Published in Proc Natl Acad Sci U S A on March 24, 2003
Synthetic analogues of cysteinate-ligated non-heme iron and non-corrinoid cobalt enzymes. Chem Rev (2004) 1.54
Biological inorganic chemistry at the beginning of the 21st century. Proc Natl Acad Sci U S A (2003) 1.43
Nox4: a hydrogen peroxide-generating oxygen sensor. Biochemistry (2014) 1.14
Understanding how the thiolate sulfur contributes to the function of the non-heme iron enzyme superoxide reductase. Acc Chem Res (2007) 1.03
Steric and electronic control over the reactivity of a thiolate-ligated Fe(II) complex with dioxygen and superoxide: reversible mu-oxo dimer formation. Inorg Chem (2004) 1.01
Periodic trends within a series of five-coordinate thiolate-ligated [MII(SMe2N4(tren))]+ (M = Mn, Fe, Co, Ni, Cu, Zn) complexes, including a rare example of a stable CuII-thiolate. Inorg Chem (2007) 0.94
Properties of square-pyramidal alkyl-thiolate Fe(III) complexes, including an analogue of the unmodified form of nitrile hydratase. Inorg Chem (2008) 0.84
Comparison of Structurally-Related Alkoxide, Amine, and Thiolate-Ligated M (M= Fe, Co) Complexes: the Influence of Thiolates on the Properties of Biologically Relevant Metal Complexes. Inorganica Chim Acta (2008) 0.83
Influence of thiolate ligands on reductive N-O bond activation. Probing the O2(-) binding site of a biomimetic superoxide reductase analogue and examining the proton-dependent reduction of nitrite. J Am Chem Soc (2011) 0.83
The zebrafish embryo as a tool for screening and characterizing pleurocidin host-defense peptides as anti-cancer agents. Dis Model Mech (2011) 0.83
Spectroscopic and computational investigation of iron(III) cysteine dioxygenase: implications for the nature of the putative superoxo-Fe(III) intermediate. Biochemistry (2014) 0.82
Role of protons in superoxide reduction by a superoxide reductase analogue. Inorg Chem (2005) 0.81
1-Aminocyclopropane-1-carboxylic acid oxidase reaction mechanism and putative post-translational activities of the ACCO protein. AoB Plants (2013) 0.78
Water-soluble Fe(II)-H2O complex with a weak O-H bond transfers a hydrogen atom via an observable monomeric Fe(III)-OH. J Am Chem Soc (2015) 0.75
Metal-Assisted Oxo Atom Addition to an Fe(III) Thiolate. J Am Chem Soc (2016) 0.75
The Cambridge Structural Database: a quarter of a million crystal structures and rising. Acta Crystallogr B (2002) 234.73
Anaerobic microbes: oxygen detoxification without superoxide dismutase. Science (1999) 3.44
Spontaneous cancer and its possible relationship to oxygen metabolism. Proc Natl Acad Sci U S A (1980) 2.43
Structures of the superoxide reductase from Pyrococcus furiosus in the oxidized and reduced states. Biochemistry (2000) 1.87
Spectroscopic studies of Pyrococcus furiosus superoxide reductase: implications for active-site structures and the catalytic mechanism. J Am Chem Soc (2002) 1.60
A synthetic analogue of the active site of Fe-containing nitrile hydratase with carboxamido N and thiolato S as donors: synthesis, structure, and reactivities. J Am Chem Soc (2001) 1.43
Synthetic models for the cysteinate-ligated non-heme iron enzyme superoxide reductase: observation and structural characterization by XAS of an Fe(III)-OOH intermediate. J Am Chem Soc (2002) 1.26
Functional mimics of superoxide dismutase enzymes as therapeutic agents. Chem Rev (1999) 1.22
Modeling the reactivity of superoxide reducing metalloenzymes with a nitrogen and sulfur coordinated iron complex. Inorg Chem (2001) 1.18
Superoxide reductase from Desulfoarculus baarsii: reaction mechanism and role of glutamate 47 and lysine 48 in catalysis. Biochemistry (2001) 1.18
Spectroscopic properties of desulfoferrodoxin from Desulfovibrio desulfuricans (ATCC 27774). J Biol Chem (1994) 1.16
Superoxide reductase: fact or fiction? J Biol Inorg Chem (2002) 1.12
Superoxide dismutase, oxidative stress, and cell metabolism. Curr Top Cell Regul (2000) 1.12
X-ray spectroscopy of nitrile hydratase at pH 7 and 9. Biochemistry (1996) 1.09
Identification of iron(III) peroxo species in the active site of the superoxide reductase SOR from Desulfoarculus baarsii. J Am Chem Soc (2002) 1.09
Probing the influence of local coordination environment on the properties of Fe-type nitrile hydratase model complexes. Inorg Chem (2001) 1.07
