Published in Angew Chem Int Ed Engl on January 01, 2007
Attenuated Organomagnesium Activation of White Phosphorus. Angew Chem Int Ed Engl (2015) 0.77
The chemistry of cationic polyphosphorus cages--syntheses, structure and reactivity. Chem Soc Rev (2014) 0.75
Metal-free activation of EH3 (E = P, As) by an ylide-like silylene and formation of a donor-stabilized arsasilene with a HSi=AsH subunit. Angew Chem Int Ed Engl (2010) 1.39
N-heterocyclic carbene analogues with low-valent group 13 and group 14 elements: syntheses, structures, and reactivities of a new generation of multitalented ligands. Chem Rev (2010) 1.31
An isolable NHC-supported silanone. J Am Chem Soc (2009) 1.02
A "side-on" superoxonickel complex [LNi(O2)] with a square-planar tetracoordinate nickel(II) center and its conversion into [LNi(mu-OH)2NiL]. Angew Chem Int Ed Engl (2008) 0.95
From NHC-->germylenes to stable NHC-->germanone complexes. Chem Commun (Camb) (2009) 0.93
Lessons from isolable nickel(I) precursor complexes for small molecule activation. Acc Chem Res (2011) 0.91
Copper-catalyzed intermolecular amidation and imidation of unactivated alkanes. J Am Chem Soc (2014) 0.91
Unification of catalytic water oxidation and oxygen reduction reactions: amorphous beat crystalline cobalt iron oxides. J Am Chem Soc (2014) 0.91
O-O bond activation in heterobimetallic peroxides: synthesis of the peroxide [LNi(mu,eta2:eta2-O2)K] and its conversion into a bis(mu-hydroxo) nickel zinc complex. Angew Chem Int Ed Engl (2009) 0.90
Reversible P(4) activation with nickel(I) and an eta(3)-coordinated tetraphosphorus ligand between two Ni(I) centers. Chemistry (2010) 0.88
Active mixed-valent MnO(x) water oxidation catalysts through partial oxidation (corrosion) of nanostructured MnO particles. Angew Chem Int Ed Engl (2013) 0.88
Reductive cleavage of P4 by iron(I) centres: synthesis and structural characterisation of Fe2(P2)2 complexes with two bridging P2(2-) ligands. Chem Commun (Camb) (2015) 0.87
Pushing the σ-donor strength in iridium pincer complexes: bis(silylene) and bis(germylene) ligands are stronger donors than bis(phosphorus(III)) ligands. Angew Chem Int Ed Engl (2012) 0.87
Iridium-catalyzed regioselective silylation of secondary alkyl C-H bonds for the synthesis of 1,3-diols. J Am Chem Soc (2014) 0.86
Hydride binding to the active site of [FeFe]-hydrogenase. Inorg Chem (2014) 0.85
Heterogeneous water oxidation: surface activity versus amorphization activation in cobalt phosphate catalysts. Angew Chem Int Ed Engl (2015) 0.85
A high-valent heterobimetallic [Cu(III)(μ-O)2Ni(III)]2+ core with nucleophilic oxo groups. Angew Chem Int Ed Engl (2013) 0.85
A low-temperature molecular approach to highly conductive tin-rich indium tin oxide thin films with durable electro-optical performance. Angew Chem Int Ed Engl (2009) 0.83
N-heterocyclic carbene (NHC)-stabilized silanechalcogenones: NHC-->Si(R2)=E (E=O, S, Se, Te). Chemistry (2010) 0.83
Formation of a donor-stabilized tetrasilacyclobutadiene dication by a Lewis acid assisted reaction of an N-heterocyclic chloro silylene. J Am Chem Soc (2011) 0.82
From silicon(II)-based dioxygen activation to adducts of elusive dioxasiliranes and sila-ureas stable at room temperature. Nat Chem (2010) 0.82
A molecular approach to self-supported cobalt-substituted ZnO materials as remarkably stable electrocatalysts for water oxidation. Angew Chem Int Ed Engl (2014) 0.82
On the role of oxygen defects in the catalytic performance of zinc oxide. Angew Chem Int Ed Engl (2006) 0.81
New vistas in N-heterocyclic silylene (NHSi) transition-metal coordination chemistry: syntheses, structures and reactivity towards activation of small molecules. Chemistry (2012) 0.81
A neutral tetraphosphacyclobutadiene ligand in cobalt(I) complexes. Angew Chem Int Ed Engl (2014) 0.81
An N-heterocyclic carbene-disilyne complex and its reactivity toward ZnCl2. J Am Chem Soc (2010) 0.81
