Published in Org Lett on September 05, 2008
Rhodium-catalyzed asymmetric 1,4-addition and its related asymmetric reactions. Chem Rev (2003) 2.19
Rhodium-catalyzed carbon-carbon bond forming reactions of organometallic compounds. Chem Rev (2003) 1.31
More than bystanders: the effect of olefins on transition-metal-catalyzed cross-coupling reactions. Angew Chem Int Ed Engl (2008) 1.31
Chiral olefins as steering ligands in asymmetric catalysis. Angew Chem Int Ed Engl (2008) 1.16
Catalytic cycle of rhodium-catalyzed asymmetric 1,4-addition of organoboronic acids. Arylrhodium, oxa-pi-allylrhodium, and hydroxorhodium intermediates. J Am Chem Soc (2002) 1.13
A chiral chelating diene as a new type of chiral ligand for transition metal catalysts: its preparation and use for the rhodium-catalyzed asymmetric 1,4-addition. J Am Chem Soc (2003) 1.09
Readily available [2.2.2]-bicyclooctadienes as new chiral ligands for Ir(I): catalytic, kinetic resolution of allyl carbonates. J Am Chem Soc (2004) 1.04
Asymmetric synthesis of 3,3-diarylpropanals with chiral diene-rhodium catalysts. J Am Chem Soc (2005) 0.97
Enantioselective preparation of 1,1-diarylethanes: aldehydes as removable steering groups for asymmetric synthesis. Angew Chem Int Ed Engl (2007) 0.93
C2-symmetric bicyclo[2.2.2]octadienes as chiral ligands: their high performance in rhodium-catalyzed asymmetric arylation of N-tosylarylimines. J Am Chem Soc (2004) 0.90
Chiral [2.2.2] dienes as ligands for Rh(I) in conjugate additions of boronic acids to a wide range of acceptors. Org Lett (2004) 0.89
Catalytic asymmetric synthesis of allylsilanes through rhodium/chiral diene-catalyzed 1,4-addition of alkenyl[2-(hydroxymethyl)phenyl]dimethylsilanes. Org Lett (2007) 0.88
Preparation of C2-symmetric bicyclo[2.2.2]octa-2,5-diene ligands and their use for rhodium-catalyzed asymmetric 1,4-addition of arylboronic acids. J Org Chem (2005) 0.86
Expanding the C2-symmetric bicyclo[2.2.1]hepta-2,5-diene ligand family: concise synthesis and catalytic activity in rhodium-catalyzed asymmetric addition. J Org Chem (2006) 0.85
Catalytic asymmetric synthesis with rh-diene complexes: 1,4-addition of arylboronic acids to unsaturated esters. Org Lett (2005) 0.85
Rhodium/diene-catalyzed asymmetric 1,4-addition of arylboronic acids to alpha,beta-unsaturated Weinreb amides. Chem Commun (Camb) (2005) 0.83
C2-symmetric bicyclo[3.3.1]nonadiene as a chiral ligand for rhodium-catalyzed asymmetric arylation of N-(4-nitrobenzenesulfonyl)arylimines. Org Lett (2005) 0.82
Carbon-carbon bond-forming enantioselective synthesis of chiral organosilicon compounds by rhodium/chiral diene-catalyzed asymmetric 1,4-addition reaction. Org Lett (2005) 0.82
Rhodium/chiral diene-catalyzed asymmetric 1,4-addition of arylboronic acids to arylmethylene cyanoacetates. Org Lett (2008) 0.82
Rhodium-catalysed substitutive arylation of cis-allylic diols with arylboroxines. Chem Commun (Camb) (2006) 0.80
Highly chemo- and enantioselective arylative cyclization of alkyne-tethered electron-deficient olefins catalyzed by rhodium complexes with chiral dienes. Angew Chem Int Ed Engl (2005) 0.80
Asymmetric addition of dimethylzinc to N-tosylarylimines catalyzed by a rhodium-diene complex toward the synthesis of chiral 1-arylethylamines. Org Lett (2006) 0.79
A cationic rhodium-chiral diene complex as a high-performance catalyst for the intramolecular asymmetric [4+2] cycloaddition of alkyne-1,3-dienes. Angew Chem Int Ed Engl (2007) 0.79
