Published in J Am Chem Soc on March 25, 2009
Cu(I)-amido complexes in the Ullmann reaction: reactions of Cu(I)-amido complexes with iodoarenes with and without autocatalysis by CuI. J Am Chem Soc (2010) 1.05
Evidence for alkene cis-aminocupration, an aminooxygenation case study: kinetics, EPR spectroscopy, and DFT calculations. Chemistry (2012) 1.03
Closed-shell and open-shell square-planar iridium nitrido complexes. Nat Chem (2012) 0.82
Mechanism of nitric oxide reactivity and fluorescence enhancement of the NO-specific probe CuFL1. Inorg Chem (2010) 0.80
Evidence of two-state reactivity in alkane hydroxylation by Lewis-acid bound copper-nitrene complexes. Chem Commun (Camb) (2014) 0.77
Detecting and understanding the roles of nitric oxide in biology. Inorg Chem (2010) 0.77
Di- and Trinuclear Mixed-Valence Copper Amidinate Complexes from Reduction of Iodine. Inorg Chem (2015) 0.75
Metalloenzymes: the entatic nature of their active sites. Proc Natl Acad Sci U S A (1968) 4.27
Copper coordination in blue proteins. J Biol Inorg Chem (2000) 3.05
Catalytic galactose oxidase models: biomimetic Cu(II)-phenoxyl-radical reactivity. Science (1998) 1.99
Crystal structure of the type-2 Cu depleted laccase from Coprinus cinereus at 2.2 A resolution. Nat Struct Biol (1998) 1.70
A stable aminyl radical metal complex. Science (2005) 1.66
A quantitative description of the ground-state wave function of Cu(A) by X-ray absorption spectroscopy: comparison to plastocyanin and relevance to electron transfer. J Am Chem Soc (2001) 1.55
Electron transfer by copper centers. Chem Rev (2004) 1.49
Three-coordinate copper(II)-phenolate complexes. Inorg Chem (2001) 0.91
Aerobic Oxidation of Primary Alcohols by a New Mononuclear Cu(II) -Radical Catalyst. Angew Chem Int Ed Engl (1999) 0.90
A structural and functional model of galactose oxidase: control of the one-electron oxidized active form through two differentiated phenolic arms in a tripodal ligand. Angew Chem Int Ed Engl (2002) 0.89
Cassette mutagenesis of Met121 in azurin from Pseudomonas aeruginosa. Protein Eng (1991) 0.89
Probing the electronic structures of [Cu2(mu-XR2)]n+ diamond cores as a function of the bridging X atom (X = N or P) and charge (n = 0, 1, 2). J Am Chem Soc (2008) 0.87
A definitive example of a geometric "entatic state" effect: electron-transfer kinetics for a copper(II/I) complex involving A quinquedentate macrocyclic trithiaether-bipyridine ligand. J Am Chem Soc (2007) 0.84
Generation of a RuII-semiquinone-anilino-radical complex through the deprotonation of a RuIII-semiquinone-anilido complex. Angew Chem Int Ed Engl (2007) 0.84
Amido-bridged Cu2N2 diamond cores that minimize structural reorganization and facilitate reversible redox behavior between a Cu1Cu1 and a class III delocalized Cu1.5Cu1.5 species. J Am Chem Soc (2004) 0.83
Electronic structure and its relation to function in copper proteins. Curr Opin Chem Biol (2002) 0.81
Metal complexes of aminyl radicals. Angew Chem Int Ed Engl (2008) 0.81
Diazoalkanes react with a bis(phosphino)borate copper(i) source to generate [Ph2BP(tBu)2]Cu(eta1-N2CR2), [Ph2BP(tBu)2]Cu(CPh2), and [Ph2BP(tBu)2]Cu-N(CPh2)(NCPh2). Chem Commun (Camb) (2008) 0.79
Electronic structures of metal sites in proteins and models: contributions to function in blue copper proteins. Chem Rev (2004) 2.51
