Published in Science on October 27, 2005
Spectroscopic and quantum chemical studies on low-spin FeIV=O complexes: Fe-O bonding and its contributions to reactivity. J Am Chem Soc (2007) 1.74
Axial ligand tuning of a nonheme iron(IV)-oxo unit for hydrogen atom abstraction. Proc Natl Acad Sci U S A (2007) 1.70
Crystal structure of a metal ion-bound oxoiron(IV) complex and implications for biological electron transfer. Nat Chem (2010) 1.58
Axial ligand effects on the geometric and electronic structures of nonheme oxoiron(IV) complexes. J Am Chem Soc (2008) 1.32
Slow hydrogen atom transfer reactions of oxo- and hydroxo-vanadium compounds: the importance of intrinsic barriers. J Am Chem Soc (2009) 1.18
A functional model for the cysteinate-ligated non-heme iron enzyme superoxide reductase (SOR). J Am Chem Soc (2006) 1.16
Characterization of the terminal iron(IV) imides [[PhBP(t)(Bu)2(pz')]Fe(IV)NAd]+. J Am Chem Soc (2006) 1.14
The biology and chemistry of high-valent iron-oxo and iron-nitrido complexes. Nat Commun (2012) 1.10
Understanding how the thiolate sulfur contributes to the function of the non-heme iron enzyme superoxide reductase. Acc Chem Res (2007) 1.03
Prediction of high-valent iron K-edge absorption spectra by time-dependent density functional theory. Dalton Trans (2011) 0.99
[Fe(IV)═O(TBC)(CH3CN)]2+: comparative reactivity of iron(IV)-oxo species with constrained equatorial cyclam ligation. J Am Chem Soc (2012) 0.96
Nonheme Oxoiron(IV) Complexes of Pentadentate N5 Ligands: Spectroscopy, Electrochemistry, and Oxidative Reactivity. Chem Sci (2013) 0.96
Modeling the cis-oxo-labile binding site motif of non-heme iron oxygenases: water exchange and oxidation reactivity of a non-heme iron(IV)-oxo compound bearing a tripodal tetradentate ligand. Chemistry (2011) 0.91
Dramatically accelerated selective oxygen-atom transfer by a nonheme iron(IV)-oxo complex: tuning of the first and second coordination spheres. J Am Chem Soc (2014) 0.89
Sulfur oxygenation in biomimetic non-heme iron-thiolate complexes. Dalton Trans (2012) 0.86
Oxoiron(IV) complexes of the tris(2-pyridylmethyl)amine ligand family: effect of pyridine alpha-substituents. J Biol Inorg Chem (2006) 0.85
Steric hindrance effect of the equatorial ligand on Fe(IV)O and Ru(IV)O complexes: a density functional study. J Biol Inorg Chem (2010) 0.84
Sulfur versus iron oxidation in an iron-thiolate model complex. J Am Chem Soc (2010) 0.84
Kinetic analysis of the conversion of nonheme (alkylperoxo)iron(III) species to iron(IV) complexes. Inorg Chem (2007) 0.83
Characterization of a thiolato iron(III) Peroxy dianion complex. Angew Chem Int Ed Engl (2012) 0.83
Spectroscopic description of an unusual protonated ferryl species in the catalase from Proteus mirabilis and density functional theory calculations on related models. Consequences for the ferryl protonation state in catalase, peroxidase and chloroperoxidase. J Biol Inorg Chem (2007) 0.81
Theoretical study of the mechanism of oxoiron(IV) formation from H2O2 and a nonheme iron(II) complex: O-O cleavage involving proton-coupled electron transfer. Inorg Chem (2011) 0.80
Catalytic strategy for carbon-carbon bond scission by the cytochrome P450 OleT. Proc Natl Acad Sci U S A (2016) 0.80
Intramolecular gas-phase reactions of synthetic nonheme oxoiron(IV) ions: proximity and spin-state reactivity rules. Chemistry (2012) 0.79
Identification and spectroscopic characterization of nonheme iron(III) hypochlorite intermediates. Angew Chem Int Ed Engl (2015) 0.79
Iron-oxidation-state-dependent O-O bond cleavage of meta-chloroperbenzoic acid to form an iron(IV)-oxo complex. Inorganica Chim Acta (2008) 0.78
Paramagnetic nuclear magnetic resonance relaxation and molecular mechanics studies of the chloroperoxidase-indole complex: insights into the mechanism of chloroperoxidase-catalyzed regioselective oxidation of indole. Biochemistry (2013) 0.78
Spectroscopic Evidence for the Two C-H-Cleaving Intermediates of Aspergillus nidulans Isopenicillin N Synthase. J Am Chem Soc (2016) 0.78
Oriented electric fields as future smart reagents in chemistry. Nat Chem (2016) 0.78
Theoretical study of cyclohexane hydroxylation by three possible isomers of [FeIV(O)(R-TPEN)] 2+: does the pentadentate ligand wrapping around the metal center differently lead to the different stability and reactivity? J Biol Inorg Chem (2009) 0.77
