1
|
Structural requirements for optimized delivery, inhibition of oxidative stress, and antiapoptotic activity of targeted nitroxides.
|
J Pharmacol Exp Ther
|
2006
|
1.36
|
2
|
Biomimetic carbene-catalyzed oxidations of aldehydes using TEMPO.
|
Angew Chem Int Ed Engl
|
2008
|
1.26
|
3
|
NHC catalyzed oxidations of aldehydes to esters: chemoselective acylation of alcohols in presence of amines.
|
J Am Chem Soc
|
2010
|
1.13
|
4
|
Nitroxides: applications in synthesis and in polymer chemistry.
|
Angew Chem Int Ed Engl
|
2011
|
1.10
|
5
|
Steric and electronic effects in cyclic alkoxyamines--synthesis and applications as regulators for controlled/living radical polymerization.
|
Chemistry
|
2004
|
1.05
|
6
|
One-pot homolytic aromatic substitutions/HWE olefinations under microwave conditions for the formation of a small oxindole library.
|
Org Lett
|
2004
|
1.03
|
7
|
Radical transfer hydroamination with aminated cyclohexadienes using polarity reversal catalysis: scope and limitations.
|
J Am Chem Soc
|
2007
|
1.02
|
8
|
NHC-catalyzed Michael addition to α,β-unsaturated aldehydes by redox activation.
|
Angew Chem Int Ed Engl
|
2010
|
0.98
|
9
|
Oxidative coupling of arylboronic acids with arenes via Rh-catalyzed direct C-H arylation.
|
Org Lett
|
2007
|
0.95
|
10
|
Oxidative amidation and azidation of aldehydes by NHC catalysis.
|
Org Lett
|
2010
|
0.93
|
11
|
Microflow radical carboaminoxylations with a novel alkoxyamine.
|
Org Lett
|
2009
|
0.93
|
12
|
Evolution of functional cyclohexadiene-based synthetic reagents: the importance of becoming aromatic.
|
Acc Chem Res
|
2005
|
0.92
|
13
|
Divergent reactions for racemates: catalytic, enantioselective, and regiodivergent nitroso diels-alder reactions.
|
Angew Chem Int Ed Engl
|
2007
|
0.92
|
14
|
Total synthesis of (+)-trans-dihydronarciclasine by a catalytic enantioselective regiodivergent nitroso Diels-Alder reaction.
|
Chemistry
|
2008
|
0.91
|
15
|
Oxidative biaryl coupling of thiophenes and thiazoles with arylboronic acids through palladium catalysis: otherwise difficult C4-selective C-H arylation enabled by boronic acids.
|
Angew Chem Int Ed Engl
|
2011
|
0.91
|
16
|
Transition-metal-free trifluoromethylaminoxylation of alkenes.
|
Angew Chem Int Ed Engl
|
2012
|
0.90
|
17
|
Enantioselective nitroso-Diels-Alder reaction and its application for the synthesis of (-)-peracetylated conduramine A-1.
|
Chemistry
|
2009
|
0.89
|
18
|
Coat thickness dependent adsorption of hydrophobic molecules at polymer brushes.
|
J Chem Phys
|
2013
|
0.89
|
19
|
Oxidative homocoupling of aryl, alkenyl, and alkynyl Grignard reagents with TEMPO and dioxygen.
|
Angew Chem Int Ed Engl
|
2008
|
0.88
|
20
|
Catalysis with N-heterocyclic carbenes under oxidative conditions.
|
Chemistry
|
2013
|
0.88
|
21
|
6-Trifluoromethyl-phenanthridines through radical trifluoromethylation of isonitriles.
|
Angew Chem Int Ed Engl
|
2013
|
0.87
|
22
|
Phenyl hydrazine as initiator for direct arene C-H arylation via base promoted homolytic aromatic substitution.
|
Org Lett
|
2013
|
0.87
|
23
|
Chemical surface modification via radical C-C bond-forming reactions.
|
J Am Chem Soc
|
2007
|
0.87
|
24
|
N-aminopyridinium salts as precursors for N-centered radicals--direct amidation of arenes and heteroarenes.
|
Org Lett
|
2014
|
0.87
|
25
|
1,2,3-trisubstituted indanes by highly diastereoselective palladium-catalyzed oxyarylation of indenes with arylboronic acids and nitroxides.
