Published in Org Lett on February 22, 2012
Mechanistic studies of Wacker-type amidocyclization of alkenes catalyzed by (IMes)Pd(TFA)2(H2O): kinetic and stereochemical implications of proton transfer. J Org Chem (2012) 0.93
Stereoselective synthesis of morpholines via copper-promoted oxyamination of alkenes. Org Lett (2012) 0.88
Characterization of DMSO coordination to palladium(II) in solution and insights into the aerobic oxidation catalyst, Pd(DMSO)2(TFA)2. Inorg Chem (2012) 0.86
The syn/anti-dichotomy in the palladium-catalyzed addition of nucleophiles to alkenes. Chemistry (2014) 0.85
Palladium-Catalyzed Modular Synthesis of Substituted Piperazines and Related Nitrogen Heterocycles. Org Lett (2016) 0.78
Diazafluorenone-Promoted Oxidation Catalysis: Insights into the Role of Bidentate Ligands in Pd-Catalyzed Aerobic Aza-Wacker Reactions. ACS Catal (2016) 0.77
Molecular ligand modulation of palladium nanocatalysts for highly efficient and robust heterogeneous oxidation of cyclohexenone to phenol. Sci Adv (2017) 0.75
Ligand-Enabled γ-C(sp(3))-H Olefination of Amines: En Route to Pyrrolidines. J Am Chem Soc (2016) 0.75
Hydroamination: direct addition of amines to alkenes and alkynes. Chem Rev (2008) 3.05
Palladium oxidase catalysis: selective oxidation of organic chemicals by direct dioxygen-coupled turnover. Angew Chem Int Ed Engl (2004) 3.00
Catalytic C-H bond functionalization with palladiumII: aerobic oxidative annulations of indoles. J Am Chem Soc (2003) 2.73
Transition-metal-catalyzed reactions in heterocyclic synthesis. Chem Rev (2004) 2.23
Synthesis of heterocycles via palladium pi-olefin and pi-alkyne chemistry. Chem Rev (2004) 2.04
Serial ligand catalysis: a highly selective allylic C-H oxidation. J Am Chem Soc (2005) 1.89
C-C, C-O, C-N bond formation on sp2 carbon by Pd(II)-catalyzed reactions involving oxidant agents. Chem Rev (2007) 1.88
Pd(II)-catalyzed enantioselective oxidative tandem cyclization reactions. Synthesis of indolines through C-N and C-C bond formation. J Am Chem Soc (2006) 1.86
Palladium(II)-catalyzed alkene functionalization via nucleopalladation: stereochemical pathways and enantioselective catalytic applications. Chem Rev (2011) 1.76
A sulfoxide-promoted, catalytic method for the regioselective synthesis of allylic acetates from monosubstituted olefins via C-H oxidation. J Am Chem Soc (2004) 1.75
Ligand-modulated palladium-catalyzed aerobic alcohol oxidations. Acc Chem Res (2006) 1.70
Synthesis of heterocycles via palladium-catalyzed oxidative addition. Chem Rev (2006) 1.68
Coinage metal-assisted synthesis of heterocycles. Chem Rev (2008) 1.60
Oxidative cyclizations in a nonpolar solvent using molecular oxygen and studies on the stereochemistry of oxypalladation. J Am Chem Soc (2005) 1.55
A short synthetic route to (+)-austamide, (+)-deoxyisoaustamide, and (+)-hydratoaustamide from a common precursor by a novel palladium-mediated indole --> dihydroindoloazocine cyclization. J Am Chem Soc (2002) 1.51
syn-1,2-Amino alcohols via diastereoselective allylic C-H amination. J Am Chem Soc (2007) 1.47
Twofold C-H functionalization: palladium-catalyzed ortho arylation of anilides. Org Lett (2008) 1.46
Palladium-catalyzed aerobic oxidative amination of alkenes: development of intra- and intermolecular aza-Wacker reactions. Inorg Chem (2007) 1.43
Palladium(II)-Catalyzed Cyclization of Olefinic Tosylamides. J Org Chem (1996) 1.41
