PubRank

Gerhard Erker

Author PubWeight™ 56.63‹?›

Top papers

Rank Title Journal Year PubWeight™‹?›
1 Frustrated Lewis pairs: metal-free hydrogen activation and more. Angew Chem Int Ed Engl 2010 1.94
2 Bis(diphenylphosphino)acetonitrile: synthesis, ligand properties and application in catalytic carbon-carbon coupling. Dalton Trans 2007 1.62
3 Five-membered metallacyclic allenoids: synthesis and structure of remarkably stable strongly distorted cyclic allene derivatives. Angew Chem Int Ed Engl 2008 1.21
4 Remarkable product diversity in the "self-organized" reaction of deprotonated acetonitrile with chlorophosphines. J Am Chem Soc 2009 1.16
5 Linear alkane polymerization on a gold surface. Science 2011 0.98
6 Rapid intramolecular heterolytic dihydrogen activation by a four-membered heterocyclic phosphane-borane adduct. Chem Commun (Camb) 2007 0.97
7 Reversible metal-free carbon dioxide binding by frustrated Lewis pairs. Angew Chem Int Ed Engl 2009 0.93
8 Exploring CH-activation pathways in bifunctional zirconocene/borane systems. J Am Chem Soc 2004 0.92
9 Control of the coordination structure of organometallic palladium complexes in an apo-ferritin cage. J Am Chem Soc 2008 0.92
10 Frustrated lewis pair mediated hydrogenations. Top Curr Chem 2013 0.92
11 When do interacting atoms form a chemical bond? Spectroscopic measurements and theoretical analyses of dideuteriophenanthrene. Angew Chem Int Ed Engl 2009 0.91
12 Reactions of dimethylzirconocene complexes with a vicinal frustrated P/B Lewis pair. Dalton Trans 2013 0.90
13 Chelate bis(imino)pyridine cobalt complexes: synthesis, reduction, and evidence for the generation of ethene polymerization catalysts by Li+ cation activation. J Am Chem Soc 2005 0.90
14 Reactions of an intramolecular frustrated Lewis pair with unsaturated substrates: evidence for a concerted olefin addition reaction. J Am Chem Soc 2009 0.88
15 Formation of dinuclear titanium and zirconium complexes by olefin metathesis--catalytic preparation of organometallic catalyst systems. Chemistry 2003 0.87
16 Functional-group chemistry of organolithium compounds: photochemical [2+2] cycloaddition of alkenyl-substituted lithium cyclopentadienides. Angew Chem Int Ed Engl 2006 0.86
17 Formation of a bifunctional zirconocene complex that favours intramolecular -B(C6F5)2 addition to a Cp ring over sigma-ligand abstraction. Chem Commun (Camb) 2004 0.86
18 Metal-free catalytic hydrogenation of enamines, imines, and conjugated phosphinoalkenylboranes. Angew Chem Int Ed Engl 2008 0.86
19 1,1-Carboboration. Chem Commun (Camb) 2011 0.85
20 Formation of a unique ansa-metallocene framework by intramolecular photochemical [2+2] cycloaddition of bis(2-alkenylindenyl)zirconium complexes. Angew Chem Int Ed Engl 2004 0.85
21 The mechanism of dihydrogen activation by frustrated Lewis pairs revisited. Angew Chem Int Ed Engl 2010 0.85
22 Heterolytic dihydrogen activation with the 1,8-bis(diphenylphosphino)naphthalene/B(C6F5)3 pair and its application for metal-free catalytic hydrogenation of silyl enol ethers. Chem Commun (Camb) 2008 0.84
23 N,N-addition of frustrated Lewis pairs to nitric oxide: an easy entry to a unique family of aminoxyl radicals. J Am Chem Soc 2012 0.83
24 Noninteracting, vicinal frustrated P/B-Lewis pair at the norbornane framework: synthesis, characterization, and reactions. J Am Chem Soc 2013 0.83
25 Dibenzopentalenes from B(C6F5)3-induced cyclization reactions of 1,2-bis(phenylethynyl)benzenes. Angew Chem Int Ed Engl 2013 0.83
26 Formylborane formation with frustrated Lewis pair templates. Angew Chem Int Ed Engl 2013 0.83
27 Intramolecular frustrated lewis pairs: formation and chemical features. Top Curr Chem 2013 0.82
