Published in J Am Chem Soc on August 13, 2003
Palladium(II)-catalyzed C-H activation/C-C cross-coupling reactions: versatility and practicality. Angew Chem Int Ed Engl (2009) 5.09
Catalytic C-H functionalization by metal carbenoid and nitrenoid insertion. Nature (2008) 5.08
Direct transition metal-catalyzed functionalization of heteroaromatic compounds. Chem Soc Rev (2007) 3.09
Pd(II)-catalyzed olefination of electron-deficient arenes using 2,6-dialkylpyridine ligands. J Am Chem Soc (2009) 1.90
Palladium(II)-catalyzed alkene functionalization via nucleopalladation: stereochemical pathways and enantioselective catalytic applications. Chem Rev (2011) 1.76
Elucidating the significance of beta-hydride elimination and the dynamic role of acid/base chemistry in a palladium-catalyzed aerobic oxidation of alcohols. J Am Chem Soc (2004) 1.66
Direct functionalization of nitrogen heterocycles via Rh-catalyzed C-H bond activation. Acc Chem Res (2008) 1.56
Oxidative cyclizations in a nonpolar solvent using molecular oxygen and studies on the stereochemistry of oxypalladation. J Am Chem Soc (2005) 1.55
Pd(II)-catalyzed olefination of sp3 C-H bonds. J Am Chem Soc (2010) 1.50
Stereoselective alkylation of alpha,beta-unsaturated imines via C-H bond activation. J Am Chem Soc (2006) 1.47
Ligand-accelerated C-H activation reactions: evidence for a switch of mechanism. J Am Chem Soc (2010) 1.46
Twofold C-H functionalization: palladium-catalyzed ortho arylation of anilides. Org Lett (2008) 1.46
Developing ligands for palladium(II)-catalyzed C-H functionalization: intimate dialogue between ligand and substrate. J Org Chem (2013) 1.33
Experimental and computational studies on the mechanism of N-heterocycle C-H activation by Rh(I). J Am Chem Soc (2006) 1.29
Pd(II)-catalyzed hydroxyl-directed C-H olefination enabled by monoprotected amino acid ligands. J Am Chem Soc (2010) 1.24
Scope and mechanistic study of the ruthenium-catalyzed ortho-C-H bond activation and cyclization reactions of arylamines with terminal alkynes. J Am Chem Soc (2005) 1.04
Efficient iridium-catalyzed C-H functionalization/silylation of heteroarenes. Angew Chem Int Ed Engl (2008) 1.03
Ligand-accelerated cross-coupling of C(sp2)-H bonds with arylboron reagents. J Am Chem Soc (2011) 1.02
Rh(I)-catalyzed arylation of heterocycles via C-H bond activation: expanded scope through mechanistic insight. J Am Chem Soc (2008) 1.01
Rh(III)-catalyzed oxidative coupling of unactivated alkenes via C-H activation. Org Lett (2010) 0.98
Mechanistic studies of Wacker-type intramolecular aerobic oxidative amination of alkenes catalyzed by Pd(OAc)2/pyridine. J Org Chem (2011) 0.97
The renaissance of palladium(II)-catalyzed oxidation chemistry. Org Biomol Chem (2004) 0.95
Constructing multiply substituted arenes using sequential palladium(II)-catalyzed C-H olefination. Angew Chem Int Ed Engl (2010) 0.94
Rhodium(I)-catalyzed decarbonylative spirocyclization through C-C bond cleavage of benzocyclobutenones: an efficient approach to functionalized spirocycles. Angew Chem Int Ed Engl (2014) 0.91
Intramolecular Pd(II)-catalyzed aerobic oxidative amination of alkenes: synthesis of six-membered N-heterocycles. Org Lett (2012) 0.91
Development and comparison of the substrate scope of Pd-catalysts for the aerobic oxidation of alcohols. J Org Chem (2005) 0.89
Direct, chemoselective N-tert-prenylation of indoles by C-H functionalization. Angew Chem Int Ed Engl (2009) 0.89
C-H Bond Functionalizations with Palladium(II): Intramolecular Oxidative Annulations of Arenes. Tetrahedron (2008) 0.89
N-acylsulfonamide assisted tandem C-H olefination/annulation: synthesis of isoindolinones. Org Lett (2011) 0.87
Rhodium(III)-catalyzed intramolecular hydroarylation, amidoarylation, and Heck-type reaction: three distinct pathways determined by an amide directing group. Angew Chem Int Ed Engl (2013) 0.86
