Published in J Org Chem on March 21, 2003
One-pot synthesis of enantiopure syn-1,3-diacetates from racemic syn/anti mixtures of 1,3-diols by dynamic kinetic asymmetric transformation. Proc Natl Acad Sci U S A (2004) 0.75
Mechanistic aspects of transition metal-catalyzed hydrogen transfer reactions. Chem Soc Rev (2006) 1.38
Catalytic oxidation of organic substrates by molecular oxygen and hydrogen peroxide by multistep electron transfer--a biomimetic approach. Angew Chem Int Ed Engl (2008) 1.32
Combination of enzymes and metal catalysts. A powerful approach in asymmetric catalysis. Chem Rev (2003) 1.14
X-ray structure of Candida antarctica lipase A shows a novel lid structure and a likely mode of interfacial activation. J Mol Biol (2007) 1.01
Combined ruthenium(II) and lipase catalysis for efficient dynamic kinetic resolution of secondary alcohols. Insight into the racemization mechanism. J Am Chem Soc (2005) 1.01
Enantioselective alpha-hydroxylation of 2-arylacetic acid derivatives and buspirone catalyzed by engineered cytochrome P450 BM-3. J Am Chem Soc (2006) 1.00
Palladium(II)-catalyzed oxidative carbocyclization of aza-enallenes. Angew Chem Int Ed Engl (2010) 0.95
(S)-selective kinetic resolution and chemoenzymatic dynamic kinetic resolution of secondary alcohols. Chemistry (2005) 0.95
Combinatorial reshaping of the Candida antarctica lipase A substrate pocket for enantioselectivity using an extremely condensed library. Proc Natl Acad Sci U S A (2011) 0.95
Photosensitized water oxidation by use of a bioinspired manganese catalyst. Angew Chem Int Ed Engl (2011) 0.93
Palladium-catalyzed oxidative borylative carbocyclization of enallenes. Angew Chem Int Ed Engl (2011) 0.93
Highly efficient synthesis of enantiopure diacetylated C(2)-symmetric diols by ruthenium- and enzyme-catalyzed dynamic kinetic asymmetric transformation (DYKAT). Chemistry (2006) 0.90
Dynamic kinetic resolution catalyzed by enzymes and metals. Curr Opin Chem Biol (2007) 0.90
Directed evolution of an enantioselective lipase with broad substrate scope for hydrolysis of alpha-substituted esters. J Am Chem Soc (2010) 0.90
Water as nucleophile in palladium-catalyzed oxidative carbohydroxylation of allene-substituted conjugated dienes. J Am Chem Soc (2007) 0.89
Palladium-catalyzed oxidative arylating carbocyclization of allenynes. Angew Chem Int Ed Engl (2012) 0.89
Control of selectivity in palladium-catalyzed oxidative carbocyclization/borylation of allenynes. Angew Chem Int Ed Engl (2013) 0.89
Efficient ruthenium-catalyzed transfer hydrogenation/hydrogenation of 1,3-cycloalkanediones to 1,3-cycloalkanediols using microwave heating. J Org Chem (2006) 0.89
Palladium-catalyzed oxidative carbocyclizations. Chemistry (2012) 0.88
PdII-catalyzed aerobic allylic oxidative carbocyclization of allene-substituted olefins: immobilization of an oxygen-activating catalyst. Angew Chem Int Ed Engl (2006) 0.88
Enantioselective synthesis of α-methyl carboxylic acids from readily available starting materials via chemoenzymatic dynamic kinetic resolution. J Org Chem (2010) 0.87
Mechanistic study of hydrogen transfer to imines from a hydroxycyclopentadienyl ruthenium hydride. Experimental support for a mechanism involving coordination of imine to ruthenium prior to hydrogen transfer. J Am Chem Soc (2006) 0.87
Carbon-carbon bond formation in palladium(II)-catalyzed allylic oxidation: a novel oxidative carbocyclization of allene-substituted olefins. J Am Chem Soc (2003) 0.87
Efficient ruthenium-catalyzed aerobic oxidation of alcohols using a biomimetic coupled catalytic system. J Org Chem (2002) 0.86
Copper-catalyzed N-allenylation of allylic sulfonamides. Org Lett (2009) 0.86
Highly dispersed palladium nanoparticles on mesocellular foam: an efficient and recyclable heterogeneous catalyst for alcohol oxidation. Chemistry (2012) 0.85
Chemoenzymatic dynamic kinetic resolution of axially chiral allenes. Chemistry (2010) 0.85
Highly compatible metal and enzyme catalysts for efficient dynamic kinetic resolution of alcohols at ambient temperature. Angew Chem Int Ed Engl (2004) 0.85
Palladium(II)/Brønsted Acid-Catalyzed Enantioselective Oxidative Carbocyclization-Borylation of Enallenes. Angew Chem Int Ed Engl (2015) 0.85
The syn/anti-dichotomy in the palladium-catalyzed addition of nucleophiles to alkenes. Chemistry (2014) 0.85
Mechanism of hydrogen transfer to imines from a hydroxycyclopentadienyl ruthenium hydride. Support for a stepwise mechanism. Chem Commun (Camb) (2004) 0.84