Rhodium-catalyzed annulation reactions of 2-cyanophenylboronic acid with alkynes and strained alkenes. Org Lett (2005) 0.79
High performance of a chiral diene-rhodium catalyst for the asymmetric 1,4-addition of arylboroxines to alpha,beta-unsaturated ketones. Org Lett (2006) 0.79
Enantiomerically pure rhodium complexes bearing 1,5-diphenyl-1,5-cyclooctadiene as a chiral diene ligand. Their use as catalysts for asymmetric 1,4-addition of phenylzinc chloride. Org Lett (2005) 0.78
Rhodium-catalysed 1,4-addition of diarylindium hydroxides to alpha,beta-unsaturated carbonyl compounds. Chem Commun (Camb) (2005) 0.77
General synthesis of persistent trityl radicals for EPR imaging of biological systems. J Org Chem (2002) 2.06
Hydrogen bonding: single enantiomers from a chiral-alcohol catalyst. Nature (2003) 1.79
Chiral squaramide derivatives are excellent hydrogen bond donor catalysts. J Am Chem Soc (2008) 1.67
Rapid synthesis of the N-methylwelwitindolinone skeleton. Org Lett (2005) 1.66
Broadly effective enantioselective Diels-Alder reactions of 1-amino-substituted-1,3-butadienes. Org Lett (2002) 1.56
Total synthesis of N-methylwelwitindolinone D isonitrile. J Am Chem Soc (2011) 1.23
Total synthesis of mycalamide A. J Am Chem Soc (2005) 1.12
Highly diastereo- and enantioselective Mukaiyama aldol reactions catalyzed by hydrogen bonding. Angew Chem Int Ed Engl (2006) 1.12
Hydrogen-bond-promoted hetero-Diels-Alder reactions of unactivated ketones. J Am Chem Soc (2002) 1.12
Axially chiral biaryl diols catalyze highly enantioselective hetero-Diels-Alder reactions through hydrogen bonding. J Am Chem Soc (2005) 1.11
Palladium-catalyzed [3 + 3] cycloaddition of trimethylenemethane with azomethine imines. J Am Chem Soc (2006) 1.10
Chiral norbornadienes as efficient ligands for the rhodium-catalyzed asymmetric 1,4-addition of arylboronic acids to fumaric and maleic compounds. Org Lett (2004) 1.10
Iron-catalyzed Grignard cross-coupling with alkyl halides possessing beta-hydrogens. Org Lett (2004) 1.10
Enantioselective Diels-Alder reactions catalyzed by hydrogen bonding. Proc Natl Acad Sci U S A (2004) 1.06
Palladium-catalyzed beta-allylation of 2,3-disubstituted indoles. Org Lett (2008) 1.04
Stereoselective synthesis of spirooxindoles by palladium-catalyzed decarboxylative cyclization of gamma-methylidene-delta-valerolactones with isatins. Org Lett (2009) 1.03
Palladium-catalyzed C3-benzylation of indoles. J Am Chem Soc (2011) 1.03
Rhodium-catalyzed asymmetric construction of quaternary carbon stereocenters: ligand-dependent regiocontrol in the 1,4-addition to substituted maleimides. J Am Chem Soc (2006) 1.03
Facile synthesis of the indeno-tetrahydropyridine core of haouamine A. Org Lett (2005) 1.02
Design and development of highly effective Lewis acid catalysts for enantioselective Diels-Alder reactions. J Am Chem Soc (2002) 1.01
Squaramide-catalyzed enantioselective Michael addition of diphenyl phosphite to nitroalkenes. Angew Chem Int Ed Engl (2010) 1.00
A unified route to the welwitindolinone alkaloids: total syntheses of (-)-N-methylwelwitindolinone C isothiocyanate, (-)-N-methylwelwitindolinone C isonitrile, and (-)-3-hydroxy-N-methylwelwitindolinone C isothiocyanate. J Am Chem Soc (2012) 0.99
Total synthesis of pederin. Angew Chem Int Ed Engl (2007) 0.98
Rhodium-catalyzed isomerization of alpha-arylpropargyl alcohols to indanones: involvement of an unexpected reaction cascade. J Am Chem Soc (2005) 0.97
A general strategy to elisabethane diterpenes: stereocontrolled synthesis of elisapterosin B via oxidative cyclization of an elisabethin precursor. J Am Chem Soc (2003) 0.97
