Published in J Am Chem Soc on May 04, 2005
Catalytic asymmetric intermolecular Stetter reaction of glyoxamides with alkylidenemalonates. J Am Chem Soc (2008) 1.84
A highly enantioselective intramolecular Michael reaction catalyzed by N-heterocyclic carbenes. Angew Chem Int Ed Engl (2007) 1.52
Carbene catalysts. Top Curr Chem (2010) 1.48
An efficient synthesis of achiral and chiral 1,2,4-triazolium salts: bench stable precursors for N-heterocyclic carbenes. J Org Chem (2005) 1.46
N-heterocyclic carbene and Brønsted acid cooperative catalysis: asymmetric synthesis of trans-γ-lactams. J Am Chem Soc (2011) 1.36
Enantio- and diastereoselective intermolecular Stetter reaction of glyoxamide and alkylidene ketoamides. Org Lett (2009) 1.35
Asymmetric synthesis of hydrobenzofuranones via desymmetrization of cyclohexadienones using the intramolecular Stetter reaction. J Am Chem Soc (2006) 1.30
Organocatalytic Reactions Enabled by N-Heterocyclic Carbenes. Chem Rev (2015) 1.19
Metallophosphite-catalyzed asymmetric acylation of alpha,beta-unsaturated amides. J Am Chem Soc (2006) 1.15
Asymmetric N-Heterocyclic Carbene (NHC) Catalyzed Acyl Anion Reactivity. Aldrichimica Acta (2011) 1.14
Scope of the asymmetric intramolecular stetter reaction catalyzed by chiral nucleophilic triazolinylidene carbenes. J Org Chem (2008) 1.14
The Catalytic Asymmetric Intramolecular Stetter Reaction. Synlett (2009) 1.07
Enantioselective Synthesis of Hydrobenzofuranones Using an Asymmetric Desymmetrizing Intramolecular Stetter Reaction of Cyclohexadienones. Org Process Res Dev (2007) 1.04
Catalytic asymmetric intermolecular Stetter reactions of enolizable aldehydes with nitrostyrenes: computational study provides insight into the success of the catalyst. Angew Chem Int Ed Engl (2012) 1.03
Mechanistic investigation of the enantioselective intramolecular stetter reaction: proton transfer is the first irreversible step. Org Lett (2011) 1.02
Alpha'-hydroxyenones as mechanistic probes and scope-expanding surrogates for alpha,beta-unsaturated aldehydes in N-heterocyclic carbene-catalyzed reactions. J Am Chem Soc (2009) 1.00
Quantum mechanical investigation of the effect of catalyst fluorination in the intermolecular asymmetric Stetter reaction. J Am Chem Soc (2011) 0.99
3-Methyl-4H-chromen-4-one. Acta Crystallogr Sect E Struct Rep Online (2010) 0.94
Nucleophilic carbene catalyzed synthesis of 1,2 amino alcohols via azidation of epoxy aldehydes. J Org Chem (2008) 0.92
Stereodivergency of triazolium and imidazolium-derived NHCs for catalytic, enantioselective cyclopentane synthesis. Org Lett (2009) 0.91
Catalytic asymmetric stetter reaction onto vinylphosphine oxides and vinylphosphonates. Org Lett (2008) 0.84
Late-stage diversification of chiral N-heterocyclic-carbene precatalysts for enantioselective homoenolate additions. Chem Asian J (2010) 0.81
Organocatalytic hydroacylation of unactivated alkenes. Angew Chem Int Ed Engl (2011) 0.79
2,5-Diphenyl-2,5,6,8-tetra-hydro-1,2,4-triazolo[3,4-c][1,4]oxazin-4-ium hexa-fluorido-phosphate. Acta Crystallogr Sect E Struct Rep Online (2008) 0.75
5-Benzyl-2-phenyl-6,8-dihydro-5H-1,2,4-triazolo[3,4-c][1,4]oxazin-2-ium hexa-fluoridophosphate. Acta Crystallogr Sect E Struct Rep Online (2009) 0.75
Novel actions of estrogen receptor-beta on anxiety-related behaviors. Endocrinology (2004) 2.20
