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Ammonia formation by metal-ligand cooperative hydrogenolysis of a nitrido ligand.
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Nat Chem
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2011
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1.58
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2
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Total synthesis of meloscine by a [2+2]-photocycloaddition/ring-expansion route.
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Chemistry
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2009
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1.51
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3
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Pd(II)-catalyzed regioselective 2-alkylation of indoles via a norbornene-mediated C-H activation: mechanism and applications.
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J Am Chem Soc
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2012
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1.12
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4
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Efficient assembly of iminodicarboxamides by a "truly" four-component reaction.
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Angew Chem Int Ed Engl
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2012
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1.03
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5
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Isolation, crystal and solution structure determination, and biosynthesis of tubulysins--powerful inhibitors of tubulin polymerization from myxobacteria.
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Angew Chem Int Ed Engl
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2004
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1.02
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6
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Polycyclic indole alkaloid-type compounds by MCR.
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Chem Commun (Camb)
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2009
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1.01
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7
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Mono- and bis- methyltrioxorhenium(VII) complexes with salen ligands: synthesis, properties, applications.
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Inorg Chem
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2009
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1.00
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8
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Enantioselective Lewis acid catalysis in intramolecular [2+2] photocycloaddition reactions of coumarins.
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Angew Chem Int Ed Engl
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2010
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0.96
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9
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Tritylamine as an ammonia surrogate in the Ugi tetrazole synthesis.
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Org Lett
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2013
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10
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MCR synthesis of praziquantel derivatives.
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Chem Biol Drug Des
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2012
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0.94
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11
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Crystal-packing-induced antiferromagnetic interactions of metallocenes: cyanonickelocenes, -cobaltocenes, and -ferrocenes.
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Chemistry
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2008
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0.93
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12
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Solid-state NMR of a paramagnetic DIAD-FeII catalyst: sensitivity, resolution enhancement, and structure-based assignments.
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J Am Chem Soc
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2006
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13
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Halogen-bond-induced activation of a carbon-heteroatom bond.
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Angew Chem Int Ed Engl
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2011
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14
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Polycyclic compounds by Ugi-Pictet-Spengler sequence.
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J Org Chem
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2010
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15
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Organocatalysis by neutral multidentate halogen-bond donors.
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Angew Chem Int Ed Engl
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2013
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0.90
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16
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A defined N-heterocyclic carbene complex for the palladium-catalyzed Suzuki cross-coupling of aryl chlorides at ambient temperatures.
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Angew Chem Int Ed Engl
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2002
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0.89
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17
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Mechanistic insights into heterogeneous zinc dicarboxylates and theoretical considerations for CO2-epoxide copolymerization.
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J Am Chem Soc
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2011
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0.86
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18
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Highly enantioselective Diels-Alder reaction of a photochemically generated o-quinodimethane with olefins.
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Angew Chem Int Ed Engl
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2003
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0.85
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19
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Massive parallel catalyst screening: toward asymmetric MCRs.
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Org Lett
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2003
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20
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Various cyclization scaffolds by a truly Ugi 4-CR.
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Org Biomol Chem
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2013
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21
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Octahedral bipyridine and bipyrimidine dioxomolybdenum(VI) complexes: characterization, application in catalytic epoxidation, and density functional mechanistic study.
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Chemistry
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2002
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0.83
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22
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Short and diverse route toward complex natural product-like macrocycles.
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Org Lett
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2003
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0.82
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23
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A photocycloaddition/fragmentation approach toward the 3,12-dioxatricyclo[8.2.1.0(6,13)]tridecane skeleton of terpenoid natural products.
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Org Lett
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2011
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24
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A universal isocyanide for diverse heterocycle syntheses.
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Org Lett
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2014
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One-pot synthesis of 2-amino-indole-3-carboxamide and analogous.
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ACS Comb Sci
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2010
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26
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Isothermal calorimetric titrations on charge-assisted halogen bonds: role of entropy, counterions, solvent, and temperature.
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J Am Chem Soc
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2012
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0.82
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Nonclassical vs classical metal...H3C-C interactions: accurate characterization of a 14-electron ruthenium(II) system by neutron diffraction, database analysis, solution dynamics, and DFT studies.
