Published in Chemistry on July 21, 2003
The first transannular [4+3] cycloaddition reaction: synthesis of the ABCD ring structure of cortistatins. Tetrahedron Lett (2008) 1.18
Palladium(II)/Brønsted Acid-Catalyzed Enantioselective Oxidative Carbocyclization-Borylation of Enallenes. Angew Chem Int Ed Engl (2015) 0.85
Mechanistic aspects of transition metal-catalyzed hydrogen transfer reactions. Chem Soc Rev (2006) 1.38
Catalytic oxidation of organic substrates by molecular oxygen and hydrogen peroxide by multistep electron transfer--a biomimetic approach. Angew Chem Int Ed Engl (2008) 1.32
Asymmetric organocatalytic epoxidation of alpha,beta-unsaturated aldehydes with hydrogen peroxide. J Am Chem Soc (2005) 1.23
Combination of enzymes and metal catalysts. A powerful approach in asymmetric catalysis. Chem Rev (2003) 1.14
Fgf20 governs formation of primary and secondary dermal condensations in developing hair follicles. Genes Dev (2013) 1.10
X-ray structure of Candida antarctica lipase A shows a novel lid structure and a likely mode of interfacial activation. J Mol Biol (2007) 1.01
Combined ruthenium(II) and lipase catalysis for efficient dynamic kinetic resolution of secondary alcohols. Insight into the racemization mechanism. J Am Chem Soc (2005) 1.01
Enantioselective alpha-hydroxylation of 2-arylacetic acid derivatives and buspirone catalyzed by engineered cytochrome P450 BM-3. J Am Chem Soc (2006) 1.00
Palladium(II)-catalyzed oxidative carbocyclization of aza-enallenes. Angew Chem Int Ed Engl (2010) 0.95
(S)-selective kinetic resolution and chemoenzymatic dynamic kinetic resolution of secondary alcohols. Chemistry (2005) 0.95
Combinatorial reshaping of the Candida antarctica lipase A substrate pocket for enantioselectivity using an extremely condensed library. Proc Natl Acad Sci U S A (2011) 0.95
Photosensitized water oxidation by use of a bioinspired manganese catalyst. Angew Chem Int Ed Engl (2011) 0.93
Palladium-catalyzed oxidative borylative carbocyclization of enallenes. Angew Chem Int Ed Engl (2011) 0.93
Asymmetric multicomponent domino reactions and highly enantioselective conjugated addition of thiols to alpha,beta-unsaturated aldehydes. J Am Chem Soc (2005) 0.91
Dynamic kinetic resolution catalyzed by enzymes and metals. Curr Opin Chem Biol (2007) 0.90
Directed evolution of an enantioselective lipase with broad substrate scope for hydrolysis of alpha-substituted esters. J Am Chem Soc (2010) 0.90
Highly efficient synthesis of enantiopure diacetylated C(2)-symmetric diols by ruthenium- and enzyme-catalyzed dynamic kinetic asymmetric transformation (DYKAT). Chemistry (2006) 0.90
Palladium-catalyzed oxidative arylating carbocyclization of allenynes. Angew Chem Int Ed Engl (2012) 0.89
Control of selectivity in palladium-catalyzed oxidative carbocyclization/borylation of allenynes. Angew Chem Int Ed Engl (2013) 0.89
Efficient ruthenium-catalyzed transfer hydrogenation/hydrogenation of 1,3-cycloalkanediones to 1,3-cycloalkanediols using microwave heating. J Org Chem (2006) 0.89
Water as nucleophile in palladium-catalyzed oxidative carbohydroxylation of allene-substituted conjugated dienes. J Am Chem Soc (2007) 0.89
PdII-catalyzed aerobic allylic oxidative carbocyclization of allene-substituted olefins: immobilization of an oxygen-activating catalyst. Angew Chem Int Ed Engl (2006) 0.88
Palladium-catalyzed oxidative carbocyclizations. Chemistry (2012) 0.88
Enantioselective synthesis of α-methyl carboxylic acids from readily available starting materials via chemoenzymatic dynamic kinetic resolution. J Org Chem (2010) 0.87
Carbon-carbon bond formation in palladium(II)-catalyzed allylic oxidation: a novel oxidative carbocyclization of allene-substituted olefins. J Am Chem Soc (2003) 0.87
Mechanistic study of hydrogen transfer to imines from a hydroxycyclopentadienyl ruthenium hydride. Experimental support for a mechanism involving coordination of imine to ruthenium prior to hydrogen transfer. J Am Chem Soc (2006) 0.87
Organocatalytic conjugate addition of malonates to alpha,beta-unsaturated aldehydes: asymmetric formal synthesis of (-)-paroxetine, chiral lactams, and lactones. Angew Chem Int Ed Engl (2006) 0.86
Synthesis of 4-methyldienoates using a vinylogous Horner-Wadsworth-Emmons reagent. Application to the synthesis of trichostatic acid. J Org Chem (2010) 0.86