|
Angew Chem Int Ed Engl
|
2010
|
0.86
|
26
|
Polymer fibers as carriers for homogeneous catalysts.
|
Chemistry
|
2007
|
0.86
|
27
|
Oxidation of catecholboron enolates with TEMPO.
|
Angew Chem Int Ed Engl
|
2009
|
0.86
|
28
|
Glaser coupling at metal surfaces.
|
Angew Chem Int Ed Engl
|
2013
|
0.85
|
29
|
Stereoselective radical azidooxygenation of alkenes.
|
Org Lett
|
2013
|
0.85
|
30
|
Highly stereoselective synthesis of 1,2,3-trisubstituted indanes via oxidative N-heterocyclic carbene-catalyzed cascades.
|
Org Lett
|
2011
|
0.85
|
31
|
Total synthesis of resveratrol-based natural products using a palladium-catalyzed decarboxylative arylation and an oxidative Heck reaction.
|
Angew Chem Int Ed Engl
|
2014
|
0.84
|
32
|
N,N-addition of frustrated Lewis pairs to nitric oxide: an easy entry to a unique family of aminoxyl radicals.
|
J Am Chem Soc
|
2012
|
0.83
|
33
|
Copper-catalyzed intermolecular aminoazidation of alkenes.
|
Org Lett
|
2014
|
0.83
|
34
|
Bis(phosphoryl)-bridged biphenyls by radical phosphanylation: synthesis and photophysical and electrochemical properties.
|
Angew Chem Int Ed Engl
|
2011
|
0.82
|
35
|
Stable reagents for the generation of N-centered radicals: hydroamination of norbornene.
|
Angew Chem Int Ed Engl
|
2005
|
0.82
|
36
|
Memory of axial chirality in aryl radical phosphanylations.
|
J Am Chem Soc
|
2010
|
0.82
|
37
|
Stereoselective palladium-catalyzed carboaminoxylations of indoles with arylboronic acids and TEMPO.
|
Angew Chem Int Ed Engl
|
2009
|
0.81
|
38
|
Decarboxylative polymerization of 2,6-naphthalenedicarboxylic acid at surfaces.
|
J Am Chem Soc
|
2014
|
0.81
|
39
|
Thiol-catalyzed stereoselective transfer hydroamination of olefins with N-aminated dihydropyridines.
|
Angew Chem Int Ed Engl
|
2008
|
0.81
|
40
|
Radical alkylphosphanylation of olefins with stannylated or silylated phosphanes and alkyl iodides.
|
Org Lett
|
2011
|
0.81
|
41
|
Hydroxy- and silyloxy-substituted TEMPO derivatives for the living free-radical polymerization of styrene and n-butyl acrylate: synthesis, kinetics, and mechanistic studies.
|
J Am Chem Soc
|
2003
|
0.81
|
42
|
Stereospecific palladium-catalyzed decarboxylative C(sp3)-C(sp2) coupling of 2,5-cyclohexadiene-1-carboxylic acid derivatives with aryl iodides.
|
Angew Chem Int Ed Engl
|
2011
|
0.81
|
43
|
Homolytic substitution at phosphorus for the synthesis of alkyl and aryl phosphanes.
|
Angew Chem Int Ed Engl
|
2007
|
0.81
|
44
|
Transition-metal-free oxyarylation of alkenes with aryl diazonium salts and TEMPONa.
|
J Am Chem Soc
|
2012
|
0.80
|
45
|
Isonitrile trapping reactions under thermolysis of alkoxyamines for the synthesis of quinolines.
|
Org Lett
|
2006
|
0.80
|
46
|
Radical addition of arylboronic acids to various olefins under oxidative conditions.
|
Org Lett
|
2010
|
0.80
|
47
|
Synthesis of dihydrobenzo[b]furans by diastereoselective acyloxyarylation.
|
Chem Commun (Camb)
|
2014
|
0.80
|
48
|
Radical-transfer hydroamination of olefins with N-aminated dihydropyridines.
|
Chem Asian J
|
2011
|
0.79
|
49
|
Bifunctional mesoporous silica nanoparticles as cooperative catalysts for the Tsuji-Trost reaction--tuning the reactivity of silica nanoparticles.
|
Chem Commun (Camb)
|
2013
|
0.79
|
50
|
Oxidative Heck arylation for the stereoselective synthesis of tetrasubstituted olefins using nitroxides as oxidants.