Molecular features of the copper binding sites in the octarepeat domain of the prion protein. Biochemistry (2002) 2.16
Electrocatalytic hydrogen evolution at low overpotentials by cobalt macrocyclic glyoxime and tetraimine complexes. J Am Chem Soc (2007) 2.00
Chelation of intracellular iron with the antifungal agent ciclopirox olamine induces cell death in leukemia and myeloma cells. Blood (2009) 1.99
The octarepeat domain of the prion protein binds Cu(II) with three distinct coordination modes at pH 7.4. J Am Chem Soc (2005) 1.80
Triggering N(2) uptake via redox-induced expulsion of coordinated NH(3) and N(2) silylation at trigonal bipyramidal iron. Nat Chem (2010) 1.75
Benchmarking heterogeneous electrocatalysts for the oxygen evolution reaction. J Am Chem Soc (2013) 1.75
Copper coordination in the full-length, recombinant prion protein. Biochemistry (2003) 1.66
The membrane-associated methane monooxygenase (pMMO) and pMMO-NADH:quinone oxidoreductase complex from Methylococcus capsulatus Bath. J Bacteriol (2003) 1.64
Dinitrogen chemistry from trigonally coordinated iron and cobalt platforms. J Am Chem Soc (2003) 1.61
A tetrahedrally coordinated L3Fe-Nx platform that accommodates terminal nitride (Fe(IV)N) and dinitrogen (Fe(I)-N2-Fe(I)) ligands. J Am Chem Soc (2004) 1.60
Benchmarking hydrogen evolving reaction and oxygen evolving reaction electrocatalysts for solar water splitting devices. J Am Chem Soc (2015) 1.48
A low-spin d5 iron imide: nitrene capture by low-coordinate iron(I) provides the 4-coordinate Fe(III) complex [PhB(CH2PPh2)3]Fe=N-p-tolyl. J Am Chem Soc (2003) 1.45
On the feasibility of N2 fixation via a single-site FeI/FeIV cycle: Spectroscopic studies of FeI(N2)FeI, FeIV[triple bond]N, and related species. Proc Natl Acad Sci U S A (2006) 1.40
Catalytic conversion of nitrogen to ammonia by an iron model complex. Nature (2013) 1.38
Dithiomethylether as a ligand in the hydrogenase h-cluster. J Am Chem Soc (2008) 1.38
Spectral, kinetic, and thermodynamic properties of Cu(I) and Cu(II) binding by methanobactin from Methylosinus trichosporium OB3b. Biochemistry (2006) 1.36
Mössbauer studies of the membrane-associated methane monooxygenase from Methylococcus capsulatus bath: evidence for a Diiron center. J Am Chem Soc (2007) 1.36
Nature of the intermediate formed in the reduction of O(2) to H(2)O at the trinuclear copper cluster active site in native laccase. J Am Chem Soc (2002) 1.30
Electrocatalytic hydrogen evolution by cobalt difluoroboryl-diglyoximate complexes. Chem Commun (Camb) (2005) 1.29
Sulfur K-edge X-ray absorption spectroscopy as a probe of ligand-metal bond covalency: metal vs ligand oxidation in copper and nickel dithiolene complexes. J Am Chem Soc (2007) 1.29
Doxorubicin inactivates myocardial cytochrome c oxidase in rats: cardioprotection by Mito-Q. Biophys J (2009) 1.28
Ground-state singlet L3Fe-(mu-N)-FeL3 and L3Fe(NR) complexes featuring pseudotetrahedral Fe(II) centers. J Am Chem Soc (2005) 1.28
N2 functionalization at iron metallaboratranes. J Am Chem Soc (2011) 1.25
Spectral and thermodynamic properties of Ag(I), Au(III), Cd(II), Co(II), Fe(III), Hg(II), Mn(II), Ni(II), Pb(II), U(IV), and Zn(II) binding by methanobactin from Methylosinus trichosporium OB3b. J Inorg Biochem (2006) 1.23
