Published in J Am Chem Soc on July 06, 2012
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Enhanced electron-transfer reactivity of nonheme manganese(IV)-oxo complexes by binding scandium ions. J Am Chem Soc (2013) 0.94
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Dramatically accelerated selective oxygen-atom transfer by a nonheme iron(IV)-oxo complex: tuning of the first and second coordination spheres. J Am Chem Soc (2014) 0.89
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Nonheme FeIVO complexes that can oxidize the C-H bonds of cyclohexane at room temperature. J Am Chem Soc (2004) 2.26
Evidence for hydrogen abstraction from C1 of taurine by the high-spin Fe(IV) intermediate detected during oxygen activation by taurine:alpha-ketoglutarate dioxygenase (TauD). J Am Chem Soc (2003) 2.11
Direct detection of oxygen intermediates in the non-heme Fe enzyme taurine/alpha-ketoglutarate dioxygenase. J Am Chem Soc (2004) 1.81
Direct spectroscopic evidence for a high-spin Fe(IV) intermediate in tyrosine hydroxylase. J Am Chem Soc (2007) 1.80
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EXAFS spectroscopic evidence for an Fe=O unit in the Fe(IV) intermediate observed during oxygen activation by taurine:alpha-ketoglutarate dioxygenase. J Am Chem Soc (2004) 1.74
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Formation, structure, and EPR detection of a high spin Fe(IV)-oxo species derived from either an Fe(III)-oxo or Fe(III)-OH complex. J Am Chem Soc (2010) 1.44
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Spectroscopic evidence for a high-spin Br-Fe(IV)-oxo intermediate in the alpha-ketoglutarate-dependent halogenase CytC3 from Streptomyces. J Am Chem Soc (2007) 1.40
Proton- and reductant-assisted dioxygen activation by a nonheme iron(II) complex to form an oxoiron(IV) intermediate. Angew Chem Int Ed Engl (2008) 1.33
The crystal structure of a high-spin oxoiron(IV) complex and characterization of its self-decay pathway. J Am Chem Soc (2010) 1.30
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A high-spin iron(IV)-oxo complex supported by a trigonal nonheme pyrrolide platform. J Am Chem Soc (2012) 1.14
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Axial ligand substituted nonheme FeIV=O complexes: observation of near-UV LMCT bands and Fe=O Raman vibrations. J Am Chem Soc (2005) 1.11
The fundamental role of exchange-enhanced reactivity in C-H activation by S=2 oxo iron(IV) complexes. Angew Chem Int Ed Engl (2010) 1.06
Dioxygen activation and catalytic aerobic oxidation by a mononuclear nonheme iron(II) complex. J Am Chem Soc (2005) 1.04
Synthesis, structure determination, and spectroscopic/computational characterization of a series of Fe(II)-thiolate model complexes: implications for Fe-S bonding in superoxide reductases. J Am Chem Soc (2005) 1.04
Evidence for a high-spin Fe(IV) species in the catalytic cycle of a bacterial phenylalanine hydroxylase. Biochemistry (2011) 1.03
Reactivities of mononuclear non-heme iron intermediates including evidence that iron(III)-hydroperoxo species is a sluggish oxidant. J Am Chem Soc (2006) 0.99
Nuclear resonance vibrational spectroscopy on the Fe(IV)=O S=2 non-heme site in TMG3tren: experimentally calibrated insights into reactivity. Angew Chem Int Ed Engl (2011) 0.99
New example of a non-heme mononuclear iron(IV) oxo complex. Spectroscopic data and oxidation activity. Inorg Chem (2005) 0.99
Metal ion effect on the switch of mechanism from direct oxygen transfer to metal ion-coupled electron transfer in the sulfoxidation of thioanisoles by a non-heme iron(IV)-oxo complex. J Am Chem Soc (2011) 0.96
Formation of an aqueous oxoiron(IV) complex at pH 2-6 from a nonheme iron(II) complex and H2O2. Angew Chem Int Ed Engl (2006) 0.95
Scandium ion-enhanced oxidative dimerization and N-demethylation of N,N-dimethylanilines by a non-heme iron(IV)-oxo complex. Inorg Chem (2011) 0.91
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Formation, stability, and reactivity of a mononuclear nonheme oxoiron(IV) complex in aqueous solution. Chem Commun (Camb) (2005) 0.88
Axial coordination of carboxylate activates the non-heme FeIV=O unit. Angew Chem Int Ed Engl (2005) 0.88
Ligand topology effect on the reactivity of a mononuclear nonheme iron(IV)-oxo complex in oxygenation reactions. J Am Chem Soc (2011) 0.88
Proton-promoted oxygen atom transfer vs proton-coupled electron transfer of a non-heme iron(IV)-oxo complex. J Am Chem Soc (2012) 0.87
