Published in Nat Chem on May 30, 2010
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Reactivity of dioxygen-copper systems. Chem Rev (2004) 3.34
Switching off hydrogen peroxide hydrogenation in the direct synthesis process. Science (2009) 1.49
A stable silicon(0) compound with a Si=Si double bond. Science (2008) 1.39
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Geometric and electronic structure and reactivity of a mononuclear "side-on" nickel(III)-peroxo complex. Nat Chem (2009) 1.19
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N-heterocyclic carbene (NHC)-stabilized silanechalcogenones: NHC-->Si(R2)=E (E=O, S, Se, Te). Chemistry (2010) 0.83
Si=X multiple bonding with four-coordinate silicon? Insights into the nature of the Si=O and Si=S double bonds in stable silanoic esters and related thioesters: a combined NMR spectroscopic and computational study. J Am Chem Soc (2010) 0.80
From a stable silylene to a mixed-valent disiloxane and an isolable silaformamide-borane complex with considerable silicon-oxygen double-bond character. Angew Chem Int Ed Engl (2007) 0.80
An isolable silanoic ester by oxygenation of a stable silylene. J Am Chem Soc (2007) 0.79
A new type of N-heterocyclic silylene with ambivalent reactivity. J Am Chem Soc (2006) 0.79
Time-resolved gas-phase kinetic and quantum chemical studies of the reaction of silylene with oxygen. Phys Chem Chem Phys (2005) 0.79
Chemistry. Enhanced: a view of unusual peroxides. Science (2003) 0.78
Magnetic multicore nanoparticles for hyperthermia--influence of particle immobilization in tumour tissue on magnetic properties. Nanotechnology (2011) 1.49
Identification of the hemangioblast in postnatal life. Blood (2002) 1.42
Metal-free activation of EH3 (E = P, As) by an ylide-like silylene and formation of a donor-stabilized arsasilene with a HSi=AsH subunit. Angew Chem Int Ed Engl (2010) 1.39
Structure of the nucleotide radical formed during reaction of CDP/TTP with the E441Q-alpha2beta2 of E. coli ribonucleotide reductase. J Am Chem Soc (2009) 1.32
N-heterocyclic carbene analogues with low-valent group 13 and group 14 elements: syntheses, structures, and reactivities of a new generation of multitalented ligands. Chem Rev (2010) 1.31
Induction and analysis of aggregates in a liquid IgG1-antibody formulation. Eur J Pharm Biopharm (2005) 1.20
An isolable NHC-supported silanone. J Am Chem Soc (2009) 1.02
Structure of the nitrogen-centered radical formed during inactivation of E. coli ribonucleotide reductase by 2'-azido-2'-deoxyuridine-5'-diphosphate: trapping of the 3'-ketonucleotide. J Am Chem Soc (2005) 0.99
13C NMR study of halogen bonding of haloarenes: measurements of solvent effects and theoretical analysis. J Am Chem Soc (2004) 0.97
Formation and characterization of the iridium tetroxide molecule with iridium in the oxidation state +VIII. Angew Chem Int Ed Engl (2009) 0.95
A "side-on" superoxonickel complex [LNi(O2)] with a square-planar tetracoordinate nickel(II) center and its conversion into [LNi(mu-OH)2NiL]. Angew Chem Int Ed Engl (2008) 0.95
From NHC-->germylenes to stable NHC-->germanone complexes. Chem Commun (Camb) (2009) 0.93
Exciton trapping in pi-conjugated materials: a quantum-chemistry-based protocol applied to perylene bisimide dye aggregates. J Am Chem Soc (2008) 0.92
Lessons from isolable nickel(I) precursor complexes for small molecule activation. Acc Chem Res (2011) 0.91
Copper-catalyzed intermolecular amidation and imidation of unactivated alkanes. J Am Chem Soc (2014) 0.91
Unification of catalytic water oxidation and oxygen reduction reactions: amorphous beat crystalline cobalt iron oxides. J Am Chem Soc (2014) 0.91
O-O bond activation in heterobimetallic peroxides: synthesis of the peroxide [LNi(mu,eta2:eta2-O2)K] and its conversion into a bis(mu-hydroxo) nickel zinc complex. Angew Chem Int Ed Engl (2009) 0.90
Characteristic spin-orbit induced 1H(CH2) chemical shifts upon deprotonation of group 9 polyamine aqua and alcohol complexes. J Am Chem Soc (2009) 0.89
Mercury is a transition metal: the first experimental evidence for HgF(4). Angew Chem Int Ed Engl (2007) 0.88
[Pb5{Mo(CO)3}2]4-: a complex containing a planar Pb5 unit. Angew Chem Int Ed Engl (2005) 0.88
Reversible P(4) activation with nickel(I) and an eta(3)-coordinated tetraphosphorus ligand between two Ni(I) centers. Chemistry (2010) 0.88
Active mixed-valent MnO(x) water oxidation catalysts through partial oxidation (corrosion) of nanostructured MnO particles. Angew Chem Int Ed Engl (2013) 0.88
