Published in Angew Chem Int Ed Engl on June 10, 2014
Diastereo- and enantioselective iridium-catalyzed allylation of cyclic ketone enolates: synergetic effect of ligands and barium enolates. J Am Chem Soc (2014) 0.83
Iridium-catalyzed regio- and enantioselective allylic substitution of silyl dienolates derived from dioxinones. Angew Chem Int Ed Engl (2014) 0.77
Iridium-Catalyzed Enantioselective Allylic Substitution of Enol Silanes from Vinylogous Esters and Amides. J Am Chem Soc (2015) 0.76
Iridium-Catalyzed Regio- and Enantioselective Allylic Substitution of Trisubstituted Allylic Electrophiles. Angew Chem Int Ed Engl (2016) 0.75
Synthesis and activity of a new generation of ruthenium-based olefin metathesis catalysts coordinated with 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene ligands. Org Lett (1999) 9.01
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The enantioselective Tsuji allylation. J Am Chem Soc (2004) 3.45
Metal-catalyzed enantioselective allylation in asymmetric synthesis. Angew Chem Int Ed Engl (2008) 2.34
Enantio- and diastereodivergent dual catalysis: α-allylation of branched aldehydes. Science (2013) 1.97
Palladium-catalyzed decarboxylative asymmetric allylic alkylation of enol carbonates. J Am Chem Soc (2009) 1.72
Regio- and enantioselective allylic amination of achiral allylic esters catalyzed by an iridium-phosphoramidite complex. J Am Chem Soc (2002) 1.58
Regioselective and enantioselective iridium-catalyzed allylation of enamines. J Am Chem Soc (2007) 1.38
Palladium-catalyzed asymmetric allylic alpha-alkylation of acyclic ketones. J Am Chem Soc (2005) 1.34
Identification of an activated catalyst in the iridium-catalyzed allylic amination and etherification. Increased rates, scope, and selectivity. J Am Chem Soc (2003) 1.23
Iridium-catalysed asymmetric allylic substitutions. Chem Commun (Camb) (2006) 1.22
Neopeltolide, a macrolide from a lithistid sponge of the family Neopeltidae. J Nat Prod (2007) 1.19
Total synthesis and stereochemical reassignment of (+)-neopeltolide. Angew Chem Int Ed Engl (2007) 1.18
Iridium-catalyzed regio- and enantioselective allylation of ketone enolates. J Am Chem Soc (2005) 1.12
Recent advances and applications of iridium-catalysed asymmetric allylic substitution. Org Biomol Chem (2012) 1.11
Construction of vicinal tertiary and all-carbon quaternary stereocenters via Ir-catalyzed regio-, diastereo-, and enantioselective allylic alkylation and applications in sequential Pd catalysis. J Am Chem Soc (2013) 1.11
Iridium-catalyzed enantioselective polyene cyclization. J Am Chem Soc (2012) 1.05
Recent developments in the synthesis of prostaglandins and analogues. Chem Rev (2007) 1.04
Iridium-catalyzed allylic alkylation reaction with N-aryl phosphoramidite ligands: scope and mechanistic studies. J Am Chem Soc (2012) 1.04
Control of diastereoselectivity for iridium-catalyzed allylation of a prochiral nucleophile with a phosphate counterion. J Am Chem Soc (2013) 1.03
Stereodivergent α-allylation of linear aldehydes with dual iridium and amine catalysis. J Am Chem Soc (2014) 1.01
Enantio-, diastereo-, and regioselective iridium-catalyzed asymmetric allylic alkylation of acyclic β-ketoesters. J Am Chem Soc (2013) 1.00
Iridium-catalyzed enantioselective allylic vinylation. J Am Chem Soc (2013) 1.00
Enantio- and diastereoselective ir-catalyzed allylic substitutions for asymmetric synthesis of amino acid derivatives. Angew Chem Int Ed Engl (2003) 0.99
Palladium-catalyzed alpha-arylation of esters and amides under more neutral conditions. J Am Chem Soc (2003) 0.99
Enantioselective iridium-catalyzed allylic arylation. Chemistry (2009) 0.97
The Construction of All-Carbon Quaternary Stereocenters by Use of Pd-Catalyzed Asymmetric Allylic Alkylation Reactions in Total Synthesis. European J Org Chem (2013) 0.96
