Published in J Am Chem Soc on January 13, 2010
Preparation and properties of a monomeric high-spin Mn(V)-oxo complex. J Am Chem Soc (2012) 1.11
Mechanism of S-oxygenation by a cysteine dioxygenase model complex. J Phys Chem A (2011) 0.90
Secondary coordination sphere influence on the reactivity of nonheme iron(II) complexes: an experimental and DFT approach. J Am Chem Soc (2013) 0.89
Structural and spectroscopic characterization of metastable thiolate-ligated manganese(III)-alkylperoxo species. J Am Chem Soc (2011) 0.84
Characterization of a thiolato iron(III) Peroxy dianion complex. Angew Chem Int Ed Engl (2012) 0.83
X-ray absorption spectroscopy and reactivity of thiolate-ligated Fe(III)-OOR complexes. Inorg Chem (2010) 0.82
Spectroscopic and computational characterization of CuII-OOR (R = H or cumyl) complexes bearing a Me6-tren ligand. Dalton Trans (2011) 0.81
Axial and equatorial ligand effects on biomimetic cysteine dioxygenase model complexes. Org Biomol Chem (2012) 0.81
Correlation between structural, spectroscopic, and reactivity properties within a series of structurally analogous metastable manganese(III)-alkylperoxo complexes. J Am Chem Soc (2013) 0.81
Preparation of aluminum(III) (bis(amido)pyridine)(thiolate) complexes: unexpected transmetalation mediated by LiAlH(4). Inorganica Chim Acta (2012) 0.76
Perturbing the Copper(III)-Hydroxide Unit through Ligand Structural Variation. J Am Chem Soc (2015) 0.76
Density Functional Theory Calculations on Fe-O and O-O Cleavage of Ferric Hydroperoxide Species: Role of axial ligand and spin state. Inorganica Chim Acta (2010) 0.76
Thioether-ligated iron(II) and iron(III)-hydroperoxo/alkylperoxo complexes with an H-bond donor in the second coordination sphere. Dalton Trans (2014) 0.75
Proton-Coupled Electron Transfer in Organic Synthesis: Fundamentals, Applications, and Opportunities. Top Curr Chem (J) (2016) 0.75
Structure and chemistry of cytochrome P450. Chem Rev (2005) 5.85
Crystallographic and spectroscopic characterization of a nonheme Fe(IV)-O complex. Science (2003) 3.40
Theoretical perspective on the structure and mechanism of cytochrome P450 enzymes. Chem Rev (2005) 2.10
Structures of the superoxide reductase from Pyrococcus furiosus in the oxidized and reduced states. Biochemistry (2000) 1.87
End-on and side-on peroxo derivatives of non-heme iron complexes with pentadentate ligands: models for putative intermediates in biological iron/dioxygen chemistry. Inorg Chem (2003) 1.70
Spectroscopic studies of Pyrococcus furiosus superoxide reductase: implications for active-site structures and the catalytic mechanism. J Am Chem Soc (2002) 1.60
Synthetic analogues of cysteinate-ligated non-heme iron and non-corrinoid cobalt enzymes. Chem Rev (2004) 1.54
Raman-assisted crystallography reveals end-on peroxide intermediates in a nonheme iron enzyme. Science (2007) 1.52
Neelaredoxin, an iron-binding protein from the syphilis spirochete, Treponema pallidum, is a superoxide reductase. J Biol Chem (2000) 1.31
Electronic structure of high-spin iron(III)-alkylperoxo complexes and its relation to low-spin analogues: reaction coordinate of O-O bond homolysis. J Am Chem Soc (2001) 1.29
High-valent nonheme iron. Two distinct iron(IV) species derived from a common iron(II) precursor. J Am Chem Soc (2005) 1.29
Role of the heme active site and protein environment in structure, spectra, and function of the cytochrome p450s. Chem Rev (2000) 1.22
Avoiding high-valent iron intermediates: superoxide reductase and rubrerythrin. J Inorg Biochem (2006) 1.18
