Published in Chemistry on November 21, 2013
The potential of palladacycles: more than just precatalysts. Chem Rev (2005) 3.51
Pd(II)-catalyzed enantioselective activation of C(sp2)-H and C(sp3)-H bonds using monoprotected amino acids as chiral ligands. Angew Chem Int Ed Engl (2008) 2.23
Proton abstraction mechanism for the palladium-catalyzed intramolecular arylation. J Am Chem Soc (2006) 1.82
Computational study of the mechanism of cyclometalation by palladium acetate. J Am Chem Soc (2005) 1.68
Catalytic intermolecular direct arylation of perfluorobenzenes. J Am Chem Soc (2006) 1.65
Platinum Group Organometallics Based on "Pincer" Complexes: Sensors, Switches, and Catalysts In memory of Prof. Dr. Luigi M. Venanzi and his pioneering work in organometallic chemistry, particularly in PCP pincer chemistry. Angew Chem Int Ed Engl (2001) 1.61
Transition metal-catalyzed C-H activation reactions: diastereoselectivity and enantioselectivity. Chem Soc Rev (2009) 1.61
Analysis of the concerted metalation-deprotonation mechanism in palladium-catalyzed direct arylation across a broad range of aromatic substrates. J Am Chem Soc (2008) 1.54
Pd(II)-catalyzed enantioselective C-H olefination of diphenylacetic acids. J Am Chem Soc (2010) 1.50
Catalytic asymmetric rearrangement of allylic trichloroacetimidates. A practical method for preparing allylic amines and congeners of high enantiomeric purity. J Am Chem Soc (2003) 1.39
Kinetic and computational analysis of the palladium(II)-catalyzed asymmetric allylic trichloroacetimidate rearrangement: development of a model for enantioselectivity. J Am Chem Soc (2007) 1.33
Proton-abstraction mechanism in the palladium-catalyzed intramolecular arylation: substituent effects. J Am Chem Soc (2007) 1.29
Catalytic asymmetric rearrangement of allylic N-aryl trifluoroacetimidates. A useful method for transforming prochiral allylic alcohols to chiral allylic amines. Org Lett (2003) 1.28
Synthesis of substituted oxindoles from alpha-chloroacetanilides via palladium-catalyzed C[bond]H functionalization. J Am Chem Soc (2003) 1.27
Monomeric cobalt oxazoline palladacycles (COP). Useful catalysts for catalytic asymmetric rearrangement of allylic trichloroacetimidates. J Org Chem (2004) 1.07
Catalytic asymmetric synthesis of allylic aryl ethers. Org Lett (2007) 1.03
Catalytic asymmetric synthesis of chiral allylic esters. J Am Chem Soc (2005) 1.01
Biaryl synthesis via direct arylation: establishment of an efficient catalyst for intramolecular processes. J Am Chem Soc (2004) 1.01
Enantioselective synthesis of planar chiral ferrocenes via palladium-catalyzed direct coupling with arylboronic acids. J Am Chem Soc (2012) 0.95
Catalytic Asymmetric Synthesis of Branched Chiral Allylic Phenyl Ethers from (E)-Allylic Alcohols. Adv Synth Catal (2009) 0.91
Mechanism of the cobalt oxazoline palladacycle (COP)-catalyzed asymmetric synthesis of allylic esters. J Am Chem Soc (2010) 0.87
Palladium-catalyzed allylic transposition of (allyloxy) iminodiazaphospholidines: a formal [3,3]-aza-phospha-oxa-Cope sigmatropic rearrangement for the stereoselective synthesis of allylic amines. J Am Chem Soc (2005) 0.86
Practical, highly active, and enantioselective ferrocenyl-imidazoline palladacycle catalysts (FIPs) for the aza-Claisen rearrangement of N-para-methoxyphenyl trifluoroacetimidates. Angew Chem Int Ed Engl (2006) 0.83
Catalytic asymmetric intramolecular aminopalladation: improved palladium(II) catalysts. J Org Chem (2005) 0.83
