Published in Polyhedron on July 13, 2013
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A homogeneous catalyst for selective O(2) oxidation at ambient temperature. diversity-based discovery and mechanistic investigation of thioether oxidation by the Au(III)Cl(2)NO(3)(thioether)/O(2) system. J Am Chem Soc (2001) 0.81
Iron-catalyzed asymmetric sulfide oxidation with aqueous hydrogen peroxide. Angew Chem Int Ed Engl (2003) 0.80
Spectroscopic characterization of the active Fe(III)Fe(III) and Fe(III)Fe(II) forms of a purple acid phosphatase model system. Inorg Chem (2012) 0.80
Reaction of singlet oxygen with thioanisole in ionic liquids: a solvent induced mechanistic dichotomy. Org Lett (2009) 0.77
Mechanism of the selective sulfide oxidation promoted by HNO(3)/FeBr(3). J Org Chem (2009) 0.76
Role of intermolecular interactions in oxygen transfer catalyzed by silsesquioxane trisilanolate vanadium(V). Inorg Chem (2009) 0.76
Preparation of aluminum(III) (bis(amido)pyridine)(thiolate) complexes: unexpected transmetalation mediated by LiAlH(4). Inorganica Chim Acta (2012) 0.76
Ultra-deep desulfurization of diesel: oxidation with a recoverable catalyst assembled in emulsion. Chemistry (2004) 0.76
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Catalysis of oxo transfer to prochiral sulfides by oxovanadium(v) compounds that model the active center of haloperoxidases. Chemistry (2003) 0.76
The first example of direct oxidation of sulfides to sulfones by an osmate molecular oxygen system. Chem Commun (Camb) (2003) 0.76
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Bio-social origins of depression in the community. Interactions between social adversity, cortisol and serotonin neurotransmission. Br J Psychiatry (2002) 3.18
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Unprecedented rate enhancements of hydrogen-atom transfer to a manganese(V)-oxo corrolazine complex. Angew Chem Int Ed Engl (2010) 1.29
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Octalkoxy-substituted phosphorus(V) triazatetrabenzcorroles via ring contraction of phthalocyanine precursors. Inorg Chem (2003) 1.00
A low-spin alkylperoxo-iron(III) complex with weak Fe-O and O-O bonds: implications for the mechanism of superoxide reductase. J Am Chem Soc (2006) 0.99
Rational tuning of the thiolate donor in model complexes of superoxide reductase: direct evidence for a trans influence in Fe(III)-OOR complexes. J Am Chem Soc (2008) 0.99
Discovery of the aggregation pheromone of the brown marmorated stink bug (Halyomorpha halys) through the creation of stereoisomeric libraries of 1-bisabolen-3-ols. J Nat Prod (2014) 0.99
Influence of the nitrogen donors on nonheme iron models of superoxide reductase: high-spin Fe(III)-OOR complexes. J Am Chem Soc (2010) 0.98
Copper(I)/O2 chemistry with imidazole containing tripodal tetradentate ligands leading to mu-1,2-peroxo-dicopper(II) species. Inorg Chem (2009) 0.96
O2 activation by bis(imino)pyridine iron(II)-thiolate complexes. J Am Chem Soc (2011) 0.95
A single, low, oral dose of a 5-carbon-linked trioxane dimer orthoester plus mefloquine cures malaria-infected mice. Bioorg Med Chem Lett (2010) 0.95
Iron(II)-thiolate S-oxygenation by O2: synthetic models of cysteine dioxygenase. J Am Chem Soc (2010) 0.94
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Dramatic influence of an anionic donor on the oxygen-atom transfer reactivity of a Mn(V) -oxo complex. Chemistry (2014) 0.92
Coordination chemistry and reactivity of a cupric hydroperoxide species featuring a proximal H-bonding substituent. Inorg Chem (2012) 0.92
Activation of a high-valent manganese-oxo complex by a nonmetallic Lewis acid. Inorg Chem (2014) 0.92
Chromium(IV)-peroxo complex formation and its nitric oxide dioxygenase reactivity. J Am Chem Soc (2012) 0.92
Characterization of the first N2S(alkylthiolate)lead compound: a model for three-coordinate lead in biological systems. Inorg Chem (2006) 0.91
Catalyst selection based on intermediate stability measured by mass spectrometry. Nat Chem (2010) 0.91
Mechanism of S-oxygenation by a cysteine dioxygenase model complex. J Phys Chem A (2011) 0.90
A new bis(imidazolyl)(alkylthiolate) tripodal ligand and the spontaneous formation of a disulfide-linked, hydroxo-bridged dinuclear zinc complex. Chem Commun (Camb) (2002) 0.90