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J Am Chem Soc
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2004
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Diastereotopos-differentiation in the Rh-catalyzed amination of benzylic methylene groups in the α-position to a stereogenic center.
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J Am Chem Soc
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2012
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0.81
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New benzo[h]quinoline-based ligands and their pincer Ru and Os complexes for efficient catalytic transfer hydrogenation of carbonyl compounds.
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Chemistry
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2008
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30
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Imidazolin-2-iminato titanium complexes: synthesis, structure and use in ethylene polymerization catalysis.
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Dalton Trans
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2005
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0.80
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31
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Novel T-shaped 14-electron platinum(II) complexes stabilized by one agostic interaction.
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Angew Chem Int Ed Engl
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2003
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0.80
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32
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Square-planar iridium(II) and iridium(III) amido complexes stabilized by a PNP pincer ligand.
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Angew Chem Int Ed Engl
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2011
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33
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Intramolecular [2+2] photocycloaddition reactions as an entry to the 2-oxatricyclo[4.2.1.0(4,9)]nonan-3-one skeleton of lactiflorin.
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Chem Asian J
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2012
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34
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A square-planar ruthenium(II) complex with a low-spin configuration.
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Angew Chem Int Ed Engl
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2010
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Titanium complexes with imidazolin-2-iminato ligands.
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Chem Commun (Camb)
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2004
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36
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Tricycles by a new Ugi variation and Pictet-Spengler reaction in one pot.
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Chemistry
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2013
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37
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Enantioselective [6pi]-photocyclization reaction of an acrylanilide mediated by a chiral host. Interplay between enantioselective ring closure and enantioselective protonation.
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J Org Chem
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2003
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0.78
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38
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Novel nonpeptidic inhibitors of HIV-1 protease obtained via a new multicomponent chemistry strategy.
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Bioorg Med Chem Lett
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2004
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39
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N-heterocyclic carbenes of iridium(I): ligand effects on the catalytic activity in transfer hydrogenation.
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Dalton Trans
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2009
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0.77
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40
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Stereospecific polymerization of isoprene with molecular and MCM-48-grafted lanthanide(III) tetraalkylaluminates.
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Angew Chem Int Ed Engl
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2004
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0.77
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41
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Stereoselective allyl transfer to chiral alpha-methoxycarbaldehydes: a model study related to the C-9/C-15 fragment of geldanamycin.
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Bioorg Med Chem
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2006
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0.77
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42
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Hydrogen-bond mediated regio- and enantioselectivity in a C-H amination reaction catalysed by a supramolecular Rh(II) complex.
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Chem Commun (Camb)
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2013
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0.76
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43
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A cyclen-based tetraphosphinate chelator for the preparation of radiolabeled tetrameric bioconjugates.
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Chemistry
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2013
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0.76
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44
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4,4'-Azobis(halopyridinium) derivatives: strong multidentate halogen-bond donors with a redox-active core.
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Chemistry
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2012
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0.76
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45
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2,30-Bis(10H-indole) heterocycles: New p53/MDM2/MDMX antagonists.
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Bioorg Med Chem Lett
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46
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Square-planar ruthenium(II) complexes: control of spin state by pincer ligand functionalization.
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Chemistry
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2014
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0.76
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47
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Bi(OTf)3-catalyzed diastereoselective S(N)1-type reactions of chiral propargylic acetates.
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Angew Chem Int Ed Engl
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2008
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0.76
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48
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5-Iodo-1,2,3-triazolium-based multidentate halogen-bond donors as activating reagents.
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Chem Commun (Camb)
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2012
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0.76
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49
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Receptor-bound conformation of cilengitide better represented by its solution-state structure than the solid-state structure.
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Chemistry
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2014
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0.76
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50
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CNN pincer ruthenium catalysts for hydrogenation and transfer hydrogenation of ketones: experimental and computational studies.
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Chemistry
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2014
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Addressing association entropy by reconstructing guanidinium anchor groups for anion binding: design, synthesis, and host-guest binding studies in polar and protic solutions.
