Efficient ruthenium-catalyzed synthesis of [3]dendralenes from 1,3-dienic allylic carbonates.

Ruthenium(II)-catalyzed C-H bond activation and functionalization. Chem Rev (2012) 1.71

Transforming growth factor-β1 induces epithelial-to-mesenchymal transition in human lung cancer cells via PI3K/Akt and MEK/Erk1/2 signaling pathways. Mol Biol Rep (2011) 1.19

Eta6-mesityl,eta1-imidazolinylidene-carbene-ruthenium(II) complexes: catalytic activity of their allenylidene derivatives in alkene metathesis and cycloisomerisation reactions. Chemistry (2003) 1.16

Ethenolysis of methyl oleate in room-temperature ionic liquids. ChemSusChem (2008) 1.07

Regioselective ring expansion of 2,4-diiminoazetidines via cleavage of C-N and C(sp3)-H bonds: efficient construction of 2,3-dihydropyrimidinesulfonamides. J Am Chem Soc (2012) 1.05

A direct route to bifunctional aldehyde derivatives via self- and cross-metathesis of unsaturated aldehydes. ChemSusChem (2009) 0.99

Hydride-induced novel cyclization of dienedinitriles leading to multifunctionalized cyclopentadienes. Org Lett (2009) 0.96

Palladium-catalyzed intermolecular coupling of 2-silylaryl bromides with alkynes: synthesis of benzosiloles and heteroarene-fused siloles by catalytic cleavage of the C(sp3)-Si bond. Angew Chem Int Ed Engl (2012) 0.95

Activation and functionalization of benzylic derivatives by palladium catalysts. Chem Soc Rev (2007) 0.94

Autocatalysis for C-H bond activation by ruthenium(II) complexes in catalytic arylation of functional arenes. J Am Chem Soc (2011) 0.93

Co-operative effect of Lewis acids with transition metals for organic synthesis. Chem Soc Rev (2007) 0.91

A functional-group-tolerant catalytic trans hydrogenation of alkynes. Angew Chem Int Ed Engl (2012) 0.90

Tandem catalytic acrylonitrile cross-metathesis and hydrogenation of nitriles with ruthenium catalysts: direct access to linear α,ω-aminoesters from renewables. ChemSusChem (2012) 0.86

Impaired social decision making in patients with major depressive disorder. Brain Behav (2012) 0.85

sp3 C-H bond activation with ruthenium(II) catalysts and C(3)-alkylation of cyclic amines. J Am Chem Soc (2011) 0.85

A straightforward access to guaiazulene derivatives using palladium-catalysed sp2 or sp3 C-H bond functionalisation. Chem Commun (Camb) (2013) 0.84

Direct arylation of arene C-H bonds by cooperative action of NHcarbene-ruthenium(II) catalyst and carbonate via proton abstraction mechanism. J Am Chem Soc (2008) 0.84

[Cp*(eta2-bipy)(MeCN)RuII][PF6] catalysts for regioselective allylic substitution and characterization of dicationic [Cp*(eta2-bipy)(eta3-allyl)RuIV][PF6]2 intermediates. Angew Chem Int Ed Engl (2003) 0.84

Ruthenium-indenylidene olefin metathesis catalyst with enhanced thermal stability. Chemistry (2010) 0.84

Zirconocene-mediated intermolecular coupling of one molecule of Si-tethered diyne with three molecules of organonitriles: one-pot formation of pyrrolo[3,2-c]pyridine derivatives via cleavage of CN triple bonds of organonitriles. J Am Chem Soc (2004) 0.84

Ruthenium-catalyzed synthesis of alkylidenecyclobutenes via head-to-head dimerization of propargylic alcohols and cyclobutadiene-ruthenium intermediates. Chemistry (2005) 0.83

Particularly interesting new cysteine-histidine rich protein expression in colorectal adenocarcinomas. World J Gastroenterol (2006) 0.83

Synthesis of multiply substituted alkylidene silacyclohexadiene derivatives via palladium-catalyzed insertion of alkynes into alkylidene silacyclobutenes. J Org Chem (2007) 0.83

Dimethyl carbonate: an eco-friendly solvent in ruthenium-catalyzed olefin metathesis transformations. ChemSusChem (2008) 0.83

First enantioselective allylic etherification with phenols catalyzed by chiral ruthenium bisoxazoline complexes. Chem Commun (Camb) (2004) 0.83

Zn(OTf)(2)-catalyzed addition of amines to carbodiimides: efficient synthesis of guanidines and unpredicted formation of Zn-N amido species. Org Biomol Chem (2010) 0.82

Cyclobutene ring-opening of bicyclo[4.2.0]octa-1,6-dienes: access to CF3-substituted 5,6,7,8-tetrahydro-1,7-naphthyridines. J Org Chem (2012) 0.82

