A Long-Lived Fe(III)-(Hydroperoxo) Intermediate in the Active H200C Variant of Homoprotocatechuate 2,3-Dioxygenase: Characterization by Mössbauer, Electron Paramagnetic Resonance, and Density Functional Theory Methods.

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Published in Inorg Chem on October 20, 2015

Authors

Katlyn K Meier1, Melanie S Rogers2, Elena G Kovaleva3, Michael M Mbughuni2, Emile L Bominaar1, John D Lipscomb2, Eckard Münck1

Author Affiliations

1: Department of Chemistry, Carnegie Mellon University , Pittsburgh, Pennsylvania 15213, United States.
2: Department of Biochemistry, Molecular Biology and Biophysics and Center for Metals in Biocatalysis, University of Minnesota , Minneapolis, Minnesota 55455, United States.
3: Stanford Synchrotron Radiation Lightsource, 2575 Sand Hill Road, Menlo Park, California 94025, United States.

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