Terminal iron dinitrogen and iron imide complexes supported by a tris(phosphino)borane ligand. Angew Chem Int Ed Engl (2011) 1.23
Assembly of cytochrome-c oxidase in the absence of assembly protein Surf1p leads to loss of the active site heme. J Biol Chem (2005) 1.20
Exploring new frontiers of nitrogenase structure and mechanism. Curr Opin Chem Biol (2006) 1.18
Effect of methanobactin on the activity and electron paramagnetic resonance spectra of the membrane-associated methane monooxygenase in Methylococcus capsulatus Bath. Microbiology (2005) 1.17
Catalytic reduction of N2 to NH3 by an Fe-N2 complex featuring a C-atom anchor. J Am Chem Soc (2014) 1.16
Characterization of the terminal iron(IV) imides [[PhBP(t)(Bu)2(pz')]Fe(IV)NAd]+. J Am Chem Soc (2006) 1.14
Terminal FeI-N2 and FeII...H-C interactions supported by tris(phosphino)silyl ligands. Angew Chem Int Ed Engl (2007) 1.12
Detection of a [3Fe-4S] cluster intermediate of cytosolic aconitase in yeast expressing iron regulatory protein 1. Insights into the mechanism of Fe-S cluster cycling. J Biol Chem (2001) 1.11
Activation of HydA(DeltaEFG) requires a preformed [4Fe-4S] cluster. Biochemistry (2009) 1.09
Characterization of structurally unusual diiron N(x)H(y) complexes. J Am Chem Soc (2009) 1.08
Transition-metal-catalyzed alkylations of amines with alkyl halides: photoinduced, copper-catalyzed couplings of carbazoles. Angew Chem Int Ed Engl (2013) 1.08
Neuroprotection by a mitochondria-targeted drug in a Parkinson's disease model. Free Radic Biol Med (2010) 1.07
Photoinduced Ullmann C-N coupling: demonstrating the viability of a radical pathway. Science (2012) 1.07
The solution structure of [Cu(aq)]2+ and its implications for rack-induced bonding in blue copper protein active sites. Inorg Chem (2005) 1.06
Dinitrogen complexes supported by tris(phosphino)silyl ligands. Inorg Chem (2009) 1.06
Hydrogenolysis of [PhBP3]Fe[triple bond]N-p-tolyl: probing the reactivity of an iron imide with H2. J Am Chem Soc (2004) 1.06
Vanadium(V) reduction by Shewanella oneidensis MR-1 requires menaquinone and cytochromes from the cytoplasmic and outer membranes. Appl Environ Microbiol (2004) 1.05
Oxidative group transfer to Co(I) affords a terminal Co(III) imido complex. J Am Chem Soc (2002) 1.04
Comparative assessment of the composition and charge state of nitrogenase FeMo-cofactor. Inorg Chem (2011) 1.04
Silylation of iron-bound carbon monoxide affords a terminal Fe carbyne. J Am Chem Soc (2011) 1.03
Reduction of hexavalent chromium by human cytochrome b5: generation of hydroxyl radical and superoxide. Free Radic Biol Med (2006) 1.02
Evidence that NiNi acetyl-CoA synthase is active and that the CuNi enzyme is not. Biochemistry (2004) 1.02
Photoinduced, copper-catalyzed alkylation of amides with unactivated secondary alkyl halides at room temperature. J Am Chem Soc (2014) 1.02
Heterolytic H2 activation mediated by low-coordinate L3Fe-(mu-N)-FeL3 complexes to generate Fe(mu-NH)(mu-H)Fe species. J Am Chem Soc (2005) 1.01
A radical solution for the biosynthesis of the H-cluster of hydrogenase. FEBS Lett (2005) 1.01
Conversion of Fe-NH2 to Fe-N2 with release of NH3. J Am Chem Soc (2013) 1.01