A functional model for the cysteinate-ligated non-heme iron enzyme superoxide reductase (SOR). J Am Chem Soc (2006) 1.16
Spectroscopic properties and electronic structure of low-spin Fe(III)-alkylperoxo complexes: homolytic cleavage of the O-O bond. J Am Chem Soc (2001) 1.16
Spectroscopic properties of desulfoferrodoxin from Desulfovibrio desulfuricans (ATCC 27774). J Biol Chem (1994) 1.16
Structure of superoxide reductase bound to ferrocyanide and active site expansion upon X-ray-induced photo-reduction. Structure (2004) 1.15
Thirty years of microbial P450 monooxygenase research: peroxo-heme intermediates--the central bus station in heme oxygenase catalysis. Biochem Biophys Res Commun (2005) 1.14
Discovery of superoxide reductase: an historical perspective. J Biol Inorg Chem (2004) 1.14
Identification of iron(III) peroxo species in the active site of the superoxide reductase SOR from Desulfoarculus baarsii. J Am Chem Soc (2002) 1.09
Nitric oxide binding at the mononuclear active site of reduced Pyrococcus furiosus superoxide reductase. Proc Natl Acad Sci U S A (2003) 1.07
Sulfur K-edge X-ray absorption spectroscopy and density functional theory calculations on superoxide reductase: role of the axial thiolate in reactivity. J Am Chem Soc (2007) 1.04
Synthesis, structure determination, and spectroscopic/computational characterization of a series of Fe(II)-thiolate model complexes: implications for Fe-S bonding in superoxide reductases. J Am Chem Soc (2005) 1.04
Understanding how the thiolate sulfur contributes to the function of the non-heme iron enzyme superoxide reductase. Acc Chem Res (2007) 1.03
A low-spin alkylperoxo-iron(III) complex with weak Fe-O and O-O bonds: implications for the mechanism of superoxide reductase. J Am Chem Soc (2006) 0.99
The 'push' effect of the thiolate ligand in cytochrome P450: a theoretical gauging. J Inorg Biochem (2002) 0.99
Rational tuning of the thiolate donor in model complexes of superoxide reductase: direct evidence for a trans influence in Fe(III)-OOR complexes. J Am Chem Soc (2008) 0.99
Spectroscopy of non-heme iron thiolate complexes: insight into the electronic structure of the low-spin active site of nitrile hydratase. Inorg Chem (2005) 0.99
Spin concentration measurements of high-spin (g' = 4.3) rhombic iron(III) ions in biological samples: theory and application. J Biol Inorg Chem (2007) 0.96
The first crystal structure of class III superoxide reductase from Treponema pallidum. J Biol Inorg Chem (2006) 0.95
EPR investigation and spectral simulations of iron-catecholate complexes and iron-peptide models of marine adhesive cross-links. Inorg Chem (2006) 0.94
Mononuclear, dinuclear, and pentanuclear [[N,S(thiolate)]iron(II)] complexes: nuclearity control, incorporation of hydroxide bridging ligands, and magnetic behavior. Chemistry (2005) 0.93
Computational study of the non-heme iron active site in superoxide reductase and its reaction with superoxide. Inorg Chem (2003) 0.91
Assessing the role of the active-site cysteine ligand in the superoxide reductase from Desulfoarculus baarsii. J Biol Chem (2007) 0.90
Electronic structure and reactivity of high-spin iron--alkyl- and--pterinperoxo complexes. Inorg Chem (2003) 0.89
Mössbauer characterization of an unusual high-spin side-on peroxo-Fe3+ species in the active site of superoxide reductase from Desulfoarculus Baarsii. Density functional calculations on related models. Biochemistry (2004) 0.89