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Chemistry
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2008
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0.76
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52
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Strong hydrogen bonds in the ionic pair (1,3-diisopropyl-4,5-dimethyl-4-imidazolin-2-ylidene)ammonium trichloro(1,3-diisopropyl-4,5-dimethyl-4-imidazolin-2-ylideneamine)iron(II).
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Acta Crystallogr C
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2006
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0.76
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53
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Highly substituted pyrrolidinones and pyridones by 4-CR/2-CR sequence.
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Org Lett
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2004
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0.76
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54
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A carbocyclic carbene as an efficient catalyst ligand for C-C coupling reactions.
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Angew Chem Int Ed Engl
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2006
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0.76
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55
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Cyanoacetamides (IV): versatile one-pot route to 2-quinoline-3-carboxamides.
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ACS Comb Sci
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2012
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0.76
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Toward molecular recognition: three-point halogen bonding in the solid state and in solution.
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J Am Chem Soc
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2014
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New MCRs: the first 4-component reaction leading to 2,4-disubstituted thiazoles.
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Mol Divers
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2003
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0.76
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Complete control of regioselectivity in the intramolecular [2 + 2] photocycloaddition of 2-alkenyl-3(2H)-furanones by the length of the side chain.
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J Org Chem
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2003
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0.75
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59
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Redetermination of [Gd(NO₃)₃(H₂O)₄]·2H₂O.
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Acta Crystallogr Sect E Struct Rep Online
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2012
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0.75
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60
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Enantioselective access to bicyclo[4.2.0]octanes by a sequence of [2+2] photocycloaddition/reduction/fragmentation.
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Chemistry
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2013
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0.75
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61
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Intramolecular [2+2] photocycloaddition of substituted isoquinolones: enantioselectivity and kinetic resolution induced by a chiral template.
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Angew Chem Int Ed Engl
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2011
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0.75
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62
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Dicarboxylate-bridged (Mo2)n (n = 2, 3, 4) paddle-wheel complexes: potential intermediate building blocks for metal-organic frameworks.
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Dalton Trans
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2011
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0.75
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63
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Enantioselectivity in visible light-induced, singlet oxygen [2+4] cycloaddition reactions (type II photooxygenations) of 2-pyridones.
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Chem Commun (Camb)
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2012
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0.75
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64
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Copper(II) complexes incorporating poly/perfluorinated alkoxyaluminate-type weakly coordinating anions: syntheses, characterization and catalytic application in stereoselective olefin aziridination.
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Dalton Trans
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2011
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0.75
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65
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Grafting of [Mn(CH2tBu)2(tmeda)] on silica and comparison with its reaction with a silsesquioxane.
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Chemistry
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2005
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0.75
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66
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Studies on bis(halogeno) dioxomolybdenum(VI)-bipyridine complexes: synthesis and catalytic activity.
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Dalton Trans
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2009
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0.75
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67
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Synthesis and catalytic application of octahedral lewis base adducts of dichloro and dialkyl dioxotungsten(VI).
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Inorg Chem
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2002
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0.75
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68
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Biologically relevant O,S-donor compounds. Synthesis, molybdenum complexation and xanthine oxidase inhibition.
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Dalton Trans
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2008
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0.75
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69
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Homoleptic rare-earth metal(III) tetramethylaluminates: structural chemistry, reactivity, and performance in isoprene polymerization.
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Chemistry
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2007
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0.75
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70
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Corrigendum: Multiple Multidentate Halogen Bonding in Solution, in the Solid State, and in the (Calculated) Gas Phase.
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Chemistry
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71
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Regioselective Si-C bond activation in silicon-bridged ansa-cycloheptatrienyl-cyclopentadienyl complexes.
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Chem Commun (Camb)
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2005
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0.75
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72
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Highly reactive polyisobutenes prepared with manganese(II) complexes as initiators.
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Angew Chem Int Ed Engl
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2003
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73
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Palladium N(CH2CH2P(i)Pr2)2-dialkylamides: synthesis, structural characterization, and reactivity.