28 Internal adduct formation of active intramolecular C4-bridged frustrated phosphane/borane Lewis pairs. J Am Chem Soc 2014 0.82
29 Carbon-carbon bond activation by 1,1-carboboration of internal alkynes. J Am Chem Soc 2010 0.81
30 Reaction of frustrated Lewis pairs with conjugated ynones-selective hydrogenation of the carbon-carbon triple bond. Angew Chem Int Ed Engl 2011 0.81
31 Polymorphism in P,P-[3]ferrocenophanes: insights from an NMR crystallographic approach. Dalton Trans 2014 0.81
32 Facile carbon monoxide reduction at intramolecular frustrated phosphane/borane Lewis pair templates. Angew Chem Int Ed Engl 2013 0.80
33 Remarkably variable reaction modes of frustrated Lewis pairs with non-conjugated terminal diacetylenes. Chem Commun (Camb) 2010 0.80
34 Imidazolin-2-iminato titanium complexes: synthesis, structure and use in ethylene polymerization catalysis. Dalton Trans 2005 0.80
35 Reactions of a cationic geminal Zr+/P pair with small molecules. J Am Chem Soc 2013 0.80
36 Formation of cyclic allenes and cumulenes by cooperative addition of frustrated Lewis pairs to conjugated enynes and diynes. Angew Chem Int Ed Engl 2010 0.80
37 Surface-mounted molecular rotors with variable functional groups and rotation radii. Nano Lett 2009 0.80
38 Cyclizations via frustrated Lewis pairs: Lewis acid induced intramolecular additions of amines to olefins and alkynes. Chemistry 2010 0.80
39 Benzannulation of heterocyclic frameworks by 1,1-carboboration pathways. J Org Chem 2015 0.80
40 Borata-alkene derivatives conveniently made by frustrated Lewis pair chemistry. Dalton Trans 2013 0.80
41 Reaction of aminodihydropentalenes with HB(C6F5)2: the crucial role of dihydrogen elimination. J Am Chem Soc 2011 0.79
42 Bis("ferrocene-saliminato") group 4 metal complexes: synthesis, structural features and use in homogenous Ziegler-Natta polymerization catalysis. Dalton Trans 2009 0.79
43 Capture of NO by a Frustrated Lewis Pair: a new type of persistent N-oxyl radical. Angew Chem Int Ed Engl 2011 0.79
44 Addition reactions to the intramolecular mesityl2P-CH2-CH2-B(C6F5)2 frustrated Lewis pair. Dalton Trans 2010 0.79
45 Structural importance of secondary interactions in molecules: origin of unconventional conformations of phosphine-borane adducts. Chemistry 2008 0.78
46 Functional group chemistry at intramolecular frustrated Lewis pairs: substituent exchange at the Lewis acid site with 9-BBN. Dalton Trans 2013 0.78
47 Catalytic hydrogenation of sensitive organometallic compounds by antagonistic N/B Lewis pair catalyst systems. J Am Chem Soc 2009 0.78
48 Chemistry of a geminal frustrated Lewis pair featuring electron withdrawing C6F5 substituents at both phosphorus and boron. Chem Commun (Camb) 2011 0.78
49 The 1,1-carboboration of bis(alkynyl)phosphanes as a route to phosphole compounds. Angew Chem Int Ed Engl 2012 0.78
50 Exploring the limits of frustrated Lewis pair chemistry with alkynes: detection of a system that favors 1,1-carboboration over cooperative 1,2-P/B-addition. Chem Asian J 2010 0.78
51 Borole formation by 1,1-carboboration. J Am Chem Soc 2013 0.78
52 The B(C6F5)3 boron Lewis acid route to arene-annulated pentalenes. Chem Asian J 2014 0.78
53 Carbon-carbon bond cleavage by strongly electrophilic boranes. Chemistry 2010 0.78
54 Noncovalent insertion of ferrocenes into the protein shell of apo-ferritin. Chem Commun (Camb) 2008 0.78
55 Enamine/butadienylborane cycloaddition in the frustrated Lewis pair regime. Org Biomol Chem 2015 0.78
56 1,1-carboboration of 1-alkynes: a conceptual alternative to the hydroboration reaction. Org Lett 2010 0.78
57 Direct synthesis of a geminal zwitterionic phosphonium/hydridoborate system--developing an alternative tool for generating frustrated Lewis pair hydrogen activation systems. Org Biomol Chem 2015 0.77
