Published in Nat Chem on May 16, 2010
The effects of redox-inactive metal ions on the activation of dioxygen: isolation and characterization of a heterobimetallic complex containing a Mn(III)-(μ-OH)-Ca(II) core. J Am Chem Soc (2011) 1.44
Catalytic conversion of nitrogen to ammonia by an iron model complex. Nature (2013) 1.38
Heterobimetallic Complexes with M(III)-(μ-OH)-M(II) Cores (M(III) = Fe, Mn, Ga; M(II) = Ca, Sr, and Ba): Structural, Kinetic, and Redox Properties. Chem Sci (2013) 1.30
N2 functionalization at iron metallaboratranes. J Am Chem Soc (2011) 1.25
Terminal iron dinitrogen and iron imide complexes supported by a tris(phosphino)borane ligand. Angew Chem Int Ed Engl (2011) 1.23
Catalytic reduction of N2 to NH3 by an Fe-N2 complex featuring a C-atom anchor. J Am Chem Soc (2014) 1.16
The biology and chemistry of high-valent iron-oxo and iron-nitrido complexes. Nat Commun (2012) 1.10
Recent developments in the homogeneous reduction of dinitrogen by molybdenum and iron. Nat Chem (2013) 1.05
Assembly and properties of heterobimetallic Co(II/III)/Ca(II) complexes with aquo and hydroxo ligands. J Am Chem Soc (2012) 1.04
Conversion of Fe-NH2 to Fe-N2 with release of NH3. J Am Chem Soc (2013) 1.01
Low-temperature N2 binding to two-coordinate L2Fe(0) enables reductive trapping of L2FeN2(-) and NH3 generation. Angew Chem Int Ed Engl (2014) 1.00
Fe-N2/CO complexes that model a possible role for the interstitial C atom of FeMo-cofactor (FeMoco). Proc Natl Acad Sci U S A (2013) 0.97
Iron-catalysed transformation of molecular dinitrogen into silylamine under ambient conditions. Nat Commun (2012) 0.96
Transformation of an [Fe(η2-N2H3)]+ species to π-delocalized [Fe2(μ-N2H2)](2+/+) complexes. Angew Chem Int Ed Engl (2011) 0.94
Dinitrogen complexes of sulfur-ligated iron. J Am Chem Soc (2011) 0.91
An Fe-N2 Complex That Generates Hydrazine and Ammonia via Fe═NNH2: Demonstrating a Hybrid Distal-to-Alternating Pathway for N2 Reduction. J Am Chem Soc (2016) 0.90
A Synthetic Single-Site Fe Nitrogenase: High Turnover, Freeze-Quench (57)Fe Mössbauer Data, and a Hydride Resting State. J Am Chem Soc (2016) 0.88
Heterolytic H2 Cleavage and Catalytic Hydrogenation by an Iron Metallaboratrane. Organometallics (2013) 0.86
H-H and Si-H bond addition to Fe≡NNR2 intermediates derived from N2. J Am Chem Soc (2013) 0.86
A nonclassical dihydrogen adduct of S = ½ Fe(I). J Am Chem Soc (2011) 0.86
Ammonia formation by a thiolate-bridged diiron amide complex as a nitrogenase mimic. Nat Chem (2013) 0.84
Mononuclear five- and six-coordinate iron hydrazido and hydrazine species. Inorg Chem (2012) 0.81
Evaluating Molecular Cobalt Complexes for the Conversion of N2 to NH3. Inorg Chem (2015) 0.80
Nitric Oxide Activation by Distal Redox Modulation in Tetranuclear Iron Nitrosyl Complexes. J Am Chem Soc (2015) 0.80
Cobalt-Magnesium and Iron-Magnesium Complexes with Weakened Dinitrogen Bridges. Eur J Inorg Chem (2013) 0.79
Alkali Metal Variation and Twisting of the FeNNFe Core in Bridging Diiron Dinitrogen Complexes. Inorg Chem (2016) 0.77
Synthesis, structure and reactivity of Fe(II/III)-NH3 complexes bearing a tripodal sulfonamido ligand. Chem Commun (Camb) (2014) 0.76