A new family of nucleophiles for photoinduced, copper-catalyzed cross-couplings via single-electron transfer: reactions of thiols with aryl halides under mild conditions (O °C). J Am Chem Soc (2013) 1.01
Fe(I)-mediated reductive cleavage and coupling of CO(2): an Fe(II)(mu-O, mu-CO)Fe(II) core. J Am Chem Soc (2007) 1.00
M≡E and M=E Complexes of Iron and Cobalt that Emphasize Three-fold Symmetry (E = O, N, NR). Coord Chem Rev (2011) 1.00
Low-temperature N2 binding to two-coordinate L2Fe(0) enables reductive trapping of L2FeN2(-) and NH3 generation. Angew Chem Int Ed Engl (2014) 1.00
A versatile approach to Ullmann C-N couplings at room temperature: new families of nucleophiles and electrophiles for photoinduced, copper-catalyzed processes. J Am Chem Soc (2013) 0.99
Oxidase, superoxide dismutase, and hydrogen peroxide reductase activities of methanobactin from types I and II methanotrophs. J Inorg Biochem (2008) 0.99
Ligand design for site-selective installation of Pd and Pt centers to generate homo- and heteropolymetallic motifs. Chem Commun (Camb) (2010) 0.98
Damage to mitochondrial complex I during cardiac ischemia reperfusion injury is reduced indirectly by anti-anginal drug ranolazine. Biochim Biophys Acta (2011) 0.98
Fe-N2/CO complexes that model a possible role for the interstitial C atom of FeMo-cofactor (FeMoco). Proc Natl Acad Sci U S A (2013) 0.97
Mid- to high-valent imido and nitrido complexes of iron. J Inorg Biochem (2006) 0.97
Catalytic N-N coupling of aryl azides to yield azoarenes via trigonal bipyramid iron-nitrene intermediates. J Am Chem Soc (2010) 0.96
Generation of novel copper sites by mutation of the axial ligand of amicyanin. Atomic resolution structures and spectroscopic properties. Biochemistry (2007) 0.95
Transformation of an [Fe(η2-N2H3)]+ species to π-delocalized [Fe2(μ-N2H2)](2+/+) complexes. Angew Chem Int Ed Engl (2011) 0.94
Considering Fe(II/IV) redox processes as mechanistically relevant to the catalytic hydrogenation of olefins by [PhBP iPr 3]Fe-H x species. Inorg Chem (2004) 0.94
Spectroscopic studies of the Met182Thr mutant of nitrite reductase: role of the axial ligand in the geometric and electronic structure of blue and green copper sites. J Am Chem Soc (2003) 0.94
Vibrational spectroscopy and analysis of pseudo-tetrahedral complexes with metal imido bonds. Inorg Chem (2006) 0.93
Electronic structure description of the mu(4)-sulfide bridged tetranuclear Cu(Z) center in N(2)O reductase. J Am Chem Soc (2002) 0.93
Reversible H2 addition across a nickel-borane unit as a promising strategy for catalysis. J Am Chem Soc (2012) 0.93
Electrocatalytic hydrogen evolution in acidic water with molecular cobalt tetraazamacrocycles. J Am Chem Soc (2012) 0.92
Hydrogen evolution by cobalt tetraimine catalysts adsorbed on electrode surfaces. Chem Commun (Camb) (2009) 0.92
[Cu3(mu-S)2]3+ clusters supported by N-donor ligands: progress toward a synthetic model of the catalytic site of nitrous oxide reductase. J Am Chem Soc (2005) 0.92
Structures of HO(2)-Co(III)bleomycin A(2) bound to d(GAGCTC)(2) and d(GGAAGCTTCC)(2): structure-reactivity relationships of Co and Fe bleomycins. J Inorg Biochem (2002) 0.91
Dinitrogen complexes of sulfur-ligated iron. J Am Chem Soc (2011) 0.91
Spectral and thermodynamic properties of methanobactin from γ-proteobacterial methane oxidizing bacteria: a case for copper competition on a molecular level. J Inorg Biochem (2010) 0.91