Palladium-catalyzed oxidative carbocyclization/arylation of enallenes. Org Lett (2011) 0.84
An enantioselective route to alpha-methyl carboxylic acids via metal and enzyme catalysis. Org Lett (2007) 0.84
A chemoenzymatic approach to enantiomerically pure amines using dynamic kinetic resolution: application to the synthesis of norsertraline. Chemistry (2009) 0.83
Dynamic processes in the copper-catalyzed substitution of chiral allylic acetates leading to loss of chiral information. Chemistry (2007) 0.83
Chemoenzymatic dynamic kinetic resolution of beta-halo alcohols. An efficient route to chiral epoxides. J Org Chem (2002) 0.83
Efficient ruthenium-catalyzed aerobic oxidation of amines by using a biomimetic coupled catalytic system. Chemistry (2005) 0.83
Small Pd nanoparticles supported in large pores of mesocellular foam: an excellent catalyst for racemization of amines. Chemistry (2011) 0.83
Chemoenzymatic dynamic kinetic resolution. Trends Biotechnol (2004) 0.83
Dehydrogenation of aromatic amines to imines via ruthenium-catalyzed hydrogen transfer. Chem Commun (Camb) (2002) 0.83
Allenes as carbon nucleophiles in intramolecular attack on (pi-1,3-diene)palladium complexes: evidence for trans carbopalladation of the 1,3-diene. Chemistry (2003) 0.83
Palladium-catalyzed oxidative acyloxylation/carbocyclization of allenynes. Angew Chem Int Ed Engl (2013) 0.82
Palladium-catalyzed aerobic domino oxidative carbocyclization-alkynylation of allenynes. Angew Chem Int Ed Engl (2013) 0.82
Enantioselective synthesis of syn- and anti-1,3-aminoalcohols via β-aminoketones and subsequent reduction/dynamic kinetic asymmetric transformation. J Am Chem Soc (2010) 0.82
Aerobic lactonization of diols by biomimetic oxidation. Chemistry (2011) 0.82
Palladium-catalyzed oxidative arylating carbocyclization of allenynes: control of selectivity and role of H₂O. Angew Chem Int Ed Engl (2014) 0.82
Palladium-catalyzed oxidative diarylating carbocyclization of enynes. Org Lett (2012) 0.81
Influence of delta-functional groups on the enantiorecognition of secondary alcohols by Candida antarctica lipase B. Chembiochem (2008) 0.81
Gold-catalyzed cyclization of allene-substituted malonate esters: synthesis of beta,gamma-unsaturated delta-lactones. Org Lett (2007) 0.81
Palladium-catalyzed oxidative carbocyclization-carbonylation of allenynes and enallenes. Chemistry (2014) 0.81
Palladium(II)-catalyzed oxidative cyclization of allylic tosylcarbamates: scope, derivatization, and mechanistic aspects. Chemistry (2012) 0.81
Cycloisomerization of acetylenic acids to γ-alkylidene lactones using a palladium(II) catalyst supported on amino-functionalized siliceous mesocellular foam. J Org Chem (2014) 0.80
An efficient route to chiral alpha- and beta-hydroxyalkanephosphonates. J Org Chem (2003) 0.80
Aerobic double dehydrogenative cross coupling between cyclic saturated ketones and simple arenes. Chemistry (2014) 0.80
Efficient reoxidation of palladium by a hybrid catalyst in aerobic palladium-catalyzed carbocyclization of enallenes. Chemistry (2009) 0.80
Enantioselective enzymatic desymmetrization of prochiral allenic diols. Angew Chem Int Ed Engl (2011) 0.80
Asymmetric synthesis of bicyclic diol derivatives through metal and enzyme catalysis: application to the formal synthesis of sertraline. Chemistry (2010) 0.80
Mechanism of ruthenium-catalyzed hydrogen transfer reactions. Concerted transfer of OH and CH hydrogens from an alcohol to a (Cyclopentadienone)ruthenium complex. J Org Chem (2003) 0.79
Stereoselective palladium-catalyzed carbocyclization of allenic allylic carboxylates. J Am Chem Soc (2003) 0.79
Unexpected formation of a cyclopentadienylruthenium alkoxycarbonyl complex with a coordinated C=C bond. J Am Chem Soc (2009) 0.79
Enzymatic kinetic resolution and chemoenzymatic dynamic kinetic resolution of delta-hydroxy esters. An efficient route to chiral delta-lactones. J Org Chem (2002) 0.79
Allenes as carbon nucleophiles in palladium-catalyzed reactions: observation of anti attack of allenes on (pi-allyl)palladium complexes. J Am Chem Soc (2002) 0.79
Enantiopure 1,5-diols from dynamic kinetic asymmetric transformation. Useful synthetic intermediates for the preparation of chiral heterocycles. Org Lett (2008) 0.79
Biomimetic aerobic oxidation of amino alcohols to lactams. Chemistry (2012) 0.78
Biomimetic oxidative coupling of benzylamines and 2-aminophenols: synthesis of benzoxazoles. Chemistry (2012) 0.78
C-2 selective arylation of indoles with heterogeneous nanopalladium and diaryliodonium salts. Chemistry (2014) 0.78
