization, structure, and chiroptical properties. J Am Chem Soc (2011) 0.82
A density functional study of the 13C NMR chemical shifts in functionalized single-walled carbon nanotubes. J Am Chem Soc (2007) 0.82
Electronic structure and circular dichroism of tris(bipyridyl) metal complexes within density functional theory. Inorg Chem (2010) 0.81
Effects of the dopamine reuptake inhibitor PTT on reinstatement and on food- and cocaine-maintained responding in rhesus monkeys. Psychopharmacology (Berl) (2004) 0.81
Silica-immobilized chiral dirhodium(II) catalyst for enantioselective carbenoid reactions. Org Lett (2013) 0.81
Interaction tensors and local dynamics in common structural motifs of nitrogen: a solid-state 14N NMR and DFT study. J Am Chem Soc (2010) 0.81
Ruthenium-vinylhelicenes: remote metal-based enhancement and redox switching of the chiroptical properties of a helicene core. J Am Chem Soc (2012) 0.81
Multifunctional and reactive enantiopure organometallic helicenes: tuning chiroptical properties by structural variations of mono- and bis(platinahelicene)s. Chemistry (2011) 0.81
Accurate dipole polarizabilities for water clusters n=2-12 at the coupled-cluster level of theory and benchmarking of various density functionals. J Chem Phys (2009) 0.81
Diastereo- and enantioselective synthesis of organometallic bis(helicene)s by a combination of C-H activation and dynamic isomerization. Chemistry (2013) 0.81
On the relation between time-dependent and variational density functional theory approaches for the determination of excitation energies and transition moments. J Chem Phys (2009) 0.81
Magnitude of zero-point vibrational corrections to optical rotation in rigid organic molecules: a time-dependent density functional study. J Phys Chem A (2005) 0.81
Concise syntheses of dictyodendrins A and F by a sequential C-H functionalization strategy. J Am Chem Soc (2015) 0.80
Metal-bis(helicene) assemblies incorporating pi-conjugated phosphole-azahelicene ligands: impacting chiroptical properties by metal variation. J Am Chem Soc (2009) 0.80
Rhodium(II)-catalyzed stereoselective synthesis of allylsilanes. Org Lett (2013) 0.80
Guide to Enantioselective Dirhodium(II)-Catalyzed Cyclopropanation with Aryldiazoacetates. Tetrahedron (2013) 0.80
enantio-Enriched CPL-active helicene-bipyridine-rhenium complexes. Chem Commun (Camb) (2015) 0.80
Periodic trends in indirect nuclear spin-spin coupling tensors: relativistic density functional calculations for interhalogen diatomics. J Am Chem Soc (2002) 0.79
Importance of vibronic effects on the circular dichroism spectrum of dimethyloxirane. J Chem Phys (2005) 0.79
Helicene-grafted vinyl- and carbene-osmium complexes: an example of acid-base chiroptical switching. Chem Commun (Camb) (2013) 0.79
Density functional calculation of the electronic circular dichroism spectra of the transition metal complexes [M(phen)3]2+ (M = Fe, Ru, Os). J Phys Chem A (2005) 0.79
Metallahelicenes: easily accessible helicene derivatives with large and tunable chiroptical properties. Angew Chem Int Ed Engl (2010) 0.79
Irreversible binding of a novel phenylisothiocyanate tropane analog to monoamine transporters in rat brain. Biochem Pharmacol (2007) 0.79
Sequential transformations to access polycyclic chemotypes: asymmetric crotylation and metal carbenoid reactions. Angew Chem Int Ed Engl (2011) 0.79
A revised electronic Hessian for approximate time-dependent density functional theory. J Chem Phys (2008) 0.79
Theoretical studies of surface enhanced hyper-Raman spectroscopy: the chemical enhancement mechanism. J Chem Phys (2010) 0.79
Effect of HD-23, a potent long acting cocaine-analog, on cocaine self-administration in rats. Psychopharmacology (Berl) (2003) 0.79
Experimental and theoretical investigations of the thermodynamic stability of Ba-c(60) and K-C(60) compound clusters. ACS Nano (2008) 0.79
Effects of stereoelectronic interactions on the relativistic spin-orbit and paramagnetic components of the (13)C NMR shielding tensors of dihaloethenes. Phys Chem Chem Phys (2015) 0.78
Metal-free N-H insertions of donor/acceptor carbenes. Org Lett (2012) 0.78