A N3S(thioether)-ligated Cu(II)-superoxo with enhanced reactivity. J Am Chem Soc (2015) 0.89
Dramatically accelerated selective oxygen-atom transfer by a nonheme iron(IV)-oxo complex: tuning of the first and second coordination spheres. J Am Chem Soc (2014) 0.89
Oxygen-atom transfer reactivity of axially ligated Mn(V)-oxo complexes: evidence for enhanced electrophilic and nucleophilic pathways. J Am Chem Soc (2014) 0.89
Secondary coordination sphere influence on the reactivity of nonheme iron(II) complexes: an experimental and DFT approach. J Am Chem Soc (2013) 0.89
Addition of dioxygen to an N4S(thiolate) iron(II) cysteine dioxygenase model gives a structurally characterized sulfinato-iron(II) complex. J Am Chem Soc (2012) 0.89
N-acetylmethionine and biotin as photocleavable protective groups for ruthenium polypyridyl complexes. Chemistry (2011) 0.89
High-valent transition metal corrolazines. J Inorg Biochem (2006) 0.88
Identification of depression by medical and surgical general hospital physicians. Gen Hosp Psychiatry (2002) 0.88
Stepwise protonation and electron-transfer reduction of a primary copper-dioxygen adduct. J Am Chem Soc (2013) 0.87
Catalytic sulfoxidation and epoxidation with a Mn(III) triazacorrole: evidence for a "third oxidant" in high-valent porphyrinoid oxidations. J Am Chem Soc (2004) 0.87
Sulfur oxygenation in biomimetic non-heme iron-thiolate complexes. Dalton Trans (2012) 0.86
Generation of an isolable, monomeric manganese(V)-oxo complex from O2 and visible light. J Am Chem Soc (2012) 0.86
Amine oxidative N-dealkylation via cupric hydroperoxide Cu-OOH homolytic cleavage followed by site-specific fenton chemistry. J Am Chem Soc (2015) 0.85
Tuning of the copper-thioether bond in tetradentate N₃S(thioether) ligands; O-O bond reductive cleavage via a [Cu(II)₂(μ-1,2-peroxo)]²⁺/[Cu(III)₂(μ-oxo)₂]²⁺ equilibrium. J Am Chem Soc (2014) 0.85
A high-valent iron-oxo corrolazine activates C-H bonds via hydrogen-atom transfer. J Am Chem Soc (2012) 0.85
Synthesis and antimalarial efficacy of two-carbon-linked, artemisinin-derived trioxane dimers in combination with known antimalarial drugs. J Med Chem (2013) 0.85
Base-free production of H2 by dehydrogenation of formic acid using an iridium-bisMETAMORPhos complex. Chemistry (2013) 0.85
Photochemical oxidation of a manganese(III) complex with oxygen and toluene derivatives to form a manganese(V)-oxo complex. Inorg Chem (2013) 0.85
IPr* an easily accessible highly hindered N-heterocyclic carbene. Dalton Trans (2009) 0.85
Heme/copper assembly mediated nitrite and nitric oxide interconversion. J Am Chem Soc (2012) 0.84
Copper(III) and vanadium(IV)-oxo corrolazines. Inorg Chem (2004) 0.84
Preparation of non-heme {FeNO}7 models of cysteine dioxygenase: sulfur versus nitrogen ligation and photorelease of nitric oxide. J Am Chem Soc (2013) 0.84
Spontaneous formation in the dark, and visible light-induced cleavage, of a Ru-S bond in water: a thermodynamic and kinetic study. Inorg Chem (2013) 0.83
Generation of a high-valent iron imido corrolazine complex and NR group transfer reactivity. Inorg Chem (2013) 0.83
Hydrolysis of 4-nitrophenyl acetate by a (N2S(thiolate))zinc hydroxide complex: a model of the catalytically active intermediate for the zinc form of peptide deformylase. Inorg Chem (2003) 0.82
Evidence for the formation of a mononuclear ferric-hydroperoxo complex via the reaction of dioxygen with an (N4S(thiolate))iron(II) complex. Chem Commun (Camb) (2009) 0.82
NH+-F hydrogen bonding in a fluorinated "proton sponge" derivative: integration of solution, solid-state, gas-phase, and computational studies. J Org Chem (2011) 0.82
X-ray absorption spectroscopy and reactivity of thiolate-ligated Fe(III)-OOR complexes. Inorg Chem (2010) 0.82
Photocatalytic oxygenation of 10-methyl-9,10-dihydroacridine by O₂ with manganese porphyrins. J Phys Chem A (2014) 0.81
Axial and equatorial ligand effects on biomimetic cysteine dioxygenase model complexes. Org Biomol Chem (2012) 0.81
Direct, catalytic monofluorination of sp³ C-H bonds: a radical-based mechanism with ionic selectivity. J Am Chem Soc (2014) 0.80
Inverse axial-ligand effects in the activation of H(2)O(2) and ROOH by an Mn(III) corrolazine. Angew Chem Int Ed Engl (2006) 0.80