Efficient ruthenium-catalyzed aerobic oxidation of alcohols using a biomimetic coupled catalytic system. J Org Chem (2002) 0.86
Copper-catalyzed N-allenylation of allylic sulfonamides. Org Lett (2009) 0.86
Chemoenzymatic dynamic kinetic resolution of axially chiral allenes. Chemistry (2010) 0.85
Highly compatible metal and enzyme catalysts for efficient dynamic kinetic resolution of alcohols at ambient temperature. Angew Chem Int Ed Engl (2004) 0.85
The syn/anti-dichotomy in the palladium-catalyzed addition of nucleophiles to alkenes. Chemistry (2014) 0.85
Palladium(II)/Brønsted Acid-Catalyzed Enantioselective Oxidative Carbocyclization-Borylation of Enallenes. Angew Chem Int Ed Engl (2015) 0.85
Highly dispersed palladium nanoparticles on mesocellular foam: an efficient and recyclable heterogeneous catalyst for alcohol oxidation. Chemistry (2012) 0.85
An enantioselective route to alpha-methyl carboxylic acids via metal and enzyme catalysis. Org Lett (2007) 0.84
Mechanism of hydrogen transfer to imines from a hydroxycyclopentadienyl ruthenium hydride. Support for a stepwise mechanism. Chem Commun (Camb) (2004) 0.84
Palladium-catalyzed oxidative carbocyclization/arylation of enallenes. Org Lett (2011) 0.84
Small Pd nanoparticles supported in large pores of mesocellular foam: an excellent catalyst for racemization of amines. Chemistry (2011) 0.83
Chemoenzymatic dynamic kinetic resolution of beta-halo alcohols. An efficient route to chiral epoxides. J Org Chem (2002) 0.83
Dynamic processes in the copper-catalyzed substitution of chiral allylic acetates leading to loss of chiral information. Chemistry (2007) 0.83
A chemoenzymatic approach to enantiomerically pure amines using dynamic kinetic resolution: application to the synthesis of norsertraline. Chemistry (2009) 0.83
Dehydrogenation of aromatic amines to imines via ruthenium-catalyzed hydrogen transfer. Chem Commun (Camb) (2002) 0.83
Chemoenzymatic dynamic kinetic resolution. Trends Biotechnol (2004) 0.83
Efficient ruthenium-catalyzed aerobic oxidation of amines by using a biomimetic coupled catalytic system. Chemistry (2005) 0.83
Palladium-catalyzed oxidative acyloxylation/carbocyclization of allenynes. Angew Chem Int Ed Engl (2013) 0.82
Palladium-catalyzed aerobic domino oxidative carbocyclization-alkynylation of allenynes. Angew Chem Int Ed Engl (2013) 0.82
Palladium-catalyzed oxidative arylating carbocyclization of allenynes: control of selectivity and role of H₂O. Angew Chem Int Ed Engl (2014) 0.82
Enantioselective synthesis of syn- and anti-1,3-aminoalcohols via β-aminoketones and subsequent reduction/dynamic kinetic asymmetric transformation. J Am Chem Soc (2010) 0.82
Aerobic lactonization of diols by biomimetic oxidation. Chemistry (2011) 0.82
Palladium-catalyzed oxidative carbocyclization-carbonylation of allenynes and enallenes. Chemistry (2014) 0.81
Palladium-catalyzed oxidative diarylating carbocyclization of enynes. Org Lett (2012) 0.81
Gold-catalyzed cyclization of allene-substituted malonate esters: synthesis of beta,gamma-unsaturated delta-lactones. Org Lett (2007) 0.81
Palladium(II)-catalyzed oxidative cyclization of allylic tosylcarbamates: scope, derivatization, and mechanistic aspects. Chemistry (2012) 0.81
Influence of delta-functional groups on the enantiorecognition of secondary alcohols by Candida antarctica lipase B. Chembiochem (2008) 0.81
Analysis of tissue interactions in ectodermal organ culture. Methods Mol Biol (2013) 0.80
Efficient reoxidation of palladium by a hybrid catalyst in aerobic palladium-catalyzed carbocyclization of enallenes. Chemistry (2009) 0.80
An efficient route to chiral alpha- and beta-hydroxyalkanephosphonates. J Org Chem (2003) 0.80
Enantioselective enzymatic desymmetrization of prochiral allenic diols. Angew Chem Int Ed Engl (2011) 0.80
Cycloisomerization of acetylenic acids to γ-alkylidene lactones using a palladium(II) catalyst supported on amino-functionalized siliceous mesocellular foam. J Org Chem (2014) 0.80
Asymmetric synthesis of bicyclic diol derivatives through metal and enzyme catalysis: application to the formal synthesis of sertraline. Chemistry (2010) 0.80
Aerobic double dehydrogenative cross coupling between cyclic saturated ketones and simple arenes. Chemistry (2014) 0.80
