Published in Angew Chem Int Ed Engl on October 21, 2014
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Spirocyclic hypervalent iodine(III)-mediated radiofluorination of non-activated and hindered aromatics. Nat Commun (2014) 1.37
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A general copper-mediated nucleophilic 18F fluorination of arenes. Angew Chem Int Ed Engl (2014) 1.14
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Palladium-catalyzed difluoroalkylation of aryl boronic acids: a new method for the synthesis of aryldifluoromethylated phosphonates and carboxylic acid derivatives. Angew Chem Int Ed Engl (2014) 0.97
One-pot synthesis of hypervalent iodine reagents for electrophilic trifluoromethylation. J Org Chem (2013) 0.97
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Catalytic decarboxylative fluorination for the synthesis of tri- and difluoromethyl arenes. Org Lett (2013) 0.93
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Regio- and stereoselective allylic trifluoromethylation and fluorination using CuCF3 and CuF reagents. J Org Chem (2013) 0.91
Silver-catalyzed oxidative activation of benzylic C-H bonds for the synthesis of difluoromethylated arenes. Angew Chem Int Ed Engl (2014) 0.90
Addition of CF3 across unsaturated moieties: a powerful functionalization tool. Chem Soc Rev (2014) 0.90
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Copper-mediated difluoromethylation of (hetero)aryl iodides and β-styryl halides with tributyl(difluoromethyl)stannane. Angew Chem Int Ed Engl (2012) 0.87
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Mechanistic investigation of the palladium-catalyzed synthesis of allylic silanes and boronates from allylic alcohols. J Am Chem Soc (2012) 0.84
A universal procedure for the [¹⁸F]trifluoromethylation of aryl iodides and aryl boronic acids with highly improved specific activity. Angew Chem Int Ed Engl (2014) 0.84
Copper-mediated C-H trifluoromethylation of quinones. Chem Commun (Camb) (2013) 0.84
Copper-mediated cyanotrifluoromethylation of styrenes using the Togni reagent. J Org Chem (2013) 0.82
1-Fluoro-3,3-dimethyl-1,3-dihydro-1λ(3)-benzo[d][1,2]iodoxole. Acta Crystallogr Sect E Struct Rep Online (2012) 0.82
Electrophilic fluorination using a hypervalent iodine reagent derived from fluoride. Chem Commun (Camb) (2013) 0.82
Mechanism of Electrophilic Fluorination with Pd(IV): Fluoride Capture and Subsequent Oxidative Fluoride Transfer(.) Chem Sci (2014) 0.81
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Palladium pincer complex catalyzed substitution of vinyl cyclopropanes, vinyl aziridines, and allyl acetates with tetrahydroxydiboron. An efficient route to functionalized allylboronic acids and potassium trifluoro(allyl)borates. J Am Chem Soc (2005) 0.96
Electrophilic trifluoromethylation by copper-catalyzed addition of CF3-transfer reagents to alkenes and alkynes. Org Lett (2012) 0.94
Catalytic allylic C-H acetoxylation and benzoyloxylation via suggested (eta(3)-allyl)palladium(IV) intermediates. Org Lett (2009) 0.94
Trifluoromethylation of propargylic halides and trifluoroacetates using (Ph3P)3Cu(CF3) reagent. Org Lett (2012) 0.91
Single-pot triple catalytic transformations based on coupling of in situ generated allyl boronates with in situ hydrolyzed acetals. Chem Commun (Camb) (2008) 0.91
Regio- and stereoselective allylic trifluoromethylation and fluorination using CuCF3 and CuF reagents. J Org Chem (2013) 0.91
Palladium-catalyzed synthesis and isolation of functionalized allylboronic acids: selective, direct allylboration of ketones. Angew Chem Int Ed Engl (2012) 0.89
Palladium-catalyzed coupling of allyl acetates with aldehyde and imine electrophiles in the presence of Bis(pinacolato)diboron. Org Lett (2003) 0.88
Palladium pincer-complex catalyzed allylation of tosylimines by potassium trifluoro(allyl)borates. Org Lett (2005) 0.88
Selective C-H borylation of alkenes by palladium pincer complex catalyzed oxidative functionalization. Angew Chem Int Ed Engl (2010) 0.88
Palladium-pincer complex catalyzed C-C coupling of allyl nitriles with tosyl imines via regioselective allylic C-H bond functionalization. Org Lett (2008) 0.87
Palladium-catalyzed direct synthesis of organoboronic acids. Angew Chem Int Ed Engl (2011) 0.85
Copper-mediated C-H trifluoromethylation of quinones. Chem Commun (Camb) (2013) 0.84