Proton-Coupled Reduction of an Iron Cyanide Complex to Methane and Ammonia. Angew Chem Int Ed Engl (2016) 0.75
A Sulfide-Bridged Diiron(II) Complex with a cis-N2H4Ligand. Z Anorg Allg Chem (2013) 0.75
Alkali-Controlled C-H Cleavage or N-C Bond Formation by N2-Derived Iron Nitrides and Imides. J Am Chem Soc (2016) 0.75
Synthesis of diamidopyrrolyl molybdenum complexes relevant to reduction of dinitrogen to ammonia. Inorg Chem (2010) 0.75
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion. ACS Cent Sci (2016) 0.75
Exploring secondary-sphere interactions in Fe-N x H y complexes relevant to N2 fixation. Chem Sci (2016) 0.75
Nitrogen activation: an iron step towards N(2) fixation. Nat Chem (2010) 0.75
Electronic nature of zwitterionic alkali metal methanides, silanides and germanides - a combined experimental and computational approach. Chem Sci (2016) 0.75
Coordination chemistry insights into the role of alkali metal promoters in dinitrogen reduction. Catal Today (2016) 0.75
A Triad of Highly Reduced, Linear Iron Nitrosyl Complexes: {FeNO}(8-10). Angew Chem Int Ed Engl (2016) 0.75
N-H Bond Dissociation Enthalpies and Facile H Atom Transfers for Early Intermediates of Fe-N2 and Fe-CN Reductions. J Am Chem Soc (2017) 0.75
Studies relevant to catalytic reduction of dinitrogen to ammonia by molybdenum triamidoamine complexes. Inorg Chem (2005) 1.69
Intermediates trapped during nitrogenase reduction of N triple bond N, CH3-N=NH, and H2N-NH2. J Am Chem Soc (2005) 1.68
Dinitrogen chemistry from trigonally coordinated iron and cobalt platforms. J Am Chem Soc (2003) 1.61
Reduction of dinitrogen to ammonia at a well-protected reaction site in a molybdenum triamidoamine complex. J Am Chem Soc (2002) 1.47
On the feasibility of N2 fixation via a single-site FeI/FeIV cycle: Spectroscopic studies of FeI(N2)FeI, FeIV[triple bond]N, and related species. Proc Natl Acad Sci U S A (2006) 1.40
Diazene (HN=NH) is a substrate for nitrogenase: insights into the pathway of N2 reduction. Biochemistry (2007) 1.29
A methyldiazene (HN=N-CH3)-derived species bound to the nitrogenase active-site FeMo cofactor: Implications for mechanism. Proc Natl Acad Sci U S A (2006) 1.28
Modeling a central ligand in the nitrogenase FeMo cofactor. J Am Chem Soc (2003) 1.17
Terminal FeI-N2 and FeII...H-C interactions supported by tris(phosphino)silyl ligands. Angew Chem Int Ed Engl (2007) 1.12
Characterization of structurally unusual diiron N(x)H(y) complexes. J Am Chem Soc (2009) 1.08
The first side-on bound metal complex of diazene, HN[double bond]NH. Chem Commun (Camb) (2008) 1.06
Dinitrogen complexes supported by tris(phosphino)silyl ligands. Inorg Chem (2009) 1.06
Synthesis and characterization of an iron(II) eta(2)-hydrazine complex. Inorg Chem (2007) 1.02
Intermediates in the reduction of N(2) to NH(3): synthesis of iron eta(2) hydrazido(1-) and diazene complexes. Dalton Trans (2009) 0.99
Intra- and intermolecular N-H...F-C hydrogen-bonding interactions in amine adducts of tris(pentafluorophenyl)borane and -alane. Inorg Chem (2005) 0.94
Carbon monoxide complexes of iron(II): synthesis and structural studies of five- and six-coordinate complexes of the macrocyclic ligand, C22H22N42. J Am Chem Soc (1976) 0.94