Rh(I)-bisphosphine-catalyzed asymmetric, intermolecular hydroheteroarylation of α-substituted acrylate derivatives. J Am Chem Soc (2014) 0.86
C7-derivatization of C3-alkylindoles including tryptophans and tryptamines. J Org Chem (2014) 0.85
Olefin-Directed Palladium-Catalyzed Regio- and Stereoselective Oxidative Arylation of Allenes. Angew Chem Int Ed Engl (2015) 0.85
Combined oxypalladation/C-H functionalization: palladium(II)-catalyzed intramolecular oxidative oxyarylation of hydroxyalkenes. Angew Chem Int Ed Engl (2012) 0.84
Formation of bicyclic pyrroles from the catalytic coupling reaction of 2,5-disubstituted pyrroles with terminal alkynes, involving the activation of multiple C-H bonds. Chem Commun (Camb) (2008) 0.82
Total synthesis and antiviral activity of indolosesquiterpenoids from the xiamycin and oridamycin families. Nat Commun (2015) 0.82
Heterocycle Formation via Palladium-Catalyzed C-H Functionalization. Synthesis (Stuttg) (2012) 0.81
N-Boc amines to oxazolidinones via Pd(II)/bis-sulfoxide/Brønsted acid co-catalyzed allylic C-H oxidation. J Am Chem Soc (2014) 0.81
A steric tethering approach enables palladium-catalysed C-H activation of primary amino alcohols. Nat Chem (2015) 0.80
The synthesis of C-3β functionalized indoles via a hydroboration/Suzuki-Miyaura coupling sequence. Tetrahedron Lett (2006) 0.80
Palladium-catalyzed dual C-H or N-H functionalization of unfunctionalized indole derivatives with alkenes and arenes. Beilstein J Org Chem (2012) 0.79
Structurally Diverse Diazafluorene-Ligated Palladium(II) Complexes and Their Implications for Aerobic Oxidation Reactions. J Am Chem Soc (2016) 0.78
Ligand-Accelerated ortho-C-H Olefination of Phenylacetic Acids. Organic Synth (2015) 0.75
Reactions of Indene and Indoles with Platinum Methyl Cations: Indene C-H Activation, Indole π vs. Nitrogen Lone-Pair Coordination. Organometallics (2016) 0.75
Highly Efficient Cascade Reaction for Selective Formation of Spirocyclobutenes from Dienallenes via Palladium-Catalyzed Oxidative Double Carbocyclization-Carbonylation-Alkynylation. J Am Chem Soc (2016) 0.75
The enantioselective Tsuji allylation. J Am Chem Soc (2004) 3.45
Deracemization of quaternary stereocenters by Pd-catalyzed enantioconvergent decarboxylative allylation of racemic beta-ketoesters. Angew Chem Int Ed Engl (2005) 3.29
Reversible inhibitor of p97, DBeQ, impairs both ubiquitin-dependent and autophagic protein clearance pathways. Proc Natl Acad Sci U S A (2011) 3.20
Synthesis and structural analysis of 2-quinuclidonium tetrafluoroborate. Nature (2006) 2.51
A comprehensive history of arynes in natural product total synthesis. Chem Rev (2012) 2.41
Enantioselective Tsuji allylations. Chem Asian J (2007) 2.10
The total synthesis of (-)-cyanthiwigin F by means of double catalytic enantioselective alkylation. Nature (2008) 1.97
The inner-sphere process in the enantioselective Tsuji allylation reaction with (S)-t-Bu-phosphinooxazoline ligands. J Am Chem Soc (2007) 1.80
The total synthesis of (+)-dragmacidin F. J Am Chem Soc (2004) 1.79
Catalytic enantioselective decarboxylative protonation. J Am Chem Soc (2006) 1.64
The catalytic asymmetric total synthesis of elatol. J Am Chem Soc (2007) 1.62
Oxidative cyclizations in a nonpolar solvent using molecular oxygen and studies on the stereochemistry of oxypalladation. J Am Chem Soc (2005) 1.55
The catalytic enantioselective, protecting group-free total synthesis of (+)-dichroanone. J Am Chem Soc (2006) 1.49
Enantioselective decarboxylative alkylation reactions: catalyst development, substrate scope, and mechanistic studies. Chemistry (2011) 1.47
Catalytic enantioselective alkylation of substituted dioxanone enol ethers: ready access to Calpha-tetrasubstituted hydroxyketones, acids, and esters. Angew Chem Int Ed Engl (2008) 1.43