Half-sandwich bis(propiolamidinate) rare-earth metal complexes: synthesis, structure and dissociation of the cyclopentadienyl ligand via competition with an amidinate. Dalton Trans (2013) 0.81

One-pot synthesis of pyrrolo[3,2-d]pyridazines and pyrrole-2,3-diones via zirconocene-mediated four-component coupling of Si-tethered diyne, nitriles, and azide. Org Lett (2011) 0.81

Ruthenium(IV) complexes featuring P,O-chelating ligands: regioselective substitution directly from allylic alcohols. Angew Chem Int Ed Engl (2010) 0.80

Ruthenium-catalyzed synthesis of allylic alcohols: boronic acid as a hydroxide source. Chemistry (2008) 0.80

Transition metal catalyzed nucleophilic allylic substitution: activation of allylic alcohols via π-allylic species. Chem Soc Rev (2012) 0.80

Iridium-catalyzed oxidant-free dehydrogenative C-H bond functionalization: selective preparation of N-arylpiperidines through tandem hydrogen transfers. Angew Chem Int Ed Engl (2012) 0.80

NAC is associated with additional alleviation of lung injury induced by invasive pulmonary aspergillosis in a neutropenic model. Acta Pharmacol Sin (2009) 0.79

Light-driven hydrogen generation: efficient iron-based water reduction catalysts. Angew Chem Int Ed Engl (2009) 0.79

Lewis Acid promoted tandem intermolecular Diels-Alder/intramolecular allylation reactions of silyl-substituted 1,3-butadienes leading to multisubstituted 7-norbornenones and related polycyclic compounds. Org Lett (2007) 0.79

Transfer of aryl halide to alkyl halide: reductive elimination of alkylhalide from alkylpalladium halides containing syn-β-hydrogen atoms. Angew Chem Int Ed Engl (2014) 0.78

Palladium-catalysed direct arylation of thiophenes tolerant to silyl groups. Chem Commun (Camb) (2010) 0.78

Ruthenium-containing phosphinesulfonate chelate for the hydrogenation of aryl ketones. Chemistry (2013) 0.78

Preparation and electrophilic cyclization of multisubstituted dienamides leading to cyclic iminoethers. J Org Chem (2005) 0.78

Recent development of synthetic preparation methods for guanidines via transition metal catalysis. Chem Commun (Camb) (2014) 0.78

Synthesis of heteroarylated polyfluorobiphenyls via palladium-catalyzed sequential sp2 C-H bonds functionalizations. J Org Chem (2013) 0.78

Barium dibenzopentalenide as a main-group metal η⁸ complex: facile synthesis from 1,4-dilithio-1,3-butadienes and Ba[N(SiMe₃)₂]₂, structural characterization, and reaction chemistry. Angew Chem Int Ed Engl (2013) 0.78

Metal mediated synthesis of substituted cyclooctatetraenes. Chem Commun (Camb) (2007) 0.78

Palladium-catalyzed one-pot three- or four-component coupling of aryl iodides, alkynes, and amines through C-N bond cleavage: efficient synthesis of indole derivatives. Chemistry (2014) 0.78

Rapid Eye Movement Sleep Behavior Disorder Symptoms Correlate with Domains of Cognitive Impairment in Parkinson's Disease. Chin Med J (Engl) (2016) 0.78

Ene-yne cross-metathesis with ruthenium carbene catalysts. Beilstein J Org Chem (2011) 0.78

Isoquinoline derivatives via stepwise regioselective sp(2) and sp(3) C-H bond functionalizations. J Org Chem (2012) 0.78

Ruthenium-catalyzed reductive amination of allylic alcohols. Org Lett (2011) 0.78

Ruthenium-Catalyzed One-Step Transformation of Propargylic Alcohols into Alkylidene Cyclobutenes: X-ray Characterization of an Ru(eta(3)-cyclobutenyl) Intermediate This work was supported by the CNRS and the Ministère de la Recherche. The authors are grateful to the latter for a PhD grant to J. LP. The authors wish to thank the European Cost Program D17/003/00 and the Région Bretagne for financial support. They are also grateful to A. Bondon for helpful assistance in NMR analysis. Angew Chem Int Ed Engl (2001) 0.78

Dearomatizing anionic cyclization and novel skeletal rearrangement: high yield formation of multiply substituted bicyclic or polycyclic spirocyclopentadienes and phenanthrene derivatives from 4-aryl 1-lithio-1,3-butadienes. J Org Chem (2007) 0.77

Construction of benzosiloles, six- and eight-membered silacyclic skeletons, via a Pd-catalyzed intramolecular Mizoroki-Heck reaction of vinylsilanes. Org Lett (2012) 0.77