N-1-Alkyl-2-oxo-2-aryl amides as novel antagonists of the TRPA1 receptor. Bioorg Med Chem Lett (2012) 0.80
Mechanism of ruthenium-catalyzed hydrogen transfer reactions. Concerted transfer of OH and CH hydrogens from an alcohol to a (Cyclopentadienone)ruthenium complex. J Org Chem (2003) 0.79
Stereoselective palladium-catalyzed carbocyclization of allenic allylic carboxylates. J Am Chem Soc (2003) 0.79
Enantiopure 1,5-diols from dynamic kinetic asymmetric transformation. Useful synthetic intermediates for the preparation of chiral heterocycles. Org Lett (2008) 0.79
Allenes as carbon nucleophiles in palladium-catalyzed reactions: observation of anti attack of allenes on (pi-allyl)palladium complexes. J Am Chem Soc (2002) 0.79
Enzymatic kinetic resolution and chemoenzymatic dynamic kinetic resolution of delta-hydroxy esters. An efficient route to chiral delta-lactones. J Org Chem (2002) 0.79
Unexpected formation of a cyclopentadienylruthenium alkoxycarbonyl complex with a coordinated C=C bond. J Am Chem Soc (2009) 0.79
Palladium-catalyzed oxidative domino carbocyclization-carbonylation-alkynylation of enallenes. Org Lett (2014) 0.78
On the mechanism of the unexpected facile formation of meso-diacetate products in enzymatic acetylation of alkanediols. J Org Chem (2003) 0.78
CO assistance in ligand exchange of a ruthenium racemization catalyst: identification of an acyl intermediate. J Am Chem Soc (2009) 0.78
Investigation of the impact of water on the enantioselectivity displayed by CALB in the kinetic resolution of δ-functionalized alkan-2-ol derivatives. Chemistry (2014) 0.78
Biomimetic oxidative coupling of benzylamines and 2-aminophenols: synthesis of benzoxazoles. Chemistry (2012) 0.78
Divergent asymmetric synthesis of 3,5-disubstituted piperidines. J Org Chem (2006) 0.78
Biomimetic aerobic oxidation of amino alcohols to lactams. Chemistry (2012) 0.78
Highly efficient route for enantioselective preparation of chlorohydrins via dynamic kinetic resolution. Org Lett (2008) 0.78
Efficient bioreduction of bicyclo[2.2.2]octane-2,5-dione and bicyclo[2.2.2]oct-7-ene-2,5-dione by genetically engineered Saccharomyces cerevisiae. Org Biomol Chem (2006) 0.78
C-2 selective arylation of indoles with heterogeneous nanopalladium and diaryliodonium salts. Chemistry (2014) 0.78
Light-induced water oxidation by a Ru complex containing a bio-inspired ligand. Chemistry (2011) 0.78
Synthesis of conjugated dienes via a biomimetic aerobic oxidative coupling of two C(vinyl)-H bonds. Chemistry (2013) 0.78
Enzyme- and ruthenium-catalyzed dynamic kinetic asymmetric transformation of 1,5-diols. Application to the synthesis of (+)-Solenopsin A. J Org Chem (2009) 0.78
Aerobic oxidative coupling of arenes and olefins through a biomimetic approach. Chemistry (2013) 0.78
Chemoenzymatic dynamic kinetic resolution of allylic alcohols: a highly enantioselective route to acyloin acetates. Org Lett (2007) 0.77
Preparation and redox properties of N,N,N-1,3,5-trialkylated flavin derivatives and their activity as redox catalysts. Chemistry (2004) 0.77
An unexpectedly mild thermal Alder-ene-type cyclization of enallenes. J Org Chem (2006) 0.77
Enzymatic kinetic resolution of primary allenic alcohols. Application to the total synthesis and stereochemical assignment of striatisporolide A. Org Biomol Chem (2009) 0.77
Mutated variant of Candida antarctica lipase B in (S)-selective dynamic kinetic resolution of secondary alcohols. Org Biomol Chem (2010) 0.77
Co-immobilization of an enzyme and a metal into the compartments of mesoporous silica for cooperative tandem catalysis: an artificial metalloenzyme. Angew Chem Int Ed Engl (2013) 0.77
Ruthenium-catalyzed transfer hydrogenation of imines by propan-2-ol in benzene. Chemistry (2002) 0.77
Aerobic direct C-H arylation of nonbiased olefins. Org Lett (2014) 0.77
Efficient and selective sulfoxidation by hydrogen peroxide, using a recyclable flavin--[BMIm]PF6 catalytic system. J Org Chem (2006) 0.77
A chemoenzymatic dynamic kinetic resolution approach to enantiomerically pure (R)- and (S)-duloxetine. J Org Chem (2011) 0.76
Access to cinnamyl derivatives from arenes and allyl esters by a biomimetic aerobic oxidative dehydrogenative coupling. Org Lett (2014) 0.76