Unusual allylpalladium carboxylate complexes: identification of the resting state of catalytic enantioselective decarboxylative allylic alkylation reactions of ketones. Angew Chem Int Ed Engl (2009) 1.40
The first total synthesis of dragmacidin d. J Am Chem Soc (2002) 1.40
Palladium-catalyzed oxidative wacker cyclizations in nonpolar organic solvents with molecular oxygen: a stepping stone to asymmetric aerobic cyclizations. Angew Chem Int Ed Engl (2003) 1.39
A facile and modular synthesis of phosphinooxazoline ligands. Org Lett (2007) 1.39
Palladium-catalyzed asymmetric conjugate addition of arylboronic acids to five-, six-, and seven-membered β-substituted cyclic enones: enantioselective construction of all-carbon quaternary stereocenters. J Am Chem Soc (2011) 1.34
The direct acyl-alkylation of arynes. J Am Chem Soc (2005) 1.31
Catalytic enantioselective approach to the eudesmane sesquiterpenoids: total synthesis of (+)-carissone. Org Lett (2009) 1.30
Development of an enantiodivergent strategy for the total synthesis of (+)- and (-)-dragmacidin f from a single enantiomer of quinic Acid. J Am Chem Soc (2005) 1.29
Side chain chemistry mediates backbone fragmentation in hydrogen deficient peptide radicals. J Proteome Res (2009) 1.29
Orthogonal synthesis of indolines and isoquinolines via aryne annulation. J Am Chem Soc (2008) 1.25
Catalytic enantioselective stereoablative reactions: an unexploited approach to enantioselective catalysis. Org Biomol Chem (2007) 1.19
Homogeneous pd-catalyzed enantioselective decarboxylative protonation. Org Lett (2008) 1.18
Enantioselective total synthesis of (+)-cassiol. Org Lett (2009) 1.17
The reaction mechanism of the enantioselective Tsuji allylation: inner-sphere and outer-sphere pathways, internal rearrangements, and asymmetric C-C bond formation. J Am Chem Soc (2012) 1.17
Synthesis of the carbocyclic core of zoanthenol: implementation of an unusual acid-catalyzed cyclization. Angew Chem Int Ed Engl (2007) 1.17
Palladium-catalyzed enantioselective oxidation of alcohols: a dramatic rate acceleration by Cs2CO3/t-BuOH. Org Lett (2003) 1.16
Enantioselective construction of quaternary N-heterocycles by palladium-catalysed decarboxylative allylic alkylation of lactams. Nat Chem (2011) 1.15
A palladium-catalysed enolate alkylation cascade for the formation of adjacent quaternary and tertiary stereocentres. Nat Chem (2010) 1.14
Natural products as inspiration for the development of asymmetric catalysis. Nature (2008) 1.13
Enantioselective protonation. Nat Chem (2009) 1.13
Palladium-catalyzed oxidative kinetic resolution with ambient air as the stoichiometric oxidation gas. Angew Chem Int Ed Engl (2004) 1.12
Construction of vicinal tertiary and all-carbon quaternary stereocenters via Ir-catalyzed regio-, diastereo-, and enantioselective allylic alkylation and applications in sequential Pd catalysis. J Am Chem Soc (2013) 1.11
Rapid synthesis of an electron-deficient t-BuPHOX ligand: cross-coupling of aryl bromides with secondary phosphine oxides. Tetrahedron Lett (2010) 1.10
An experimentally derived model for stereoselectivity in the aerobic oxidative kinetic resolution of secondary alcohols by (sparteine)PdCl2. J Am Chem Soc (2004) 1.09
Regioselective reactions of highly substituted arynes. Org Lett (2010) 1.08
Catalytic enantioselective stereoablative alkylation of 3-halooxindoles: facile access to oxindoles with C3 all-carbon quaternary stereocenters. Angew Chem Int Ed Engl (2009) 1.08
A computational model relating structure and reactivity in enantioselective oxidations of secondary alcohols by (-)-sparteine-Pd(II) complexes. J Am Chem Soc (2004) 1.06
Welwitindolinone C synthetic studies. Construction of the welwitindolinone carbon skeleton via a transannular nitrone cycloaddition. Tetrahedron (2010) 1.03
The catalytic enantioselective total synthesis of (+)-liphagal. Angew Chem Int Ed Engl (2011) 1.03