Ruthenium polypyridyl complexes hopping at anionic lipid bilayers through a supramolecular bond sensitive to visible light. Chemistry (2012) 0.80
Development of N-substituted hydroxylamines as efficient nitroxyl (HNO) donors. J Am Chem Soc (2012) 0.80
Synthesis, structures, and properties of a series of four-, five-, and six-coordinate cobalt(III) triazacorrole complexes: the first examples of transition metal corrolazines. Inorg Chem (2002) 0.79
Nitric oxide generation from heme/copper assembly mediated nitrite reductase activity. J Biol Inorg Chem (2014) 0.79
Catalytic reactivity of a meso-N-substituted corrole and evidence for a high-valent iron-oxo species. J Am Chem Soc (2009) 0.79
Determination of the stereochemistry of the aggregation pheromone of harlequin bug, Murgantia histrionica. J Chem Ecol (2014) 0.79
Redox-active ligand-induced homolytic bond activation. Angew Chem Int Ed Engl (2014) 0.79
Geometric preferences in iron(II) and zinc(II) model complexes of peptide deformylase. Inorg Chem (2006) 0.78
A two-step spin crossover mononuclear iron(II) complex with a [HS-LS-LS] intermediate phase. Chem Commun (Camb) (2008) 0.78
α-Chloro-β,γ-ethylenic esters: enantiocontrolled synthesis and substitutions. Org Lett (2010) 0.78
Highly stereocontrolled and regiocontrolled syntheses of 2,3,4-trisubstituted alkanoates and lactones. J Org Chem (2011) 0.78
Versatile new C(3)-symmetric tripodal tetraphosphine ligands; structural flexibility to stabilize Cu(I) and Rh(I) species and tune their reactivity. Inorg Chem (2010) 0.77
H2O2 oxidations catalyzed by an iron(III) corrolazine: avoiding high-valent iron-oxido species? Angew Chem Int Ed Engl (2007) 0.77
New monomeric cobalt(II) and zinc(II) complexes of a mixed N,S(alkylthiolate) ligand: model complexes of (His)(His)(Cys) metalloprotein active sites. Inorg Chem (2002) 0.77
Preparation, size control, surface deposition, and catalytic reactivity of hydrophobic corrolazine nanoparticles in an aqueous environment. Inorg Chem (2010) 0.77
Dichlorostannylene complexes of group 10 metals, a unique bonding mode stabilized by bridging 2-pyridyldiphenylphosphine ligands. Dalton Trans (2010) 0.77
Epoxidations catalyzed by manganese(V) oxo and imido complexes: role of the oxidant-Mn-oxo (imido) intermediate. Inorg Chem (2010) 0.77
A molecular cage of nickel(II) and copper(I): a [{Ni(L)2}2(CuI)6] cluster resembling the active site of nickel-containing enzymes. Chem Commun (Camb) (2009) 0.77
Preparation of aluminum(III) (bis(amido)pyridine)(thiolate) complexes: unexpected transmetalation mediated by LiAlH(4). Inorganica Chim Acta (2012) 0.76
Synthesis of functionalizable boron-containing pi-electron materials that incorporate formally aromatic fused borepin rings. Angew Chem Int Ed Engl (2010) 0.76
An example of O2 binding in a cobalt(II) corrole system and high-valent cobalt-cyano and cobalt-alkynyl complexes. J Am Chem Soc (2004) 0.76
Peroxynitrite chemistry derived from nitric oxide reaction with a Cu(II)-OOH species and a copper mediated NO reductive coupling reaction. Chem Commun (Camb) (2013) 0.76
Direct observation of a nonheme iron(IV)-oxo complex that mediates aromatic C-F hydroxylation. J Am Chem Soc (2014) 0.76
Lewis acid-induced change from four- to two-electron reduction of dioxygen catalyzed by copper complexes using scandium triflate. J Am Chem Soc (2015) 0.76
Dinuclear palladium complexes with two ligand-centered radicals and a single bridging ligand: subtle tuning of magnetic properties. Chemistry (2015) 0.76
High-frequency and -field electron paramagnetic resonance of high-spin manganese(III) in tetrapyrrole complexes. Spectrochim Acta A Mol Biomol Spectrosc (2002) 0.76
Thiophene-fused borepins as directly functionalizable boron-containing π-electron systems. J Am Chem Soc (2014) 0.75
Meta-B-entacenes: new polycyclic aromatics incorporating two fused borepin rings. Chem Commun (Camb) (2012) 0.75
Synthesis and ligand non-innocence of thiolate-ligated (N4S) Iron(II) and nickel(II) bis(imino)pyridine complexes. Inorg Chem (2013) 0.75
Thioether-ligated iron(II) and iron(III)-hydroperoxo/alkylperoxo complexes with an H-bond donor in the second coordination sphere. Dalton Trans (2014) 0.75