58 Molecular-template-mediated chemical decoration. Chemphyschem 2003 0.77
59 Carbonylation reactions of intramolecular vicinal frustrated phosphane/borane Lewis pairs. J Am Chem Soc 2013 0.77
60 Frustrated Lewis pair modification by 1,1-carboboration: disclosure of a phosphine oxide triggered nitrogen monoxide addition to an intramolecular P/B frustrated Lewis pair. J Am Chem Soc 2014 0.77
61 1,1-Carboboration route to substituted naphthalenes. Org Lett 2012 0.77
62 Incorporation of organometallic Ru complexes into apo-ferritin cage. Dalton Trans 2010 0.77
63 Reaction of a bridged frustrated Lewis pair with nitric oxide: a kinetics study. J Am Chem Soc 2013 0.77
64 Reaction of an "invisible" frustrated N/B Lewis pair with dihydrogen. Chem Asian J 2012 0.77
65 Metal-free dihydrogen activation chemistry: structural and dynamic features of intramolecular P/B pairs. Dalton Trans 2009 0.77
66 1,1-Alkenylboration of diarylphosphino-enynes: convenient synthetic entry to vicinal P/B Lewis pairs at extended conjugated π-frameworks. Org Biomol Chem 2015 0.77
67 CO2 and formate complexes of phosphine/borane frustrated Lewis pairs. Chemistry 2011 0.77
68 Nitrile insertion into a boryl-substituted five-membered zirconacycloallenoid: unexpected formation of a zwitterionic boratirane product. Chem Commun (Camb) 2009 0.77
69 Reaction of strongly electrophilic alkenylboranes with phosphanylalkynes: rare examples of intermolecular 1,1-alkenylboration reactions. Chem Commun (Camb) 2013 0.77
70 Structure and dynamic features of an intramolecular frustrated Lewis pair. Chemistry 2010 0.77
71 Phosphirenium-borate zwitterion: formation in the 1,1-carboboration reaction of phosphinylalkynes. Chem Commun (Camb) 2011 0.77
72 The frustrated Lewis pair induced formation of a pentafulvene [6 + 4] cycloaddition product. Chem Commun (Camb) 2011 0.76
73 P-C bond activation chemistry: evidence for 1,1-carboboration reactions proceeding with phosphorus-carbon bond cleavage. J Am Chem Soc 2011 0.76
74 Formation of a dihydroborole by catalytic isomerization of a divinylborane. Dalton Trans 2014 0.76
75 Stabilized borata-alkene formation: structural features, reactions and the role of the counter cation. Dalton Trans 2015 0.76
76 Electronic control in frustrated Lewis pair chemistry: adduct formation of intramolecular FLP systems with -P(C(6)F(5))(2) Lewis base components. Dalton Trans 2013 0.76
77 Formation of an organometallic ladderane derivative by dynamic topochemical reaction control. Angew Chem Int Ed Engl 2006 0.75
78 Ansa-metallocene polymerization catalysts derived from [2+2]cycloaddition reactions of bis(1-methylethenyl-cyclopentadienyl)zirconium systems. Proc Natl Acad Sci U S A 2006 0.75
79 CO-Reduction Chemistry: Reaction of a CO-Derived Formylhydridoborate with Carbon Monoxide, with Carbon Dioxide, and with Dihydrogen. J Am Chem Soc 2017 0.75
80 Ring-closing metathesis of sterically congested functionalized zirconocenes-ethene polymerization catalysts derived from related bridged and open metallocenes. Dalton Trans 2009 0.75
81 Synthesis of [3]ferrocenophane-bridged Cp-amido zirconium complexes and ansa-zirconocene complexes and their use in catalytic polymerisation reactions. Dalton Trans 2011 0.75
82 Preparation of dithienylphospholes by 1,1-carboboration. Chemistry 2014 0.75
83 Tetradecylferrocene: ordered molecular array of an organometallic amphiphile in the crystal and in a two-dimensional assembled structure on a surface. Langmuir 2006 0.75
84 Reactivity of an intramolecular fluorophosphonium fluoroborate. Chemistry 2014 0.75
85 Branched wires of CdTe nanocrystals using amphiphilic molecules as templates. Small 2005 0.75
86 Structural Features of [(CpPPh2AuCl)2ZrCl2]: exploring the limits of aurophilic interactions. Chem Asian J 2008 0.75
