Published in Inorg Chem on May 05, 2014
Synthesis and characterization of a neutral tricoordinate organoboron isoelectronic with amines. Science (2011) 1.84
Carbodiphosphoranes: the chemistry of divalent carbon(0). Angew Chem Int Ed Engl (2006) 1.54
Isolation of a C5-deprotonated imidazolium, a crystalline "abnormal" N-heterocyclic carbene. Science (2009) 1.49
The interplay between steric and electronic effects in S(N)2 reactions. Chemistry (2009) 1.41
The nature of the chemical bond revisited: an energy-partitioning analysis of nonpolar bonds. Chemistry (2005) 1.39
N-heterocyclic carbene analogues with low-valent group 13 and group 14 elements: syntheses, structures, and reactivities of a new generation of multitalented ligands. Chem Rev (2010) 1.31
Stable magnesium(I) compounds with Mg-Mg bonds. Science (2007) 1.28
Beta-diketiminate-stabilized magnesium(I) dimers and magnesium(II) hydride complexes: synthesis, characterization, adduct formation, and reactivity studies. Chemistry (2010) 1.13
Structurally sophisticated octahedral metal complexes as highly selective protein kinase inhibitors. J Am Chem Soc (2011) 1.11
A stable two-coordinate acyclic silylene. J Am Chem Soc (2012) 1.10
Critical comments on "One molecule, two atoms, three views, four bonds?". Angew Chem Int Ed Engl (2013) 1.08
Oxidative addition of imidazolium salts to Ni(0) and Pd(0): synthesis and structural characterization of unusually stable metal-hydride complexes. Angew Chem Int Ed Engl (2004) 0.99
C(NHC)2: divalent carbon(0) compounds with N-heterocyclic carbene ligands-theoretical evidence for a class of molecules with promising chemical properties. Angew Chem Int Ed Engl (2007) 0.98
Isolation of crystalline carbene-stabilized P(2)-radical cations and P(2)-dications. Nat Chem (2010) 0.95
Aromaticity in metallabenzenes. Chemistry (2007) 0.94
Theoretical Studies of Some Transition-Metal-Mediated Reactions of Industrial and Synthetic Importance. Chem Rev (2000) 0.93
Exocyclic delocalization at the expense of aromaticity in 3,5-bis(pi-donor) substituted pyrazolium ions and corresponding cyclic bent allenes. J Am Chem Soc (2009) 0.93
Is this a chemical bond? A theoretical study of Ng2@C60 (Ng=He, Ne, Ar, Kr, Xe). Chemistry (2007) 0.93
Sigma and pi donation in an unsupported uranium-gallium bond. Angew Chem Int Ed Engl (2009) 0.89
Rate-determining factors in nucleophilic aromatic substitution reactions. J Org Chem (2010) 0.89
Isolation of neutral mono- and dinuclear gold complexes of cyclic (alkyl)(amino)carbenes. Angew Chem Int Ed Engl (2013) 0.89
Olefin epoxidation with inorganic peroxides. Solutions to four long-standing controversies on the mechanism of oxygen transfer. Acc Chem Res (2004) 0.89
Structures, bond energies, heats of formation, and quantitative bonding analysis of main-group metallocenes [E(Cp)2] (E = Be-Ba, Zn, Si-Pb) and [E(Cp)] (E = Li-Cs, B-Tl). Chemistry (2002) 0.88
Why do the heavy-atom analogues of acetylene E2H2 (E = Si-Pb) exhibit unusual structures? J Am Chem Soc (2005) 0.88
Synthesis of Highly Stable 1,3-Diaryl-1H-1,2,3-triazol-5-ylidenes and their Applications in Ruthenium-Catalyzed Olefin Metathesis. Organometallics (2011) 0.88
Orbital overlap and chemical bonding. Chemistry (2006) 0.88
Direct estimate of the strength of conjugation and hyperconjugation by the energy decomposition analysis method. Chemistry (2006) 0.87
First and second proton affinities of carbon bases. Chemphyschem (2008) 0.87
Oxidation reactions of an anionic gallium(I) N-heterocyclic carbene analogue with group 16 compounds. Dalton Trans (2005) 0.87
Divalent carbon(0) chemistry, part 1: Parent compounds. Chemistry (2008) 0.87
Direct estimate of conjugation and aromaticity in cyclic compounds with the EDA method. Faraday Discuss (2007) 0.87
Hyperconjugative stabilization in alkyl carbocations: direct estimate of the beta-effect of group-14 elements. J Phys Chem A (2007) 0.86
Borylene complexes (BH)L2 and nitrogen cation complexes (N+)L2: isoelectronic homologues of carbones CL2. Chemistry (2012) 0.86