The asymmetric aza-Claisen rearrangement: development of widely applicable pentaphenylferrocenyl palladacycle catalysts. Chemistry (2009) 0.82
Catalytic asymmetric synthesis of allylic thiol derivatives. Org Lett (2008) 0.82
Allylic imidate rearrangements catalyzed by planar chiral palladacycles. Chem Asian J (2010) 0.82
Enantioselective palladium(II)-catalyzed formal [3,3]-sigmatropic rearrangement of 2-allyloxypyridines and related heterocycles. Org Lett (2010) 0.81
Catalytic asymmetric synthesis of chiral allylic esters. J Am Chem Soc (2010) 0.81
Palladium(II)-catalyzed enantioselective synthesis of 2-vinyl oxygen heterocycles. J Org Chem (2012) 0.81
Iterative approach to polyketide-type structures: stereoselective synthesis of 1,3-polyols utilizing the catalytic asymmetric Overman esterification. Chem Commun (Camb) (2007) 0.81
An investigation into the allylic imidate rearrangement of trichloroacetimidates catalysed by cobalt oxazoline palladacycles. Chemistry (2007) 0.79
Asymmetric formation of allylic amines with N-substituted quaternary stereocenters by Pd(II)-catalyzed aza-Claisen rearrangements. Angew Chem Int Ed Engl (2007) 0.79
Synthesis of a [2.2]paracyclophane based planar chiral palladacycle by a highly selective kinetic resolution/C-H activation reaction. Chem Commun (Camb) (2011) 0.78
Catalyst versus substrate induced selectivity: kinetic resolution by palladacycle catalyzed allylic imidate rearrangements. Chem Asian J (2010) 0.78
Bispalladacycle-catalyzed Brønsted acid/base-promoted asymmetric tandem azlactone formation-Michael addition. J Am Chem Soc (2010) 0.78
Stereoselective synthesis of hydroxylated 3-aminoazepanes using a multi-bond forming, three-step tandem process. Org Biomol Chem (2012) 0.77
Non-racemic (scalemic) planar-chiral five-membered metallacycles: routes, means, and pitfalls in their synthesis and characterization. Chem Soc Rev (2007) 0.77
A neutral, chiral, bis(imidazolidine)-derived NCN-type palladium pincer complex with catalytic activity. Chemistry (2013) 0.77
Catalytic enantioselective decarboxylative cyanoalkylation of imines by using palladium pincer complexes with C2-symmetric chiral bis(imidazoline)s. Chemistry (2013) 0.77
Paramagnetic palladacycles with Pd(III) centers are highly active catalysts for asymmetric aza-Claisen rearrangements. J Am Chem Soc (2012) 0.77
Stereoselective synthesis of polyhydroxylated aminocyclohexanes. Org Biomol Chem (2011) 0.77
Pd(II)-catalyzed regio-, enantio-, and diastereoselective 1,4-addition of azlactones formed in situ from racemic unprotected amino acids and acetic anhydride. J Org Chem (2012) 0.76
A tandem aza-Claisen rearrangement and ring closing metathesis reaction for the synthesis of cyclic allylic trichloroacetamides. Org Lett (2007) 0.76
Synthesis of planar chiral phosphapalladacycles by highly enantioselective transcyclopalladation. J Am Chem Soc (2005) 0.76
Catalytic enantioselective synthesis of 4-vinyl-2-trichloromethyloxazoline: an access to enantioenriched vinylglycinol surrogate. J Org Chem (2010) 0.76
Palladacyclic imidazoline-naphthalene complexes: synthesis and catalytic performance in Pd(II)-catalyzed enantioselective reactions of allylic trichloroacetimidates. J Org Chem (2012) 0.76
A stereoselective synthesis of (+)-physoperuvine using a tandem aza-Claisen rearrangement and ring closing metathesis reaction. Org Biomol Chem (2009) 0.76
