Published in J Am Chem Soc on September 25, 2002
On the feasibility of N2 fixation via a single-site FeI/FeIV cycle: Spectroscopic studies of FeI(N2)FeI, FeIV[triple bond]N, and related species. Proc Natl Acad Sci U S A (2006) 1.40
Formation of a cobalt(III) imido from a cobalt(II) amido complex. Evidence for proton-coupled electron transfer. J Am Chem Soc (2007) 0.90
Examination of the mechanism of Rh(2)(II)-catalyzed carbazole formation using intramolecular competition experiments. J Org Chem (2009) 0.88
Characterization of Iron-Imido Species Relevant for N-Group Transfer Chemistry. J Am Chem Soc (2016) 0.82
Synthesis and Structures of Dimeric Iron(III)-Oxo and -Imido Complexes Containing Intramolecular Hydrogen Bonds. Inorganica Chim Acta (2007) 0.81
Three-coordinate terminal imidoiron(III) complexes: structure, spectroscopy, and mechanism of formation. Inorg Chem (2010) 0.80
Carbon-hydrogen bond activation, C-N bond coupling, and cycloaddition reactivity of a three-coordinate nickel complex featuring a terminal imido ligand. Inorg Chem (2014) 0.79
Arene C-H amination at nickel in terphenyl-diphosphine complexes with labile metal-arene interactions. Chemistry (2013) 0.78
Homolytic N-H Activation of Ammonia: Hydrogen Transfer of Parent Iridium Ammine, Amide, Imide, and Nitride Species. Inorg Chem (2015) 0.77
Redox Non-Innocent Behavior of a Terminal Iridium Hydrazido(2-) Triple Bond. Angew Chem Int Ed Engl (2016) 0.75
Synthesis of a "Masked" Terminal Nickel(II) Sulfide by Reductive Deprotection and its Reaction with Nitrous Oxide. Angew Chem Int Ed Engl (2015) 0.75
Synthesis and characterization of mononuclear, pseudotetrahedral cobalt(III) compounds. Inorg Chem (2014) 0.75
Pseudotetrahedral manganese complexes supported by the anionic tris(phosphino)borate ligand [PhBP(iPr)3]. Inorg Chem (2006) 0.75
Generating and stabilizing Co(I) in a nanocage environment. J Am Chem Soc (2014) 0.75
Electrocatalytic hydrogen evolution at low overpotentials by cobalt macrocyclic glyoxime and tetraimine complexes. J Am Chem Soc (2007) 2.00
Triggering N(2) uptake via redox-induced expulsion of coordinated NH(3) and N(2) silylation at trigonal bipyramidal iron. Nat Chem (2010) 1.75
Benchmarking heterogeneous electrocatalysts for the oxygen evolution reaction. J Am Chem Soc (2013) 1.75
Dinitrogen chemistry from trigonally coordinated iron and cobalt platforms. J Am Chem Soc (2003) 1.61
A tetrahedrally coordinated L3Fe-Nx platform that accommodates terminal nitride (Fe(IV)N) and dinitrogen (Fe(I)-N2-Fe(I)) ligands. J Am Chem Soc (2004) 1.60
Benchmarking hydrogen evolving reaction and oxygen evolving reaction electrocatalysts for solar water splitting devices. J Am Chem Soc (2015) 1.48
A low-spin d5 iron imide: nitrene capture by low-coordinate iron(I) provides the 4-coordinate Fe(III) complex [PhB(CH2PPh2)3]Fe=N-p-tolyl. J Am Chem Soc (2003) 1.45
On the feasibility of N2 fixation via a single-site FeI/FeIV cycle: Spectroscopic studies of FeI(N2)FeI, FeIV[triple bond]N, and related species. Proc Natl Acad Sci U S A (2006) 1.40
Catalytic conversion of nitrogen to ammonia by an iron model complex. Nature (2013) 1.38
Electrocatalytic hydrogen evolution by cobalt difluoroboryl-diglyoximate complexes. Chem Commun (Camb) (2005) 1.29
Ground-state singlet L3Fe-(mu-N)-FeL3 and L3Fe(NR) complexes featuring pseudotetrahedral Fe(II) centers. J Am Chem Soc (2005) 1.28
N2 functionalization at iron metallaboratranes. J Am Chem Soc (2011) 1.25