Synthesis of cyclic enones via direct palladium-catalyzed aerobic dehydrogenation of ketones. J Am Chem Soc (2011) 1.39
Efficient intramolecular oxidative amination of olefins through direct dioxygen-coupled palladium catalysis. Angew Chem Int Ed Engl (2002) 1.32
Palladium-catalyzed intramolecular aminofluorination of unactivated alkenes. J Am Chem Soc (2009) 1.30
Development of Safe and Scalable Continuous-Flow Methods for Palladium-Catalyzed Aerobic Oxidation Reactions. Green Chem (2010) 1.29
Palladium(II)-Catalyzed Oxidation of Alcohols to Aldehydes and Ketones by Molecular Oxygen. J Org Chem (1999) 1.28
A concise asymmetric synthesis of cis-2,6-disubstituted N-aryl piperazines via Pd-catalyzed carboamination reactions. Org Lett (2007) 1.19
Intramolecular aminopalladation of alkenes as a key step to pyrrolidines and related heterocycles. Chem Soc Rev (2007) 1.16
Total synthesis of (+/-)-rhazinal using novel palladium-catalyzed cyclizations. J Org Chem (2009) 1.14
Rhodium-catalyzed intramolecular, anti-Markovnikov hydroamination. Synthesis of 3-arylpiperidines. J Am Chem Soc (2006) 1.05
Allylic C-H amination for the preparation of syn-1,3-amino alcohol motifs. J Am Chem Soc (2009) 1.04
Silver-mediated synthesis of heterocycles. Chem Rev (2008) 1.03
Gold(I)-catalyzed intramolecular hydroamination of alkenyl carbamates. Angew Chem Int Ed Engl (2006) 1.01
Modular synthesis of 1,2-diamine derivatives by palladium-catalyzed aerobic oxidative cyclization of allylic sulfamides. Angew Chem Int Ed Engl (2010) 1.00
Intramolecular anodic olefin coupling reactions and the synthesis of cyclic amines. J Am Chem Soc (2010) 0.98
New strategy for the synthesis of substituted morpholines. J Org Chem (2009) 0.92
Palladium-catalyzed oxidative amination of alkenes: improved catalyst reoxidation enables the use of alkene as the limiting reagent. Org Lett (2007) 0.89
Intramolecular hydroamination of unbiased and functionalized primary aminoalkenes catalyzed by a rhodium aminophosphine complex. J Am Chem Soc (2010) 0.86
Brønsted base-modulated regioselective pd-catalyzed intramolecular aerobic oxidative amination of alkenes: formation of seven-membered amides and evidence for allylic C-H activation. Org Lett (2009) 0.85
Platinum-catalyzed intramolecular hydrohydrazination: evidence for alkene insertion into a Pt-N bond. J Am Chem Soc (2010) 0.85
More sustainable approaches for the synthesis of N-based heterocycles. Chem Rev (2009) 0.84
Solvent-enhanced diastereo- and regioselectivity in the Pd(II)-catalyzed synthesis of six- and eight-membered heterocycles via cis-aminopalladation. Chemistry (2009) 0.82
Constrained geometry organoactinides as versatile catalysts for the intramolecular hydroamination/cyclization of primary and secondary amines having diverse tethered C-C unsaturation. J Am Chem Soc (2007) 0.80
Aerobic oxidative cyclization under Pd(II) catalysis: a regioselective approach to heterocycles. Org Lett (2005) 0.77
Mimicry of antimicrobial host-defense peptides by random copolymers. J Am Chem Soc (2007) 2.12
Copper-catalyzed aerobic oxidative C-H functionalizations: trends and mechanistic insights. Angew Chem Int Ed Engl (2011) 1.79
Palladium(II)-catalyzed alkene functionalization via nucleopalladation: stereochemical pathways and enantioselective catalytic applications. Chem Rev (2011) 1.76