Mild palladium-catalyzed selective monoarylation of nitriles. J Am Chem Soc (2005) 0.96
Simple and efficient asymmetric alpha-alkylation and alpha,alpha-bisalkylation of acyclic ketones by using chiral N-amino cyclic carbamate hydrazones. Angew Chem Int Ed Engl (2008) 0.95
Cation control of diastereoselectivity in iridium-catalyzed allylic substitutions. Formation of enantioenriched tertiary alcohols and thioethers by allylation of 5H-oxazol-4-ones and 5H-thiazol-4-ones. J Am Chem Soc (2013) 0.95
Ir-catalyzed regio- and enantioselective decarboxylative allylic alkylations. Org Lett (2007) 0.91
Total synthesis of (-)-spongidepsin. Org Lett (2006) 0.91
Iridium-catalyzed regioselective and enantioselective allylation of trimethylsiloxyfuran. J Am Chem Soc (2012) 0.89
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Iridium-catalyzed enantioselective allylic alkynylation. Angew Chem Int Ed Engl (2013) 0.86
Enantioselective functionalization of indoles and pyrroles via an in situ-formed spiro intermediate. J Am Chem Soc (2013) 0.86
Preparation and evaluation of o/w type emulsions containing antitumor prostaglandin. Adv Drug Deliv Rev (2000) 0.81
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Designed prostaglandins with neurotrophic activities. Chembiochem (2000) 0.76
Synthesis of neuroprotective cyclopentenone prostaglandin analogs: suppression of manganese-induced apoptosis of PC12 cells. Bioorg Med Chem Lett (2006) 0.76
C-H activation for the construction of C-B bonds. Chem Rev (2010) 3.17
Palladium-catalyzed alpha-arylation of carbonyl compounds and nitriles. Acc Chem Res (2003) 2.47
Mild iridium-catalyzed borylation of arenes. High turnover numbers, room temperature reactions, and isolation of a potential intermediate. J Am Chem Soc (2002) 2.41
A simple, multidimensional approach to high-throughput discovery of catalytic reactions. Science (2011) 1.90
Air stable, sterically hindered ferrocenyl dialkylphosphines for palladium-catalyzed C[bond]C, C[bond]N, and C[bond]O bond-forming cross-couplings. J Org Chem (2002) 1.72
Enantioselective alpha-arylation of ketones with aryl triflates catalyzed by difluorphos complexes of palladium and nickel. J Am Chem Soc (2007) 1.72
Highly reactive, general, and long-lived catalysts for coupling heteroaryl and aryl chlorides with primary nitrogen nucleophiles. Angew Chem Int Ed Engl (2005) 1.71
Rhodium-catalyzed intermolecular C-H silylation of arenes with high steric regiocontrol. Science (2014) 1.69
A broadly applicable copper reagent for trifluoromethylations and perfluoroalkylations of aryl iodides and bromides. Angew Chem Int Ed Engl (2011) 1.68
Palladium-catalyzed coupling of ammonia and lithium amide with aryl halides. J Am Chem Soc (2006) 1.67
Hydroamination and hydroalkoxylation catalyzed by triflic acid. Parallels to reactions initiated with metal triflates. Org Lett (2006) 1.66
Brønsted acid-catalyzed intramolecular hydroamination of protected alkenylamines. Synthesis of pyrrolidines and piperidines. Org Lett (2002) 1.66
Copper complexes of anionic nitrogen ligands in the amidation and imidation of aryl halides. J Am Chem Soc (2008) 1.63
On the interpretation of deuterium kinetic isotope effects in C-H bond functionalizations by transition-metal complexes. Angew Chem Int Ed Engl (2012) 1.61
Highly reactive, general and long-lived catalysts for palladium-catalyzed amination of heteroaryl and aryl chlorides, bromides, and iodides: scope and structure-activity relationships. J Am Chem Soc (2008) 1.60
Regio- and enantioselective allylic amination of achiral allylic esters catalyzed by an iridium-phosphoramidite complex. J Am Chem Soc (2002) 1.58
Mechanism of the mild functionalization of arenes by diboron reagents catalyzed by iridium complexes. Intermediacy and chemistry of bipyridine-ligated iridium trisboryl complexes. J Am Chem Soc (2005) 1.49