A highly enantioselective catalytic intramolecular Stetter reaction. J Am Chem Soc (2002) 2.07
Biotinylated Rh(III) complexes in engineered streptavidin for accelerated asymmetric C-H activation. Science (2012) 1.87
Enantioselective rhodium-catalyzed [2+2+2] cycloaddition of alkenyl isocyanates and terminal alkynes: application to the total synthesis of (+)-lasubine II. J Am Chem Soc (2006) 1.84
Catalytic asymmetric intermolecular Stetter reaction of glyoxamides with alkylidenemalonates. J Am Chem Soc (2008) 1.84
Rhodium-catalyzed [2 + 2 + 2] cycloaddition of alkenyl isocyanates and alkynes. J Am Chem Soc (2006) 1.60
Enantioselective synthesis of quaternary stereocenters via a catalytic asymmetric Stetter reaction. J Am Chem Soc (2004) 1.56
Catalytic asymmetric intermolecular stetter reaction of heterocyclic aldehydes with nitroalkenes: backbone fluorination improves selectivity. J Am Chem Soc (2009) 1.52
Enantioselective protonation of catalytically generated chiral enolates as an approach to the synthesis of alpha-chloroesters. J Am Chem Soc (2005) 1.50
Carbene catalysts. Top Curr Chem (2010) 1.48
An efficient synthesis of achiral and chiral 1,2,4-triazolium salts: bench stable precursors for N-heterocyclic carbenes. J Org Chem (2005) 1.46
Conversion of alpha-haloaldehydes into acylating agents by an internal redox reaction catalyzed by nucleophilic carbenes. J Am Chem Soc (2004) 1.41
Rhodium-catalyzed oxidative cycloaddition of benzamides and alkynes via C-H/N-H activation. J Am Chem Soc (2010) 1.40
Catalytic asymmetric α-acylation of tertiary amines mediated by a dual catalysis mode: N-heterocyclic carbene and photoredox catalysis. J Am Chem Soc (2012) 1.38
Enantioselective synthesis of indolizidines bearing quaternary substituted stereocenters via rhodium-catalyzed [2+2+2] cycloaddition of alkenyl isocyanates and terminal alkynes. Org Lett (2008) 1.38
Asymmetric synthesis of bicyclic amidines via rhodium-catalyzed [2+2+2] cycloaddition of carbodiimides. J Am Chem Soc (2008) 1.37
N-heterocyclic carbene and Brønsted acid cooperative catalysis: asymmetric synthesis of trans-γ-lactams. J Am Chem Soc (2011) 1.36
Enantio- and diastereoselective intermolecular Stetter reaction of glyoxamide and alkylidene ketoamides. Org Lett (2009) 1.35
More than bystanders: the effect of olefins on transition-metal-catalyzed cross-coupling reactions. Angew Chem Int Ed Engl (2008) 1.31
Asymmetric synthesis of hydrobenzofuranones via desymmetrization of cyclohexadienones using the intramolecular Stetter reaction. J Am Chem Soc (2006) 1.30
Nucleophilic carbene and HOAt relay catalysis in an amide bond coupling: an orthogonal peptide bond forming reaction. J Am Chem Soc (2007) 1.29
Predictable and regioselective insertion of internal unsymmetrical alkynes in rhodium-catalyzed cycloadditions with alkenyl isocyanates. J Am Chem Soc (2009) 1.24
Enantioselective rhodium-catalyzed [2 + 2 + 2] cycloadditions of terminal alkynes and alkenyl isocyanates: mechanistic insights lead to a unified model that rationalizes product selectivity. J Am Chem Soc (2009) 1.21
Pyridine synthesis from oximes and alkynes via rhodium(III) catalysis: Cp* and Cp(t) provide complementary selectivity. Chem Commun (Camb) (2011) 1.19