Borane B-C Bond Cleavage by a Low-Coordinate Iron Hydride Complex and N-N Bond Cleavage by the Hydridoborate Product. Organometallics (2007) 0.94
Base-mediated conversion of hydrazine to diazene and dinitrogen at an iron center. Inorg Chem (2009) 0.92
Weak hydrogen bridges: a systematic theoretical study on the nature and strength of C--H...F--C interactions. Chemistry (2004) 0.87
Vanadium complexes of the N(CH2CH2S)3(3-) and O(CH2CH2S)2(2-) ligands with coligands relevant to nitrogen fixation processes. Inorg Chem (2001) 0.83
The C-F...cation interaction: an ammonium complex of a hexafluoro macrocyclic cage compound. Chemistry (2000) 0.82
Electrocatalytic hydrogen evolution at low overpotentials by cobalt macrocyclic glyoxime and tetraimine complexes. J Am Chem Soc (2007) 2.00
Benchmarking heterogeneous electrocatalysts for the oxygen evolution reaction. J Am Chem Soc (2013) 1.75
Dinitrogen chemistry from trigonally coordinated iron and cobalt platforms. J Am Chem Soc (2003) 1.61
A tetrahedrally coordinated L3Fe-Nx platform that accommodates terminal nitride (Fe(IV)N) and dinitrogen (Fe(I)-N2-Fe(I)) ligands. J Am Chem Soc (2004) 1.60
Benchmarking hydrogen evolving reaction and oxygen evolving reaction electrocatalysts for solar water splitting devices. J Am Chem Soc (2015) 1.48
A low-spin d5 iron imide: nitrene capture by low-coordinate iron(I) provides the 4-coordinate Fe(III) complex [PhB(CH2PPh2)3]Fe=N-p-tolyl. J Am Chem Soc (2003) 1.45
On the feasibility of N2 fixation via a single-site FeI/FeIV cycle: Spectroscopic studies of FeI(N2)FeI, FeIV[triple bond]N, and related species. Proc Natl Acad Sci U S A (2006) 1.40
Catalytic conversion of nitrogen to ammonia by an iron model complex. Nature (2013) 1.38
Electrocatalytic hydrogen evolution by cobalt difluoroboryl-diglyoximate complexes. Chem Commun (Camb) (2005) 1.29
Ground-state singlet L3Fe-(mu-N)-FeL3 and L3Fe(NR) complexes featuring pseudotetrahedral Fe(II) centers. J Am Chem Soc (2005) 1.28
N2 functionalization at iron metallaboratranes. J Am Chem Soc (2011) 1.25
Terminal iron dinitrogen and iron imide complexes supported by a tris(phosphino)borane ligand. Angew Chem Int Ed Engl (2011) 1.23
Catalytic reduction of N2 to NH3 by an Fe-N2 complex featuring a C-atom anchor. J Am Chem Soc (2014) 1.16
Characterization of the terminal iron(IV) imides [[PhBP(t)(Bu)2(pz')]Fe(IV)NAd]+. J Am Chem Soc (2006) 1.14
Terminal FeI-N2 and FeII...H-C interactions supported by tris(phosphino)silyl ligands. Angew Chem Int Ed Engl (2007) 1.12
Palladium-catalyzed cross-coupling of pyrrole anions with aryl chlorides, bromides, and iodides. Org Lett (2004) 1.11
Characterization of structurally unusual diiron N(x)H(y) complexes. J Am Chem Soc (2009) 1.08
Transition-metal-catalyzed alkylations of amines with alkyl halides: photoinduced, copper-catalyzed couplings of carbazoles. Angew Chem Int Ed Engl (2013) 1.08
Photoinduced Ullmann C-N coupling: demonstrating the viability of a radical pathway. Science (2012) 1.07
Dinitrogen complexes supported by tris(phosphino)silyl ligands. Inorg Chem (2009) 1.06