Oxidative addition of aryl tosylates to palladium(0) and coupling of unactivated aryl tosylates at room temperature. J Am Chem Soc (2003) 1.46
Catalytic functionalization of unactivated primary C-H bonds directed by an alcohol. Nature (2012) 1.40
Regioselective and enantioselective iridium-catalyzed allylation of enamines. J Am Chem Soc (2007) 1.38
Unparalleled rates for the activation of aryl chlorides and bromides: coupling with amines and boronic acids in minutes at room temperature. Angew Chem Int Ed Engl (2002) 1.38
A simple iridium catalyst with a single resolved stereocenter for enantioselective allylic amination. Catalyst selection from mechanistic analysis. J Am Chem Soc (2005) 1.37
A highly active palladium catalyst for intermolecular hydroamination. Factors that control reactivity and additions of functionalized anilines to dienes and vinylarenes. J Am Chem Soc (2006) 1.37
A stoichiometric aromatic CbondH borylation catalyzed by iridium(i)/2,2'-bipyridine complexes at room temperature. Angew Chem Int Ed Engl (2002) 1.35
Synthesis, structure, theoretical studies, and Ligand exchange reactions of monomeric, T-shaped arylpalladium(II) halide complexes with an additional, weak agostic interaction. J Am Chem Soc (2004) 1.35
Lewis acid acceleration of C-N bond-forming reductive elimination from heteroarylpalladium complexes and catalytic amidation of heteroaryl bromides. J Am Chem Soc (2007) 1.27
Iridium-catalyzed arene ortho-silylation by formal hydroxyl-directed C-H activation. J Am Chem Soc (2010) 1.27
Copper-mediated fluorination of aryl iodides. J Am Chem Soc (2012) 1.26
Zinc trimethylsilylamide as a mild ammonia equivalent and base for the amination of aryl halides and triflates. Org Lett (2005) 1.26
Regiospecific functionalization of methyl C-H bonds of alkyl groups in reagents with heteroatom functionality. J Am Chem Soc (2004) 1.26
Palladium-catalyzed arylation of trimethylsilyl enolates of esters and imides. High functional group tolerance and stereoselective synthesis of alpha-aryl carboxylic acid derivatives. J Am Chem Soc (2004) 1.26
Silyl-directed, iridium-catalyzed ortho-borylation of arenes. A one-pot ortho-borylation of phenols, arylamines, and alkylarenes. J Am Chem Soc (2008) 1.25
Distinguishing between pathways for transmetalation in Suzuki-Miyaura reactions. J Am Chem Soc (2011) 1.25
A general and long-lived catalyst for the palladium-catalyzed coupling of aryl halides with thiols. J Am Chem Soc (2006) 1.25
Intermolecular, catalytic asymmetric hydroamination of bicyclic alkenes and dienes in high yield and enantioselectivity. J Am Chem Soc (2008) 1.25
Identification of an activated catalyst in the iridium-catalyzed allylic amination and etherification. Increased rates, scope, and selectivity. J Am Chem Soc (2003) 1.23
Regio- and enantioselective iridium-catalyzed intermolecular allylic etherification of achiral allylic carbonates with phenoxides. J Am Chem Soc (2003) 1.23
Rhodium-catalyzed anti-Markovnikov hydroamination of vinylarenes. J Am Chem Soc (2003) 1.23
Kumada coupling of aryl and vinyl tosylates under mild conditions. J Org Chem (2005) 1.22
Direct, catalytic hydroaminoalkylation of unactivated olefins with N-alkyl arylamines. J Am Chem Soc (2007) 1.21
Synthesis, structure, and reductive elimination chemistry of three-coordinate arylpalladium amido complexes. J Am Chem Soc (2004) 1.21
Oxidative addition of ammonia to form a stable monomeric amido hydride complex. Science (2005) 1.21
Autocatalytic oxidative addition of PhBr to Pd(PtBu3)2 via Pd(PtBu3)2(H)(Br). J Am Chem Soc (2008) 1.20
Meta halogenation of 1,3-disubstituted arenes via iridium-catalyzed arene borylation. J Am Chem Soc (2007) 1.20
Ruthenium-catalyzed anti-Markovnikov hydroamination of vinylarenes. J Am Chem Soc (2004) 1.20