Terminal iron dinitrogen and iron imide complexes supported by a tris(phosphino)borane ligand. Angew Chem Int Ed Engl (2011) 1.23
Catalytic C-H bond amination from high-spin iron imido complexes. J Am Chem Soc (2011) 1.23
Synthesis and redox properties of triiron complexes featuring strong Fe-Fe interactions. Angew Chem Int Ed Engl (2011) 1.22
Complex N-heterocycle synthesis via iron-catalyzed, direct C-H bond amination. Science (2013) 1.17
Catalytic reduction of N2 to NH3 by an Fe-N2 complex featuring a C-atom anchor. J Am Chem Soc (2014) 1.16
Characterization of the terminal iron(IV) imides [[PhBP(t)(Bu)2(pz')]Fe(IV)NAd]+. J Am Chem Soc (2006) 1.14
Terminal FeI-N2 and FeII...H-C interactions supported by tris(phosphino)silyl ligands. Angew Chem Int Ed Engl (2007) 1.12
Characterization of structurally unusual diiron N(x)H(y) complexes. J Am Chem Soc (2009) 1.08
Transition-metal-catalyzed alkylations of amines with alkyl halides: photoinduced, copper-catalyzed couplings of carbazoles. Angew Chem Int Ed Engl (2013) 1.08
Photoinduced Ullmann C-N coupling: demonstrating the viability of a radical pathway. Science (2012) 1.07
Hydrogenolysis of [PhBP3]Fe[triple bond]N-p-tolyl: probing the reactivity of an iron imide with H2. J Am Chem Soc (2004) 1.06
Dinitrogen complexes supported by tris(phosphino)silyl ligands. Inorg Chem (2009) 1.06
Silylation of iron-bound carbon monoxide affords a terminal Fe carbyne. J Am Chem Soc (2011) 1.03
Photoinduced, copper-catalyzed alkylation of amides with unactivated secondary alkyl halides at room temperature. J Am Chem Soc (2014) 1.02
Conversion of Fe-NH2 to Fe-N2 with release of NH3. J Am Chem Soc (2013) 1.01
Heterolytic H2 activation mediated by low-coordinate L3Fe-(mu-N)-FeL3 complexes to generate Fe(mu-NH)(mu-H)Fe species. J Am Chem Soc (2005) 1.01
A new family of nucleophiles for photoinduced, copper-catalyzed cross-couplings via single-electron transfer: reactions of thiols with aryl halides under mild conditions (O °C). J Am Chem Soc (2013) 1.01
M≡E and M=E Complexes of Iron and Cobalt that Emphasize Three-fold Symmetry (E = O, N, NR). Coord Chem Rev (2011) 1.00
Fe(I)-mediated reductive cleavage and coupling of CO(2): an Fe(II)(mu-O, mu-CO)Fe(II) core. J Am Chem Soc (2007) 1.00
Low-temperature N2 binding to two-coordinate L2Fe(0) enables reductive trapping of L2FeN2(-) and NH3 generation. Angew Chem Int Ed Engl (2014) 1.00
A versatile approach to Ullmann C-N couplings at room temperature: new families of nucleophiles and electrophiles for photoinduced, copper-catalyzed processes. J Am Chem Soc (2013) 0.99
Ligand design for site-selective installation of Pd and Pt centers to generate homo- and heteropolymetallic motifs. Chem Commun (Camb) (2010) 0.98
Mid- to high-valent imido and nitrido complexes of iron. J Inorg Biochem (2006) 0.97
Fe-N2/CO complexes that model a possible role for the interstitial C atom of FeMo-cofactor (FeMoco). Proc Natl Acad Sci U S A (2013) 0.97
Catalytic N-N coupling of aryl azides to yield azoarenes via trigonal bipyramid iron-nitrene intermediates. J Am Chem Soc (2010) 0.96
Oxidative group transfer to a triiron complex to form a nucleophilic μ(3)-nitride, [Fe3(μ(3)-N)]-. J Am Chem Soc (2011) 0.95
Transformation of an [Fe(η2-N2H3)]+ species to π-delocalized [Fe2(μ-N2H2)](2+/+) complexes. Angew Chem Int Ed Engl (2011) 0.94
Considering Fe(II/IV) redox processes as mechanistically relevant to the catalytic hydrogenation of olefins by [PhBP iPr 3]Fe-H x species. Inorg Chem (2004) 0.94