87 Facile cyclometalation reactions of Cp-zirconium complexes with weakly Lewis acidic pendent boron functionalities. Chemistry 2009 0.75
88 Photochemical isomerisation of boryl-substituted silole derivatives. Chem Commun (Camb) 2010 0.75
89 Reaction of frustrated Lewis pairs with ketones and esters. Chem Asian J 2012 0.75
90 Catalytic Abilities of [(C6F5)2BR] (R=NC4H4 and NC4H8) deduced from experimental and theoretical charge-density investigations. Chemistry 2009 0.75
91 Selective synthesis of the 2-hydroxyferrocene-aldimine enantiomers--extended planar chiral analogues of the "flat" salicylaldimine ligand family. Dalton Trans 2009 0.75
92 Formation of unsaturated vicinal Zr(+)/P frustrated Lewis pairs by the unique 1,1-carbozirconation reactions. J Am Chem Soc 2014 0.75
93 Unusual product formation in a 1,1-carboboration reaction. Chem Commun (Camb) 2015 0.75
94 Thiophene synthesis via 1,1-carboboration. Chem Commun (Camb) 2015 0.75
95 Ethene/alkyne exchange reaction at an intramolecular frustrated Lewis pair. Chem Commun (Camb) 2014 0.75
96 TEMPO-mediated homocoupling of aryl Grignard reagents: mechanistic studies. Org Biomol Chem 2015 0.75
97 Remarkable behavior of a bifunctional alkynylborane zirconocene complex toward donor ligands and acetylenes. J Am Chem Soc 2013 0.75
98 Reaction of a 6-dimethylaminopentafulvene with the Mes2PCH2CH2B(C6F5)2 frustrated Lewis pair. Chemistry 2012 0.75
99 Mastering the third dimension of salicylaldimine-type ligand systems: development of a convenient route to bis("ferrocene-saliminato")zirconium chemistry. Chemistry 2008 0.75
100 Formation and structural characterization of a five-membered zirconacycloallenoid. Dalton Trans 2013 0.75
101 Phosphole formation by 1,1-carboboration - reactions of bis-alkynyl phosphanes with a frustrated P/B Lewis pair. Dalton Trans 2015 0.75
102 Reaction of five-membered zirconacycloallenoids with the strong Lewis acid B(C6F5)3. Dalton Trans 2014 0.75
103 Indirect "no-bond" ³¹P···³¹P spin-spin couplings in P,P-[3]ferrocenophanes: insights from solid-state NMR spectroscopy and DFT calculations. J Phys Chem A 2014 0.75
104 Formation and reactions of metal-metal bonded heterobimetallic (C5H4PR2)-bridged (Zr-Ir) and (Zr-Rh) complexes: evidence for the participation of metal hydride intermediates. Dalton Trans 2004 0.75
105 Synthesis of [(π-cyano-P-nacnac)Cp] and [(π-cyano-nacnac)Cp]-zirconium complexes, and their remote activation for ethylene polymerization. Dalton Trans 2011 0.75
106 Formation of cyclodimeric (sp(2)-C(1))-bridged Cp/-oxido ("CpC(1)O"M(IV)X(2)) group 4 metal Ziegler-Natta catalyst systems--how important is the "constrained geometry" effect? J Am Chem Soc 2002 0.75
107 New insights into frustrated Lewis pairs: structural investigations of intramolecular phosphane-borane adducts by using modern solid-state NMR techniques and DFT calculations. J Am Chem Soc 2012 0.75
108 Unusual carbamate-directed CH-activation at an annulated ferrocenophane framework. Dalton Trans 2011 0.75
109 Multilevel supramolecular architectures self-assembled on metal surfaces. ACS Nano 2010 0.75
110 Cooperation through the decades. Chem Asian J 2012 0.75
111 1,1-carbozirconation: unusual reaction of an alkyne with a methyl zirconocene cation and subsequent frustrated lewis pair like reactivity. Angew Chem Int Ed Engl 2013 0.75
112 Hydrogen activation by an intramolecular boron Lewis acid/zirconocene pair. Angew Chem Int Ed Engl 2012 0.75
113 Development of a convenient new synthetic route to [3]ferrocenophanones. Dalton Trans 2006 0.75
114 Developing phospha-Stork chemistry induced by a borane Lewis acid. Angew Chem Int Ed Engl 2014 0.75
115 Evidence for a rapid degenerate hetero-Cope-type rearrangement in [Cp*W(S)2S-CH2-CH=CH2]. Chem Asian J 2009 0.75