From a stable silylene to a mixed-valent disiloxane and an isolable silaformamide-borane complex with considerable silicon-oxygen double-bond character. Angew Chem Int Ed Engl (2007) 0.80
Monooxygenase-like reactivity of an unprecedented heterobimetallic {FeO2Ni} moiety. Angew Chem Int Ed Engl (2010) 0.80
Si=X multiple bonding with four-coordinate silicon? Insights into the nature of the Si=O and Si=S double bonds in stable silanoic esters and related thioesters: a combined NMR spectroscopic and computational study. J Am Chem Soc (2010) 0.80
Bis(silylenyl)- and bis(germylenyl)-substituted ferrocenes: synthesis, structure, and catalytic applications of bidentate silicon(II)-cobalt complexes. Angew Chem Int Ed Engl (2012) 0.79
Lithium-promoted hydrogenation of carbon dioxide to formates by heterobimetallic hydridozinc alkoxide clusters. Chem Commun (Camb) (2008) 0.79
Cobalt-manganese-based spinels as multifunctional materials that unify catalytic water oxidation and oxygen reduction reactions. ChemSusChem (2014) 0.79
Facile access to silicon-functionalized bis-silylene titanium(II) complexes. Chemistry (2012) 0.79
Steering S-H and N-H bond activation by a stable n-heterocyclic silylene: different addition of H(2)S, NH(3), and organoamines on a silicon(II) ligand versus its Si(II)-->Ni(CO)(3) complex. J Am Chem Soc (2010) 0.79
Synthesis of a "half"-parent phosphasilene R2Si=PH and its metalation to the corresponding P-zinciophosphasilene [R2Si=PM]. Angew Chem Int Ed Engl (2006) 0.79
A new type of N-heterocyclic silylene with ambivalent reactivity. J Am Chem Soc (2006) 0.79
A fragile zwitterionic phosphasilene as a transfer agent of the elusive parent phosphinidene (:PH). J Am Chem Soc (2013) 0.79
An isolable silanoic ester by oxygenation of a stable silylene. J Am Chem Soc (2007) 0.79
A heterofulvene-like germylene with a betain reactivity. Angew Chem Int Ed Engl (2006) 0.79
Iridium-catalyzed regioselective silylation of aromatic and benzylic C-H bonds directed by a secondary amine. Angew Chem Int Ed Engl (2014) 0.79
Unprecedented silicon(II)→calcium complexes with N-heterocyclic silylenes. Dalton Trans (2015) 0.78
A donor-stabilized zwitterionic "half-parent" phosphasilene and its unusual reactivity towards small molecules. Chemistry (2014) 0.78
Synthesis, structure, and reactivity of a pyridine-stabilized germanone. Chemistry (2011) 0.78
Copper-catalyzed oxidative dehydrogenative carboxylation of unactivated alkanes to allylic esters via alkenes. J Am Chem Soc (2014) 0.78
Chemical vapor synthesis of size-selected zinc oxide nanoparticles. Small (2005) 0.78
Synthesis and unexpected coordination of a silicon(II)-based SiCSi pincerlike arene to palladium. Angew Chem Int Ed Engl (2012) 0.78
An isolable bis-silylene oxide ("disilylenoxane") and its metal coordination. J Am Chem Soc (2010) 0.78
An ylide-like phosphasilene and striking formation of a 4π-electron, resonance-stabilized 2,4-disila-1,3-diphosphacyclobutadiene. J Am Chem Soc (2011) 0.78
A series of isolable silanoic thio-, seleno-, and telluroesters (LSi(=X)OR) with donor-supported Si=X double bonds (L = beta-diketiminate; X = S, Se, Te). Chem Asian J (2008) 0.77
Synthesis of mixed silylene-carbene chelate ligands from N-heterocyclic silylcarbenes mediated by nickel. Angew Chem Int Ed Engl (2014) 0.77
Unprecedented alkylzinc-magnesium alkoxide clusters as suitable organometallic precursors for magnesium-containing ZnO nanoparticles. Chemistry (2011) 0.77
Dioxygenase-like reactivity of an isolable superoxo-nickel(II) complex. Chemistry (2010) 0.77
Using nickel manganese oxide catalysts for efficient water oxidation. Chem Commun (Camb) (2015) 0.77
Molecular encoding at the nanoscale: from complex cubes to bimetallic oxides. Angew Chem Int Ed Engl (2005) 0.77
Aromatic ylide-stabilized carbocyclic silylene. Angew Chem Int Ed Engl (2011) 0.76