|
Angew Chem Int Ed Engl
|
2012
|
0.79
|
51
|
Fabrication of hydrophilic polymer nanocontainers by use of supramolecular templates.
|
J Am Chem Soc
|
2015
|
0.79
|
52
|
Microwave-assisted free radical chemistry using the persistent radical effect.
|
Chem Commun (Camb)
|
2003
|
0.79
|
53
|
Formation of isoxazolidines by enantioselective copper-catalyzed annulation of 2-nitrosopyridine with allylstannanes.
|
Angew Chem Int Ed Engl
|
2011
|
0.79
|
54
|
Transition-metal-free Sonogashira-type coupling of ortho-substituted aryl and alkynyl Grignard reagents by using 2,2,6,6-tetramethylpiperidine-N-oxyl radical as an oxidant.
|
Org Lett
|
2010
|
0.78
|
55
|
Mechanistic studies on the Pd-catalyzed direct C-H arylation of 2-substituted thiophene derivatives with arylpalladium bipyridyl complexes.
|
Chem Asian J
|
2012
|
0.78
|
56
|
Reactions of arynes with nitrosoarenes--an approach to substituted carbazoles.
|
Angew Chem Int Ed Engl
|
2013
|
0.78
|
57
|
Enantioselective cyclopropanation of enals by oxidative N-heterocyclic carbene catalysis.
|
Chem Commun (Camb)
|
2012
|
0.78
|
58
|
Cyclizing radical carboiodination, carbotelluration, and carboaminoxylation of aryl amines.
|
Angew Chem Int Ed Engl
|
2014
|
0.78
|
59
|
Alternating copolymerization by nitroxide-mediated polymerization and subsequent orthogonal functionalization.
|
Angew Chem Int Ed Engl
|
2015
|
0.78
|
60
|
Amination of benzoxazoles and 1,3,4-oxadiazoles using 2,2,6,6-tetramethylpiperidine-N-oxoammonium tetrafluoroborate as an organic oxidant.
|
Angew Chem Int Ed Engl
|
2011
|
0.78
|
61
|
Radical aminooxygenation of alkenes with N-fluoro-benzenesulfonimide (NFSI) and TEMPONa.
|
Chem Commun (Camb)
|
2015
|
0.77
|
62
|
On-surface azide-alkyne cycloaddition on Au(111).
|
ACS Nano
|
2013
|
0.77
|
63
|
Tin-free radical alkoxyamine addition and isomerization reactions by using the persistent radical effect: variation of the alkoxyamine structure.
|
Chemistry
|
2005
|
0.77
|
64
|
On-surface reductive coupling of aldehydes on Au(111).
|
Chem Commun (Camb)
|
2015
|
0.77
|
65
|
Transition-metal-free synthesis of conjugated polymers from bis-Grignard reagents by using TEMPO as oxidant.
|
Chemistry
|
2010
|
0.77
|
66
|
Desymmetrization of 1,4-cyclohexadienyltriisopropoxysilane using copper catalysis.
|
Org Lett
|
2007
|
0.77
|
67
|
Selective synthesis of [7]- and [8]cycloparaphenylenes.
|
Chem Commun (Camb)
|
2014
|
0.77
|
68
|
Desymmetrization of metallated cyclohexadienes with chiral N-tert-butanesulfinyl imines.
|
Org Lett
|
2008
|
0.77
|
69
|
Stereoselective cyclization reactions of IBX-generated alkoxyamidyl radicals.
|
J Org Chem
|
2005
|
0.77
|
70
|
Preparation of phenanthrenes from ortho-amino-biphenyls and alkynes via base-promoted homolytic aromatic substitution.
|
Chem Commun (Camb)
|
2015
|
0.77
|
71
|
Radical perfluoroalkylation - easy access to 2-perfluoroalkylindol-3-imines via electron catalysis.
|
Chem Commun (Camb)
|
2016
|
0.77
|
72
|
2-Trifluoromethylated indoles via radical trifluoromethylation of isonitriles.
|
Org Lett
|
2014
|
0.77
|
73
|
An efficient approach to chiral allyloxyamines by stereospecific allylation of nitrosoarenes with chiral allylboronates.
|
Angew Chem Int Ed Engl
|
2015
|
0.77
|
74
|
Radical/anionic S(RN)1-type polymerization for preparation of oligoarenes.
|
Angew Chem Int Ed Engl
|
2012
|
0.77
|
75
|
Site-specific immobilization of proteins at zeolite L crystals by nitroxide exchange reactions.