Direct estimate of the conjugative and hyperconjugative stabilization in diynes, dienes, and related compounds. Angew Chem Int Ed Engl (2005) 0.86
Divalent carbon(0) chemistry, part 2: Protonation and complexes with main group and transition metal Lewis acids. Chemistry (2008) 0.85
Aurolysis of alpha-C-deprotonated group 6 aminocarbene and thiocarbene complexes with Ph3PAu+. Dalton Trans (2006) 0.85
Bonding analysis of N-heterocyclic carbene tautomers and phosphine ligands in transition-metal complexes: a theoretical study. Chem Asian J (2007) 0.85
Stable dimeric magnesium(I) compounds: from chemical landmarks to versatile reagents. Dalton Trans (2011) 0.84
Beryllium chemistry the safe way: a theoretical evaluation of low oxidation state beryllium compounds. Dalton Trans (2013) 0.84
First experimental characterization of a non-nuclear attractor in a dimeric magnesium(I) compound. J Phys Chem A (2010) 0.84
Structures and bonding of the sandwich complexes [Ti(eta5-E5)2]2- (E = CH, N, P, As, Sb): a theoretical study. Inorg Chem (2003) 0.83
New chiral auxiliaries for dynamic kinetic resolution: from theory to experiment. Chemistry (2004) 0.83
Transition metal-carbon complexes. A theoretical study. J Am Chem Soc (2007) 0.83
End-on and side-on π-acid ligand adducts of gold(I): carbonyl, cyanide, isocyanide, and cyclooctyne gold(I) complexes supported by N-heterocyclic carbenes and phosphines. Inorg Chem (2012) 0.83
Correlation between Hammett substituent constants and directly calculated pi-conjugation strength. J Org Chem (2006) 0.83
Twelve one-electron ligands coordinating one metal center: structure and bonding of [Mo(ZnCH3)9(ZnCp*)3]. Angew Chem Int Ed Engl (2008) 0.83
Molecular alloys, linking organometallics with intermetallic Hume-Rothery phases: the highly coordinated transition metal compounds [M(ZnR)(n)] (n >or= 8) containing organo-zinc ligands. J Am Chem Soc (2009) 0.83
Chemical bonding in phosphane and amine complexes of main group elements and transition metals. Inorg Chem (2006) 0.83
The σ-aromatic clusters [Zn₃]⁺ and [Zn₂Cu]: embryonic brass. Angew Chem Int Ed Engl (2015) 0.82
Carbon monoxide bonding with BeO and BeCO3 : surprisingly high CO stretching frequency of OCBeCO3. Angew Chem Int Ed Engl (2014) 0.82
Borylene-based direct functionalization of organic substrates: synthesis, characterization, and photophysical properties of novel pi-conjugated borirenes. J Am Chem Soc (2009) 0.82
N-heterocyclic carbene stabilized digermanium(0). Angew Chem Int Ed Engl (2009) 0.82
The nature of Ru-NO bonds in ruthenium tetraazamacrocycle nitrosyl complexes--a computational study. Dalton Trans (2012) 0.82
Are carbodiphosphoranes better ligands than N-heterocyclic carbenes for Grubb's catalysts? Chem Commun (Camb) (2008) 0.82
An N-heterocyclic carbene adduct of diatomic tin, :Sn=Sn:. Chem Commun (Camb) (2012) 0.82
DFT investigation of the thermodynamics and mechanism of electrophilic chlorination and iodination of arenes. J Mol Model (2011) 0.82
Stable adducts of a dimeric magnesium(I) compound. Angew Chem Int Ed Engl (2008) 0.81
Antitumor activity of bent metallocenes: electronic structure analysis using DFT computations. J Mol Model (2010) 0.81
Reductive elimination: a pathway to low-valent aluminium species. Chem Commun (Camb) (2013) 0.81
Bonding analysis of metal-metal multiple bonds in R3M-M'R3 (M, M' = Cr, Mo, W; R = Cl, NMe2). Inorg Chem (2011) 0.81
A dimeric magnesium(I) compound as a facile two-center/two-electron reductant. Angew Chem Int Ed Engl (2009) 0.81
A stable singlet biradicaloid siladicarbene: (L:)2Si. Angew Chem Int Ed Engl (2013) 0.81
Cationic gold carbonyl complex on a phosphine support. Inorg Chem (2011) 0.81
Isolation of bridging and terminal coinage metal-nitrene complexes. J Am Chem Soc (2014) 0.81
Chemo- and periselectivity in the addition of [OsO2(CH2)2] to ethylene: a theoretical study. Chemistry (2005) 0.81
Physiologic response to a simplified venovenous perfusion-induced systemic hyperthermia system. ASAIO J (2012) 0.81