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An inverted and more oxidizing isomer of [Fe(IV)(O)(tmc)(NCCH3)]2+. Angew Chem Int Ed Engl (2008) 0.86
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Functional delineation and differentiation dynamics of human CD4+ T cells expressing the FoxP3 transcription factor. Immunity (2009) 9.01
Structural genomics of the Thermotoga maritima proteome implemented in a high-throughput structure determination pipeline. Proc Natl Acad Sci U S A (2002) 6.00
Preferential recruitment of CCR6-expressing Th17 cells to inflamed joints via CCL20 in rheumatoid arthritis and its animal model. J Exp Med (2007) 5.58
Foxp3 controls regulatory T-cell function by interacting with AML1/Runx1. Nature (2007) 5.14
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Altered thymic T-cell selection due to a mutation of the ZAP-70 gene causes autoimmune arthritis in mice. Nature (2003) 4.22
Palonosetron plus dexamethasone versus granisetron plus dexamethasone for prevention of nausea and vomiting during chemotherapy: a double-blind, double-dummy, randomised, comparative phase III trial. Lancet Oncol (2009) 3.69
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Foxp3-dependent and -independent molecules specific for CD25+CD4+ natural regulatory T cells revealed by DNA microarray analysis. Int Immunol (2006) 2.93
A role for fungal {beta}-glucans and their receptor Dectin-1 in the induction of autoimmune arthritis in genetically susceptible mice. J Exp Med (2005) 2.80
Alternative mutations at position 76 of the vacuolar transmembrane protein PfCRT are associated with chloroquine resistance and unique stereospecific quinine and quinidine responses in Plasmodium falciparum. Mol Pharmacol (2002) 2.57
Treatment of advanced tumors with agonistic anti-GITR mAb and its effects on tumor-infiltrating Foxp3+CD25+CD4+ regulatory T cells. J Exp Med (2005) 2.51
A highly selective fluorescent chemosensor for Pb2+. J Am Chem Soc (2005) 2.33
Nonheme FeIVO complexes that can oxidize the C-H bonds of cyclohexane at room temperature. J Am Chem Soc (2004) 2.26
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Oxygen activation by the noncoupled binuclear copper site in peptidylglycine alpha-hydroxylating monooxygenase. Reaction mechanism and role of the noncoupled nature of the active site. J Am Chem Soc (2004) 2.01
Structural insights into a protein-bound iron-molybdenum cofactor precursor. Proc Natl Acad Sci U S A (2006) 1.95
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Development of autoimmunity against transcriptionally unrepressed target antigen in the thymus of Aire-deficient mice. J Immunol (2005) 1.88
Computed tomography findings in pathological usual interstitial pneumonia: relationship to survival. Am J Respir Crit Care Med (2007) 1.85
Imaging whole Escherichia coli bacteria by using single-particle x-ray diffraction. Proc Natl Acad Sci U S A (2002) 1.75
Spectroscopic and quantum chemical studies on low-spin FeIV=O complexes: Fe-O bonding and its contributions to reactivity. J Am Chem Soc (2007) 1.74
FeMo cofactor maturation on NifEN. Proc Natl Acad Sci U S A (2006) 1.73
Spectroscopic characterization of a hydroperoxo-heme intermediate: conversion of a side-on peroxo to an end-on hydroperoxo complex. Angew Chem Int Ed Engl (2009) 1.71
Axial ligand tuning of a nonheme iron(IV)-oxo unit for hydrogen atom abstraction. Proc Natl Acad Sci U S A (2007) 1.70
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High resolution 3D x-ray diffraction microscopy. Phys Rev Lett (2002) 1.63
Spectroscopic and electronic structure studies of aromatic electrophilic attack and hydrogen-atom abstraction by non-heme iron enzymes. Proc Natl Acad Sci U S A (2006) 1.63
Solvent tuning of electrochemical potentials in the active sites of HiPIP versus ferredoxin. Science (2007) 1.63
Direct inhibition by nitric oxide of the transcriptional ferric uptake regulation protein via nitrosylation of the iron. Proc Natl Acad Sci U S A (2002) 1.62
Giant thermoelectric Seebeck coefficient of a two-dimensional electron gas in SrTiO3. Nat Mater (2007) 1.62
Complement drives Th17 cell differentiation and triggers autoimmune arthritis. J Exp Med (2010) 1.62
A [Cu2O]2+ core in Cu-ZSM-5, the active site in the oxidation of methane to methanol. Proc Natl Acad Sci U S A (2009) 1.62
Nitrogenase Fe protein: A molybdate/homocitrate insertase. Proc Natl Acad Sci U S A (2006) 1.60
Crystal structure of a metal ion-bound oxoiron(IV) complex and implications for biological electron transfer. Nat Chem (2010) 1.58