Progress toward the Synthesis of garsubellin A and related phloroglucins: the direct diastereoselective synthesis of the bicyclo[3.3.1]nonane core. Org Lett (2002) 1.03
Convergency and divergency as strategic elements in total synthesis: the total synthesis of (-)-drupacine and the formal total synthesis of (+/-)-cephalotaxine, (-)-cephalotaxine, and (+)-cephalotaxine. J Org Chem (2007) 1.02
Mechanism and enantioselectivity in palladium-catalyzed conjugate addition of arylboronic acids to β-substituted cyclic enones: insights from computation and experiment. J Am Chem Soc (2013) 1.02
A diastereodivergent synthetic strategy for the syntheses of communesin F and perophoramidine. Org Lett (2014) 1.01
A unified synthetic approach to the pyrazinone dragmacidins. Chem Commun (Camb) (2006) 1.00
Enantio-, diastereo-, and regioselective iridium-catalyzed asymmetric allylic alkylation of acyclic β-ketoesters. J Am Chem Soc (2013) 1.00
A convergent and enantioselective synthesis of (+)-amurensinine via selective C-H and C-C bond insertion reactions. J Am Chem Soc (2006) 0.99
The biology and chemistry of the zoanthamine alkaloids. Angew Chem Int Ed Engl (2008) 0.98
Direct oxidative Heck cyclizations: intramolecular Fujiwara-Moritani arylations for the synthesis of functionalized benzofurans and dihydrobenzofurans. Angew Chem Int Ed Engl (2004) 0.98
Ring-contraction strategy for the practical, scalable, catalytic asymmetric synthesis of versatile γ-quaternary acylcyclopentenes. Angew Chem Int Ed Engl (2011) 0.97
PREPARATION OF (S)-tert-ButylPHOX (Oxazole, 4-(1,1-dimethylethyl)-2-[2-(diphenylphosphino)phenyl]-4,5-dihydro- (4S)-). Organic Synth (2009) 0.96
Palladium-catalyzed enantioselective oxidation of chiral secondary alcohols: access to both enantiomeric series. Angew Chem Int Ed Engl (2008) 0.94
Synthesis of 2-quinuclidonium by eliminating water: experimental quantification of the high basicity of extremely twisted amides. J Am Chem Soc (2007) 0.94
A palladium-catalyzed vinylcyclopropane (3+2) cycloaddition approach to the Melodinus alkaloids. Org Lett (2011) 0.94
Expanding insight into asymmetric palladium-catalyzed allylic alkylation of N-heterocyclic molecules and cyclic ketones. Chemistry (2013) 0.91
Enantioselective construction of α-quaternary cyclobutanones by catalytic asymmetric allylic alkylation. Angew Chem Int Ed Engl (2013) 0.91
Structural features and reactivity of (sparteine)PdCl2: a model for selectivity in the oxidative kinetic resolution of secondary alcohols. J Am Chem Soc (2008) 0.91
High-Throughput Screening of the Asymmetric Decarboxylative Alkylation Reaction of Enolate-Stabilized Enol Carbonates. Synlett (2010) 0.90
Enantioselective total synthesis of the reported structures of (-)-9-epi-presilphiperfolan-1-ol and (-)-presilphiperfolan-1-ol: structural confirmation and reassignment and biosynthetic insights. Angew Chem Int Ed Engl (2012) 0.90
Enantioselective synthesis of α-quaternary Mannich adducts by palladium-catalyzed allylic alkylation: total synthesis of (+)-sibirinine. J Am Chem Soc (2015) 0.90
Pd-catalyzed enantioselective aerobic oxidation of secondary alcohols: applications to the total synthesis of alkaloids. J Am Chem Soc (2008) 0.90
Enantioselective synthesis of α-secondary and α-tertiary piperazin-2-ones and piperazines by catalytic asymmetric allylic alkylation. Angew Chem Int Ed Engl (2014) 0.90
The palladium-catalyzed aerobic kinetic resolution of secondary alcohols: reaction development, scope, and applications. Chemistry (2009) 0.89
C-H Bond Functionalizations with Palladium(II): Intramolecular Oxidative Annulations of Arenes. Tetrahedron (2008) 0.89
Progress toward the total synthesis of saudin: development of a tandem Stille-oxa-electrocyclization reaction. Org Lett (2005) 0.89