Improving sustainability in ene-yne cross-metathesis for transformation of unsaturated fatty esters. ChemSusChem (2010) 0.77

Up-regulation of growth factor independence 1 in endotoxin tolerant macrophages with low secretion of TNF-alpha and IL-6. Inflamm Res (2010) 0.77

Cationic scandium allyl complexes bearing mono(cyclopentadienyl) ligands: synthesis, novel structural variety, and olefin-polymerization catalysis. Chem Asian J (2008) 0.77

Ruthenium-catalyzed synthesis of functionalized 1,3-dienes. Org Lett (2009) 0.77

A new alkaloid and flavonoids from the aerial parts of Euphorbia guyoniana. Nat Prod Commun (2010) 0.77

New ruthenium metathesis catalysts with chelating indenylidene ligands: synthesis, characterization and reactivity. Dalton Trans (2012) 0.77

Cyclopentadiene-phosphine/palladium-catalyzed cleavage of C-N bonds in secondary amines: synthesis of pyrrole and indole derivatives from secondary amines and alkenyl or aryl dibromides. J Am Chem Soc (2012) 0.77

Programmed selective sp2 C-O bond activation toward multiarylated benzenes. Org Lett (2013) 0.77

Facile one-pot construction of polycyclic frameworks using a synergistic Diels-Alder reaction, ene reaction, and allylation reaction strategy. Chem Asian J (2011) 0.76

Autocatalytic intermolecular versus intramolecular deprotonation in C-H bond activation of functionalized arenes by ruthenium(II) or palladium(II) complexes. Chemistry (2013) 0.76

Alkenylzirconocene-mediated preparation of alkenylphosphines. J Org Chem (2007) 0.76

Tandem isomerization/Claisen transformation of allyl homoallyl and diallyl ethers into gamma,delta-unsaturated aldehydes with a new three component catalyst Ru3(CO)12/imidazolinium salt/Cs2CO3. Chem Commun (Camb) (2002) 0.76

Stereoselective synthesis of polysubstituted 2,5-dihydrofurans from reaction of 1,4-dilithio-1,3-dienes with aldehydes. Org Lett (2002) 0.76

GC/MS analysis and antimicrobial activity of the essential oil of fresh leaves of Eucalytus globulus, and leaves and stems of Smyrnium olusatrum from Constantine (Algeria). Nat Prod Commun (2010) 0.76

Ruthenium-catalyzed selective N ,N-diallylation- and N ,N ,O-triallylation of free amino acids. Org Biomol Chem (2009) 0.76

[Epithelial-mesenchymal transition (EMT) and its effect on microRNA expression in lung cancer]. Zhonghua Zhong Liu Za Zhi (2011) 0.76

C-H bond functionalization in water catalyzed by carboxylato ruthenium(II) systems. Angew Chem Int Ed Engl (2010) 0.76

Concomitant monoreduction and hydrogenation of unsaturated cyclic imides to lactams catalyzed by ruthenium compounds. Angew Chem Int Ed Engl (2005) 0.76

N-Heterocyclic carbene-palladium catalysts for the direct arylation of pyrrole derivatives with aryl chlorides. Beilstein J Org Chem (2013) 0.75

Efficient one-pot synthesis of 2,3-dihydropyrimidinthiones via multicomponent coupling of terminal alkynes, elemental sulfur, and carbodiimides. J Am Chem Soc (2009) 0.75

GC/MS analysis and analgesic effect of the essential oil of Matricaria pubescens from Algeria. Nat Prod Commun (2011) 0.75

Efficient one-pot synthesis of N-containing heterocycles by multicomponent coupling of silicon-tethered diynes, nitriles, and isocyanides through intramolecular cyclization of iminoacyl-Zr intermediates. Chemistry (2010) 0.75

Formation of alpha-lithio siloles from silylated 1,4-dilithio-1,3-butadienes: mechanism and applications. Chem Asian J (2010) 0.75

Hydride-induced cleavage of C-O bond in pyran ring of 2-pyranylidene carbene complexes: mechanism and synthetic application. Dalton Trans (2009) 0.75

New sesquiterpene lactone and other constituents from Centaurea sulphurea (Asteraceae). Nat Prod Commun (2010) 0.75

A general cyclocarbonylation of aryl bromides and triflates with acetylenes: palladium-catalyzed synthesis of 3-alkylidenefuran-2-ones. Chemistry (2011) 0.75

One-pot multicomponent synthesis of azaindoles and pyrroles from one molecule of a silicon-tethered diyne and three or two molecules of organonitriles mediated by zirconocene. Chemistry (2009) 0.75

A general palladium-catalyzed carbonylative sonogashira coupling of aryl triflates. Chemistry (2010) 0.75