Total synthesis of indolizidine alkaloid (-)-209D: overriding substrate bias in the asymmetric rhodium-catalyzed [2+2+2] cycloaddition. Angew Chem Int Ed Engl (2009) 1.19
Rh(III)-catalyzed regioselective synthesis of pyridines from alkenes and α,β-unsaturated oxime esters. J Am Chem Soc (2012) 1.18
N-Heterocyclic carbene catalyzed asymmetric hydration: direct synthesis of alpha-protio and alpha-deuterio alpha-chloro and alpha-fluoro carboxylic acids. J Am Chem Soc (2010) 1.16
Scope of the asymmetric intramolecular stetter reaction catalyzed by chiral nucleophilic triazolinylidene carbenes. J Org Chem (2008) 1.14
Exploiting Acyl and Enol Azolium Intermediates via NHeterocyclic Carbene Catalyzed Reactions of Alpha-Reducible Aldehydes. Adv Synth Catal (2012) 1.10
Beyond Reppe: building substituted arenes by [2+2+2] cycloadditions of alkynes. Angew Chem Int Ed Engl (2009) 1.08
The Catalytic Asymmetric Intramolecular Stetter Reaction. Synlett (2009) 1.07
Isolable analogues of the Breslow intermediate derived from chiral triazolylidene carbenes. J Am Chem Soc (2012) 1.06
Multi-component cycloaddition approaches in the catalytic asymmetric synthesis of alkaloid targets. Chem Soc Rev (2009) 1.06
Decarbonylative cross-coupling of cyclic anhydrides: introducing stereochemistry at an sp3 carbon in the cross-coupling event. J Am Chem Soc (2003) 1.05
Asymmetric synthesis of functionalized cyclopentanones via a multicatalytic secondary amine/N-heterocyclic carbene catalyzed cascade sequence. J Am Chem Soc (2009) 1.04
Enantioselective Synthesis of Hydrobenzofuranones Using an Asymmetric Desymmetrizing Intramolecular Stetter Reaction of Cyclohexadienones. Org Process Res Dev (2007) 1.04
Catalytic asymmetric intermolecular Stetter reactions of enolizable aldehydes with nitrostyrenes: computational study provides insight into the success of the catalyst. Angew Chem Int Ed Engl (2012) 1.03
Mechanistic investigation of the enantioselective intramolecular stetter reaction: proton transfer is the first irreversible step. Org Lett (2011) 1.02
Catalytic asymmetric intermolecular Stetter reaction of enals with nitroalkenes: enhancement of catalytic efficiency through bifunctional additives. J Am Chem Soc (2011) 1.02
Enantioselective rhodium-catalyzed [4+2+2] cycloaddition of dienyl isocyanates for the synthesis of bicyclic azocine rings. J Am Chem Soc (2009) 1.01
Towards the total synthesis of FD-838: modular enantioselective assembly of the core. Chem Commun (Camb) (2008) 1.00
Quantum mechanical investigation of the effect of catalyst fluorination in the intermolecular asymmetric Stetter reaction. J Am Chem Soc (2011) 0.99
Rhodium(III)-catalyzed oxidative carbonylation of benzamides with carbon monoxide. Chem Commun (Camb) (2011) 0.99
Rh(III)-catalyzed decarboxylative coupling of acrylic acids with unsaturated oxime esters: carboxylic acids serve as traceless activators. J Am Chem Soc (2014) 0.98
An asymmetric synthesis of 1,2,4-trioxane anticancer agents via desymmetrization of peroxyquinols through a Brønsted acid catalysis cascade. J Am Chem Soc (2012) 0.98
Regioselective rhodium-catalyzed intermolecular [2+2+2] cycloaddition of alkynes and isocyanates to form pyridones. Tetrahedron (2009) 0.98