Direct, iridium-catalyzed enantioselective and regioselective allylic etherification with aliphatic alcohols. Angew Chem Int Ed Engl (2008) 1.17
Iridium-catalyzed, silyl-directed borylation of nitrogen-containing heterocycles. J Am Chem Soc (2010) 1.17
Palladium-catalyzed amination of aromatic C-H bonds with oxime esters. J Am Chem Soc (2010) 1.17
Iridium-catalyzed intermolecular allylic etherification with aliphatic alkoxides: asymmetric synthesis of dihydropyrans and dihydrofurans. Angew Chem Int Ed Engl (2004) 1.17
Palladium-catalyzed alpha-arylation of aldehydes with bromo- and chloroarenes catalyzed by [{Pd(allyl)Cl}2] and dppf or Q-phos. Angew Chem Int Ed Engl (2008) 1.16
Copper-mediated difluoromethylation of aryl and vinyl iodides. J Am Chem Soc (2012) 1.16
Intermolecular insertion of ethylene and octene into a palladium-amide bond. Spectroscopic evidence for an ethylene amido intermediate. J Am Chem Soc (2010) 1.16
Palladium-catalyzed coupling of ammonia with aryl chlorides, bromides, iodides, and sulfonates: a general method for the preparation of primary arylamines. J Am Chem Soc (2009) 1.14
Effect of ligand steric properties and halide identity on the mechanism for oxidative addition of haloarenes to trialkylphosphine Pd(0) complexes. J Am Chem Soc (2009) 1.14
Efficient synthesis of alpha-aryl esters by room-temperature palladium-catalyzed coupling of aryl halides with ester enolates. J Am Chem Soc (2002) 1.13
Enantioselective iridium-catalyzed allylic amination of ammonia and convenient ammonia surrogates. Org Lett (2007) 1.13
Resting state and kinetic studies on the asymmetric allylic substitutions catalyzed by iridium-phosphoramidite complexes. J Am Chem Soc (2007) 1.12
Directly observed reductive elimination of aryl halides from monomeric arylpalladium(II) halide complexes. J Am Chem Soc (2003) 1.12
A new pathway for hydroamination. Mechanism of palladium-catalyzed addition of anilines to vinylarenes. J Am Chem Soc (2002) 1.12
Iridium-catalyzed regio- and enantioselective allylation of ketone enolates. J Am Chem Soc (2005) 1.12
Iridium-catalyzed, asymmetric amination of allylic alcohols activated by Lewis acids. J Am Chem Soc (2007) 1.10
Organometallic chemistry of amidate complexes. accelerating effect of bidentate ligands on the reductive elimination of N-aryl amidates from palladium(II). J Am Chem Soc (2006) 1.10
Reevaluation of the mechanism of the amination of aryl halides catalyzed by BINAP-ligated palladium complexes. J Am Chem Soc (2006) 1.09
A general strategy for the perfluoroalkylation of arenes and arylbromides by using arylboronate esters and [(phen)CuR(F)]. Angew Chem Int Ed Engl (2011) 1.09
Selective, nickel-catalyzed hydrogenolysis of aryl ethers. Science (2011) 1.08
Copper(I) phenoxide complexes in the etherification of aryl halides. Angew Chem Int Ed Engl (2010) 1.08
Synthesis, characterization, and reactivity of monomeric, arylpalladium halide complexes with a hindered phosphine as the only dative ligand. J Am Chem Soc (2002) 1.08
Nickel-catalyzed asymmetric α-arylation and heteroarylation of ketones with chloroarenes: effect of halide on selectivity, oxidation state, and room-temperature reactions. J Am Chem Soc (2011) 1.08
Recent advances in the discovery of organometallic catalysts using high-throughput screening assays. Curr Opin Chem Biol (2003) 1.07
Palladium-catalyzed arylation of malonates and cyanoesters using sterically hindered trialkyl- and ferrocenyldialkylphosphine ligands. J Org Chem (2002) 1.07
The allyl intermediate in regioselective and enantioselective iridium-catalyzed asymmetric allylic substitution reactions. J Am Chem Soc (2009) 1.07
Enantioselective allylation of aromatic amines after in situ generation of an activated cyclometalated iridium catalyst. Angew Chem Int Ed Engl (2004) 1.06
A general nickel-catalyzed hydroamination of 1,3-dienes by alkylamines: catalyst selection, scope, and mechanism. J Am Chem Soc (2002) 1.06