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Inorg Chem
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2009
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74
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Synthesis of 2,2,5,5-tetrasubstituted 1,4-dioxa-2,5-disilacyclohexanes via organotin(IV)-catalyzed transesterification of (acetoxymethyl)alkoxysilanes.
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Chemistry
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2013
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0.75
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75
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S(N)1-type substitution reactions of N-protected β-hydroxytyrosine esters: stereoselective synthesis of β-aryl and β-alkyltyrosines.
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Chem Asian J
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2012
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76
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Synthesis and characterisation of chelated cationic ReI(CO)3bis(NHC)(WCA) complexes.
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Dalton Trans
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2014
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77
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Ansa-bridged eta5-cyclopentadienyl molybdenum and tungsten complexes: synthesis, structure and application in olefin epoxidation.
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Dalton Trans
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2007
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0.75
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78
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Hydrogen bond induced enantioselectivity in Mn(salen)-catalysed sulfoxidaton reactions.
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Chem Commun (Camb)
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2011
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0.75
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79
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Synthesis and comparison of transition metal complexes of abnormal and normal tetrazolylidenes: a neglected ligand species.
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Inorg Chem
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2013
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80
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Loop shaped dicarboxylate-bridged dimolybdenum(II) bisphosphine compounds--a rational synthesis.
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Dalton Trans
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2014
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81
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Indenyl ring slippage in crown thioether complexes [IndMo(CO)2L]+ and C-S activation of trithiacyclononane: experimental and theoretical studies.
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Dalton Trans
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2011
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82
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Trapping unstable terminal M-O multiple bonds of monocyclopentadienyl niobium and tantalum complexes with Lewis acids.
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Inorg Chem
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2010
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83
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(N-salicylidene)aniline derived Schiff base complexes of methyltrioxorhenium(VII): ligand influence and catalytic performance.
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Chem Asian J
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Equilibrium studies of the reactions of palladium(II) bis(imidazolin-2-imine) complexes with biologically relevant nucleophiles. The crystal structures of [(TLtBu)PdCl]ClO4 and [(BLiPr)PdCl2].
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Dalton Trans
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2011
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0.75
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85
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Synthesis and characterization of propylene and butylene bridged fac-tricarbonylrhenium(I) biscarbene complexes.
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Dalton Trans
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2011
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86
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Mechanistic studies on initiation and propagation of rare earth metal-mediated group transfer polymerization of vinylphosphonates.
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J Am Chem Soc
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2013
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87
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Molybdenum(III) compounds as catalysts for 2-methylpropene polymerization.
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Angew Chem Int Ed Engl
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88
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Ansa-cycloheptatrienyl-cyclopentadienyl complexes.
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Angew Chem Int Ed Engl
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Enantioselective [4+2]-cycloaddition reaction of a photochemically generated o-quinodimethane: mechanistic details, association studies, and pressure effects.
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Chemistry
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2004
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0.75
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90
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Mono- and bimetallic Ir(III) based catalysts for the homogeneous photocatalytic reduction of CO₂ under visible light irradiation. New insights into catalyst deactivation.
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Dalton Trans
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2014
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0.75
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91
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Ruthenium complexes with cooperative PNP-pincer amine, amido, imine, and enamido ligands: facile ligand backbone functionalization processes.
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Inorg Chem
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2010
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92
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Synthesis and properties of chiral pyrazolidines derived from (+)-pulegone.
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Chemistry
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2010
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93
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Reactivity of yttrium carboxylates toward alkylaluminum hydrides.
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Chemistry
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2013
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94
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Highly diastereoselective formation of ruthenium complexes for efficient catalytic asymmetric transfer hydrogenation.
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Angew Chem Int Ed Engl
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2007
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Cationic rare-earth metal SALEN complexes.
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Dalton Trans
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2008
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96
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Solvent-ligated manganese(II) complexes for the homopolymerization of isobutene and the copolymerization of isobutene and isoprene.
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Chemistry
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2004
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0.75
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97
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Ultra-rigid metallocenes for highly iso- and regiospecific polymerization of propene: the search for the perfect polypropylene helix.
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Chemistry
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2012
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