Hydrogenolysis of [PhBP3]Fe[triple bond]N-p-tolyl: probing the reactivity of an iron imide with H2. J Am Chem Soc (2004) 1.06
Oxidative group transfer to Co(I) affords a terminal Co(III) imido complex. J Am Chem Soc (2002) 1.04
Silylation of iron-bound carbon monoxide affords a terminal Fe carbyne. J Am Chem Soc (2011) 1.03
Photoinduced, copper-catalyzed alkylation of amides with unactivated secondary alkyl halides at room temperature. J Am Chem Soc (2014) 1.02
Heterolytic H2 activation mediated by low-coordinate L3Fe-(mu-N)-FeL3 complexes to generate Fe(mu-NH)(mu-H)Fe species. J Am Chem Soc (2005) 1.01
Two metals are better than one in the gold catalyzed oxidative heteroarylation of alkenes. J Am Chem Soc (2011) 1.01
Conversion of Fe-NH2 to Fe-N2 with release of NH3. J Am Chem Soc (2013) 1.01
A new family of nucleophiles for photoinduced, copper-catalyzed cross-couplings via single-electron transfer: reactions of thiols with aryl halides under mild conditions (O °C). J Am Chem Soc (2013) 1.01
Fe(I)-mediated reductive cleavage and coupling of CO(2): an Fe(II)(mu-O, mu-CO)Fe(II) core. J Am Chem Soc (2007) 1.00
M≡E and M=E Complexes of Iron and Cobalt that Emphasize Three-fold Symmetry (E = O, N, NR). Coord Chem Rev (2011) 1.00
Low-temperature N2 binding to two-coordinate L2Fe(0) enables reductive trapping of L2FeN2(-) and NH3 generation. Angew Chem Int Ed Engl (2014) 1.00
A versatile approach to Ullmann C-N couplings at room temperature: new families of nucleophiles and electrophiles for photoinduced, copper-catalyzed processes. J Am Chem Soc (2013) 0.99
Ligand design for site-selective installation of Pd and Pt centers to generate homo- and heteropolymetallic motifs. Chem Commun (Camb) (2010) 0.98
Mid- to high-valent imido and nitrido complexes of iron. J Inorg Biochem (2006) 0.97
Fe-N2/CO complexes that model a possible role for the interstitial C atom of FeMo-cofactor (FeMoco). Proc Natl Acad Sci U S A (2013) 0.97
Catalytic N-N coupling of aryl azides to yield azoarenes via trigonal bipyramid iron-nitrene intermediates. J Am Chem Soc (2010) 0.96
Transformation of an [Fe(η2-N2H3)]+ species to π-delocalized [Fe2(μ-N2H2)](2+/+) complexes. Angew Chem Int Ed Engl (2011) 0.94
Considering Fe(II/IV) redox processes as mechanistically relevant to the catalytic hydrogenation of olefins by [PhBP iPr 3]Fe-H x species. Inorg Chem (2004) 0.94
Reversible H2 addition across a nickel-borane unit as a promising strategy for catalysis. J Am Chem Soc (2012) 0.93
Vibrational spectroscopy and analysis of pseudo-tetrahedral complexes with metal imido bonds. Inorg Chem (2006) 0.93
Electrocatalytic hydrogen evolution in acidic water with molecular cobalt tetraazamacrocycles. J Am Chem Soc (2012) 0.92
Hydrogen evolution by cobalt tetraimine catalysts adsorbed on electrode surfaces. Chem Commun (Camb) (2009) 0.92
Application of fundamental organometallic chemistry to the development of a gold-catalyzed synthesis of sulfinate derivatives. Angew Chem Int Ed Engl (2014) 0.92
Dinitrogen complexes of sulfur-ligated iron. J Am Chem Soc (2011) 0.91
Catalytic copolymerization of CO and ethylene with a charge neutral palladium(II) zwitterion. J Am Chem Soc (2002) 0.90