Dioxygen activation by nonheme iron enzymes with the 2-His-1-carboxylate facial triad that generate high-valent oxoiron oxidants. J Biol Inorg Chem (2017) 0.77
Applications of density functional theory to iron-containing molecules of bioinorganic interest. Front Chem (2014) 0.75
Synthesis, characterization, and theoretical studies of metal complexes derived from the chiral tripyridyldiamine ligand Bn-CDPy3. Inorg Chem (2010) 0.75
Indefinitely stable iron(IV) cage complexes formed in water by air oxidation. Nat Commun (2017) 0.75
Metal-Assisted Oxo Atom Addition to an Fe(III) Thiolate. J Am Chem Soc (2016) 0.75
Identification and Spectroscopic Characterization of Nonheme Iron(III) Hypochlorite Intermediates. Angew Chem Weinheim Bergstr Ger (2015) 0.75
High-Valent Nonheme Iron Oxidants in Biology: Lessons from Synthetic Fe(IV)=O Complexes. Bull Jpn Soc Coord Chem (2013) 0.75
What factors influence the reactivity of C-H hydroxylation and C=C epoxidation by [Fe(IV)(Lax)(1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane)(O)](n.). J Biol Inorg Chem (2015) 0.75
Dioxygen activation at mononuclear nonheme iron active sites: enzymes, models, and intermediates. Chem Rev (2004) 6.11
Crystallographic and spectroscopic characterization of a nonheme Fe(IV)-O complex. Science (2003) 3.40
The 2-His-1-carboxylate facial triad: a versatile platform for dioxygen activation by mononuclear non-heme iron(II) enzymes. J Biol Inorg Chem (2005) 2.82
A highly selective fluorescent chemosensor for Pb2+. J Am Chem Soc (2005) 2.33
Nonheme FeIVO complexes that can oxidize the C-H bonds of cyclohexane at room temperature. J Am Chem Soc (2004) 2.26
Crystallographic comparison of manganese- and iron-dependent homoprotocatechuate 2,3-dioxygenases. J Bacteriol (2004) 1.84
Million-fold activation of the [Fe(2)(micro-O)(2)] diamond core for C-H bond cleavage. Nat Chem (2010) 1.82
A synthetic precedent for the [FeIV2(mu-O)2] diamond core proposed for methane monooxygenase intermediate Q. Proc Natl Acad Sci U S A (2007) 1.76
Spectroscopic and quantum chemical studies on low-spin FeIV=O complexes: Fe-O bonding and its contributions to reactivity. J Am Chem Soc (2007) 1.74
Aqueous FeIV==O: spectroscopic identification and oxo-group exchange. Angew Chem Int Ed Engl (2005) 1.74
Axial ligand tuning of a nonheme iron(IV)-oxo unit for hydrogen atom abstraction. Proc Natl Acad Sci U S A (2007) 1.70
End-on and side-on peroxo derivatives of non-heme iron complexes with pentadentate ligands: models for putative intermediates in biological iron/dioxygen chemistry. Inorg Chem (2003) 1.70
Chemical and spectroscopic evidence for an FeV-oxo complex. Science (2006) 1.64
Two-state reactivity in alkane hydroxylation by non-heme iron-oxo complexes. J Am Chem Soc (2006) 1.63
Structures of nonheme oxoiron(IV) complexes from X-ray crystallography, NMR spectroscopy, and DFT calculations. Angew Chem Int Ed Engl (2005) 1.62
A synthetic high-spin oxoiron(IV) complex: generation, spectroscopic characterization, and reactivity. Angew Chem Int Ed Engl (2009) 1.59
Crystal structure of a metal ion-bound oxoiron(IV) complex and implications for biological electron transfer. Nat Chem (2010) 1.58
Trapping and spectroscopic characterization of an FeIII-superoxo intermediate from a nonheme mononuclear iron-containing enzyme. Proc Natl Acad Sci U S A (2010) 1.57
A highly active zinc catalyst for the controlled polymerization of lactide. J Am Chem Soc (2003) 1.57
Human deoxyhypusine hydroxylase, an enzyme involved in regulating cell growth, activates O2 with a nonheme diiron center. Proc Natl Acad Sci U S A (2009) 1.52
Shape-selective interception by hydrocarbons of the O2-derived oxidant of a biomimetic nonheme iron complex. Angew Chem Int Ed Engl (2009) 1.48
Swapping metals in Fe- and Mn-dependent dioxygenases: evidence for oxygen activation without a change in metal redox state. Proc Natl Acad Sci U S A (2008) 1.47
High-valent nonheme iron-oxo species in biomimetic oxidations. J Inorg Biochem (2006) 1.46
Structural insights into nonheme alkylperoxoiron(III) and oxoiron(IV) intermediates by X-ray absorption spectroscopy. J Am Chem Soc (2004) 1.45
An FeIV=O complex of a tetradentate tripodal nonheme ligand. Proc Natl Acad Sci U S A (2003) 1.44