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A highly active zinc catalyst for the controlled polymerization of lactide. J Am Chem Soc (2003) 1.57
Spectroscopic and electronic structure studies of the diamagnetic side-on CuII-superoxo complex Cu(O2)[HB(3-R-5-iPrpz)3]: antiferromagnetic coupling versus covalent delocalization. J Am Chem Soc (2003) 1.56
Cutting Edge: Ectopic expression of CD40 ligand on B cells induces lupus-like autoimmune disease. J Immunol (2002) 1.55
Protonless NMR experiments for sequence-specific assignment of backbone nuclei in unfolded proteins. J Am Chem Soc (2006) 1.54
A 1:1 copper-dioxygen adduct is an end-on bound superoxo copper(II) complex which undergoes oxygenation reactions with phenols. J Am Chem Soc (2007) 1.54
Description of the ground state wave functions of Ni dithiolenes using sulfur K-edge X-ray absorption spectroscopy. J Am Chem Soc (2003) 1.52
Crystal structure of TM1367 from Thermotoga maritima at 1.90 A resolution reveals an atypical member of the cyclophilin (peptidylprolyl isomerase) fold. Proteins (2006) 1.51
VTVH-MCD and DFT studies of thiolate bonding to [FeNO]7/[FeO2]8 complexes of isopenicillin N synthase: substrate determination of oxidase versus oxygenase activity in nonheme Fe enzymes. J Am Chem Soc (2007) 1.50
A low-spin ruthenium(IV)-oxo complex: does the spin state have an impact on the reactivity? Angew Chem Int Ed Engl (2010) 1.48
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Mechanism of N2O reduction by the mu4-S tetranuclear CuZ cluster of nitrous oxide reductase. J Am Chem Soc (2006) 1.46
O2 activation by binuclear Cu sites: noncoupled versus exchange coupled reaction mechanisms. Proc Natl Acad Sci U S A (2004) 1.46
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A thiolate-ligated nonheme oxoiron(IV) complex relevant to cytochrome P450. Science (2005) 1.45
X-ray absorption edge spectroscopy and computational studies on LCuO2 species: Superoxide-Cu(II) versus peroxide-Cu(III) bonding. J Am Chem Soc (2006) 1.45
Structural insights into nonheme alkylperoxoiron(III) and oxoiron(IV) intermediates by X-ray absorption spectroscopy. J Am Chem Soc (2004) 1.45
Crystal structure of thy1, a thymidylate synthase complementing protein from Thermotoga maritima at 2.25 A resolution. Proteins (2002) 1.45
An FeIV=O complex of a tetradentate tripodal nonheme ligand. Proc Natl Acad Sci U S A (2003) 1.44
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Nature of the peroxo intermediate of the W48F/D84E ribonucleotide reductase variant: implications for O2 activation by binuclear non-heme iron enzymes. J Am Chem Soc (2004) 1.43
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Structure and reactivity of a mononuclear non-haem iron(III)-peroxo complex. Nature (2011) 1.40
L-edge X-ray absorption spectroscopy of non-heme iron sites: experimental determination of differential orbital covalency. J Am Chem Soc (2003) 1.39
Photoreduction of the active site of the metalloprotein putidaredoxin by synchrotron radiation. Acta Crystallogr D Biol Crystallogr (2007) 1.37
A peroxide bridge between Fe and Cu ions in the O2 reduction site of fully oxidized cytochrome c oxidase could suppress the proton pump. Proc Natl Acad Sci U S A (2009) 1.37
Oxygen activation by the noncoupled binuclear copper site in peptidylglycine alpha-hydroxylating monooxygenase. Spectroscopic definition of the resting sites and the putative CuIIM-OOH intermediate. Biochemistry (2004) 1.36
Spectroscopic and quantum chemical characterization of the electronic structure and bonding in a non-heme FeIV[double bond]O complex. J Am Chem Soc (2004) 1.35
Crystal structure of the apo-PerR-Zn protein from Bacillus subtilis. Mol Microbiol (2006) 1.34
Density-functional investigation on the mechanism of H-atom abstraction by lipoxygenase. J Biol Inorg Chem (2002) 1.34
Structural and functional characterization of 2-oxo-histidine in oxidized PerR protein. Nat Chem Biol (2008) 1.33
Nickel complexes of carboxylate-containing polydentate ligands as models for the active site of urease. Inorg Chem (2004) 1.33
Axial ligand effects on the geometric and electronic structures of nonheme oxoiron(IV) complexes. J Am Chem Soc (2008) 1.32
Description of the ground-state covalencies of the bis(dithiolato) transition-metal complexes from X-ray absorption spectroscopy and time-dependent density-functional calculations. Chemistry (2007) 1.30
Nature of the intermediate formed in the reduction of O(2) to H(2)O at the trinuclear copper cluster active site in native laccase. J Am Chem Soc (2002) 1.30