Three-coordinate copper(I) amido and aminyl radical complexes. J Am Chem Soc (2009) 0.90
Phosphido pincer complexes of platinum: synthesis, structure and reactivity. Dalton Trans (2011) 0.89
Dihydrogen binding to isostructural S = ½ and S = 0 cobalt complexes. J Am Chem Soc (2012) 0.89
Boryl-mediated reversible H2 activation at cobalt: catalytic hydrogenation, dehydrogenation, and transfer hydrogenation. J Am Chem Soc (2013) 0.88
Probing the electronic structures of [Cu2(mu-XR2)]n+ diamond cores as a function of the bridging X atom (X = N or P) and charge (n = 0, 1, 2). J Am Chem Soc (2008) 0.87
The strong-field tripodal phosphine donor, [PhB(CH2PiPr2)3]-, provides access to electronically and coordinatively unsaturated transition metal complexes. Inorg Chem (2003) 0.87
Elucidation of a low spin cobalt(II) system in a distorted tetrahedral geometry. J Am Chem Soc (2002) 0.87
Two-coordinate Fe⁰ and Co⁰ complexes supported by cyclic (alkyl)(amino)carbenes. Angew Chem Int Ed Engl (2014) 0.87
Heterolytic H2 Cleavage and Catalytic Hydrogenation by an Iron Metallaboratrane. Organometallics (2013) 0.86
Synthetic, structural, and mechanistic aspects of an amine activation process mediated at a zwitterionic Pd(II) center. J Am Chem Soc (2004) 0.86
H-H and Si-H bond addition to Fe≡NNR2 intermediates derived from N2. J Am Chem Soc (2013) 0.86
A nonclassical dihydrogen adduct of S = ½ Fe(I). J Am Chem Soc (2011) 0.86
Synthetic control of excited-state properties in cyclometalated Ir(III) complexes using ancillary ligands. Inorg Chem (2005) 0.85
A five-coordinate phosphino/acetate iron(II) scaffold that binds N2, N2H2, N2H4, and NH3 in the sixth site. Inorg Chem (2011) 0.85
Modeling the signatures of hydrides in metalloenzymes: ENDOR analysis of a Di-iron Fe(μ-NH)(μ-H)Fe core. J Am Chem Soc (2012) 0.84
Rapid water reduction to H2 catalyzed by a cobalt bis(iminopyridine) complex. J Am Chem Soc (2011) 0.84
A polar copper-boron one-electron σ-bond. J Am Chem Soc (2013) 0.83
Spin-state tuning at pseudotetrahedral d(7) ions: examining the structural and magnetic phenomena of four-coordinate [BP3]CoII-X systems. J Am Chem Soc (2005) 0.83
Amido-bridged Cu2N2 diamond cores that minimize structural reorganization and facilitate reversible redox behavior between a Cu1Cu1 and a class III delocalized Cu1.5Cu1.5 species. J Am Chem Soc (2004) 0.83
The coordination chemistry of "[BP3]NiX" platforms: targeting low-valent nickel sources as promising candidates to L3Ni=E and L3Ni(triple bond)E linkages. Inorg Chem (2004) 0.82
A 10(6)-fold enhancement in N2-binding affinity of an Fe2(μ-H)2 core upon reduction to a mixed-valence Fe(II)Fe(I) state. J Am Chem Soc (2014) 0.82
A homologous series of cobalt, rhodium, and iridium metalloradicals. Inorg Chem (2011) 0.82
Base metal catalysts for photochemical C-H borylation that utilize metal-metal cooperativity. J Am Chem Soc (2013) 0.82
E-type delayed fluorescence of a phosphine-supported Cu2(mu-NAr2)2 diamond core: harvesting singlet and triplet excitons in OLEDs. J Am Chem Soc (2010) 0.81
Studies of cobalt-mediated electrocatalytic CO2 reduction using a redox-active ligand. Inorg Chem (2014) 0.81