When does carbonylation of carbenes yield ketenes? A theoretical study with implications for synthesis. J Am Chem Soc (2011) 0.80
Theoretical chemistry: the six-bond bound. Nature (2007) 0.80
Ligand-tuned regioselectivity of a cobalt-catalyzed Diels-Alder reaction. A theoretical study. J Am Chem Soc (2008) 0.80
The rich chemistry of [Zn2Cp*2]: trapping three different types of zinc ligands in the PdZn7 complex [Pd(ZnCp*)4(ZnMe)2{Zn(tmeda)}]. Inorg Chem (2011) 0.80
Molecular alloys: experimental and theoretical investigations on the substitution of zinc by cadmium and mercury in the homologous series [Mo(M'R)12] and [M(M'R)8] (M=Pd, Pt; M'=Zn, Cd, Hg). Chemistry (2010) 0.80
A digermyne with a Ge-Ge single bond that activates dihydrogen in the solid state. J Am Chem Soc (2011) 0.80
Conversion of a singlet silylene to a stable biradical. Angew Chem Int Ed Engl (2012) 0.80
A crystalline phosphinyl radical cation. J Am Chem Soc (2010) 0.80
A new look at the ylidic bond in phosphorus ylides and related compounds: energy decomposition analysis combined with a domain-averaged fermi hole analysis. J Phys Chem A (2007) 0.80
Donor-acceptor stabilized silaformyl chloride. Chem Commun (Camb) (2012) 0.80
Weak arene stabilization of bulky amido-germanium(II) and tin(II) monocations. Angew Chem Int Ed Engl (2012) 0.79
Synthesis and characterization of a two-coordinate manganese complex and its reaction with molecular hydrogen at room temperature. Angew Chem Int Ed Engl (2013) 0.79
Differential efficacy of combined therapy with radiation and AEE788 in high and low EGFR-expressing androgen-independent prostate tumor models. Int J Radiat Oncol Biol Phys (2008) 0.79
Stable pentacoordinate carbocations: structure and bonding. Chemistry (2007) 0.79
Synthesis and characterisation of the first carbene and diazabutadiene-indium(II) complexes. Chem Commun (Camb) (2002) 0.79
Ligand-stabilized [P4]2+ cations. Angew Chem Int Ed Engl (2012) 0.79
Synthesis and ligand properties of a persistent, all-carbon four-membered-ring allene. Angew Chem Int Ed Engl (2009) 0.79
The reactivity of [Zn2Cp*2 ]: trapping monovalent {*ZnZnCp*} in the metal-rich compounds [(Pd,Pt)(GaCp*)a(ZnCp*)(4-a)(ZnZnCp*)(4-a)] (a=0, 2). Angew Chem Int Ed Engl (2010) 0.79
Density functional study of proline-catalyzed intramolecular Baylis-Hillman reactions. Chemistry (2009) 0.79
Molecular Hume-Rothery compounds [M(ZnR)n] and [M(ZnR)a(GaR)b] (a + 2b = n ≥ 8): relations of coordination polyhedra and electronic structure. Inorg Chem (2011) 0.79
pi-Bonding in complexes of benzannulated biscarbenes, -germylenes, and -stannylenes: an experimental and theoretical study. Chemistry (2008) 0.79
Aromaticity of metallabenzenes and related compounds. Chem Soc Rev (2015) 0.79
Borylene-based functionalization of iron-alkynyl-σ-complexes and stepwise reversible metal-boryl-to-borirene transformation: synthesis, characterization, and density functional theory studies. Inorg Chem (2010) 0.79
"True" inorganic heterocycles: structures and stability of group 13-15 analogues of benzene and their dimers. Inorg Chem (2003) 0.79
Oligonuclear molecular models of intermetallic phases: a case study on [Pd2Zn6Ga2(Cp*)5(CH3)3]. Chemistry (2012) 0.79
Chemical bonding in transition metal complexes with beryllium ligands [(PMe(3))(2)M-BeCl(2)], [(PMe(3))(2)M-BeClMe], and [(PMe(3))(2)M-BeMe(2)] (M = Ni, Pd, Pt). J Phys Chem A (2010) 0.79
Isolation of neutral mononuclear copper complexes stabilized by two cyclic (alkyl)(amino)carbenes. J Am Chem Soc (2014) 0.79
Coinage metals binding as main group elements: structure and bonding of the carbene complexes [TM(cAAC)2] and [TM(cAAC)2](+) (TM = Cu, Ag, Au). J Am Chem Soc (2014) 0.78
Carbodicarbenes and related divalent carbon(0) compounds. Chemistry (2010) 0.78
Energy decomposition analysis of the chemical bond in main group and transition metal compounds. Faraday Discuss (2003) 0.78
Complexes of a gallium heterocycle with transition metal dicyclopentadienyl and cyclopentadienylcarbonyl fragments, and with a dialkylmanganese compound. Dalton Trans (2006) 0.78