Reductive cleavage of P4 by iron(I) centres: synthesis and structural characterisation of Fe2(P2)2 complexes with two bridging P2(2-) ligands. Chem Commun (Camb) (2015) 0.87
Pushing the σ-donor strength in iridium pincer complexes: bis(silylene) and bis(germylene) ligands are stronger donors than bis(phosphorus(III)) ligands. Angew Chem Int Ed Engl (2012) 0.87
Iridium-catalyzed regioselective silylation of secondary alkyl C-H bonds for the synthesis of 1,3-diols. J Am Chem Soc (2014) 0.86
Synthesis and bonding in carbene complexes of an unsymmetrical dilithio methandiide: a combined experimental and theoretical study. Chemistry (2013) 0.86
Hydride binding to the active site of [FeFe]-hydrogenase. Inorg Chem (2014) 0.85
Heterogeneous water oxidation: surface activity versus amorphization activation in cobalt phosphate catalysts. Angew Chem Int Ed Engl (2015) 0.85
Density functional study of EPR parameters and spin-density distribution of azurin and other blue copper proteins. J Phys Chem B (2007) 0.85
A thermochemically competitive local hybrid functional without gradient corrections. J Chem Phys (2007) 0.85
Fibroblast growth factor 3, a protein with a dual subcellular fate, is interacting with human ribosomal protein S2. Biochem Biophys Res Commun (2005) 0.85
Protein-cofactor interactions and EPR parameters for the Q(H) quinone binding site of quinol oxidase. A density functional study. J Am Chem Soc (2006) 0.85
A high-valent heterobimetallic [Cu(III)(μ-O)2Ni(III)]2+ core with nucleophilic oxo groups. Angew Chem Int Ed Engl (2013) 0.85
A reliable quantum-chemical protocol for the characterization of organic mixed-valence compounds. J Am Chem Soc (2009) 0.84
The significance of vasodilator-stimulated phosphoprotein for risk stratification of stent thrombosis. Thromb Haemost (2007) 0.84
Silicon analogues of the RXR-selective retinoid agonist SR11237 (BMS649): chemistry and biology. ChemMedChem (2009) 0.83
A low-temperature molecular approach to highly conductive tin-rich indium tin oxide thin films with durable electro-optical performance. Angew Chem Int Ed Engl (2009) 0.83
N-heterocyclic carbene (NHC)-stabilized silanechalcogenones: NHC-->Si(R2)=E (E=O, S, Se, Te). Chemistry (2010) 0.83
Formation of a donor-stabilized tetrasilacyclobutadiene dication by a Lewis acid assisted reaction of an N-heterocyclic chloro silylene. J Am Chem Soc (2011) 0.82
Phosphorus chemical shifts in a nucleic acid backbone from combined molecular dynamics and density functional calculations. J Am Chem Soc (2010) 0.82
Elucidating mechanisms in haem copper oxidases: the high-affinity QH binding site in quinol oxidase as studied by DONUT-HYSCORE spectroscopy and density functional theory. Faraday Discuss (2011) 0.82
A molecular approach to self-supported cobalt-substituted ZnO materials as remarkably stable electrocatalysts for water oxidation. Angew Chem Int Ed Engl (2014) 0.82
Refining the interpretation of near-infrared band shapes in a polyynediyl molecular wire. Chemistry (2013) 0.82
What can we learn from the adiabatic connection formalism about local hybrid functionals? J Chem Phys (2008) 0.82
On the self-consistent implementation of general occupied-orbital dependent exchange-correlation functionals with application to the B05 functional. J Chem Phys (2009) 0.82
On the role of oxygen defects in the catalytic performance of zinc oxide. Angew Chem Int Ed Engl (2006) 0.81
Mixed-valence ruthenium complexes rotating through a conformational Robin-Day continuum. Chemistry (2014) 0.81
New vistas in N-heterocyclic silylene (NHSi) transition-metal coordination chemistry: syntheses, structures and reactivity towards activation of small molecules. Chemistry (2012) 0.81
An N-heterocyclic carbene-disilyne complex and its reactivity toward ZnCl2. J Am Chem Soc (2010) 0.81
Impact of molecular flexibility on binding strength and self-sorting of chiral π-surfaces. J Am Chem Soc (2011) 0.81
A neutral tetraphosphacyclobutadiene ligand in cobalt(I) complexes. Angew Chem Int Ed Engl (2014) 0.81
Computational studies of EPR parameters for paramagnetic molybdenum complexes. II. Larger MoV systems relevant to molybdenum enzymes. Inorg Chem (2007) 0.81
A fully relativistic method for calculation of nuclear magnetic shielding tensors with a restricted magnetically balanced basis in the framework of the matrix Dirac-Kohn-Sham equation. J Chem Phys (2008) 0.81
From a stable silylene to a mixed-valent disiloxane and an isolable silaformamide-borane complex with considerable silicon-oxygen double-bond character. Angew Chem Int Ed Engl (2007) 0.80
Molecular mechanical devices based on quinone-pyrrole and quinone-indole dyads: a computational study. J Phys Chem B (2006) 0.80