Reversible H2 addition across a nickel-borane unit as a promising strategy for catalysis. J Am Chem Soc (2012) 0.93
[((H)L)2Fe6(NCMe)m]n+ (m = 0, 2, 4, 6; n = -1, 0, 1, 2, 3, 4, 6): an electron-transfer series featuring octahedral Fe6 clusters supported by a hexaamide ligand platform. J Am Chem Soc (2011) 0.93
Vibrational spectroscopy and analysis of pseudo-tetrahedral complexes with metal imido bonds. Inorg Chem (2006) 0.93
Hydrogen evolution by cobalt tetraimine catalysts adsorbed on electrode surfaces. Chem Commun (Camb) (2009) 0.92
Electrocatalytic hydrogen evolution in acidic water with molecular cobalt tetraazamacrocycles. J Am Chem Soc (2012) 0.92
Dinitrogen complexes of sulfur-ligated iron. J Am Chem Soc (2011) 0.91
Catalytic copolymerization of CO and ethylene with a charge neutral palladium(II) zwitterion. J Am Chem Soc (2002) 0.90
Three-coordinate copper(I) amido and aminyl radical complexes. J Am Chem Soc (2009) 0.90
Dihydrogen binding to isostructural S = ½ and S = 0 cobalt complexes. J Am Chem Soc (2012) 0.89
Phosphido pincer complexes of platinum: synthesis, structure and reactivity. Dalton Trans (2011) 0.89
Boryl-mediated reversible H2 activation at cobalt: catalytic hydrogenation, dehydrogenation, and transfer hydrogenation. J Am Chem Soc (2013) 0.88
Testing the polynuclear hypothesis: multielectron reduction of small molecules by triiron reaction sites. J Am Chem Soc (2013) 0.88
Probing the electronic structures of [Cu2(mu-XR2)]n+ diamond cores as a function of the bridging X atom (X = N or P) and charge (n = 0, 1, 2). J Am Chem Soc (2008) 0.87
Expanded redox accessibility via ligand substitution in an octahedral Fe6Br6 cluster. Chem Commun (Camb) (2011) 0.87
Elucidation of a low spin cobalt(II) system in a distorted tetrahedral geometry. J Am Chem Soc (2002) 0.87
The strong-field tripodal phosphine donor, [PhB(CH2PiPr2)3]-, provides access to electronically and coordinatively unsaturated transition metal complexes. Inorg Chem (2003) 0.87
Two-coordinate Fe⁰ and Co⁰ complexes supported by cyclic (alkyl)(amino)carbenes. Angew Chem Int Ed Engl (2014) 0.87
Heterolytic H2 Cleavage and Catalytic Hydrogenation by an Iron Metallaboratrane. Organometallics (2013) 0.86
A nonclassical dihydrogen adduct of S = ½ Fe(I). J Am Chem Soc (2011) 0.86
Synthetic, structural, and mechanistic aspects of an amine activation process mediated at a zwitterionic Pd(II) center. J Am Chem Soc (2004) 0.86
H-H and Si-H bond addition to Fe≡NNR2 intermediates derived from N2. J Am Chem Soc (2013) 0.86
A five-coordinate phosphino/acetate iron(II) scaffold that binds N2, N2H2, N2H4, and NH3 in the sixth site. Inorg Chem (2011) 0.85
Synthetic control of excited-state properties in cyclometalated Ir(III) complexes using ancillary ligands. Inorg Chem (2005) 0.85
Oxidative atom-transfer to a trimanganese complex to form Mn6(μ6-E) (E = O, N) clusters featuring interstitial oxide and nitride functionalities. J Am Chem Soc (2011) 0.85
Modeling the signatures of hydrides in metalloenzymes: ENDOR analysis of a Di-iron Fe(μ-NH)(μ-H)Fe core. J Am Chem Soc (2012) 0.84
Rapid water reduction to H2 catalyzed by a cobalt bis(iminopyridine) complex. J Am Chem Soc (2011) 0.84
Spin-state tuning at pseudotetrahedral d(7) ions: examining the structural and magnetic phenomena of four-coordinate [BP3]CoII-X systems. J Am Chem Soc (2005) 0.83
Multi-site reactivity: reduction of six equivalents of nitrite to give an Fe6(NO)6 cluster with a dramatically expanded octahedral core. J Am Chem Soc (2011) 0.83