The first example of a nitrile hydratase model complex that reversibly binds nitriles. J Am Chem Soc (2002) 1.04
Biological chemistry of copper-zinc superoxide dismutase and its link to amyotrophic lateral sclerosis. Met Ions Biol Syst (1999) 1.04
Invited award contribution for ACS Award in Inorganic Chemistry. Geometric and electronic structure contributions to function in bioinorganic chemistry: active sites in non-heme iron enzymes. Inorg Chem (2001) 0.96
The superoxide dismutase activity of desulfoferrodoxin from Desulfovibrio desulfuricans ATCC 27774. Eur J Biochem (1999) 0.95
Effect of Carboxamido N Coordination to Iron on the Redox Potential of Low-Spin Non-Heme Iron Centers with N,S Coordination: Relevance to the Iron Site of Nitrile Hydratase. Inorg Chem (1998) 0.93
Superoxide scavenging by neelaredoxin: dismutation and reduction activities in anaerobes. J Biol Inorg Chem (2002) 0.91
What is the ultimate fate of superoxide anion in vivo? J Biol Inorg Chem (2002) 0.91
Enhancing reactivity via structural distortion. Inorg Chem (2002) 0.91
The mechanism(s) of superoxide reduction by superoxide reductases in vitro and in vivo. J Biol Inorg Chem (2002) 0.87
The RATIO method for time-resolved Laue crystallography. J Synchrotron Radiat (2009) 2.10
New n-type organic semiconductors: synthesis, single crystal structures, cyclic voltammetry, photophysics, electron transport, and electroluminescence of a series of diphenylanthrazolines. J Am Chem Soc (2003) 1.78
The development of Laue techniques for single-pulse diffraction of chemical complexes: time-resolved Laue diffraction on a binuclear rhodium metal-organic complex. Acta Crystallogr A (2011) 1.53
Herapathite. Science (2009) 1.38
Time-resolved synchrotron diffraction and theoretical studies of very short-lived photo-induced molecular species. Acta Crystallogr A (2010) 1.37
Structural plasticity of malaria dihydroorotate dehydrogenase allows selective binding of diverse chemical scaffolds. J Biol Chem (2009) 1.32
Synthetic models for the cysteinate-ligated non-heme iron enzyme superoxide reductase: observation and structural characterization by XAS of an Fe(III)-OOH intermediate. J Am Chem Soc (2002) 1.26
Slow hydrogen atom transfer reactions of oxo- and hydroxo-vanadium compounds: the importance of intrinsic barriers. J Am Chem Soc (2009) 1.18
A functional model for the cysteinate-ligated non-heme iron enzyme superoxide reductase (SOR). J Am Chem Soc (2006) 1.16
How does single oxygen atom addition affect the properties of an Fe-nitrile hydratase analogue? The compensatory role of the unmodified thiolate. J Am Chem Soc (2006) 1.09
Sulfur K-edge XAS and DFT calculations on nitrile hydratase: geometric and electronic structure of the non-heme iron active site. J Am Chem Soc (2006) 1.05
The first example of a nitrile hydratase model complex that reversibly binds nitriles. J Am Chem Soc (2002) 1.04
Oxidatively induced reductive elimination from ((t)Bu2bpy)Pd(Me)2: palladium(IV) intermediates in a one-electron oxidation reaction. J Am Chem Soc (2009) 1.02
Steric and electronic control over the reactivity of a thiolate-ligated Fe(II) complex with dioxygen and superoxide: reversible mu-oxo dimer formation. Inorg Chem (2004) 1.01
Spectroscopy of non-heme iron thiolate complexes: insight into the electronic structure of the low-spin active site of nitrile hydratase. Inorg Chem (2005) 0.99
Optical rotation of achiral compounds. Angew Chem Int Ed Engl (2008) 0.97
Restricted photochemistry in the molecular solid state: structural changes on photoexcitation of Cu(I) phenanthroline metal-to-ligand charge transfer (MLCT) complexes by time-resolved diffraction. J Phys Chem A (2012) 0.96
Fluorine modulates species selectivity in the triazolopyrimidine class of Plasmodium falciparum dihydroorotate dehydrogenase inhibitors. J Med Chem (2014) 0.96
Periodic trends within a series of five-coordinate thiolate-ligated [MII(SMe2N4(tren))]+ (M = Mn, Fe, Co, Ni, Cu, Zn) complexes, including a rare example of a stable CuII-thiolate. Inorg Chem (2007) 0.94
Synthesis and oxidation of CpIrIII compounds: functionalization of a Cp methyl group. Dalton Trans (2009) 0.92