The selenium-independent inherent pro-oxidant NADPH oxidase activity of mammalian thioredoxin reductase and its selenium-dependent direct peroxidase activities. J Biol Chem (2010) 0.90
EPR of Cu2+ prion protein constructs at 2 GHz using the g(perpendicular) region to characterize nitrogen ligation. Biophys J (2009) 0.90
Spectroscopic investigation of stellacyanin mutants: axial ligand interactions at the blue copper site. J Am Chem Soc (2003) 0.90
Catalytic copolymerization of CO and ethylene with a charge neutral palladium(II) zwitterion. J Am Chem Soc (2002) 0.90
Phosphido pincer complexes of platinum: synthesis, structure and reactivity. Dalton Trans (2011) 0.89
Dihydrogen binding to isostructural S = ½ and S = 0 cobalt complexes. J Am Chem Soc (2012) 0.89
Boryl-mediated reversible H2 activation at cobalt: catalytic hydrogenation, dehydrogenation, and transfer hydrogenation. J Am Chem Soc (2013) 0.88
Sulfur K-edge XAS of WVO vs. MoVO bis(dithiolene) complexes: contributions of relativistic effects to electronic structure and reactivity of tungsten enzymes. J Inorg Biochem (2007) 0.88
Hexavalent chromium causes the oxidation of thioredoxin in human bronchial epithelial cells. Toxicology (2008) 0.88
Probing the electronic structures of [Cu2(mu-XR2)]n+ diamond cores as a function of the bridging X atom (X = N or P) and charge (n = 0, 1, 2). J Am Chem Soc (2008) 0.87
The strong-field tripodal phosphine donor, [PhB(CH2PiPr2)3]-, provides access to electronically and coordinatively unsaturated transition metal complexes. Inorg Chem (2003) 0.87
Escherichia coli gamma-glutamylcysteine synthetase. Two active site metal ions affect substrate and inhibitor binding. J Biol Chem (2001) 0.87
Elucidation of a low spin cobalt(II) system in a distorted tetrahedral geometry. J Am Chem Soc (2002) 0.87
Electronic control of the "Bailar twist" in formally d0-d2 molybdenum tris(dithiolene) complexes: a sulfur K-edge X-ray absorption spectroscopy and density functional theory study. Inorg Chem (2008) 0.87
Structurally distinct active sites in the copper(II)-substituted aminopeptidases from Aeromonas proteolytica and Escherichia coli. J Am Chem Soc (2002) 0.87
Structural, spectroscopic, and theoretical elucidation of a redox-active pincer-type ancillary applied in catalysis. J Am Chem Soc (2008) 0.87
Two-coordinate Fe⁰ and Co⁰ complexes supported by cyclic (alkyl)(amino)carbenes. Angew Chem Int Ed Engl (2014) 0.87
Dual role of selected antioxidants found in dietary supplements: crossover between anti- and pro-oxidant activities in the presence of copper. J Agric Food Chem (2012) 0.86
Systematic development of computational models for the catalytic site in galactose oxidase: impact of outer-sphere residues on the geometric and electronic structures. J Biol Inorg Chem (2007) 0.86
Heterolytic H2 Cleavage and Catalytic Hydrogenation by an Iron Metallaboratrane. Organometallics (2013) 0.86
A nonclassical dihydrogen adduct of S = ½ Fe(I). J Am Chem Soc (2011) 0.86
Sulfur K-edge X-ray absorption spectroscopy and density functional calculations on Mo(IV) and Mo(VI)=O bis-dithiolenes: insights into the mechanism of oxo transfer in DMSO reductase and related functional analogues. J Am Chem Soc (2010) 0.86