Monooxygenase-like reactivity of an unprecedented heterobimetallic {FeO2Ni} moiety. Angew Chem Int Ed Engl (2010) 0.80
Si=X multiple bonding with four-coordinate silicon? Insights into the nature of the Si=O and Si=S double bonds in stable silanoic esters and related thioesters: a combined NMR spectroscopic and computational study. J Am Chem Soc (2010) 0.80
Treatment with Cyclophosphamide for steroid-resistant nephrotic syndrome in children. Maedica (Buchar) (2010) 0.80
Bis(silylenyl)- and bis(germylenyl)-substituted ferrocenes: synthesis, structure, and catalytic applications of bidentate silicon(II)-cobalt complexes. Angew Chem Int Ed Engl (2012) 0.79
Lithium-promoted hydrogenation of carbon dioxide to formates by heterobimetallic hydridozinc alkoxide clusters. Chem Commun (Camb) (2008) 0.79
Insight into the mechanism of carbonyl hydrosilylation catalyzed by Brookhart's cationic iridium(III) pincer complex. J Am Chem Soc (2014) 0.79
Facile access to silicon-functionalized bis-silylene titanium(II) complexes. Chemistry (2012) 0.79
A fragile zwitterionic phosphasilene as a transfer agent of the elusive parent phosphinidene (:PH). J Am Chem Soc (2013) 0.79
Iridium-catalyzed regioselective silylation of aromatic and benzylic C-H bonds directed by a secondary amine. Angew Chem Int Ed Engl (2014) 0.79
A new type of N-heterocyclic silylene with ambivalent reactivity. J Am Chem Soc (2006) 0.79
Synthesis and structure of a ferrocenylboron dication. Inorg Chem (2008) 0.79
Cobalt-manganese-based spinels as multifunctional materials that unify catalytic water oxidation and oxygen reduction reactions. ChemSusChem (2014) 0.79
Steering S-H and N-H bond activation by a stable n-heterocyclic silylene: different addition of H(2)S, NH(3), and organoamines on a silicon(II) ligand versus its Si(II)-->Ni(CO)(3) complex. J Am Chem Soc (2010) 0.79
An isolable silanoic ester by oxygenation of a stable silylene. J Am Chem Soc (2007) 0.79
A heterofulvene-like germylene with a betain reactivity. Angew Chem Int Ed Engl (2006) 0.79
Consecutive insertion of a silylene into the P4 tetrahedron: facile access to strained SiP4 and Si2P4 cage compounds. Angew Chem Int Ed Engl (2007) 0.79
A donor-stabilized zwitterionic "half-parent" phosphasilene and its unusual reactivity towards small molecules. Chemistry (2014) 0.78
Carboalumination of a chromium–chromium quintuple bond. Nat Chem (2009) 0.78
Chemical vapor synthesis of size-selected zinc oxide nanoparticles. Small (2005) 0.78
Synthesis, structure, and reactivity of a pyridine-stabilized germanone. Chemistry (2011) 0.78
Predicting the localized/delocalized character of mixed-valence diquinone radical anions. Toward the right answer for the right reason. J Phys Chem A (2012) 0.78
Importance of the correlation contribution for local hybrid functionals: range separation and self-interaction corrections. J Chem Phys (2012) 0.78
Unprecedented silicon(II)→calcium complexes with N-heterocyclic silylenes. Dalton Trans (2015) 0.78
High-valent technetium fluorides. Does TcF7 exist? Inorg Chem (2007) 0.78
Squaraine dyes as efficient coupling bridges between triarylamine redox centres. Chemistry (2011) 0.78
Jacobsen's catalyst for hydrolytic kinetic resolution: structure elucidation of paramagnetic Co(III) salen complexes in solution via combined NMR and quantum chemical studies. J Am Chem Soc (2009) 0.78
Copper-catalyzed oxidative dehydrogenative carboxylation of unactivated alkanes to allylic esters via alkenes. J Am Chem Soc (2014) 0.78
From local hybrid functionals to "localized local hybrid" potentials: formalism and thermochemical tests. J Chem Phys (2006) 0.78
A trimetallic gold boride complex with a fluxional gold-boron bond. Angew Chem Int Ed Engl (2009) 0.78
Understanding the electon paramagnetic resonance parameters of protein-bound glycyl radicals. J Phys Chem B (2007) 0.78
Redox-dependent structural transformations of the [4Fe-3S] proximal cluster in O2-tolerant membrane-bound [NiFe]-hydrogenase: a DFT study. J Am Chem Soc (2013) 0.78
Synthesis and unexpected coordination of a silicon(II)-based SiCSi pincerlike arene to palladium. Angew Chem Int Ed Engl (2012) 0.78
An isolable bis-silylene oxide ("disilylenoxane") and its metal coordination. J Am Chem Soc (2010) 0.78
An ylide-like phosphasilene and striking formation of a 4π-electron, resonance-stabilized 2,4-disila-1,3-diphosphacyclobutadiene. J Am Chem Soc (2011) 0.78
A series of isolable silanoic thio-, seleno-, and telluroesters (LSi(=X)OR) with donor-supported Si=X double bonds (L = beta-diketiminate; X = S, Se, Te). Chem Asian J (2008) 0.77