Reaction of Desulfovibrio vulgaris two-iron superoxide reductase with superoxide: insights from stopped-flow spectrophotometry. Biochemistry (2007) 0.89
A nonheme iron(II) complex that models the redox cycle of lipoxygenase. J Biol Inorg Chem (2001) 0.88
Spin-state rationale for the peroxo-stabilizing role of the thiolate ligand in superoxide reductase. Angew Chem Int Ed Engl (2005) 0.87
Nonheme iron(II) complexes of macrocyclic ligands in the generation of oxoiron(IV) complexes and the catalytic epoxidation of olefins. J Inorg Biochem (2006) 0.87
Fe(3+)-eta(2)-peroxo species in superoxide reductase from Treponema pallidum. Comparison with Desulfoarculus baarsii. Biophys Chem (2005) 0.86
Synthetic models of the reduced active site of superoxide reductase. Inorg Chem (2002) 0.85
Effect of N-methylation of macrocyclic amine ligands on the spin state of iron(III): a tale of two fluoro complexes. Inorg Chem (2006) 0.85
Superoxide reduction by Archaeoglobus fulgidus desulfoferrodoxin: comparison with neelaredoxin. J Biol Inorg Chem (2006) 0.84
Kinetic analysis of the conversion of nonheme (alkylperoxo)iron(III) species to iron(IV) complexes. Inorg Chem (2007) 0.83
Geometries and electronic structures of cyanide adducts of the non-heme iron active site of superoxide reductases: vibrational and ENDOR studies. Biochemistry (2006) 0.81
Enzymatic activity mastered by altering metal coordination spheres. J Biol Inorg Chem (2008) 0.80
Synthesis and Characterization of Novel Alkylperoxo Mononuclear Iron(III) Complexes with a Tripodal Pyridylamine Ligand: A Model for Peroxo Intermediates in Reactions Catalyzed by Non-Heme Iron Enzymes. Inorg Chem (1999) 0.80
Resonance Raman study of the superoxide reductase from Archaeoglobus fulgidus, E12 mutants and a 'natural variant'. Phys Chem Chem Phys (2009) 0.79
Solvation largely accounts for the effect of N-alkylation on the properties of nickel(II/I) and chromium(III/II) cyclam complexes. Inorg Chem (2002) 0.78
Bio-social origins of depression in the community. Interactions between social adversity, cortisol and serotonin neurotransmission. Br J Psychiatry (2002) 3.18
Oxidation of heme to beta- and delta-biliverdin by Pseudomonas aeruginosa heme oxygenase as a consequence of an unusual seating of the heme. J Am Chem Soc (2002) 1.98
Nitric oxide in biological denitrification: Fe/Cu metalloenzyme and metal complex NO(x) redox chemistry. Chem Rev (2002) 1.81
Reactions of a copper(II) superoxo complex lead to C-H and O-H substrate oxygenation: modeling copper-monooxygenase C-H hydroxylation. Angew Chem Int Ed Engl (2008) 1.43
Recombination in vaccine and circulating strains of porcine reproductive and respiratory syndrome viruses. Emerg Infect Dis (2009) 1.39
Hydrogen atom abstraction by a high-valent manganese(V)-oxo corrolazine. Inorg Chem (2006) 1.30
Unprecedented rate enhancements of hydrogen-atom transfer to a manganese(V)-oxo corrolazine complex. Angew Chem Int Ed Engl (2010) 1.29
Valence tautomerism in a high-valent manganese-oxo porphyrinoid complex induced by a Lewis acid. J Am Chem Soc (2012) 1.28
Carboxylate as the protonation site in (Peroxo)diiron(III) model complexes of soluble methane monooxygenase and related diiron proteins. J Am Chem Soc (2010) 1.24
Safety and feasibility of an intravascular optical coherence tomography image wire system in the clinical setting. Am J Cardiol (2008) 1.24
DevS, a heme-containing two-component oxygen sensor of Mycobacterium tuberculosis. Biochemistry (2007) 1.24
Porcine reproductive and respiratory syndrome virus (PRRSV) suppresses interferon-beta production by interfering with the RIG-I signaling pathway. Mol Immunol (2008) 1.18