Enantioselective aza-Morita-Baylis-Hillman reactions of acrylonitrile catalyzed by palladium(II) pincer complexes having C2-symmetric chiral bis(imidazoline) ligands. Angew Chem Int Ed Engl (2012) 0.76
Bispalladacycle-catalyzed Michael addition of in situ formed azlactones to enones. Chemistry (2012) 0.76
The crystal structure of potassium (1S)-D-galactit-1-ylsulfonate. Carbohydr Res (2010) 1.61
Ligating properties of a potentially tetradentate Schiff base [(CH3)2NCH2CH2N=CHC6H3(OH)(OMe)] with zinc(II), cadmium(II), cobalt(II), cobalt(III) and manganese(III) ions: synthesis and structural studies. Dalton Trans (2006) 1.51
The crystal structures of 1,2,3,4,6-penta-O-trimethylacetyl- and 1,2,3,4,6-penta-O-dimethylacetyl-beta-D-glucopyranose. Carbohydr Res (2007) 1.47
Benzene-1,3,5-triyl triacetate. Acta Crystallogr Sect E Struct Rep Online (2009) 1.42
Catalytic asymmetric rearrangement of allylic N-aryl trifluoroacetimidates. A useful method for transforming prochiral allylic alcohols to chiral allylic amines. Org Lett (2003) 1.28
Sodium (1R)-d-glucit-1-yl-sulfonate monohydrate. Acta Crystallogr Sect E Struct Rep Online (2012) 1.27
Meta-analysis of randomized controlled trials for the incidence and risk of treatment-related mortality in patients with cancer treated with vascular endothelial growth factor tyrosine kinase inhibitors. J Clin Oncol (2012) 1.24
Benzene-1,3,5-triyl tris-(2,2-dimethyl-propanoate). Acta Crystallogr Sect E Struct Rep Online (2009) 1.18
Prospective randomized study comparing cryo-assisted and needle-wire localization of ultrasound-visible breast tumors. Am J Surg (2006) 1.14
cis-Clerodane-type furanoditerpenoids from Tinospora crispa. J Nat Prod (2010) 1.05
Recent advances in catalytic asymmetric epoxidation using the environmentally benign oxidant hydrogen peroxide and its derivatives. Chem Soc Rev (2010) 1.03
Forming-free bipolar resistive switching in nonstoichiometric ceria films. Nanoscale Res Lett (2014) 1.03
A novel {FeI-FeII-FeII-FeI} iron thiolate carbonyl assembly which electrocatalyses hydrogen evolution. Chem Commun (Camb) (2004) 1.00
Triethyl-ammonium bis-(2-oxido-2,2-diphenyl-acetato-κO,O)anti-monate(III). Acta Crystallogr Sect E Struct Rep Online (2010) 0.97
Aryl trihydroxyborates: easily isolated discrete species convenient for direct application in coupling reactions. Org Lett (2006) 0.97
Reconstruction of human evolutionary tree using polymorphic autosomal microsatellites. Am J Phys Anthropol (2003) 0.95
Potassium (1R,4R,5S,8S)-4,5,8-trihy-droxy-3-oxo-2,6-dioxabicyclo-[3.3.0]octane-4-sulfonate dihydrate. Acta Crystallogr Sect E Struct Rep Online (2012) 0.95
Intra- and intermolecular N-H...F-C hydrogen-bonding interactions in amine adducts of tris(pentafluorophenyl)borane and -alane. Inorg Chem (2005) 0.94
Combining two-directional synthesis and tandem reactions: an efficient strategy for the total syntheses of (+/-)-hippodamine and (+/-)-epi-hippodamine. Org Biomol Chem (2004) 0.94
Synthesis of 5-substituted-1H-indol-2-yl-1H-quinolin-2-ones: a novel class of KDR kinase inhibitors. J Org Chem (2005) 0.94
Anticancer drugs for the modulation of endoplasmic reticulum stress and oxidative stress. Tumour Biol (2015) 0.94
A thermally stable gold(III) hydride: synthesis, reactivity, and reductive condensation as a route to gold(II) complexes. Angew Chem Int Ed Engl (2012) 0.93
Design, synthesis, and evaluation of potent and selective ligands for the dopamine 3 (D3) receptor with a novel in vivo behavioral profile. J Med Chem (2008) 0.93