Enhancing reactivity via structural distortion. Inorg Chem (2002) 0.91
Synthesis and characterization of ruthenium bis(beta-diketonato) pyridine-imidazole complexes for hydrogen atom transfer. Inorg Chem (2007) 0.91
Protonation and concerted proton-electron transfer reactivity of a bis-benzimidazolate ligated [2Fe-2S] model for Rieske clusters. J Am Chem Soc (2012) 0.91
A solution- and solid-state investigation of medium effects on charge separation in metastable photomerocyanines. J Am Chem Soc (2010) 0.90
Ligand oxidations in high-spin nickel thiolate complexes and zinc analogues. Inorg Chem (2004) 0.90
Enantioselective palladium-catalyzed diamination of alkenes using N-fluorobenzenesulfonimide. J Am Chem Soc (2013) 0.88
A C-C bonded phenoxyl radical dimer with a zero bond dissociation free energy. J Am Chem Soc (2013) 0.88
Systematic study of the structure-property relationship of a series of ferrocenyl nonlinear optical chromophores. J Am Chem Soc (2005) 0.87
Characterization of metastable intermediates formed in the reaction between a Mn(II) complex and dioxygen, including a crystallographic structure of a binuclear Mn(III)-peroxo species. J Am Chem Soc (2013) 0.87
Investigation of the mechanism of formation of a thiolate-ligated Fe(III)-OOH. Inorg Chem (2011) 0.86
A quantitative collagen fibers orientation assessment using birefringence measurements: calibration and application to human osteons. J Struct Biol (2011) 0.85
Optical rotation of achiral pentaerythritol. J Am Chem Soc (2006) 0.85
Structural and spectroscopic characterization of metastable thiolate-ligated manganese(III)-alkylperoxo species. J Am Chem Soc (2011) 0.84
Properties of square-pyramidal alkyl-thiolate Fe(III) complexes, including an analogue of the unmodified form of nitrile hydratase. Inorg Chem (2008) 0.84
Botulinum toxin induces muscle paralysis and inhibits bone regeneration in zebrafish. J Bone Miner Res (2014) 0.84
Characterization and dioxygen reactivity of a new series of coordinatively unsaturated thiolate-ligated manganese(II) complexes. Inorg Chem (2012) 0.83
Comparison of Structurally-Related Alkoxide, Amine, and Thiolate-Ligated M (M= Fe, Co) Complexes: the Influence of Thiolates on the Properties of Biologically Relevant Metal Complexes. Inorganica Chim Acta (2008) 0.83
S K-edge X-ray absorption spectroscopy and density functional theory studies of high and low spin {FeNO}7 thiolate complexes: exchange stabilization of electron delocalization in {FeNO}7 and {FeO2}8. Inorg Chem (2010) 0.83
Influence of thiolate ligands on reductive N-O bond activation. Probing the O2(-) binding site of a biomimetic superoxide reductase analogue and examining the proton-dependent reduction of nitrite. J Am Chem Soc (2011) 0.83
Correlation between structural, spectroscopic, and reactivity properties within a series of structurally analogous metastable manganese(III)-alkylperoxo complexes. J Am Chem Soc (2013) 0.81
Role of protons in superoxide reduction by a superoxide reductase analogue. Inorg Chem (2005) 0.81
Effect of basic site substituents on concerted proton-electron transfer in hydrogen-bonded pyridyl-phenols. J Phys Chem A (2012) 0.81
Turinese stereochemistry: Eligio Perucca's enantioselectivity and Primo Levi's asymmetry. Angew Chem Int Ed Engl (2009) 0.81
Potassium hydrogen diphthalate dihydrate: a new structure and correction to the literature. Acta Crystallogr C (2004) 0.81
Proton transfer and photoluminescence intermittency of single emitters in dyed crystals. J Phys Chem B (2012) 0.81
Preparation, structural characterization, and thermochemistry of an isolable 4-arylphenoxyl radical. J Org Chem (2014) 0.80
Circular dichroism imaging microscopy: application to enantiomorphous twinning in biaxial crystals of 1,8-dihydroxyanthraquinone. J Am Chem Soc (2003) 0.80
Oxygen-oxygen bond homolysis in a novel titanium(IV) alkylperoxide complex, Cp2Ti(OOtBu)Cl. J Am Chem Soc (2002) 0.80
Nitrile hydration by thiolate- and alkoxide-ligated Co-NHase analogues. Isolation of Co(III)-amidate and Co(III)-iminol intermediates. J Am Chem Soc (2011) 0.80
Circular dichroism tensor of a triarylmethyl propeller in sodium chlorate crystals. J Am Chem Soc (2010) 0.79
Beta-diiminate platinum complexes for alkane dehydrogenation. J Am Chem Soc (2003) 0.79