A polar copper-boron one-electron σ-bond. J Am Chem Soc (2013) 0.83
Amido-bridged Cu2N2 diamond cores that minimize structural reorganization and facilitate reversible redox behavior between a Cu1Cu1 and a class III delocalized Cu1.5Cu1.5 species. J Am Chem Soc (2004) 0.83
The coordination chemistry of "[BP3]NiX" platforms: targeting low-valent nickel sources as promising candidates to L3Ni=E and L3Ni(triple bond)E linkages. Inorg Chem (2004) 0.82
Site-isolated redox reactivity in a trinuclear iron complex. Inorg Chem (2012) 0.82
Co(III) imidos exhibiting spin crossover and C-H bond activation. J Am Chem Soc (2012) 0.82
C-H bond amination from a ferrous dipyrromethene complex. Inorg Chem (2009) 0.82
A homologous series of cobalt, rhodium, and iridium metalloradicals. Inorg Chem (2011) 0.82
A 10(6)-fold enhancement in N2-binding affinity of an Fe2(μ-H)2 core upon reduction to a mixed-valence Fe(II)Fe(I) state. J Am Chem Soc (2014) 0.82
E-type delayed fluorescence of a phosphine-supported Cu2(mu-NAr2)2 diamond core: harvesting singlet and triplet excitons in OLEDs. J Am Chem Soc (2010) 0.81
Mononuclear five- and six-coordinate iron hydrazido and hydrazine species. Inorg Chem (2012) 0.81
Access to well-defined ruthenium(I) and osmium(I) metalloradicals. Angew Chem Int Ed Engl (2010) 0.81
Studies of cobalt-mediated electrocatalytic CO2 reduction using a redox-active ligand. Inorg Chem (2014) 0.81
Zwitterionic relatives to the classic [(P-P)Rh(solv)2]+ ions: neutral catalysts active for H-E bond additions to olefins (E=C, Si, B). Angew Chem Int Ed Engl (2003) 0.81
A highly emissive Cu2N2 diamond core complex supported by a [PNP]- ligand. J Am Chem Soc (2005) 0.81
Zwitterionic and cationic bis(phosphine) platinum(II) complexes: structural, electronic, and mechanistic comparisons relevant to ligand exchange and benzene C-H activation processes. J Am Chem Soc (2003) 0.80
A CO-derived iron dicarbyne that releases olefin upon hydrogenation. J Am Chem Soc (2013) 0.80
Structural snapshots of a flexible Cu2P2 core that accommodates the oxidation states Cu(I)Cu(I), Cu1.5Cu1.5, and Cu(II)Cu(II). J Am Chem Soc (2005) 0.80
High-spin and low-spin iron(II) complexes with facially-coordinated borohydride ligands. Dalton Trans (2005) 0.79
Trigonal Mn3 and Co3 clusters supported by weak-field ligands: a structural, spectroscopic, magnetic, and computational investigation into the correlation of molecular and electronic structure. Inorg Chem (2012) 0.79
A Ru(I) metalloradical that catalyzes nitrene coupling to azoarenes from arylazides. J Am Chem Soc (2012) 0.79
Free H₂ rotation vs Jahn-Teller constraints in the nonclassical trigonal (TPB)Co-H₂ complex. J Am Chem Soc (2014) 0.79
Bis(alpha-diimine)iron complexes: electronic structure determination by spectroscopy and broken symmetry density functional theoretical calculations. Inorg Chem (2008) 0.79
Diazoalkanes react with a bis(phosphino)borate copper(i) source to generate [Ph2BP(tBu)2]Cu(eta1-N2CR2), [Ph2BP(tBu)2]Cu(CPh2), and [Ph2BP(tBu)2]Cu-N(CPh2)(NCPh2). Chem Commun (Camb) (2008) 0.79
Dimanganese and diiron complexes of a binucleating cyclam ligand: four-electron, reversible oxidation chemistry at high potentials. Inorg Chem (2008) 0.79
Synthesis of open-shell, bimetallic Mn/Fe trinuclear clusters. J Am Chem Soc (2013) 0.79
Electronic perturbations of iron dipyrrinato complexes via ligand β-halogenation and meso-fluoroarylation. Inorg Chem (2011) 0.78
Metal atom lability in polynuclear complexes. Inorg Chem (2013) 0.78