Synthesis, characterization, and physicochemical properties of manganese(III) and manganese(V)-oxo corrolazines. Inorg Chem (2005) 1.16
Heme/non-heme diiron(II) complexes and O2, CO, and NO adducts as reduced and substrate-bound models for the active site of bacterial nitric oxide reductase. J Am Chem Soc (2005) 1.16
Toluene and ethylbenzene aliphatic C-H bond oxidations initiated by a dicopper(II)-mu-1,2-peroxo complex. J Am Chem Soc (2009) 1.16
Aryl hydroxylation from a mononuclear copper-hydroperoxo species. J Am Chem Soc (2007) 1.14
The genomic diversity of Chinese porcine reproductive and respiratory syndrome virus isolates from 1996 to 2009. Vet Microbiol (2010) 1.08
Electron- and hydride-transfer reactivity of an isolable manganese(V)-oxo complex. J Am Chem Soc (2011) 1.06
Molecular characterization of transcriptome-wide interactions between highly pathogenic porcine reproductive and respiratory syndrome virus and porcine alveolar macrophages in vivo. Int J Biol Sci (2011) 1.06
Fungal heme oxygenases: Functional expression and characterization of Hmx1 from Saccharomyces cerevisiae and CaHmx1 from Candida albicans. Biochemistry (2006) 1.05
Kinetic and spectroscopic studies of hemin acquisition in the hemophore HasAp from Pseudomonas aeruginosa. Biochemistry (2010) 1.05
Transcription Factor NsrR from Bacillus subtilis Senses Nitric Oxide with a 4Fe-4S Cluster (†). Biochemistry (2008) 1.04
Social precursors to onset and recovery from episodes of common mental illness. Psychol Med (2003) 1.03
Interdomain interactions within the two-component heme-based sensor DevS from Mycobacterium tuberculosis. Biochemistry (2007) 1.03
Copper(I) complex O(2)-reactivity with a N(3)S thioether ligand: a copper-dioxygen adduct including sulfur ligation, ligand oxygenation, and comparisons with all nitrogen ligand analogues. Inorg Chem (2007) 1.03
A manganese(V)-oxo π-cation radical complex: influence of one-electron oxidation on oxygen-atom transfer. J Am Chem Soc (2011) 1.02
Reactivity studies on Fe(III)-(O2(2-))-Cu(II) compounds: influence of the ligand architecture and copper ligand denticity. Inorg Chem (2007) 1.01
An isolable, nonreducible high-valent manganese(V) imido corrolazine complex. Inorg Chem (2006) 1.00
Accessibility of the distal heme face, rather than Fe-His bond strength, determines the heme-nitrosyl coordination number of cytochromes c': evidence from spectroscopic studies. Biochemistry (2005) 1.00
Insights into the nitric oxide reductase mechanism of flavodiiron proteins from a flavin-free enzyme. Biochemistry (2010) 1.00
Octalkoxy-substituted phosphorus(V) triazatetrabenzcorroles via ring contraction of phthalocyanine precursors. Inorg Chem (2003) 1.00
A low-spin alkylperoxo-iron(III) complex with weak Fe-O and O-O bonds: implications for the mechanism of superoxide reductase. J Am Chem Soc (2006) 0.99
Rational tuning of the thiolate donor in model complexes of superoxide reductase: direct evidence for a trans influence in Fe(III)-OOR complexes. J Am Chem Soc (2008) 0.99
A distal tyrosine residue is required for ligand discrimination in DevS from Mycobacterium tuberculosis. Biochemistry (2008) 0.98
Structural characterization of the hemophore HasAp from Pseudomonas aeruginosa: NMR spectroscopy reveals protein-protein interactions between Holo-HasAp and hemoglobin. Biochemistry (2009) 0.98
Synthesis and spectroscopy of micro-oxo (O(2)(-))-bridged heme/non-heme diiron complexes: models for the active site of nitric oxide reductase. Inorg Chem (2004) 0.98