|
Chem Commun (Camb)
|
2011
|
0.77
|
76
|
Intramolecular radical hydrosilylation--the first radical 5-endo-dig cyclisation.
|
Chem Commun (Camb)
|
2002
|
0.77
|
77
|
Ni-Catalyzed α-arylation of esters and amides with phenol derivatives.
|
Chem Commun (Camb)
|
2014
|
0.76
|
78
|
Nucleophilic addition of enols and enamines to α,β-unsaturated acyl azoliums: mechanistic studies.
|
Angew Chem Int Ed Engl
|
2012
|
0.76
|
79
|
Asymmetric synthesis of highly substituted β-lactones through oxidative carbene catalysis with LiCl as cooperative Lewis acid.
|
Angew Chem Int Ed Engl
|
2014
|
0.76
|
80
|
AFM-based force spectroscopy on polystyrene brushes: effect of brush thickness on protein adsorption.
|
Langmuir
|
2013
|
0.76
|
81
|
6-Aroylated phenanthridines via base promoted homolytic aromatic substitution (BHAS).
|
Org Lett
|
2013
|
0.76
|
82
|
Zinc triflate catalyzed aerobic cross-dehydrogenative coupling (CDC) of alkynes with nitrones: a new entry to isoxazoles.
|
Org Lett
|
2011
|
0.76
|
83
|
Intermolecular radical addition and addition/cyclization reactions of alkoxyamines onto nonactivated alkenes.
|
Org Lett
|
2003
|
0.76
|
84
|
6-Phosphorylated phenanthridines from 2-isocyanobiphenyls via radical C-P and C-C bond formation.
|
Org Lett
|
2013
|
0.76
|
85
|
9-Silafluorenes via base-promoted homolytic aromatic substitution (BHAS)--the electron as a catalyst.
|
Org Lett
|
2014
|
0.76
|
86
|
Radical amination with trimethylstannylated benzophenone imine.
|
Org Lett
|
2010
|
0.76
|
87
|
Recent advances in the synthesis of nitrogen heterocycles via radical cascade reactions using isonitriles as radical acceptors.
|
Chem Soc Rev
|
2015
|
0.76
|
88
|
6-Perfluoroalkylated phenanthridines via radical perfluoroalkylation of isonitriles.
|
Org Lett
|
2014
|
0.76
|
89
|
1-Trifluoromethylated isoquinolines via radical trifluoromethylation of isonitriles.
|
Org Biomol Chem
|
2014
|
0.76
|
90
|
Optical assembly of bio-hybrid micro-robots.
|
Biomed Microdevices
|
2015
|
0.75
|
91
|
Regioselective threefold aromatic substitution of benzoic acid derivatives by dearomatization, regioselective functionalization, and rearomatization.
|
Angew Chem Int Ed Engl
|
2013
|
0.75
|
92
|
Azurin-poly(N-isopropylacrylamide) conjugates by site-directed mutagenesis and their thermosensitive behavior in electron-transfer processes.
|
Angew Chem Int Ed Engl
|
2009
|
0.75
|
93
|
Patterning of functional compounds by multicomponent Langmuir-Blodgett transfer and subsequent chemical modification.
|
Langmuir
|
2010
|
0.75
|
94
|
Preparation of photoactive polymers and postmodification via nitroxide trapping under UV irradiation.
|
Macromol Rapid Commun
|
2012
|
0.75
|
95
|
Chemical surface modification of self-assembled monolayers by radical nitroxide exchange reactions.
|
Chemistry
|
2011
|
0.75
|
96
|
Ag-catalyzed stereoselective cyclohexadienyl transfer: a novel entry into arylphenylmethanols.
|
Org Lett
|
2008
|
0.75
|
97
|
Synthesis and characterization of inorganic-organic hybrid materials based on the intercalation of stable organic radicals into a fluoromica clay.
|
Dalton Trans
|
2013
|
0.75
|
98
|
Transition-metal-free oxidative coupling reactions for the formation of C-C and C-N bonds mediated by TEMPO and its derivatives.
|
Chimia (Aarau)
|
2012
|
0.75
|
99
|
Structured polymer brushes by AFM lithography.
|
Small
|
2009
|
0.75
|
100
|
Chemical modification of polymer brushes via nitroxide photoclick trapping.