Palladium pincer complex catalyzed stannyl and silyl transfer to propargylic substrates: synthetic scope and mechanism. J Am Chem Soc (2005) 0.84
Mechanistic investigation of the palladium-catalyzed synthesis of allylic silanes and boronates from allylic alcohols. J Am Chem Soc (2012) 0.84
Selective one-pot carbon-carbon bond formation by catalytic boronation of unactivated cycloalkenes and subsequent coupling. Angew Chem Int Ed Engl (2007) 0.84
Pincer complex-catalyzed allylation of aldehyde and imine substrates via nucleophilic eta1-allyl palladium intermediates. J Am Chem Soc (2004) 0.83
Catalytic performance of symmetrical and unsymmetrical sulfur-containing pincer complexes: synthesis and tandem catalytic activity of the first PCS-pincer palladium complex. Chemistry (2008) 0.83
Stereoselective intermolecular allylic C-H trifluoroacetoxylation of functionalized alkenes. J Am Chem Soc (2012) 0.83
Copper-mediated cyanotrifluoromethylation of styrenes using the Togni reagent. J Org Chem (2013) 0.82
Synthesis and catalytic application of chiral 1,1'-Bi-2-naphthol- and biphenanthrol-based pincer complexes: selective allylation of sulfonimines with allyl stannane and allyl trifluoroborate. J Org Chem (2007) 0.82
Stereocontrol in synthesis of homoallylic amines. Syn selective direct allylation of hydrazones with allylboronic acids. Org Lett (2014) 0.81
Palladium-catalyzed allylic C-OH functionalization for efficient synthesis of functionalized allylsilanes. J Am Chem Soc (2010) 0.80
Synthesis of allylsilanes and dienylsilanes by a one-pot catalytic C-H borylation--Suzuki-Miyaura coupling sequence. Org Lett (2008) 0.79
Regio- and stereoselective palladium-pincer complex catalyzed allylation of sulfonylimines with trifluoro(allyl)borates and allylstannanes: a combined experimental and theoretical study. Chemistry (2006) 0.79
Stereoselective Pincer-complex catalyzed C-H functionalization of benzyl nitriles under mild conditions. An efficient route to beta-aminonitriles. Org Lett (2008) 0.79
Palladium pincer complex catalyzed cross-coupling of vinyl epoxides and aziridines with organoboronic acids. Chemistry (2005) 0.79
Palladium-catalyzed oxidative allylic C-H silylation. Org Lett (2011) 0.78
Pincer complex-catalyzed redox coupling of alkenes with iodonium salts via presumed palladium(IV) intermediates. Org Lett (2009) 0.78
Performance of SCS palladium pincer complexes in borylation of allylic alcohols. Control of the regioselectivity in the one-pot borylation-allylation process. J Org Chem (2009) 0.77
Synthesis and transformation of organoboronates and stannanes by pincer-complex catalysts. Dalton Trans (2009) 0.77
Regioselective palladium-catalyzed electrophilic allylic substitution in the presence of hexamethylditin. Org Lett (2002) 0.77
Palladium pincer complex-catalyzed allylic stannylation with hexaalkylditin reagents. Org Lett (2004) 0.77
Palladium-catalyzed electrophilic substitution of allyl chlorides and acetates via bis-allylpalladium intermediates. J Org Chem (2003) 0.76
Borylation of propargylic substrates by bimetallic catalysis. Synthesis of allenyl, propargylic, and butadienyl Bpin derivatives. J Am Chem Soc (2014) 0.76
Selective formation of adjacent stereocenters by allylboration of ketones under mild neutral conditions. Org Lett (2013) 0.75
Employment of palladium pincer-complexes in phenylselenylation of organohalides. J Org Chem (2005) 0.75
Functionalization of unactivated alkenes through iridium-catalyzed borylation of carbon-hydrogen bonds. Mechanism and synthetic applications. J Org Chem (2009) 0.75
Palladium-catalyzed selective acyloxylation using sodium perborate as oxidant. J Org Chem (2011) 0.75
Palladium-catalyzed electrophilic substitution via monoallylpalladium intermediates. Angew Chem Int Ed Engl (2003) 0.75
Palladium pincer complex-catalyzed trimethyltin substitution of functionalized propargylic substrates. An efficient route to propargyl- and allenyl-stannanes. J Am Chem Soc (2004) 0.75
Allylic sp3 C-H borylation of alkenes via allyl-Pd intermediates: an efficient route to allylboronates. Chem Commun (Camb) (2014) 0.75
Factors influencing the selectivity in asymmetric oxidation of sulfides attached to nitrogen containing heterocycles. Chem Commun (Camb) (2007) 0.75
Origin of the regio- and stereoselectivity in palladium-catalyzed electrophilic substitution via bis(allyl)palladium complexes. Chemistry (2003) 0.75