Vibrational analysis of mononitrosyl complexes in hemerythrin and flavodiiron proteins: relevance to detoxifying NO reductase. J Am Chem Soc (2012) 0.98
Immunogenicity of the highly pathogenic porcine reproductive and respiratory syndrome virus GP5 protein encoded by a synthetic ORF5 gene. Vaccine (2009) 0.96
The millisecond intermediate in the reaction of nitric oxide with oxymyoglobin is an iron(III)--nitrato complex, not a peroxynitrite. J Am Chem Soc (2009) 0.96
Accommodation of two diatomic molecules in cytochrome bo: insights into NO reductase activity in terminal oxidases. Biochemistry (2009) 0.96
Characteristics of CD133(+) human colon cancer SW620 cells. Cell Transplant (2010) 0.95
O2 activation by bis(imino)pyridine iron(II)-thiolate complexes. J Am Chem Soc (2011) 0.95
Iron(II)-thiolate S-oxygenation by O2: synthetic models of cysteine dioxygenase. J Am Chem Soc (2010) 0.94
Construction and immunogenicity of pseudotype baculovirus expressing GP5 and M protein of porcine reproductive and respiratory syndrome virus. Vaccine (2007) 0.94
Myocardial bridge: harmless or harmful. Intern Med (2004) 0.93
A stable manganese(V)-oxo corrolazine complex. J Am Chem Soc (2002) 0.93
Mononuclear, dinuclear, and pentanuclear [[N,S(thiolate)]iron(II)] complexes: nuclearity control, incorporation of hydroxide bridging ligands, and magnetic behavior. Chemistry (2005) 0.93
Structural, NMR spectroscopic, and computational investigation of hemin loading in the hemophore HasAp from Pseudomonas aeruginosa. J Am Chem Soc (2010) 0.93
Dramatic influence of an anionic donor on the oxygen-atom transfer reactivity of a Mn(V) -oxo complex. Chemistry (2014) 0.92
Activation of a high-valent manganese-oxo complex by a nonmetallic Lewis acid. Inorg Chem (2014) 0.92
Copper(II)-hydroperoxo complex induced oxidative N-dealkylation chemistry. J Am Chem Soc (2007) 0.92
Interaction of nitric oxide with human heme oxygenase-1. J Biol Chem (2002) 0.92
Fourier transform infrared characterization of a CuB-nitrosyl complex in cytochrome ba3 from Thermus thermophilus: relevance to NO reductase activity in heme-copper terminal oxidases. J Am Chem Soc (2007) 0.91
Biochemical and structural characterization of Pseudomonas aeruginosa Bfd and FPR: ferredoxin NADP+ reductase and not ferredoxin is the redox partner of heme oxygenase under iron-starvation conditions. Biochemistry (2007) 0.91
Characterization of the first N2S(alkylthiolate)lead compound: a model for three-coordinate lead in biological systems. Inorg Chem (2006) 0.91
p53 inactivation upregulates p73 expression through E2F-1 mediated transcription. PLoS One (2012) 0.91
Mechanism of S-oxygenation by a cysteine dioxygenase model complex. J Phys Chem A (2011) 0.90
Carbon monoxide coordination and reversible photodissociation in copper(I) pyridylalkylamine compounds. Inorg Chem (2007) 0.90
Activation of NF-κB by nucleocapsid protein of the porcine reproductive and respiratory syndrome virus. Virus Genes (2010) 0.90
Characterization of NO adducts of the diiron center in protein R2 of Escherichia coli ribonucleotide reductase and site-directed variants; implications for the O2 activation mechanism. J Biol Inorg Chem (2004) 0.90
Nitric oxide dioxygenation reaction in DevS and the initial response to nitric oxide in Mycobacterium tuberculosis. Biochemistry (2011) 0.90
A new bis(imidazolyl)(alkylthiolate) tripodal ligand and the spontaneous formation of a disulfide-linked, hydroxo-bridged dinuclear zinc complex. Chem Commun (Camb) (2002) 0.90
