Published in Aldrichimica Acta on January 01, 2011
Catalytic asymmetric α-acylation of tertiary amines mediated by a dual catalysis mode: N-heterocyclic carbene and photoredox catalysis. J Am Chem Soc (2012) 1.38
Organocatalytic Reactions Enabled by N-Heterocyclic Carbenes. Chem Rev (2015) 1.19
Exploiting Acyl and Enol Azolium Intermediates via NHeterocyclic Carbene Catalyzed Reactions of Alpha-Reducible Aldehydes. Adv Synth Catal (2012) 1.10
Catalytic asymmetric intermolecular Stetter reactions of enolizable aldehydes with nitrostyrenes: computational study provides insight into the success of the catalyst. Angew Chem Int Ed Engl (2012) 1.03
Asymmetric N-heterocyclic carbene catalyzed addition of enals to nitroalkenes: controlling stereochemistry via the homoenolate reactivity pathway to access δ-lactams. J Am Chem Soc (2013) 0.90
N-heterocyclic-carbene-catalyzed asymmetric oxidative hetero-Diels-Alder reactions with simple aliphatic aldehydes. Angew Chem Int Ed Engl (2012) 0.87
Catalytic asymmetric umpolung reactions of imines. Nature (2015) 0.86
Enantioselective N-heterocyclic carbene-catalyzed β-hydroxylation of enals using nitroarenes: an atom transfer reaction that proceeds via single electron transfer. J Am Chem Soc (2014) 0.85
Intercepting the Breslow intermediate via Claisen rearrangement: synthesis of complex tertiary alcohols without organometallic reagents. Org Lett (2012) 0.79
N-Heterocyclic carbene-catalyzed direct cross-aza-benzoin reaction: Efficient synthesis of α-amino-β-keto esters. Beilstein J Org Chem (2012) 0.77
NHC-Catalyzed Asymmetric Synthesis of Functionalized Succinimides from Enals and α-Ketoamides. Chemistry (2015) 0.76
Stereo- and Chemodivergent NHC-Promoted Functionalisation of Arylalkylketenes with Chloral. Chemistry (2015) 0.75
A photoisomerization-coupled asymmetric Stetter reaction: application to the total synthesis of three diastereomers of (-)-cephalimysin A. Chem Sci (2013) 0.75
SNAr-Derived Decomposition By-products Involving Pentafluorophenyl Triazolium Carbenes. Synlett (2013) 0.75
Rate and equilibrium constants for the addition of N-heterocyclic carbenes into benzaldehydes: a remarkable 2-substituent effect. Angew Chem Int Ed Engl (2015) 0.75
Efficient synthetic protocols for the preparation of common N-heterocyclic carbene precursors. Beilstein J Org Chem (2015) 0.75
Rate and Equilibrium Constants for the Addition of N-Heterocyclic Carbenes into Benzaldehydes: A Remarkable 2-Substituent Effect. Angew Chem Weinheim Bergstr Ger (2015) 0.75
Organocatalysis by N-heterocyclic carbenes. Chem Rev (2007) 4.47
Nucleophilic carbenes in asymmetric organocatalysis. Acc Chem Res (2004) 3.57
N-heterocyclic carbenes as organocatalysts. Angew Chem Int Ed Engl (2007) 2.99
Redox economy in organic synthesis. Angew Chem Int Ed Engl (2009) 2.74
Organocatalytic cascade reactions as a new tool in total synthesis. Nat Chem (2010) 2.29
A highly enantio- and diastereoselective catalytic intramolecular Stetter reaction. J Am Chem Soc (2005) 2.25
Conversion of alpha,beta-unsaturated aldehydes into saturated esters: an Umpolung reaction catalyzed by nucleophilic carbenes. Org Lett (2005) 2.08
A highly enantioselective catalytic intramolecular Stetter reaction. J Am Chem Soc (2002) 2.07
Catalytic asymmetric intermolecular Stetter reaction of glyoxamides with alkylidenemalonates. J Am Chem Soc (2008) 1.84
An efficient nucleophilic carbene catalyst for the asymmetric benzoin condensation. Angew Chem Int Ed Engl (2002) 1.60
Enantioselective synthesis of quaternary stereocenters via a catalytic asymmetric Stetter reaction. J Am Chem Soc (2004) 1.56
Catalytic asymmetric intermolecular stetter reaction of heterocyclic aldehydes with nitroalkenes: backbone fluorination improves selectivity. J Am Chem Soc (2009) 1.52
Catalytic generation of activated carboxylates from enals: a product-determining role for the base. Org Lett (2005) 1.50
Enantioselective protonation of catalytically generated chiral enolates as an approach to the synthesis of alpha-chloroesters. J Am Chem Soc (2005) 1.50
Recent advances in carbon-carbon bond-forming reactions involving homoenolates generated by NHC catalysis. Chem Soc Rev (2008) 1.47
An efficient synthesis of achiral and chiral 1,2,4-triazolium salts: bench stable precursors for N-heterocyclic carbenes. J Org Chem (2005) 1.46
Organocatalysis--after the gold rush. Chem Soc Rev (2009) 1.42
