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1
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An activating mutant of Rac1 that fails to interact with Rho GDP-dissociation inhibitor stimulates membrane ruffling in mammalian cells.
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Biochem J
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2004
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0.99
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2
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2-(Acetoxymethyl)buta-2,3-dienoate, a versatile 1,4-biselectrophile for phosphine-catalyzed (4 + n) annulations with 1,n-Bisnucleophiles (n = 1, 2).
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J Am Chem Soc
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2010
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0.93
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3
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An activating mutant of Cdc42 that fails to interact with Rho GDP-dissociation inhibitor localizes to the plasma membrane and mediates actin reorganization.
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Exp Cell Res
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2004
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0.86
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4
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Palladium-catalyzed cycloisomerizations of (Z)-1-iodo-1,6-dienes: iodine atom transfer and mechanistic insight to alkyl iodide reductive elimination.
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J Am Chem Soc
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2011
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0.84
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5
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Rhodium-catalyzed asymmetric arylative cyclization of meso-1,6-dienynes leading to enantioenriched cis-hydrobenzofurans.
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Angew Chem Int Ed Engl
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2013
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0.82
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6
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Enantioselective amine-catalyzed [4+2] annulations of allenoates and oxo-dienes: an asymmetric synthesis of dihydropyrans.
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Angew Chem Int Ed Engl
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2011
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0.82
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7
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Tertiary amine-triggered cascade S(N)2/cycloaddition: an efficient construction of complex azaheterocycles under mild conditions.
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Org Lett
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2012
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0.80
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8
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Palladium-catalyzed tandem reaction of yne-propargylic carbonates with boronic acids: a simple method for the synthesis of fused aromatic rings through allene-mediated electrocyclization.
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Chemistry
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2004
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0.79
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9
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Palladium(0)-catalyzed iminohalogenation of alkenes: synthesis of 2-halomethyl dihydropyrroles and mechanistic insights into the alkyl halide bond formation.
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Angew Chem Int Ed Engl
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2015
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0.78
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10
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PPh3-catalyzed (3 + 3) annulations of 5-acetoxypenta-2,3-dienoate with 1C,3O-bisnucleophiles: facile entry to stable monocyclic 2H-pyrans.
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Org Lett
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2012
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0.78
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11
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Copper-catalyzed aromatic C-H bond cyanation by C-CN bond cleavage of inert acetonitrile.
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Chemistry
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2013
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0.78
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12
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Phosphine-catalyzed [3+2] annulations of γ-functionalized butynoates and 1C,3O-bisnucleophiles: highly selective reagent-controlled pathways to polysubstituted furans.
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Org Lett
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2011
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0.77
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13
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Rhodium-catalyzed carbocyclization and chlorosulfonylation of 1,6-enynes with sulfonyl chlorides.
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Chemistry
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2013
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0.77
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14
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PPh3-catalyzed reactions of alkyl propiolates with N-tosylimines: a facile synthesis of alkyl 2-[aryl(tosylimino)methyl]acrylate and an insight into the reaction mechanism.
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Chemistry
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2010
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0.77
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15
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Rhodium-catalyzed cycloaddition of 1,6-enynes with 2-bromophenylboronic acids: synthesis of a multi-substituted dihydronaphthalene scaffold.
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Chem Commun (Camb)
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2009
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0.76
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16
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Amine-catalyzed (3+n) annulations of 2-(acetoxymethyl)buta-2,3-dienoates with 1,n-bisnucleophiles (n = 3-5).
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Chem Commun (Camb)
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2010
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0.75
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17
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Palladium-catalyzed Heck-type reaction of oxime ether bearing a pendant vinyl iodide moiety.
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Chem Commun (Camb)
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2011
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0.75
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|
18
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Amine-catalyzed formal (3 + 3) annulations of 2-(acetoxymethyl)buta-2,3-dienoate with sulfur ylides: synthesis of 4H-pyrans bearing a vinyl sulfide group.
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Chem Commun (Camb)
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2012
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0.75
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19
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PPh3-catalyzed [2 + 2 + 2] and [4 + 2] annulations: synthesis of highly substituted 1,2-dihydropyridines (DHPs).
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Chem Commun (Camb)
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2009
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0.75
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20
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Pd(0)-catalyzed iodoalkynation of norbornene scaffolds: the remarkable solvent effect on reaction pathway.
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Org Lett
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2011
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0.75
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|
21
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Rh(I)-catalyzed formal [2+2+2] cycloadditions of 1,6-diynes with potassium (Z)-(2-bromovinyl)trifluoroborate: a new strategy and a facile entry to polysubstituented benzene derivatives.
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Chem Commun (Camb)
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2010
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0.75
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22
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Amine-promoted asymmetric (4+2) annulations for the enantioselective synthesis of tetrahydropyridines: a traceless and recoverable auxiliary strategy.
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Angew Chem Int Ed Engl
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2013
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0.75
|
|
23
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Rhodium-catalyzed activation of C(sp3)-X (X = Cl, Br) bond: an intermolecular halogen exchange case.
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Org Lett
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2010
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0.75
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24
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Tertiary amine-catalyzed (4 + 2) annulations of δ-acetoxy allenoates: synthesis of multisubstituted 4H-pyran and 4H-chromene.
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Org Lett
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2015
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0.75
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25
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Enantioselective construction of quaternary tetrahydropyridines by palladium-catalyzed vinylborylation of alkenes.
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Chem Commun (Camb)
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2017
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0.75
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26
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Palladium-catalyzed tandem cyclization/Suzuki coupling of 1,6-enynes: reaction scope and mechanism.
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J Org Chem
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2005
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0.75
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