|
Langmuir
|
2013
|
0.75
|
101
|
Desymmetrization of metalated cyclohexadienes and application to the synthesis of nephrosteranic acid.
|
Angew Chem Int Ed Engl
|
2004
|
0.75
|
102
|
Perfluoroalkylation of Aryl-N,N-dimethyl Hydrazones Using Hypervalent Iodine (III) Reagents or Perfluoroalkyl Iodides.
|
J Org Chem
|
2017
|
0.75
|
103
|
Aggregation behaviour of peptide-polymer conjugates containing linear peptide backbones and multiple polymer side chains prepared by nitroxide-mediated radical polymerization.
|
Org Biomol Chem
|
2011
|
0.75
|
104
|
Stereospecific formal [3+2] dipolar cycloaddition of cyclopropanes with nitrosoarenes: an approach to isoxazolidines.
|
Angew Chem Int Ed Engl
|
2014
|
0.75
|
105
|
Site-selective surface-initiated polymerization by Langmuir-Blodgett lithography.
|
Angew Chem Int Ed Engl
|
2007
|
0.75
|
106
|
α-Aminoxylation of ketones and β-chloro-α-aminoxylation of enones with TEMPO and chlorocatecholborane.
|
Org Lett
|
2012
|
0.75
|
107
|
Poly(vinyl ketone)s by controlled boron group transfer polymerization (BGTP).
|
Angew Chem Int Ed Engl
|
2010
|
0.75
|
108
|
Direct conversion of alcohols to α-chloro aldehydes and α-chloro ketones.
|
Org Lett
|
2014
|
0.75
|
109
|
Reversible switching of substrate activity of poly-N-isopropylacrylamide peptide conjugates.
|
Chem Commun (Camb)
|
2007
|
0.75
|
110
|
One product, two pathways: initially divergent radical reactions reconverge to form a single product in high yield.
|
J Am Chem Soc
|
2011
|
0.75
|
111
|
Cross dehydrogenative coupling via base-promoted homolytic aromatic substitution (BHAS): synthesis of fluorenones and xanthones.
|
Org Lett
|
2013
|
0.75
|
112
|
Carboaminoxylation as a tool to prepare functionalized polymeric materials: introduction of biologically important residues by metal-free radical C-C coupling reactions.
|
Chemistry
|
2011
|
0.75
|
113
|
Stereoselective synthesis of (+)-nephrosteranic acid, (+)-trans-cognac lactone, and (+)-trans-whisky lactone using a chiral cyclohexadienyl Ti compound.
|
Chemistry
|
2004
|
0.75
|
114
|
Intermolecular on-Surface σ-Bond Metathesis.
|
J Am Chem Soc
|
2017
|
0.75
|
115
|
TEMPO-mediated homocoupling of aryl Grignard reagents: mechanistic studies.
|
Org Biomol Chem
|
2015
|
0.75
|
116
|
Radical cascade cyclization of 1,n-enynes and diynes for the synthesis of carbocycles and heterocycles.
|
Chem Soc Rev
|
2017
|
0.75
|
117
|
Reusable catalysts based on dendrimers trapped in poly(p-xylylene) nanotubes.
|
Angew Chem Int Ed Engl
|
2009
|
0.75
|
118
|
Palladium-catalyzed diastereoselective oxyarylation of 2-alkylindoles.
|
Org Lett
|
2015
|
0.75
|
119
|
Polymer brushes by nitroxide-mediated polymerization.
|
Macromol Rapid Commun
|
2009
|
0.75
|
120
|
Surface patterning with natural and synthetic polymers via an inverse electron demand Diels-Alder reaction employing microcontact chemistry.
|
Org Biomol Chem
|
2014
|
0.75
|
121
|
CO-trapping reaction under thermolysis of alkoxyamines: application to the synthesis of 3,4-cyclopenta-1-tetralones.
|
Org Lett
|
2005
|
0.75
|
122
|
Preparation of bifunctional mesoporous silica nanoparticles by orthogonal click reactions and their application in cooperative catalysis.
|
Chemistry
|
2012
|
0.75
|
123
|
Dynamic microcrystal assembly by nitroxide exchange reactions.
|
Angew Chem Int Ed Engl
|
2010
|
0.75
|
124
|
Stereoselective formation of coordination polymers with 1,4-diaminonaphthalene on various Cu substrates.
|
Chem Commun (Camb)
|
2015
|
0.75
|