Silver-catalyzed formal inverse electron-demand Diels-Alder reaction of 1,2-diazines and siloxy alkynes. J Am Chem Soc (2012) 0.96
Ruthenium-catalyzed transformation of alkenyl triflates to alkenyl halides. Chem Commun (Camb) (2009) 0.96
Enantioselective alpha-amination of 1,3-dicarbonyl compounds using squaramide derivatives as hydrogen bonding catalysts. Org Lett (2010) 0.95
Metathesis route to bridged metallocenes. J Am Chem Soc (2002) 0.95
Stereospecific synthesis of highly substituted skipped dienes through multifunctional palladium catalysis. Org Lett (2002) 0.95
tert-Butoxide-mediated arylation of benzene with aryl halides in the presence of a catalytic 1,10-phenanthroline derivative. J Am Chem Soc (2010) 0.94
Copper-catalyzed asymmetric allylic substitution of allyl phosphates with aryl- and alkenylboronates. Angew Chem Int Ed Engl (2011) 0.94
Stereocontrolled synthesis of 20,21-dihydro N-methylwelwitindolinone B isothiocyanate. Chem Commun (Camb) (2011) 0.94
Diastereoselective and enantioselective synthesis of tertiary alpha-hydroxy phosphonates through hydrogen-bond catalysis. Angew Chem Int Ed Engl (2009) 0.93
Sodium tetraarylborates as effective nucleophiles in rhodium/diene-catalyzed 1,4-addition to beta,beta-disubstituted alpha,beta-unsaturated ketones: catalytic asymmetric construction of quaternary carbon stereocenters. J Am Chem Soc (2009) 0.93
Directed oxidative cyclizations to C2- or C4-positions of indole: efficient construction of the bicyclo[4.3.1]decane core of welwitindolinones. Org Lett (2011) 0.92
Electronic and steric tuning of chiral diene ligands for rhodium-catalyzed asymmetric arylation of imines. Chem Commun (Camb) (2009) 0.92
Organo[2-(hydroxymethyl)phenyl]dimethylsilanes as mild and reproducible agents for rhodium-catalyzed 1,4-addition reactions. J Am Chem Soc (2007) 0.92
Highly enantioselective carbonyl-ene reactions catalyzed by a hindered silyl-salen-cobalt complex. Org Lett (2007) 0.91
Rhodium-catalyzed isomerization of unactivated alkynes to 1,3-dienes. Chem Commun (Camb) (2006) 0.91
Total synthesis of (+/-)-platencin. Angew Chem Int Ed Engl (2008) 0.91
Rhodium-catalyzed asymmetric addition of aryl- and alkenylboronic acids to isatins. Angew Chem Int Ed Engl (2006) 0.91
Iridium/chiral diene-catalyzed asymmetric 1,6-addition of arylboroxines to alpha,beta,gamma,delta-unsaturated carbonyl compounds. J Am Chem Soc (2010) 0.90
Squaramide-catalyzed enantioselective Michael addition of masked acyl cyanides to substituted enones. J Am Chem Soc (2013) 0.90
Arylmagnesiation of alkynes catalyzed cooperatively by iron and copper complexes. J Am Chem Soc (2005) 0.90
Cross-Coupling of Aryl Halides and Allyl Acetates with Arylboron Reagents in Water Using an Amphiphilic Resin-Supported Palladium Catalyst. J Org Chem (1999) 0.90
C2-symmetric bicyclo[2.2.2]octadienes as chiral ligands: their high performance in rhodium-catalyzed asymmetric arylation of N-tosylarylimines. J Am Chem Soc (2004) 0.90
A kinetic study on Rh/binap-catalyzed 1,4-addition of phenylboronic acid to enones: negative nonlinear effect caused by predominant homochiral dimer contribution. J Am Chem Soc (2006) 0.89
Preparation of an amphiphilic resin-supported BINAP ligand and its use for rhodium-catalyzed asymmetric 1,4-addition of phenylboronic acid in water. Org Lett (2004) 0.89
Catalytic asymmetric synthesis of allylsilanes through rhodium/chiral diene-catalyzed 1,4-addition of alkenyl[2-(hydroxymethyl)phenyl]dimethylsilanes. Org Lett (2007) 0.88