A novel locus for autosomal dominant nuclear cataract mapped to chromosome 2p12 in a Pakistani family. Invest Ophthalmol Vis Sci (2002) 0.92
Gold peroxide complexes and the conversion of hydroperoxides into gold hydrides by successive oxygen-transfer reactions. Nat Commun (2013) 0.92
Four new dinuclear Cu(ii) hydrazone complexes using various organic spacers: syntheses, crystal structures, DNA binding and cleavage studies and selective cell inhibitory effect towards leukemic and normal lymphocytes. Dalton Trans (2009) 0.90
Selective GABAA alpha5 benzodiazepine inverse agonist antagonizes the neurobehavioral actions of alcohol. Alcohol Clin Exp Res (2005) 0.90
Discovery and development of first in class antifungal caspofungin (CANCIDAS®)--a case study. Nat Prod Rep (2014) 0.90
A remarkable side-product from the synthesis of an octaalkylphthalocyanine: formation of a tetrabenzotriazaporphyrin. Chem Commun (Camb) (2004) 0.87
A metallocene-pyrrolidinopyridine nucleophilic catalyst for asymmetric synthesis. Org Lett (2006) 0.87
Conclusive evidence for a retention-retention pathway for the molybdenum-catalyzed asymmetric alkylation. J Am Chem Soc (2004) 0.87
An electrochemical study of frustrated Lewis pairs: a metal-free route to hydrogen oxidation. J Am Chem Soc (2014) 0.87
Homozygous frame shift mutation in ECM1 gene in two siblings with lipoid proteinosis. J Dermatol Case Rep (2010) 0.86
Isolation and structure of [HC[CH(SiMe(3))(SnMe(3))](2)](+): a remarkably stable sec-alkyl cation. J Am Chem Soc (2002) 0.86
Angiotensin-converting enzyme (ACE) gene II genotype protects against the development of diabetic peripheral neuropathy in type 2 diabetes mellitus. J Diabetes (2012) 0.86
Epidemiology, major risk factors and genetic predisposition for breast cancer in the Pakistani population. Asian Pac J Cancer Prev (2013) 0.86
The synthesis, molecular structure and supramolecular architecture of complexes between the ammonia adduct of tris(pentafluorophenyl)boron and a series of mono and polydentate hydrogen-bond acceptors. Dalton Trans (2008) 0.85
CJ-1639: A Potent and Highly Selective Dopamine D3 Receptor Full Agonist. ACS Med Chem Lett (2011) 0.84
Cardiovascular and airway relaxant activities of peony root extract. Can J Physiol Pharmacol (2008) 0.84
A two-directional synthesis of (+/-)-perhydrohistrionicotoxin. J Org Chem (2004) 0.84
An expeditious route to fluorinated rapamycin analogues by utilising mutasynthesis. Chembiochem (2010) 0.83
A ferrocene based palladacyclic precatalyst for the Suzuki cross-coupling of aryl chlorides. Chem Commun (Camb) (2003) 0.83
Development of new transition metal catalysts for the oxidation of a hydroxamic acid with in situ Diels-Alder trapping of the acyl nitroso derivative. Dalton Trans (2007) 0.83
Topical glyceryl trinitrate and noninsertional Achilles tendinopathy: a clinical and cellular investigation. Am J Sports Med (2008) 0.83
World allergy organization study on aerobiology for creating first pollen and mold calendar with clinical significance in islamabad, pakistan;: a project of world allergy organization and pakistan allergy, asthma & clinical immunology centre of islamabad. World Allergy Organ J (2012) 0.83
First small molecular inhibitors of T. brucei dolicholphosphate mannose synthase (DPMS), a validated drug target in African sleeping sickness. Bioorg Med Chem Lett (2009) 0.82
Prevalence and management of anencephaly at Saidu Teaching Hospital, Swat. J Ayub Med Coll Abbottabad (2012) 0.82