Highly regioselective Pd-catalyzed intermolecular aminoacetoxylation of alkenes and evidence for cis-aminopalladation and S(N)2 C-O bond formation. J Am Chem Soc (2006) 1.69
Highly practical copper(I)/TEMPO catalyst system for chemoselective aerobic oxidation of primary alcohols. J Am Chem Soc (2011) 1.64
Synthesis of pyrrolidines via palladium(II)-catalyzed aerobic oxidative carboamination of butyl vinyl ether and styrenes with allyl tosylamides. Org Lett (2006) 1.50
Copper-catalyzed aerobic oxidative amidation of terminal alkynes: efficient synthesis of ynamides. J Am Chem Soc (2008) 1.48
Palladium-catalyzed aerobic oxidative amination of alkenes: development of intra- and intermolecular aza-Wacker reactions. Inorg Chem (2007) 1.43
Carbon-nitrogen bond formation involving well-defined aryl-copper(III) complexes. J Am Chem Soc (2008) 1.40
Synthesis of cyclic enones via direct palladium-catalyzed aerobic dehydrogenation of ketones. J Am Chem Soc (2011) 1.39
Copper-catalyzed aerobic oxidative functionalization of an arene C-H bond: evidence for an aryl-copper(III) intermediate. J Am Chem Soc (2010) 1.38
Dual mechanism of bacterial lethality for a cationic sequence-random copolymer that mimics host-defense antimicrobial peptides. J Mol Biol (2008) 1.37
Mechanistic study of copper-catalyzed aerobic oxidative coupling of arylboronic esters and methanol: insights into an organometallic oxidase reaction. J Am Chem Soc (2009) 1.34
Mechanism of Pd(OAc)2/DMSO-catalyzed aerobic alcohol oxidation: mass-transfer-limitation effects and catalyst decomposition pathways. J Am Chem Soc (2006) 1.33
Efficient intramolecular oxidative amination of olefins through direct dioxygen-coupled palladium catalysis. Angew Chem Int Ed Engl (2002) 1.32
Two-faced reactivity of alkenes: cis- versus trans-aminopalladation in aerobic Pd-catalyzed intramolecular aza-Wacker reactions. J Am Chem Soc (2007) 1.31
Development of Safe and Scalable Continuous-Flow Methods for Palladium-Catalyzed Aerobic Oxidation Reactions. Green Chem (2010) 1.29
Allylic C-H acetoxylation with a 4,5-diazafluorenone-ligated palladium catalyst: a ligand-based strategy to achieve aerobic catalytic turnover. J Am Chem Soc (2010) 1.29
Structure-activity relationships among random nylon-3 copolymers that mimic antibacterial host-defense peptides. J Am Chem Soc (2009) 1.26
Overcoming the "oxidant problem": strategies to use O2 as the oxidant in organometallic C-H oxidation reactions catalyzed by Pd (and Cu). Acc Chem Res (2012) 1.25
Palladium-catalyzed aerobic dehydrogenation of substituted cyclohexanones to phenols. Science (2011) 1.24
Enantioselective Pd(II)-catalyzed aerobic oxidative amidation of alkenes and insights into the role of electronic asymmetry in pyridine-oxazoline ligands. Org Lett (2011) 1.23
Aerobic oxidative amination of unactivated alkenes catalyzed by palladium. J Am Chem Soc (2005) 1.22
Ligand-modulated palladium oxidation catalysis: mechanistic insights into aerobic alcohol oxidation with the Pd(OAc)(2)/pyridine catalyst system. Org Lett (2002) 1.20
Mechanistic characterization of aerobic alcohol oxidation catalyzed by Pd(OAc)(2)/pyridine including identification of the catalyst resting state and the origin of nonlinear [catalyst] dependence. J Am Chem Soc (2004) 1.19
Chemoselective metal-free aerobic alcohol oxidation in lignin. J Am Chem Soc (2013) 1.18
Access to poly-beta-peptides with functionalized side chains and end groups via controlled ring-opening polymerization of beta-lactams. J Am Chem Soc (2009) 1.17