Palladium-catalyzed decarboxylative allylation and benzylation of N-alloc and N-Cbz indoles. Org Lett (2013) 0.87
Total synthesis of (+/-)-bipinnatin J. Org Lett (2006) 0.87
Design and Preparation of 3,3'-Disubstituted 2,2'-Bis(oxazolyl)-1,1'-binaphthyls (boxax): New Chiral Bis(oxazoline) Ligands for Catalytic Asymmetric Wacker-Type Cyclization. J Org Chem (1999) 0.87
Rhodium-catalyzed asymmetric 1,4-addition of arylboronic acids to coumarins: asymmetric synthesis of (R)-tolterodine. Org Lett (2005) 0.87
Asymmetric synthesis of metallocenes through enantioselective addition of organolithium reagents to 6-(dimethylamino)fulvene. J Org Chem (2002) 0.87
Preparation of C2-symmetric bicyclo[2.2.2]octa-2,5-diene ligands and their use for rhodium-catalyzed asymmetric 1,4-addition of arylboronic acids. J Org Chem (2005) 0.86
Palladium-catalyzed asymmetric [3+3] cycloaddition of trimethylenemethane derivatives with nitrones. Angew Chem Int Ed Engl (2007) 0.86
Palladium-catalyzed regiocontrolled alpha-arylation of trimethylsilyl enol ethers with aryl halides. Org Lett (2006) 0.86
Synthesis of C-15 vindoline analogues by palladium-catalyzed cross-coupling reactions. J Org Chem (2006) 0.86
Enantioselective total syntheses of (+)-arborescidine A, (-)-arborescidine B, and (-)-arborescidine C. J Org Chem (2004) 0.86
Expanding the C2-symmetric bicyclo[2.2.1]hepta-2,5-diene ligand family: concise synthesis and catalytic activity in rhodium-catalyzed asymmetric addition. J Org Chem (2006) 0.85
Chiral tetrafluorobenzobarrelenes as effective ligands for rhodium-catalyzed asymmetric 1,4-addition of arylboroxines to beta,beta-disubstituted alpha,beta-unsaturated ketones. Angew Chem Int Ed Engl (2010) 0.85
Asymmetric synthesis of 1-aryl-1,2-ethanediols from arylacetylenes by palladium-catalyzed asymmetric hydrosilylation as a key step. J Am Chem Soc (2002) 0.85
Inhibition of eukaryotic translation elongation by the antitumor natural product Mycalamide B. RNA (2011) 0.85
Asymmetric synthesis of 2-aryl-2,3-dihydro-4-quinolones by rhodium-catalyzed 1,4-addition of arylzinc reagents in the presence of chlorotrimethylsilane. Org Lett (2005) 0.85
Iron-copper cooperative catalysis in the reactions of alkyl Grignard reagents: exchange reaction with alkenes and carbometalation of alkynes. J Am Chem Soc (2011) 0.84
Asymmetric synthesis of beta-alkynyl aldehydes by rhodium-catalyzed conjugate alkynylation. Angew Chem Int Ed Engl (2009) 0.84
Chiral phosphine-olefin ligands in the rhodium-catalyzed asymmetric 1,4-addition reactions. J Am Chem Soc (2007) 0.84
Rhodium-catalyzed asymmetric [5+2] cycloaddition of alkyne-vinylcyclopropanes. Chemistry (2009) 0.84
Asymmetric synthesis of (triaryl)methylamines by rhodium-catalyzed addition of arylboroxines to cyclic N-sulfonyl ketimines. J Am Chem Soc (2012) 0.84
Synthesis of α-amino acid derivatives and peptides via enantioselective addition of masked acyl cyanides to imines. J Am Chem Soc (2014) 0.84
A new entry of nucleophiles in rhodium-catalyzed asymmetric 1,4-addition reactions: addition of organozinc reagents for the synthesis of 2-aryl-4-piperidones. J Am Chem Soc (2004) 0.83
Hydroxorhodium/chiral diene complexes as effective catalysts for the asymmetric arylation of 3-aryl-3-hydroxyisoindolin-1-ones. Angew Chem Int Ed Engl (2013) 0.83
Hydrogen bond catalyzed enantioselective vinylogous Mukaiyama aldol reaction. Org Lett (2005) 0.83