Reductive elimination of ether from T-shaped, monomeric arylpalladium alkoxides. Angew Chem Int Ed Engl (2007) 1.05
Rhodium-catalyzed intramolecular, anti-Markovnikov hydroamination. Synthesis of 3-arylpiperidines. J Am Chem Soc (2006) 1.05
Distinct mechanisms for the oxidative addition of chloro-, bromo-, and iodoarenes to a bisphosphine palladium(0) complex with hindered ligands. J Am Chem Soc (2005) 1.05
Cu(I)-amido complexes in the Ullmann reaction: reactions of Cu(I)-amido complexes with iodoarenes with and without autocatalysis by CuI. J Am Chem Soc (2010) 1.05
Palladium-catalyzed alpha-arylation of esters with chloroarenes. Org Lett (2008) 1.04
Sterically controlled, palladium-catalyzed intermolecular amination of arenes. J Am Chem Soc (2013) 1.03
Intermolecular migratory insertion of unactivated olefins into palladium-nitrogen bonds. Steric and electronic effects on the rate of migratory insertion. J Am Chem Soc (2011) 1.03
Control of diastereoselectivity for iridium-catalyzed allylation of a prochiral nucleophile with a phosphate counterion. J Am Chem Soc (2013) 1.03
Palladium-catalyzed intermolecular alpha-arylation of zinc amide enolates under mild conditions. J Am Chem Soc (2006) 1.03
One-pot synthesis of arylboronic acids and aryl trifluoroborates by Ir-catalyzed borylation of arenes. Org Lett (2007) 1.03
Scope and mechanism of palladium-catalyzed amination of five-membered heterocyclic halides. J Org Chem (2003) 1.02
Copper-mediated fluorination of arylboronate esters. Identification of a copper(III) fluoride complex. J Am Chem Soc (2013) 1.01
Palladium-catalyzed amination of aryl and heteroaryl tosylates at room temperature. J Am Chem Soc (2008) 1.00
Controlling first-row catalysts: amination of aryl and heteroaryl chlorides and bromides with primary aliphatic amines catalyzed by a BINAP-ligated single-component Ni(0) complex. J Am Chem Soc (2014) 1.00
Effects of catalyst activation and ligand steric properties on the enantioselective allylation of amines and phenoxides. Org Lett (2005) 1.00
Palladium-catalyzed alpha-arylation of esters and amides under more neutral conditions. J Am Chem Soc (2003) 0.99
Intermolecular and intramolecular, platinum-catalyzed, acceptorless dehydrogenative coupling of hydrosilanes with aryl and aliphatic methyl C-H bonds. J Am Chem Soc (2005) 0.99
Pronounced effects of substituents on the iridium-catalyzed borylation of aryl C-H bonds. Chem Commun (Camb) (2009) 0.99
Regio- and enantioselective N-allylations of imidazole, benzimidazole, and purine heterocycles catalyzed by single-component metallacyclic iridium complexes. J Am Chem Soc (2009) 0.99
Aqueous hydroxide as a base for palladium-catalyzed amination of aryl chlorides and bromides. J Org Chem (2002) 0.98
Highly reactive, single-component nickel catalyst precursor for Suzuki-Miyuara cross-coupling of heteroaryl boronic acids with heteroaryl halides. Angew Chem Int Ed Engl (2012) 0.98
Trans influence on the rate of reductive elimination. Reductive elimination of amines from isomeric arylpalladium amides with unsymmetrical coordination spheres. J Am Chem Soc (2003) 0.98
Room temperature borylation of arenes and heteroarenes using stoichiometric amounts of pinacolborane catalyzed by iridium complexes in an inert solvent. Chem Commun (Camb) (2003) 0.97
Primary tert- and sec-allylamines via palladium-catalyzed hydroamination and allylic substitution with hydrazine and hydroxylamine derivatives. Angew Chem Int Ed Engl (2007) 0.97
Arenes to anilines and aryl ethers by sequential iridium-catalyzed borylation and copper-catalyzed coupling. Org Lett (2007) 0.97
Selective C-H fluorination of pyridines and diazines inspired by a classic amination reaction. Science (2013) 0.97
Mild palladium-catalyzed selective monoarylation of nitriles. J Am Chem Soc (2005) 0.96