The striking stabilization of Ni0(eta6-arene) complexes by an ylide-like silylene ligand. Angew Chem Int Ed Engl (2009) 0.76
Main group chemistry: Breaking the limits with silylenes. Nat Chem (2012) 0.76
Formation of N-heterocyclic, donor-stabilized borenium ions. Chem Commun (Camb) (2011) 0.76
From a paramagnetic, mononuclear supersulfidonickel(II) complex to a diamagnetic dimer with a four-sulfur two-electron bond. J Am Chem Soc (2008) 0.76
Low-valent silicon cations with two-coordinate silicon and aromatic character. Angew Chem Int Ed Engl (2006) 0.75
A cyclic germadicarbene ("germylone") from germyliumylidene. J Am Chem Soc (2013) 0.75
Synthesis and unexpected reactivity of germyliumylidene hydride [:GeH]+ stabilized by a bis(N-heterocyclic carbene)borate ligand. J Am Chem Soc (2014) 0.75
Taming the germyliumylidene [CIGe:]+ and germathionium [CIGe=S]+ ions by donor-acceptor stabilization using 1,8-bis(tributylphosphazenyl)naphthalene. Chem Commun (Camb) (2012) 0.75
A cyclic silylone ("siladicarbene") with an electron-rich silicon(0) atom. Angew Chem Int Ed Engl (2013) 0.75
The elusive silyliumylidene [ClSi:]+ and silathionium [ClSi=S]+ cations stabilized by bis(iminophosphorane) chelate ligand. Angew Chem Int Ed Engl (2012) 0.75
A new type of heteroleptic complex of divalent lead and synthesis of the P-plumbyleniophosphasilene, R2Si=P-Pb(L): (L = beta-diketiminate). Chem Commun (Camb) (2007) 0.75
Twice silicon-induced C-H activation and tautomerisation of a beta-diketiminato ligand and formation of new types of N-heterocyclic silanes. Dalton Trans (2008) 0.75
One-pot synthesis of lithium alkylzinc alkoxo heterocubanes with a LiZn3O4 core as suitable organometallic precursors for Li-containing ZnO nanocrystals. Dalton Trans (2009) 0.75
Side-on coordination of a P-P bond in heterobinuclear tetraphosphorus complexes with a [Si(mu,eta(2:2)-P(4))Ni] core and nickel(I) centers. Inorg Chem (2009) 0.75
Facile dissociation of [(LNi(II))2E2] dichalcogenides: evidence for [LNi(II)E2] superselenides and supertellurides in solution. Angew Chem Int Ed Engl (2009) 0.75
Consecutive fragmentations of the cubane-like zinc cluster [CH3Zn(O-i-C3H7)]4 upon electron ionization. Phys Chem Chem Phys (2005) 0.75
A cyclopentadienide analogue containing divalent germanium and a heavy cyclobutadiene-like dianion with an unusual Ge4 core. J Am Chem Soc (2008) 0.75
A zwitterionic silylene as reactive intermediate and its unusual dimerization to an N-heterobicyclic disilane. Chem Asian J (2009) 0.75
Dichotomic reactivity of a stable silylene toward terminal alkynes: facile C-H bond insertion versus autocatalytic formation of silacycloprop-3-ene. Angew Chem Int Ed Engl (2008) 0.75
Diketiminate silicon(II) and related NHSi ligands generated in the coordination sphere of nickel(0). J Am Chem Soc (2009) 0.75
Versatile conversion of N-heterocyclic silylene to silyl metal compounds by insertion of divalent silicon into metal-carbon and metal-hydrogen bonds. Chemistry (2012) 0.75
An unsymmetric substituted digermylene with a Ge(I)-Ge(I) bond and synthesis of a germylene-stannylene with a Ge(I)-Sn(I) bond. Chem Commun (Camb) (2009) 0.75
Versatile reactivity of a zwitterionic isolable silylene toward ketones: silicon-mediated, regio- and stereoselective C-H activation. Chemistry (2009) 0.75
Bridging the materials gap in catalysis: entrapment of molecular catalysts in functional supports and beyond. Angew Chem Int Ed Engl (2009) 0.75
Striking reactivity of a stable, zwitterionic silylene towards substituted diazomethanes, azides, and isocyanides. Chemistry (2009) 0.75
First preparation of nanocrystalline zinc silicate by chemical vapor synthesis using an organometallic single-source precursor. Chemistry (2004) 0.75
Striking reactivity of ylide-like germylene toward terminal alkynes: [4+2] cycloaddition versus C-H bond activation. Chem Commun (Camb) (2008) 0.75