Secondary coordination sphere influence on the reactivity of nonheme iron(II) complexes: an experimental and DFT approach. J Am Chem Soc (2013) 0.89
Dramatically accelerated selective oxygen-atom transfer by a nonheme iron(IV)-oxo complex: tuning of the first and second coordination spheres. J Am Chem Soc (2014) 0.89
Two CO molecules can bind concomitantly at the diiron site of NO reductase from Bacillus azotoformans. J Am Chem Soc (2004) 0.89
Oxygen-atom transfer reactivity of axially ligated Mn(V)-oxo complexes: evidence for enhanced electrophilic and nucleophilic pathways. J Am Chem Soc (2014) 0.89
Construction and immunogenicity of recombinant pseudotype baculovirus expressing the capsid protein of porcine circovirus type 2 in mice. J Virol Methods (2008) 0.89
Isolation and propagation of a human CD133(-) colon tumor-derived cell line with tumorigenic and angiogenic properties. Cell Transplant (2010) 0.89
Dioxygen reactivity of copper and heme-copper complexes possessing an imidazole-phenol cross-link. Inorg Chem (2005) 0.89
Addition of dioxygen to an N4S(thiolate) iron(II) cysteine dioxygenase model gives a structurally characterized sulfinato-iron(II) complex. J Am Chem Soc (2012) 0.89
Bone repair by transplantation of hTERT-immortalized human mesenchymal stem cells in mice. Transplantation (2009) 0.88
High-valent transition metal corrolazines. J Inorg Biochem (2006) 0.88
Identification of depression by medical and surgical general hospital physicians. Gen Hosp Psychiatry (2002) 0.88
Catalytic sulfoxidation and epoxidation with a Mn(III) triazacorrole: evidence for a "third oxidant" in high-valent porphyrinoid oxidations. J Am Chem Soc (2004) 0.87
Enhanced immunogenicity of the modified GP5 of porcine reproductive and respiratory syndrome virus. Virus Genes (2006) 0.87
Purification and characterization of the MQH2:NO oxidoreductase from the hyperthermophilic archaeon Pyrobaculum aerophilum. J Biol Chem (2003) 0.87
Measurement of the heme affinity for yeast dap1p, and its importance in cellular function. Biochemistry (2007) 0.87
Phenol nitration induced by an {Fe(NO)2}(10) dinitrosyl iron complex. J Am Chem Soc (2011) 0.87
Modeling the syn disposition of nitrogen donors in non-heme diiron enzymes. Synthesis, characterization, and hydrogen peroxide reactivity of diiron(III) complexes with the syn N-donor ligand H2BPG2DEV. J Am Chem Soc (2009) 0.87
Comparison of immune responses and protective efficacy of suicidal DNA vaccine and conventional DNA vaccine encoding glycoprotein C of pseudorabies virus in mice. Vaccine (2004) 0.86
Sulfur oxygenation in biomimetic non-heme iron-thiolate complexes. Dalton Trans (2012) 0.86
Antiviral activity of type I and type III interferons against porcine reproductive and respiratory syndrome virus (PRRSV). Antiviral Res (2011) 0.86
Thioether sulfur oxygenation from O2 or H2O2 reactivity of copper complexes with tridentate N2Sthioether ligands. Inorg Chem (2006) 0.86
Spectroscopic characterization of mononitrosyl complexes in heme--nonheme diiron centers within the myoglobin scaffold (Fe(B)Mbs): relevance to denitrifying NO reductase. Biochemistry (2011) 0.86
The hemophore HasA from Yersinia pestis (HasAyp) coordinates hemin with a single residue, Tyr75, and with minimal conformational change. Biochemistry (2013) 0.86
Heme/Cu/O2 reactivity: change in FeIII-(O2 2-)-CuII unit peroxo binding geometry effected by tridentate copper chelation. J Am Chem Soc (2004) 0.86