Regioselective copper-catalyzed chlorination and bromination of arenes with O(2) as the oxidant. Chem Commun (Camb) (2009) 1.14
Mechanistic study of alcohol oxidation by the Pd(OAc)(2)/O(2)/DMSO catalyst system and implications for the development of improved aerobic oxidation catalysts. J Am Chem Soc (2002) 1.11
Aerobic Oxidative Coupling of o-Xylene: Discovery of 2-Fluoropyridine as a Ligand to Support Selective Pd-Catalyzed C-H Functionalization. Adv Synth Catal (2010) 1.10
Enantioselective hydroformylation of N-vinyl carboxamides, allyl carbamates, and allyl ethers using chiral diazaphospholane ligands. J Am Chem Soc (2010) 1.09
Practical aerobic oxidations of alcohols and amines with homogeneous copper/TEMPO and related catalyst systems. Angew Chem Int Ed Engl (2014) 1.09
Reaction of molecular oxygen with a Pd(II)-hydride to produce a Pd(II)-hydroperoxide: experimental evidence for an HX-reductive-elimination pathway. J Am Chem Soc (2008) 1.08
Unexpected roles of molecular sieves in palladium-catalyzed aerobic alcohol oxidation. J Org Chem (2006) 1.08
Catalytic transamidation reactions compatible with tertiary amide metathesis under ambient conditions. J Am Chem Soc (2009) 1.06
"Inverse-electron-demand" ligand substitution: experimental and computational insights into olefin exchange at palladium(0). J Am Chem Soc (2004) 1.04
Mechanistic study of asymmetric oxidative biaryl coupling: evidence for self-processing of the copper catalyst to achieve control of oxidase vs oxygenase activity. J Am Chem Soc (2008) 1.03
Reversible alkene insertion into the Pd-N bond of Pd(II)-sulfonamidates and implications for catalytic amidation reactions. J Am Chem Soc (2011) 1.03
Reconciling the stereochemical course of nucleopalladation with the development of enantioselective wacker-type cyclizations. Angew Chem Int Ed Engl (2012) 1.03
Mechanism of Pd(OAc)2/pyridine catalyst reoxidation by O2: influence of labile monodentate ligands and identification of a biomimetic mechanism for O2 activation. Chemistry (2009) 1.02
Catalytic transamidation under moderate conditions. J Am Chem Soc (2003) 1.01
Highly stable redox-active molecular layers by covalent grafting to conductive diamond. J Am Chem Soc (2011) 1.01
Copper(I)/ABNO-catalyzed aerobic alcohol oxidation: alleviating steric and electronic constraints of Cu/TEMPO catalyst systems. J Am Chem Soc (2013) 1.00
Modular synthesis of 1,2-diamine derivatives by palladium-catalyzed aerobic oxidative cyclization of allylic sulfamides. Angew Chem Int Ed Engl (2010) 1.00
Direct Aerobic α, β-Dehydrogenation of Aldehydes and Ketones with a Pd(TFA)(2)/4,5-Diazafluorenone Catalyst(). Chem Sci (2011) 0.98
Mechanism of copper(I)/TEMPO-catalyzed aerobic alcohol oxidation. J Am Chem Soc (2013) 0.97
Formation of enamides via palladium(II)-catalyzed vinyl transfer from vinyl ethers to nitrogen nucleophiles. Org Lett (2004) 0.97
Mechanistic studies of Wacker-type intramolecular aerobic oxidative amination of alkenes catalyzed by Pd(OAc)2/pyridine. J Org Chem (2011) 0.97
Catalyst-controlled regioselectivity in the synthesis of branched conjugated dienes via aerobic oxidative Heck reactions. J Am Chem Soc (2012) 0.96
Catalytic metathesis of simple secondary amides. Angew Chem Int Ed Engl (2007) 0.96
Regiocontrolled aerobic oxidative coupling of indoles and benzene using Pd catalysts with 4,5-diazafluorene ligands. Chem Commun (Camb) (2011) 0.95