116 Oligoethylene chains terminated by ferrocenyl end groups: synthesis, structural properties, and two-dimensional self-assembly on surfaces. Chemistry 2006 0.75
117 Unusual pathway taken in the reaction of bis(alkynyl)diisopropylaminoboranes with B(C6F5)3. Chem Asian J 2013 0.75
118 Controlling two-phase self-assembly of an adenine derivative on HOPG via kinetic effects. Chem Commun (Camb) 2014 0.75
119 Stereo-electronic interaction in complex molecules: cyclopropyl conjugation with Lewis acidic centres across connecting carbon-carbon triple bonds. Chem Commun (Camb) 2006 0.75
120 Carbohydrate-metallocene conjugates: selective formation of a zirconadioxacyclopentane-type dimer from the reaction of a bis(enolate)ZrCp2 reagent with a glucofuranoside derivative. Dalton Trans 2006 0.75
121 Zirconocene complexes bearing novel 3-dimethylamino-1,2-dihydropentalene derived ligand systems. Dalton Trans 2010 0.75
122 Temperature-dependent self-assembly of adenine derivative on HOPG. Langmuir 2013 0.75
123 Splitting of dihydrogen by five-membered zirconacycloallenoids: a novel pathway to conjugated diene zirconocene complexes. Chem Commun (Camb) 2012 0.75
124 Formation of a butadienenickel-based zwitterionic single-component catalyst for ethylene polymerization: an alternative activation pathway for homogeneous Ziegler-Natta catalysts of late transition metals. Angew Chem Int Ed Engl 2002 0.75
125 Five-membered zirconacycloallenoids: synthesis and characterization of members of a unique class of internally metal-stabilized bent allenoid compounds. J Am Chem Soc 2009 0.75
126 Binding of molecular magnesium hydrides to a zirconocene-enyne template. Angew Chem Int Ed Engl 2012 0.75
127 (Butadiene)metallocene/B(C6F5)3 pathway to catalyst systems for stereoselective methyl methacrylate polymerization: evidence for an anion dependent metallocene catalyzed polymerization process. J Am Chem Soc 2004 0.75
128 Reaction of diphenylphosphanylacetylene with RB(C6F5)2 reagents: evidence for a remarkable sequence of synergistic frustrated Lewis pair addition reactions. Inorg Chem 2013 0.75
129 Anomalous Staudinger reaction at intramolecular frustrated P-B Lewis pair frameworks. Chem Commun (Camb) 2012 0.75
130 Thymine and adenine tetrads formed on anisotropic metal surfaces. Small 2014 0.75
131 Formation, structural characterization, and reactions of a unique cyclotrimeric vicinal Lewis pair containing (C6F5)2P-Lewis base and (C6F5)BH-Lewis acid components. Dalton Trans 2014 0.75
132 Electronic tuning of thiazolyl-capped π-conjugated compounds via a coordination/cyclization protocol with B(C6F5)3. Org Lett 2010 0.75
133 Reactions of a methylzirconocene cation with phosphinoalkynes: an alternative pathway for generating Cp2Zr(II) systems. Chem Commun (Camb) 2012 0.75
134 Frustrated Lewis pair addition to conjugated diynes: formation of zwitterionic 1,2,3-butatriene derivatives. Dalton Trans 2012 0.75
135 Radical frustrated Lewis pairs. Top Curr Chem 2013 0.75
136 Unusual borane addition to conjugated dienylphosphanes under frustrated Lewis pair conditions. Dalton Trans 2015 0.75
137 Functionalized phosphorus analogues of the beta-diketiminato ligand systems: bis(N-arylphosphinimino)acetonitrile-derived complexes of rhodium and iridium. Dalton Trans 2008 0.75
138 1,2-Olefin addition of a frustrated amine-borane Lewis pair. Chem Commun (Camb) 2009 0.75
139 Facile formation of five-membered N-heterocyclic zirconacycloallenoids. Dalton Trans 2012 0.75
140 A 1,8-naphthylene-bridged bis(indenyl)zinc THF adduct: formation and structure of an ansa-zincocene derivative. Angew Chem Int Ed Engl 2007 0.75
141 α-Hydroxymethylation of pyridines at a frustrated Lewis pair template. Chemistry 2014 0.75