Mononuclear five- and six-coordinate iron hydrazido and hydrazine species. Inorg Chem (2012) 0.81
Zwitterionic relatives to the classic [(P-P)Rh(solv)2]+ ions: neutral catalysts active for H-E bond additions to olefins (E=C, Si, B). Angew Chem Int Ed Engl (2003) 0.81
Assembly, structure, and reactivity of Cu₄S and Cu₃S models for the nitrous oxide reductase active site, Cu(Z)*. Inorg Chem (2014) 0.81
Access to well-defined ruthenium(I) and osmium(I) metalloradicals. Angew Chem Int Ed Engl (2010) 0.81
A highly emissive Cu2N2 diamond core complex supported by a [PNP]- ligand. J Am Chem Soc (2005) 0.81
A CO-derived iron dicarbyne that releases olefin upon hydrogenation. J Am Chem Soc (2013) 0.80
Structural snapshots of a flexible Cu2P2 core that accommodates the oxidation states Cu(I)Cu(I), Cu1.5Cu1.5, and Cu(II)Cu(II). J Am Chem Soc (2005) 0.80
Zwitterionic and cationic bis(phosphine) platinum(II) complexes: structural, electronic, and mechanistic comparisons relevant to ligand exchange and benzene C-H activation processes. J Am Chem Soc (2003) 0.80
Synthesis and characterization of heterobimetallic complexes with direct Cu-M bonds (M = Cr, Mn, Co, Mo, Ru, W) supported by N-heterocyclic carbene ligands: a toolkit for catalytic reaction discovery. Inorg Chem (2014) 0.80
Diazoalkanes react with a bis(phosphino)borate copper(i) source to generate [Ph2BP(tBu)2]Cu(eta1-N2CR2), [Ph2BP(tBu)2]Cu(CPh2), and [Ph2BP(tBu)2]Cu-N(CPh2)(NCPh2). Chem Commun (Camb) (2008) 0.79
High-spin and low-spin iron(II) complexes with facially-coordinated borohydride ligands. Dalton Trans (2005) 0.79
Dimanganese and diiron complexes of a binucleating cyclam ligand: four-electron, reversible oxidation chemistry at high potentials. Inorg Chem (2008) 0.79
Bis(alpha-diimine)iron complexes: electronic structure determination by spectroscopy and broken symmetry density functional theoretical calculations. Inorg Chem (2008) 0.79
Free H₂ rotation vs Jahn-Teller constraints in the nonclassical trigonal (TPB)Co-H₂ complex. J Am Chem Soc (2014) 0.79
A Ru(I) metalloradical that catalyzes nitrene coupling to azoarenes from arylazides. J Am Chem Soc (2012) 0.79
XAS characterization of a nitridoiron(IV) complex with a very short Fe-N bond. Inorg Chem (2007) 0.78
Low-spin pseudotetrahedral iron(I) sites in Fe₂(μ-S) complexes. Angew Chem Int Ed Engl (2014) 0.78
Long-lived and efficient emission from mononuclear amidophosphine complexes of copper. Inorg Chem (2007) 0.78
Boryl-metal bonds facilitate cobalt/nickel-catalyzed olefin hydrogenation. J Am Chem Soc (2014) 0.77
Four-coordinate, trigonal pyramidal Pt(II) and Pd(II) complexes. J Am Chem Soc (2010) 0.76
Solution and solid-state spin-crossover behavior in a pseudotetrahedral d7 ion. J Am Chem Soc (2003) 0.76
Coordinating anions: (phosphino)tetraphenylborate ligands as new reagents for synthesis. Inorg Chem (2004) 0.76
Selective nitrite reduction at heterobimetallic CoMg complexes. J Am Chem Soc (2013) 0.76
Multifrequency EPR studies of [Cu(1.5)Cu(1.5)](+) for Cu2(mu-NR2)2 and Cu2(mu-PR2)2 diamond cores. Inorg Chem (2009) 0.75
Pseudotetrahedral manganese complexes supported by the anionic tris(phosphino)borate ligand [PhBP(iPr)3]. Inorg Chem (2006) 0.75