A unique catalyst effects the rapid room-temperature cross-coupling of organozinc reagents with carboxylic acid fluorides, chlorides, anhydrides, and thioesters. J Am Chem Soc (2004) 0.98
A coupling of benzamides and donor/acceptor diazo compounds to form γ-lactams via Rh(III)-catalyzed C-H activation. J Am Chem Soc (2013) 0.97
Rhodium-catalyzed enantioselective desymmetrization of meso-3,5-dimethyl glutaric anhydride: a general strategy to syn-deoxypolypropionate synthons. J Am Chem Soc (2007) 0.97
Nickel-catalyzed reductive carboxylation of styrenes using CO2. J Am Chem Soc (2008) 0.96
Rh(III)-catalyzed cyclopropanation initiated by C-H activation: ligand development enables a diastereoselective [2 + 1] annulation of N-enoxyphthalimides and alkenes. J Am Chem Soc (2014) 0.93
Enamine/Carbene Cascade Catalysis in the Diastereo- and Enantioselective Synthesis of Functionalized Cyclopentanones. Chem Sci (2011) 0.93
Phosphoramidite-Rhodium Complexes as Catalysts for the Asymmetric [2+2+2] Cycloaddition of Alkenyl Isocyanates and Alkynes. Pure Appl Chem (2009) 0.92
Nucleophilic carbene catalyzed synthesis of 1,2 amino alcohols via azidation of epoxy aldehydes. J Org Chem (2008) 0.92
Multicatalytic, asymmetric Michael/Stetter reaction of salicylaldehydes and activated alkynes. Proc Natl Acad Sci U S A (2010) 0.92
Excess substrate is a spectator ligand in a rhodium-catalyzed asymmetric [2 + 2 + 2] cycloaddition of alkenyl isocyanates with tolanes. Org Lett (2009) 0.91
Catalytic asymmetric cross-aza-benzoin reactions of aliphatic aldehydes with N-Boc-protected imines. Angew Chem Int Ed Engl (2012) 0.90
Enantioselective rhodium-catalyzed [4+2] cycloaddition of α,β-unsaturated imines and isocyanates. J Am Chem Soc (2011) 0.90
Asymmetric N-heterocyclic carbene catalyzed addition of enals to nitroalkenes: controlling stereochemistry via the homoenolate reactivity pathway to access δ-lactams. J Am Chem Soc (2013) 0.90
Ligand-dependent catalytic cycle and role of styrene in nickel-catalyzed anhydride cross-coupling: evidence for turnover-limiting reductive elimination. J Am Chem Soc (2007) 0.88
N-heterocyclic-carbene-catalyzed asymmetric oxidative hetero-Diels-Alder reactions with simple aliphatic aldehydes. Angew Chem Int Ed Engl (2012) 0.87
Rhodium(III)-catalyzed intramolecular hydroarylation, amidoarylation, and Heck-type reaction: three distinct pathways determined by an amide directing group. Angew Chem Int Ed Engl (2013) 0.86
Rh(I)-bisphosphine-catalyzed asymmetric, intermolecular hydroheteroarylation of α-substituted acrylate derivatives. J Am Chem Soc (2014) 0.86
A mild and efficient catalytic alkylative monofunctionalization of cyclic anhydrides. J Am Chem Soc (2002) 0.85
A catalytic asymmetric synthesis of polysubstituted piperidines using a rhodium(I)-catalyzed [2+2+2] cycloaddition employing a cleavable tether. Angew Chem Int Ed Engl (2013) 0.85
A Sakurai-Prins-Ritter sequence for the three-component diastereoselective synthesis of 4-amino tetrahydropyrans. J Am Chem Soc (2006) 0.85
Enantioselective N-heterocyclic carbene-catalyzed β-hydroxylation of enals using nitroarenes: an atom transfer reaction that proceeds via single electron transfer. J Am Chem Soc (2014) 0.85
Catalytic asymmetric stetter reaction onto vinylphosphine oxides and vinylphosphonates. Org Lett (2008) 0.84