PREPARATION OF (S)-2-Allyl-2-methylcyclohexanone (Cyclohexanone, 2-methyl-2-(2-propen-1-yl)-, (2S)-). Organic Synth (2009) 0.88
A concise total synthesis of (-)-quinocarcin via aryne annulation. J Am Chem Soc (2008) 0.88
A catalytic, asymmetric formal synthesis of (+)-hamigeran B. Org Lett (2011) 0.87
A general enantioselective route to the chamigrene natural product family. Tetrahedron (2010) 0.87
Synthesis of enantioenriched γ-quaternary cycloheptenones using a combined allylic alkylation/Stork-Danheiser approach: preparation of mono-, bi-, and tricyclic systems. Org Biomol Chem (2011) 0.86
Convergent and diastereoselective synthesis of the polycyclic pyran core of saudin. J Org Chem (2006) 0.86
Palladium-catalyzed asymmetric conjugate addition of arylboronic acids to heterocyclic acceptors. Chemistry (2012) 0.85
Enantioselective synthesis of dialkylated N-heterocycles by palladium-catalyzed allylic alkylation. Org Lett (2015) 0.85
Efforts toward rapid construction of the cortistatin A carbocyclic core via enyne-ene metathesis. Org Biomol Chem (2010) 0.85
Total syntheses of cyanthiwigins B, F, and G. Chemistry (2011) 0.85
Toward a symphony of reactivity: cascades involving catalysis and sigmatropic rearrangements. Angew Chem Int Ed Engl (2014) 0.85
Synthetic efforts toward cyathane diterpenoid natural products. Nat Prod Rep (2009) 0.84
Enantioselective synthesis of a hydroxymethyl-cis-1,3-cyclopentenediol building block. Org Lett (2012) 0.84
Palladium-Catalyzed Asymmetric Alkylation in the Synthesis of Cyclopentanoid and Cycloheptanoid Core Structures Bearing All-Carbon Quaternary Stereocenters. Tetrahedron (2011) 0.84
2-Diazoacetoacetic acid, an efficient and convenient reagent for the synthesis of alpha-diazo-beta-ketoesters. Chem Commun (Camb) (2006) 0.83
Aryne acyl-alkylation in the general and convergent synthesis of benzannulated macrolactone natural products: an enantioselective synthesis of (-)-curvularin. Org Lett (2010) 0.83
A general approach to the basiliolide/transtaganolide natural products: total syntheses of basiliolide B, epi-8-basiliolide B, transtaganolide C, and transtaganolide D. Angew Chem Int Ed Engl (2011) 0.83
Non-carbonyl-stabilized metallocarbenoids in synthesis: the development of a tandem rhodium-catalyzed bamford-stevens/thermal aliphatic claisen rearrangement sequence. J Am Chem Soc (2002) 0.83
Gas phase production and loss of isoprene epoxydiols. J Phys Chem A (2014) 0.83
Effects of a modified dye-labeled nucleotide spacer arm on incorporation by thermophilic DNA polymerases. Nucleosides Nucleotides Nucleic Acids (2006) 0.82
The development of a facile tandem Wolff/Cope rearrangement for the synthesis of fused carbocyclic skeletons. J Am Chem Soc (2003) 0.82
The total synthesis of (--)-lemonomycin. J Am Chem Soc (2003) 0.82
The synthesis of C-3β functionalized indoles via a hydroboration/Suzuki-Miyaura coupling sequence. Tetrahedron Lett (2006) 0.80
Molecular mousetraps: gas-phase studies of the covalent coupling of noncovalent complexes initiated by reactive carbenes formed by controlled activation of diazo precursors. Angew Chem Int Ed Engl (2003) 0.80
Lewis acid mediated (3 + 2) cycloadditions of donor-acceptor cyclopropanes with heterocumulenes. Org Lett (2012) 0.80
Expedient synthesis of 3-hydroxyisoquinolines and 2-hydroxy-1,4-naphthoquinones via one-pot aryne acyl-alkylation/condensation. Org Biomol Chem (2009) 0.80
Total syntheses of (-)-transtaganolide A, (+)-transtaganolide B, (+)-transtaganolide C, and (-)-transtaganolide D and biosynthetic implications. Angew Chem Int Ed Engl (2013) 0.80
Benzannulated bicycles by three-component aryne reactions. Angew Chem Int Ed Engl (2011) 0.80
Angiotensin II receptor type 1--a novel target for preventing neonatal meningitis in mice by Escherichia coli K1. J Infect Dis (2013) 0.80
Selective nucleic acid capture with shielded covalent probes. J Am Chem Soc (2013) 0.79