Catalytic asymmetric arylative cyclization of alkynals: phosphine-free rhodium/diene complexes as efficient catalysts. J Am Chem Soc (2005) 0.83
Rhodium-catalyzed asymmetric hydroarylation of diphenylphosphinylallenes with arylboronic acids. J Am Chem Soc (2006) 0.83
Palladium-catalyzed decarboxylative [4 + 3] cyclization of gamma-methylidene-delta-valerolactones with 1,1-dicyanocyclopropanes. Org Lett (2009) 0.83
Kinetic studies prove high catalytic activity of a diene-rhodium complex in 1,4-addition of phenylboronic acid to alpha,beta-unsaturated ketones. Chem Asian J (2006) 0.83
Non-precious metals catalyze formal [4 + 2] cycloaddition reactions of 1,2-diazines and siloxyalkynes under ambient conditions. Org Lett (2014) 0.83
Rhodium/diene-catalyzed asymmetric 1,4-addition of arylboronic acids to alpha,beta-unsaturated Weinreb amides. Chem Commun (Camb) (2005) 0.83
Cobalt-catalyzed asymmetric 1,6-addition of (triisopropylsilyl)-acetylene to α,β,γ,δ-unsaturated carbonyl compounds. J Am Chem Soc (2012) 0.82
Steric tuning of silylacetylenes and chiral phosphine ligands for rhodium-catalyzed asymmetric conjugate alkynylation of enones. J Am Chem Soc (2008) 0.82
C2-symmetric bicyclo[3.3.1]nonadiene as a chiral ligand for rhodium-catalyzed asymmetric arylation of N-(4-nitrobenzenesulfonyl)arylimines. Org Lett (2005) 0.82
Palladium-catalyzed asymmetric synthesis of silicon-stereogenic dibenzosiloles via enantioselective C-H bond functionalization. J Am Chem Soc (2012) 0.82
Rhodium/chiral diene-catalyzed asymmetric 1,4-addition of arylboronic acids to arylmethylene cyanoacetates. Org Lett (2008) 0.82
Iron-catalyzed oxidative homo-coupling of aryl Grignard reagents. Org Lett (2005) 0.82
Carbon-carbon bond-forming enantioselective synthesis of chiral organosilicon compounds by rhodium/chiral diene-catalyzed asymmetric 1,4-addition reaction. Org Lett (2005) 0.82
Structural determinants of blockade of eosinophil activation, adhesion and secretion by synthetic analogs of phomactin. Life Sci (2003) 0.82
Palladium-catalyzed silylation of alcohols with hexamethyldisilane. Chem Commun (Camb) (2006) 0.82
Lessons Learned while Traversing the Welwitindolinone Alkaloids Obstacle Course. Tetrahedron (2011) 0.81
A new cine-substitution of alkenyl sulfones with aryltitanium reagents catalyzed by rhodium: mechanistic studies and catalytic asymmetric synthesis of allylarenes. J Am Chem Soc (2003) 0.81
Chiral tetrafluorobenzobarrelene ligands for the rhodium-catalyzed asymmetric cycloisomerization of oxygen- and nitrogen-bridged 1,6-enynes. Angew Chem Int Ed Engl (2010) 0.81
Rhodium-catalyzed asymmetric rearrangement of alkynyl alkenyl carbinols: synthetic equivalent to asymmetric conjugate alkynylation of enones. J Am Chem Soc (2007) 0.81
Chiral phosphine-olefin bidentate ligands in asymmetric catalysis: rhodium-catalyzed asymmetric 1,4-addition of aryl boronic acids to maleimides. Angew Chem Int Ed Engl (2005) 0.81
A new type of catalytic tandem 1,4-addition-aldol reaction which proceeds through an (oxa-pi-allyl)rhodium intermediate. J Am Chem Soc (2002) 0.81
Gamma-methylidene-delta-valerolactones as a coupling partner for cycloaddition: palladium-catalyzed [4 + 3] cycloaddition with nitrones. J Am Chem Soc (2007) 0.81
Iron-catalyzed oxidative coupling of alkylamides with arenes through oxidation of alkylamides followed by Friedel-Crafts alkylation. J Org Chem (2010) 0.81
Palladium-catalyzed asymmetric synthesis of axially chiral (allenylmethyl)silanes and chirality transfer to stereogenic carbon centers in S(E)' reactions. Org Lett (2003) 0.80