Intermediates in the oxygenation of a nonheme diiron(II) complex, including the first evidence for a bound superoxo species. Proc Natl Acad Sci U S A (2005) 1.43
O2- and alpha-ketoglutarate-dependent tyrosyl radical formation in TauD, an alpha-keto acid-dependent non-heme iron dioxygenase. Biochemistry (2003) 1.41
Structure and reactivity of a mononuclear non-haem iron(III)-peroxo complex. Nature (2011) 1.40
Mössbauer studies of the membrane-associated methane monooxygenase from Methylococcus capsulatus bath: evidence for a Diiron center. J Am Chem Soc (2007) 1.36
Spectroscopic and quantum chemical characterization of the electronic structure and bonding in a non-heme FeIV[double bond]O complex. J Am Chem Soc (2004) 1.35
A sulfido-bridged diiron(II) compound and its reactions with nitrogenase-relevant substrates. J Am Chem Soc (2004) 1.34
EPR and Mössbauer spectroscopy of intact mitochondria isolated from Yah1p-depleted Saccharomyces cerevisiae. Biochemistry (2008) 1.33
Proton- and reductant-assisted dioxygen activation by a nonheme iron(II) complex to form an oxoiron(IV) intermediate. Angew Chem Int Ed Engl (2008) 1.33
Axial ligand effects on the geometric and electronic structures of nonheme oxoiron(IV) complexes. J Am Chem Soc (2008) 1.32
Catalytically active mu-Oxodiiron(IV) oxidants from Iron(III) and dioxygen. J Am Chem Soc (2005) 1.30
Planar three-coordinate high-spin Fe(II) complexes with large orbital angular momentum: Mössbauer, electron paramagnetic resonance, and electronic structure studies. J Am Chem Soc (2002) 1.30
The crystal structure of a high-spin oxoiron(IV) complex and characterization of its self-decay pathway. J Am Chem Soc (2010) 1.30
High-valent nonheme iron. Two distinct iron(IV) species derived from a common iron(II) precursor. J Am Chem Soc (2005) 1.29
[Mn(tmc)(O2)]+: a side-on peroxido manganese(III) complex bearing a non-heme ligand. Angew Chem Int Ed Engl (2007) 1.29
A diiron(IV) complex that cleaves strong C-H and O-H bonds. Nat Chem (2009) 1.26
First row divalent transition metal complexes of aryl-appended tris((pyridyl)methyl)amine ligands: syntheses, structures, electrochemistry, and hydroxamate binding properties. Inorg Chem (2003) 1.26
Synthesis, characterization, and reactivities of manganese(V)-oxo porphyrin complexes. J Am Chem Soc (2007) 1.25
Superoxide destroys the [2Fe-2S]2+ cluster of FNR from Escherichia coli. Biochemistry (2004) 1.25
Oxygen activation by nonheme iron(II) complexes: alpha-keto carboxylate versus carboxylate. J Am Chem Soc (2003) 1.25
Olefin cis-dihydroxylation versus epoxidation by non-heme iron catalysts: two faces of an Fe(III)-OOH coin. J Am Chem Soc (2002) 1.24
Electronic structure and reactivity of low-spin Fe(III)-hydroperoxo complexes: comparison to activated bleomycin. J Am Chem Soc (2002) 1.21
(TAML)FeIV O complex in aqueous solution: synthesis and spectroscopic and computational characterization. Inorg Chem (2008) 1.19
A hyperthermophilic plant-type [2Fe-2S] ferredoxin from Aquifex aeolicus is stabilized by a disulfide bond. Biochemistry (2002) 1.19
Geometric and electronic structure and reactivity of a mononuclear "side-on" nickel(III)-peroxo complex. Nat Chem (2009) 1.19
Hydrogen peroxide dependent cis-dihydroxylation of benzoate by fully oxidized benzoate 1,2-dioxygenase. Biochemistry (2007) 1.16
Metal ion-coupled electron transfer of a nonheme oxoiron(IV) complex: remarkable enhancement of electron-transfer rates by Sc3+. J Am Chem Soc (2010) 1.16
Density functional study of the electric hyperfine interactions and the redox-structural correlations in the cofactor of nitrogenase. Analysis of general trends in (57)Fe isomer shifts. Inorg Chem (2003) 1.15
Benzoate 1,2-dioxygenase from Pseudomonas putida: single turnover kinetics and regulation of a two-component Rieske dioxygenase. Biochemistry (2002) 1.15
Mononuclear metal-O2 complexes bearing macrocyclic N-tetramethylated cyclam ligands. Acc Chem Res (2012) 1.15
A two-state reactivity rationale for counterintuitive axial ligand effects on the C-H activation reactivity of nonheme FeIV=O oxidants. Chemistry (2008) 1.14
Theoretical investigation of C--H hydroxylation by (N4Py)Fe(IV)=O(2+): an oxidant more powerful than P450? J Am Chem Soc (2005) 1.14
Biophysical characterization of iron in mitochondria isolated from respiring and fermenting yeast. Biochemistry (2010) 1.12