Allylic imidate rearrangements catalyzed by planar chiral palladacycles. Chem Asian J (2010) 0.82
Efficient and general protocol for the copper-free sonogashira coupling of aryl bromides at room temperature. Org Lett (2003) 0.82
Synthesis, structure and ethylene polymerisation behaviour of vanadium(IV and V) complexes bearing chelating aryloxides. Dalton Trans (2009) 0.82
Group 10 allergens (tropomyosins) from house-dust mites may cause covariation of sensitization to allergens from other invertebrates. Allergy Rhinol (Providence) (2012) 0.82
MiR-421, miR-155 and miR-650: emerging trends of regulation of cancer and apoptosis. Asian Pac J Cancer Prev (2014) 0.81
Penetrance and phenotypic effects of C/T polymorphism at 1595 position in exon 5 of the TRAIL gene among prostate cancer patients in Pakistani population. J Exp Ther Oncol (2015) 0.81
Nitric oxide photorelease from ruthenium salen complexes in aqueous and organic solutions. Inorg Chem (2002) 0.81
Synthesis of aminoboronic acids and their applications in bifunctional catalysis. Acc Chem Res (2009) 0.81
TRAIL and vitamins: opting for keys to castle of cancer proteome instead of open sesame. Cancer Cell Int (2012) 0.81
Reactive resin facilitated preparation of an enantiopure fluorobicycloketone. Org Biomol Chem (2003) 0.81
Mutation screening of Pakistani families with congenital eye disorders. Exp Eye Res (2003) 0.80
The unusual role of CO transfer in molybdenum-catalyzed asymmetric alkylations. J Am Chem Soc (2002) 0.80
Kisspeptin Mediated Signaling in Cancer. Curr Top Med Chem (2016) 0.80
Designed ligands as probes for the catalytic binding mode in Mo-catalyzed asymmetric allylic alkylation. Angew Chem Int Ed Engl (2002) 0.80
Synthesis of a class of core-modified aza-BODIPY derivatives. J Org Chem (2014) 0.80
Synthesis of the antifungal beta-1,3-glucan synthase inhibitor CANCIDAS (caspofungin acetate) from pneumocandin B0. J Org Chem (2007) 0.80
An efficient synthesis of an alphavbeta3 antagonist. J Org Chem (2004) 0.79
Combining two-directional synthesis and tandem reactions: desymmetrisation by intramolecular cycloaddition/triazoline fragmentation. Chem Commun (Camb) (2005) 0.79
Preparation, X-ray structure and reactivity of a stable glycosyl iodide. Chem Commun (Camb) (2003) 0.79
Synthesis of monodentate ferrocenylphosphines and their application to the palladium-catalyzed Suzuki reaction of aryl chlorides. J Org Chem (2003) 0.79
Synthesis of alpha- and beta-D-glucopyranosyl triazoles by CuAAC 'click chemistry': reactant tolerance, reaction rate, product structure and glucosidase inhibitory properties. Carbohydr Res (2010) 0.79
Stereoselective preparation of a cyclopentane-based NK1 receptor antagonist bearing an unsymmetrically substituted sec-sec ether. J Org Chem (2006) 0.79
An investigation into the allylic imidate rearrangement of trichloroacetimidates catalysed by cobalt oxazoline palladacycles. Chemistry (2007) 0.79
Intramolecular asymmetric Heck reactions: evidence for dynamic kinetic resolution effects. Org Lett (2006) 0.79
InP nanowires from surfactant-free thermolysis of single molecule precursors. Dalton Trans (2012) 0.78
Syntheses and structures of thermally stable diketiminato complexes of gold and copper. Dalton Trans (2010) 0.78
Unexpected phenol production from arylboronic acids under palladium-free conditions; organocatalyzed air oxidation. Org Lett (2011) 0.78