Enantioselective cross-coupling of anhydrides with organozinc reagents: the controlled formation of carbon-carbon bonds through the nucleophilic interception of metalacycles. Acc Chem Res (2008) 0.83
Perfluorinated Taddol Phosphoramidite as an L,Z-Ligand on Rh(I) and Co(-I): Evidence for Bidentate Coordination via Metal-C6F5 Interaction. Chem Sci (2013) 0.81
Catalytic, asymmetric indolizidinone aza-quaternary stereocenter synthesis: expedient synthesis of the cylindricine alkaloid core. Org Lett (2013) 0.80
A concise synthesis of eupomatilones 4, 6, and 7 by rhodium-catalyzed enantioselective desymmetrization of cyclic meso anhydrides with organozinc reagents generated in situ. Angew Chem Int Ed Engl (2007) 0.79
Organocatalytic hydroacylation of unactivated alkenes. Angew Chem Int Ed Engl (2011) 0.79
The [1, 3] O-to-C rearrangement: opportunities for stereoselective synthesis. Org Biomol Chem (2007) 0.79
Stereoretentive O-to-C rearrangement of vinyl acetals: solvent cage effects as a stereocontrol element. J Am Chem Soc (2002) 0.79
Highly efficient nickel-catalyzed cross-coupling of succinic and glutaric anhydrides with organozinc reagents. J Am Chem Soc (2005) 0.79
A diastereoselective ring contraction of 1,3-dioxepins to 2,3,4-trisubstituted and tetrasubstituted tetrahydrofurans. J Org Chem (2007) 0.78
Stereoselective Lewis acid mediated [1,3] ring contraction of 2,5-dihydrooxepins as a route to polysubstituted cyclopentenes. Angew Chem Int Ed Engl (2005) 0.78
A palladium-catalyzed enantioselective alkylative desymmetrization of meso-succinic anhydrides. J Am Chem Soc (2004) 0.78
Stereoelectronic basis for the kinetic resolution of N-heterocycles with chiral acylating reagents. Chemistry (2014) 0.77
Regioselective Lewis acid-mediated [1,3] rearrangement of allylvinyl ethers. Org Lett (2005) 0.76
Surveying approaches to the formation of carbon-carbon bonds between a pyran and an adjacent ring. Tetrahedron (2006) 0.75
A photoisomerization-coupled asymmetric Stetter reaction: application to the total synthesis of three diastereomers of (-)-cephalimysin A. Chem Sci (2013) 0.75
Organometallic chemistry: C-H carboxylation takes gold. Nat Chem (2010) 0.75
Enantioselective rhodium-catalyzed isomerization of 4-iminocrotonates: asymmetric synthesis of a unique chiral synthon. J Am Chem Soc (2015) 0.75
Use of acid fluorides increases the scope of the reductive acylation of esters. Org Lett (2004) 0.75
A diastereoselective intermolecular heck reaction of 1,3-dioxepins. Org Lett (2007) 0.75
Complementary diastereoselective reduction of cyclic gamma-keto acids: efficient access to trisubsituted gamma-lactones. Org Lett (2005) 0.75
A modular approach to the synthesis of 2,3,4-trisubstituted tetrahydrofurans. Chem Commun (Camb) (2006) 0.75
Correction: Pyridine synthesis from oximes and alkynes via rhodium(III) catalysis: Cp* and Cp(t) provide complementary selectivity. Chem Commun (Camb) (2015) 0.75
Correction to "Oxidatively Initiated NHC-Catalyzed Enantioselective Synthesis of 3,4-Disubstituted Cyclopentanones from Enals". J Am Chem Soc (2015) 0.75
Alkene-directed regioselective nickel-catalyzed cross-coupling of cyclic anhydrides with diorganozinc reagents. Angew Chem Int Ed Engl (2007) 0.75
Selective substituent transfer from mixed zinc reagents in Ni-catalyzed anhydride alkylation. Org Lett (2006) 0.75