Aerobic oxidative Heck/dehydrogenation reactions of cyclohexenones: efficient access to meta-substituted phenols. Angew Chem Int Ed Engl (2013) 0.93
Mechanistic studies of Wacker-type amidocyclization of alkenes catalyzed by (IMes)Pd(TFA)2(H2O): kinetic and stereochemical implications of proton transfer. J Org Chem (2012) 0.93
Characterization of peroxo and hydroperoxo intermediates in the aerobic oxidation of N-heterocyclic-carbene-coordinated palladium(0). J Am Chem Soc (2004) 0.93
Pd-catalyzed Semmler-Wolff reactions for the conversion of substituted cyclohexenone oximes to primary anilines. J Am Chem Soc (2013) 0.93
PdII complexes possessing a seven-membered N-heterocyclic carbene ligand. Angew Chem Int Ed Engl (2005) 0.93
Nylon-3 copolymers that generate cell-adhesive surfaces identified by library screening. J Am Chem Soc (2009) 0.92
Mechanism of alcohol oxidation mediated by copper(II) and nitroxyl radicals. J Am Chem Soc (2014) 0.92
Observation and mechanistic study of facile C-O bond formation between a well-defined aryl-copper(III) complex and oxygen nucleophiles. Chemistry (2011) 0.91
Biophysical mimicry of lung surfactant protein B by random nylon-3 copolymers. J Am Chem Soc (2010) 0.91
Palladium-catalyzed intermolecular aminoacetoxylation of alkenes and the influence of PhI(OAc)2 on aminopalladation stereoselectivity. J Org Chem (2013) 0.90
Aerobic intramolecular oxidative amination of alkenes catalyzed by NHC-coordinated palladium complexes. Org Lett (2006) 0.89
Palladium-catalyzed oxidative amination of alkenes: improved catalyst reoxidation enables the use of alkene as the limiting reagent. Org Lett (2007) 0.89
Dioxygen-coupled oxidative amination of styrene. J Am Chem Soc (2003) 0.89
Electrochemical water oxidation with cobalt-based electrocatalysts from pH 0-14: the thermodynamic basis for catalyst structure, stability, and activity. J Am Chem Soc (2011) 0.88
Copper(I)/TEMPO-catalyzed aerobic oxidation of primary alcohols to aldehydes with ambient air. Nat Protoc (2012) 0.88
Aerobic dehydrogenation of cyclohexanone to phenol catalyzed by Pd(TFA)2/2-dimethylaminopyridine: evidence for the role of Pd nanoparticles. J Am Chem Soc (2013) 0.88
Effects of side chain configuration and backbone spacing on the gene delivery properties of lysine-derived cationic polymers. Bioconjug Chem (2005) 0.88
Insertion of molecular oxygen into a palladium-hydride bond: computational evidence for two nearly isoenergetic pathways. J Am Chem Soc (2007) 0.88
Chemoselective organocatalytic aerobic oxidation of primary amines to secondary imines. Org Lett (2012) 0.87
Reaction of O2 with [(-)-sparteine]Pd(H)Cl: evidence for an intramolecular [H-L]+ "reductive elimination" pathway. J Am Chem Soc (2011) 0.87
C-terminal functionalization of nylon-3 polymers: effects of C-terminal groups on antibacterial and hemolytic activities. Biomacromolecules (2011) 0.87
Synthesis of Pd Complexes Bearing an Enantiomerically-Resolved Seven-Membered N-Heterocyclic Carbene Ligands and Initial Studies of their Use in Asymmetric Wacker-Type Oxidative Cyclization Reactions. Tetrahedron (2009) 0.87
Cooperative electrocatalytic alcohol oxidation with electron-proton-transfer mediators. Nature (2016) 0.86
Characterization of DMSO coordination to palladium(II) in solution and insights into the aerobic oxidation catalyst, Pd(DMSO)2(TFA)2. Inorg Chem (2012) 0.86