Organocatalytic aziridine synthesis using F+ salts. Org Lett (2009) 0.78
Mapping of a novel type III variant of Knobloch syndrome (KNO3) to chromosome 17q11.2. Am J Med Genet A (2007) 0.78
Novel ion-pair receptors based on hexahomotrioxacalix[3]arene derivatives. Org Biomol Chem (2011) 0.78
Development of a new and practical route to chiral 3,4-disubstituted cyclopentanones: asymmetric alkylation and intramolecular cyclopropanation as key C-C bond-forming steps. J Org Chem (2002) 0.78
Alkaloidal constituents of Tinospora crispa. Nat Prod Commun (2010) 0.78
Synthesis of a [2.2]paracyclophane based planar chiral palladacycle by a highly selective kinetic resolution/C-H activation reaction. Chem Commun (Camb) (2011) 0.78
Molecular simulations probing Kushecarpin A as a new lipoxygenase inhibitor. Fitoterapia (2011) 0.78
Demonstrating the synergy of synthetic, mechanistic, and computational studies in a regioselective aniline synthesis. J Org Chem (2004) 0.78
Synthesis of novel KDR kinase inhibitors through catalytic reductive cyclization of o-nitrobenzylcarbonyl compounds. J Org Chem (2004) 0.77
Is apoptosis the cause of noninsertional achilles tendinopathy? Am J Sports Med (2009) 0.77
Early transition metal complexes bearing a C-capped tris(phenolate) ligand incorporating a pendant imine arm: synthesis, structure, and ethylene polymerization behavior. Inorg Chem (2008) 0.77
1,4-dibutoxy-2,3-di(4-pyridyl)-8,11,15,18,22,25-hexakis(hexyl)- phthalocyaninato zinc, a self-assembled coordination polymer in the solid state. Chem Commun (Camb) (2003) 0.77
Asymmetric synthesis of unsaturated monocyclic and bicyclic nitrogen heterocycles. Org Lett (2009) 0.77
Titanium, zinc and alkaline-earth metal complexes supported by bulky O,N,N,O-multidentate ligands: syntheses, characterisation and activity in cyclic ester polymerisation. Dalton Trans (2005) 0.77
Synthesis of apiose-containing oligosaccharide fragments of the plant cell wall: fragments of rhamnogalacturonan-II side chains A and B, and apiogalacturonan. Org Biomol Chem (2011) 0.77
Sn doping induced enhancement in the activity of ZnO nanostructures against antibiotic resistant S. aureus bacteria. Int J Nanomedicine (2013) 0.77
The synthesis of new weakly coordinating diborate anions: anion stability as a function of linker structure and steric bulk. Dalton Trans (2006) 0.77
Expedient synthesis of substituted (S)-N-(alpha-methylbenzyl)aziridines. Chem Commun (Camb) (2006) 0.76
The synthesis, structure and ethene polymerisation catalysis of mono(salicylaldiminato) titanium and zirconium complexes. Dalton Trans (2005) 0.76
Proteomics analysis of rough endoplasmic reticulum in pancreatic beta cells. Proteomics (2015) 0.76
Synthesis of planar chiral phosphapalladacycles by highly enantioselective transcyclopalladation. J Am Chem Soc (2005) 0.76
Mononuclear Ti[triple bond]N complexes formed by the facile multiple deprotonation of H3N x B(C6F5)3: the importance of chloride ligands. Chem Commun (Camb) (2008) 0.76
The structure and chemistry of tris(pentafluorophenyl)borane protected mononuclear nitridotitanium complexes. Dalton Trans (2012) 0.76
Multinuclear alkylaluminium macrocyclic Schiff base complexes: influence of procatalyst structure on the ring opening polymerisation of epsilon-caprolactone. Chem Commun (Camb) (2008) 0.76
Association of the rs1042522 polymorphism with increased risk of prostate adenocarcinoma in the Pakistani population and its HuGE review. Asian Pac J Cancer Prev (2014) 0.76