Reactions of iridium hydride pincer complexes with dioxygen: new dioxygen complexes and reversible O2 binding. Chem Commun (Camb) (2008) 0.79
Syntheses and structural investigation of some alkali metal ion-mediated LV(V)O2(-) (L(2-) = tridentate ONO ligands) species: DNA binding, photo-induced DNA cleavage and cytotoxic activities. Dalton Trans (2014) 0.78
Generation and structural characterization of a gold(III) alkene complex. Angew Chem Int Ed Engl (2013) 0.78
Synthesis and structural characterization of a series of Mn(III)OR complexes, including a water-soluble Mn(III)OH that promotes aerobic hydrogen-atom transfer. Inorg Chem (2013) 0.78
Computational and experimental methodology for site-matched investigations of the influence of mineral mass fraction and collagen orientation on the axial indentation modulus of lamellar bone. J Mech Behav Biomed Mater (2013) 0.78
Mesoscale chiroptics of rhythmic precipitates. J Am Chem Soc (2006) 0.78
Osmium phosphiniminato complexes: synthesis, protonation, structure, and redox-coupled hydrolytic scission of N-p bonds. Inorg Chem (2003) 0.78
Sigma-borane complexes of iridium: synthesis and structural characterization. J Am Chem Soc (2008) 0.78
Isolation and characterization of a dihydroxo-bridged iron(III,III)(μ-OH)2 diamond core derived from dioxygen. Inorg Chem (2013) 0.78
Aggregation induced emission (AIE) of trifluoromethyl substituted distyrylbenzenes. Chem Commun (Camb) (2012) 0.77
Absolute configuration of beer's bitter compounds. Angew Chem Int Ed Engl (2012) 0.77
A dihydroxo-bridged Fe(II)-Fe(III) complex: a new member of the diiron diamond core family. J Am Chem Soc (2003) 0.77
Characterization of a palladium dihydrogen complex. Angew Chem Int Ed Engl (2015) 0.77
Mononuclear nitrogen/sulfur-ligated zinc methoxide and hydroxide complexes: investigating ligand effects on the hydrolytic stability of zinc alkoxide species. J Am Chem Soc (2002) 0.76
Decomposition of a Mixed-Valence [2Fe-2S] Cluster to Linear Tetra-Ferric and Ferrous Clusters. Polyhedron (2013) 0.76
Trigonal bi- and monopyramidal cobalt(II) complexes of a novel guanidine-based tripodal ligand. Inorg Chem (2010) 0.76
Development of porous materials for heterogeneous catalysis: kinetic resolution of epoxides. Chem Commun (Camb) (2004) 0.76
Triplet states of the nonlinear optical chromophore DCM in single crystals of potassium hydrogen phthalate and their relationship to single-molecule dark states. J Am Chem Soc (2009) 0.76
Synthesis, structure, and reactivity of a nickel dihydrogen complex. Chemistry (2012) 0.75
Water-soluble Fe(II)-H2O complex with a weak O-H bond transfers a hydrogen atom via an observable monomeric Fe(III)-OH. J Am Chem Soc (2015) 0.75
Nucleophilic aromatic substitution on aryl-amido ligands promoted by oxidizing osmium(IV) centers. Inorg Chem (2004) 0.75
Isolation and X-ray structure of deoxycholic acid from the sponge Ircinia sp. Nat Prod Commun (2011) 0.75
Directing protons to the dioxygen ligand of a ruthenium(II) complex with pendent amines in the second coordination sphere. Angew Chem Int Ed Engl (2011) 0.75
Preparation of a dihydrogen complex of cobalt. Angew Chem Int Ed Engl (2010) 0.75
Hemilability of P(X)N-type ligands (X = O, N-H): rollover cyclometalation and benzene C-H activation from (P(X)N)PtMe2 complexes. Dalton Trans (2014) 0.75
Hydrogenolysis of palladium(II) hydroxide, phenoxide, and alkoxide complexes. J Am Chem Soc (2011) 0.75
Oxygen-promoted C-H bond activation at palladium. Angew Chem Int Ed Engl (2014) 0.75
Synthesis and reactivity of tripodal complexes containing pendant bases. Inorg Chem (2014) 0.75
Chelation-driven rearrangement of primary alkyl aminopalladation products to stable trisubstituted alkyl-palladium complexes. Angew Chem Int Ed Engl (2015) 0.75
Ligand-based reduction of CO2 and release of CO on iron(II). Inorg Chem (2012) 0.75
Platinum(II) olefin hydroarylation catalysts: tuning selectivity for the anti-Markovnikov product. Chemistry (2014) 0.75
Divalent osmium complexes: synthesis, characterization, strong red phosphorescence, and electrophosphorescence. J Am Chem Soc (2002) 0.75
Synthesis, protonation, and reduction of ruthenium-peroxo complexes with pendent nitrogen bases. Inorg Chem (2012) 0.75