Conversion of alpha-haloaldehydes into acylating agents by an internal redox reaction catalyzed by nucleophilic carbenes. J Am Chem Soc (2004) 1.41
Enantioselective linchpin catalysis by SOMO catalysis: an approach to the asymmetric alpha-chlorination of aldehydes and terminal epoxide formation. Angew Chem Int Ed Engl (2009) 1.37
Modified chiral triazolium salts for enantioselective benzoin cyclization of enolizable keto-aldehydes: synthesis of (+)-sappanone B. Org Lett (2007) 1.36
Enantio- and diastereoselective intermolecular Stetter reaction of glyoxamide and alkylidene ketoamides. Org Lett (2009) 1.35
Direct nucleophilic acylation of nitroalkenes promoted by a fluoride anion/thiourea combination. J Am Chem Soc (2006) 1.35
Catalytic generation of activated carboxylates: direct, stereoselective synthesis of beta-hydroxyesters from epoxyaldehydes. J Am Chem Soc (2004) 1.33
Asymmetric synthesis of hydrobenzofuranones via desymmetrization of cyclohexadienones using the intramolecular Stetter reaction. J Am Chem Soc (2006) 1.30
Nucleophilic carbene and HOAt relay catalysis in an amide bond coupling: an orthogonal peptide bond forming reaction. J Am Chem Soc (2007) 1.29
N-Heterocyclic carbene catalyzed asymmetric hydration: direct synthesis of alpha-protio and alpha-deuterio alpha-chloro and alpha-fluoro carboxylic acids. J Am Chem Soc (2010) 1.16
Metallophosphite-induced nucleophilic acylation of alpha,beta-unsaturated amides: facilitated catalysis by a diastereoselective retro [1,4] Brook rearrangement. Angew Chem Int Ed Engl (2005) 1.16
Metallophosphite-catalyzed asymmetric acylation of alpha,beta-unsaturated amides. J Am Chem Soc (2006) 1.15
N-heterocyclic carbene-catalyzed redox amidations of alpha-functionalized aldehydes with amines. J Am Chem Soc (2007) 1.15
Scope of the asymmetric intramolecular stetter reaction catalyzed by chiral nucleophilic triazolinylidene carbenes. J Org Chem (2008) 1.14
Enantioselective protonation. Nat Chem (2009) 1.13
Stereoselective synthesis of (E)-alpha,beta-unsaturated esters via carbene-catalyzed redox esterification. Org Lett (2006) 1.13
Thiol addition to the carbonyl group. Equilibria and kinetics. J Am Chem Soc (1966) 1.11
N-heterocyclic carbene catalyzed C--C bond cleavage in redox esterifications of chiral formylcyclopropanes. Angew Chem Int Ed Engl (2006) 1.08
The Catalytic Asymmetric Intramolecular Stetter Reaction. Synlett (2009) 1.07
Asymmetric synthesis of functionalized cyclopentanones via a multicatalytic secondary amine/N-heterocyclic carbene catalyzed cascade sequence. J Am Chem Soc (2009) 1.04
Enantioselective Synthesis of Hydrobenzofuranones Using an Asymmetric Desymmetrizing Intramolecular Stetter Reaction of Cyclohexadienones. Org Process Res Dev (2007) 1.04
Asymmetric intermolecular Stetter reactions catalyzed by a novel triazolium derived N-heterocyclic carbene. Chem Commun (Camb) (2008) 1.03
Thiazolium-catalyzed additions of acylsilanes: a general strategy for acyl anion addition reactions. J Org Chem (2006) 1.01
Catalytic ester-amide exchange using group (IV) metal alkoxide-activator complexes. J Am Chem Soc (2005) 1.01
Catalytic, asymmetric alpha-halogenation. J Am Chem Soc (2001) 0.99
Catalytic asymmetric synthesis of tertiary alkyl chlorides. Angew Chem Int Ed Engl (2007) 0.98
Enantioselective organocatalysis. Drug Discov Today (2006) 0.95
Nucleophilic carbene catalyzed synthesis of 1,2 amino alcohols via azidation of epoxy aldehydes. J Org Chem (2008) 0.92
Catalytic, asymmetric alpha-chlorination of acid halides. J Am Chem Soc (2004) 0.92
Multicatalytic, asymmetric Michael/Stetter reaction of salicylaldehydes and activated alkynes. Proc Natl Acad Sci U S A (2010) 0.92
Catalytic amide formation with alpha'-hydroxyenones as acylating reagents. Chem Commun (Camb) (2009) 0.92
Organocatalytic preparation of simple β-hydroxy and β-amino esters: low catalyst loadings and gram-scale synthesis. Org Lett (2010) 0.87
N-heterocyclic carbene-catalyzed hydroacylation of unactivated double bonds. J Am Chem Soc (2009) 0.84
Catalytic asymmetric stetter reaction onto vinylphosphine oxides and vinylphosphonates. Org Lett (2008) 0.84
N-heterocyclic carbene-catalyzed cascade reaction involving the hydroacylation of unactivated alkynes. J Am Chem Soc (2010) 0.81
N-heterocyclic carbene catalyzed nucleophilic substitution reaction for construction of benzopyrones and benzofuranones. Org Lett (2006) 0.81