Enzyme- and ruthenium-catalyzed dynamic kinetic asymmetric transformation of 1,5-diols. Application to the synthesis of (+)-Solenopsin A. J Org Chem (2009) 0.78
Palladium-catalyzed oxidative domino carbocyclization-carbonylation-alkynylation of enallenes. Org Lett (2014) 0.78
CO assistance in ligand exchange of a ruthenium racemization catalyst: identification of an acyl intermediate. J Am Chem Soc (2009) 0.78
Investigation of the impact of water on the enantioselectivity displayed by CALB in the kinetic resolution of δ-functionalized alkan-2-ol derivatives. Chemistry (2014) 0.78
Highly efficient route for enantioselective preparation of chlorohydrins via dynamic kinetic resolution. Org Lett (2008) 0.78
Light-induced water oxidation by a Ru complex containing a bio-inspired ligand. Chemistry (2011) 0.78
Synthesis of conjugated dienes via a biomimetic aerobic oxidative coupling of two C(vinyl)-H bonds. Chemistry (2013) 0.78
Divergent asymmetric synthesis of 3,5-disubstituted piperidines. J Org Chem (2006) 0.78
Aerobic oxidative coupling of arenes and olefins through a biomimetic approach. Chemistry (2013) 0.78
Co-immobilization of an enzyme and a metal into the compartments of mesoporous silica for cooperative tandem catalysis: an artificial metalloenzyme. Angew Chem Int Ed Engl (2013) 0.77
An unexpectedly mild thermal Alder-ene-type cyclization of enallenes. J Org Chem (2006) 0.77
Efficient and selective sulfoxidation by hydrogen peroxide, using a recyclable flavin--[BMIm]PF6 catalytic system. J Org Chem (2006) 0.77
Enzymatic kinetic resolution of primary allenic alcohols. Application to the total synthesis and stereochemical assignment of striatisporolide A. Org Biomol Chem (2009) 0.77
Ruthenium-catalyzed transfer hydrogenation of imines by propan-2-ol in benzene. Chemistry (2002) 0.77
Preparation and redox properties of N,N,N-1,3,5-trialkylated flavin derivatives and their activity as redox catalysts. Chemistry (2004) 0.77
Chemoenzymatic dynamic kinetic resolution of allylic alcohols: a highly enantioselective route to acyloin acetates. Org Lett (2007) 0.77
Aerobic direct C-H arylation of nonbiased olefins. Org Lett (2014) 0.77
Mutated variant of Candida antarctica lipase B in (S)-selective dynamic kinetic resolution of secondary alcohols. Org Biomol Chem (2010) 0.77
Combinatorial library based engineering of Candida antarctica lipase A for enantioselective transacylation of sec-alcohols in organic solvent. Angew Chem Int Ed Engl (2015) 0.76
Large-scale ruthenium- and enzyme-catalyzed dynamic kinetic resolution of (rac)-1-phenylethanol. Beilstein J Org Chem (2007) 0.76
Tuning of the electronic properties of a cyclopentadienylruthenium catalyst to match racemization of electron-rich and electron-deficient alcohols. Chemistry (2011) 0.76
Enantioselective synthesis of (R)-bufuralol via dynamic kinetic resolution in the key step. J Org Chem (2010) 0.76
Kinetic resolution and chemoenzymatic dynamic kinetic resolution of functionalized gamma-hydroxy amides. J Org Chem (2005) 0.76
A chemoenzymatic dynamic kinetic resolution approach to enantiomerically pure (R)- and (S)-duloxetine. J Org Chem (2011) 0.76
Palladium(II)-catalyzed intramolecular 1,4-oxyacyloxylation of conjugated dienes. A stereocontrolled route to fused six-membered lactones and pyrans. J Org Chem (2004) 0.76
Palladium-catalyzed carbocyclization of allene-diene derivatives. Exploring different nucleophiles. J Org Chem (2003) 0.76
Synthesis of a neonicotinoide pesticide derivative via chemoenzymatic dynamic kinetic resolution. J Org Chem (2009) 0.76
Access to cinnamyl derivatives from arenes and allyl esters by a biomimetic aerobic oxidative dehydrogenative coupling. Org Lett (2014) 0.76
Enantioselective route to ketones and lactones from exocyclic allylic alcohols via metal and enzyme catalysis. Org Lett (2012) 0.76
One-pot synthesis of enantiopure syn-1,3-diacetates from racemic syn/anti mixtures of 1,3-diols by dynamic kinetic asymmetric transformation. Proc Natl Acad Sci U S A (2004) 0.75
Well-defined palladium nanoparticles supported on siliceous mesocellular foam as heterogeneous catalysts for the oxidation of water. Chemistry (2015) 0.75
Mild deoxygenation of aromatic ketones and aldehydes over Pd/C using polymethylhydrosiloxane as the reducing agent. Angew Chem Int Ed Engl (2015) 0.75
Palladium-catalyzed oxidative regio- and diastereoselective diarylating carbocyclization of dienynes. Chemistry (2013) 0.75