Reaction of molecular oxygen with a PdII- hydride to produce a PdII-hydroperoxide: acid catalysis and implications for Pd-catalyzed aerobic oxidation reactions. Angew Chem Int Ed Engl (2006) 0.85
Benzoquinone-promoted reaction of O2 with a Pd(II)-hydride. J Am Chem Soc (2011) 0.85
Synthesis of beta-lactams bearing functionalized side chains from a readily available precursor. Org Lett (2008) 0.85
Steric modulation of chiral biaryl diamines via Pd-catalyzed directed C-H arylation. J Org Chem (2009) 0.85
Brønsted base-modulated regioselectivity in the aerobic oxidative amination of styrene catalyzed by palladium. J Am Chem Soc (2005) 0.84
Cu/Nitroxyl Catalyzed Aerobic Oxidation of Primary Amines into Nitriles at Room Temperature. ACS Catal (2013) 0.84
Divergence between organometallic and single-electron-transfer mechanisms in copper(II)-mediated aerobic C-H oxidation. J Am Chem Soc (2013) 0.84
Modular Synthesis of 1,2-Diamine Derivatives via Palladium-Catalyzed Aerobic Oxidative Cyclization of Allylic Sulfamides. Angew Chem Int Ed Engl (2010) 0.83
Molecular mechanism of acid-triggered aryl-halide reductive elimination in well-defined aryl-Cu(III)-halide species. Dalton Trans (2010) 0.83
Synthesis of vicinal aminoalcohols by stereoselective aza-Wacker cyclizations: access to (-)-acosamine by redox relay. Angew Chem Int Ed Engl (2013) 0.83
Mechanistic analysis of trans C-N reductive elimination from a square-planar macrocyclic aryl-copper(III) complex. Dalton Trans (2011) 0.83
Reaction of molecular oxygen with an NHC-coordinated Pd0 complex: computational insights and experimental implications. Angew Chem Int Ed Engl (2007) 0.83
Functionally Diverse Nylon-3 Copolymers from Readily Accessible β-Lactams. ACS Macro Lett (2012) 0.83
Pd-catalyzed aerobic oxidative coupling of arenes: evidence for transmetalation between two Pd(II)-aryl intermediates. J Am Chem Soc (2014) 0.82
Electronic structural comparison of the reactions of dioxygen and alkenes with nitrogen-chelated palladium(0). Inorg Chem (2010) 0.82
Fluoride-modulated cobalt catalysts for electrochemical oxidation of water under non-alkaline conditions. ChemSusChem (2010) 0.82
Bioinspired aerobic oxidation of secondary amines and nitrogen heterocycles with a bifunctional quinone catalyst. J Am Chem Soc (2013) 0.81
Aerobic dehydrogenation of cyclohexanone to cyclohexenone catalyzed by Pd(DMSO)2(TFA)2: evidence for ligand-controlled chemoselectivity. J Am Chem Soc (2013) 0.81
Modular o-quinone catalyst system for dehydrogenation of tetrahydroquinolines under ambient conditions. J Am Chem Soc (2014) 0.81
Insights into the spin-forbidden reaction between L2Pd0 and molecular oxygen. J Am Chem Soc (2004) 0.80
Kinetic and Spectroscopic Studies of Aerobic Copper(II)-Catalyzed Methoxylation of Arylboronic Esters and Insights into Aryl Transmetalation to Copper(II). Organometallics (2012) 0.78
Synthesis and isolation of a stable, axially-chiral seven-membered N-heterocyclic carbene. Dalton Trans (2009) 0.78
Copper(II)-mediated oxidative cyclization of enamides to oxazoles. Org Biomol Chem (2012) 0.78
Modular synthesis of alkyne-substituted ruthenium polypyridyl complexes suitable for "click" coupling. Inorg Chem (2013) 0.78
"Oxidatively induced" reductive elimination of dioxygen from an eta2-peroxopalladium(II) complex promoted by electron-deficient alkenes. J Am Chem Soc (2006) 0.77