Published in Angew Chem Int Ed Engl on January 01, 2009
Metal-free activation of EH3 (E = P, As) by an ylide-like silylene and formation of a donor-stabilized arsasilene with a HSi=AsH subunit. Angew Chem Int Ed Engl (2010) 1.39
N-heterocyclic carbene analogues with low-valent group 13 and group 14 elements: syntheses, structures, and reactivities of a new generation of multitalented ligands. Chem Rev (2010) 1.31
An isolable NHC-supported silanone. J Am Chem Soc (2009) 1.02
A "side-on" superoxonickel complex [LNi(O2)] with a square-planar tetracoordinate nickel(II) center and its conversion into [LNi(mu-OH)2NiL]. Angew Chem Int Ed Engl (2008) 0.95
From NHC-->germylenes to stable NHC-->germanone complexes. Chem Commun (Camb) (2009) 0.93
Lessons from isolable nickel(I) precursor complexes for small molecule activation. Acc Chem Res (2011) 0.91
Copper-catalyzed intermolecular amidation and imidation of unactivated alkanes. J Am Chem Soc (2014) 0.91
Unification of catalytic water oxidation and oxygen reduction reactions: amorphous beat crystalline cobalt iron oxides. J Am Chem Soc (2014) 0.91
O-O bond activation in heterobimetallic peroxides: synthesis of the peroxide [LNi(mu,eta2:eta2-O2)K] and its conversion into a bis(mu-hydroxo) nickel zinc complex. Angew Chem Int Ed Engl (2009) 0.90
Reversible P(4) activation with nickel(I) and an eta(3)-coordinated tetraphosphorus ligand between two Ni(I) centers. Chemistry (2010) 0.88
Active mixed-valent MnO(x) water oxidation catalysts through partial oxidation (corrosion) of nanostructured MnO particles. Angew Chem Int Ed Engl (2013) 0.88
Reductive cleavage of P4 by iron(I) centres: synthesis and structural characterisation of Fe2(P2)2 complexes with two bridging P2(2-) ligands. Chem Commun (Camb) (2015) 0.87
Pushing the σ-donor strength in iridium pincer complexes: bis(silylene) and bis(germylene) ligands are stronger donors than bis(phosphorus(III)) ligands. Angew Chem Int Ed Engl (2012) 0.87
Iridium-catalyzed regioselective silylation of secondary alkyl C-H bonds for the synthesis of 1,3-diols. J Am Chem Soc (2014) 0.86
Hydride binding to the active site of [FeFe]-hydrogenase. Inorg Chem (2014) 0.85
A high-valent heterobimetallic [Cu(III)(μ-O)2Ni(III)]2+ core with nucleophilic oxo groups. Angew Chem Int Ed Engl (2013) 0.85
Heterogeneous water oxidation: surface activity versus amorphization activation in cobalt phosphate catalysts. Angew Chem Int Ed Engl (2015) 0.85
A low-temperature molecular approach to highly conductive tin-rich indium tin oxide thin films with durable electro-optical performance. Angew Chem Int Ed Engl (2009) 0.83
N-heterocyclic carbene (NHC)-stabilized silanechalcogenones: NHC-->Si(R2)=E (E=O, S, Se, Te). Chemistry (2010) 0.83
Formation of a donor-stabilized tetrasilacyclobutadiene dication by a Lewis acid assisted reaction of an N-heterocyclic chloro silylene. J Am Chem Soc (2011) 0.82
A molecular approach to self-supported cobalt-substituted ZnO materials as remarkably stable electrocatalysts for water oxidation. Angew Chem Int Ed Engl (2014) 0.82
From silicon(II)-based dioxygen activation to adducts of elusive dioxasiliranes and sila-ureas stable at room temperature. Nat Chem (2010) 0.82
On the role of oxygen defects in the catalytic performance of zinc oxide. Angew Chem Int Ed Engl (2006) 0.81
An N-heterocyclic carbene-disilyne complex and its reactivity toward ZnCl2. J Am Chem Soc (2010) 0.81
New vistas in N-heterocyclic silylene (NHSi) transition-metal coordination chemistry: syntheses, structures and reactivity towards activation of small molecules. Chemistry (2012) 0.81
A neutral tetraphosphacyclobutadiene ligand in cobalt(I) complexes. Angew Chem Int Ed Engl (2014) 0.81
Si=X multiple bonding with four-coordinate silicon? Insights into the nature of the Si=O and Si=S double bonds in stable silanoic esters and related thioesters: a combined NMR spectroscopic and computational study. J Am Chem Soc (2010) 0.80
Monooxygenase-like reactivity of an unprecedented heterobimetallic {FeO2Ni} moiety. Angew Chem Int Ed Engl (2010) 0.80
From a stable silylene to a mixed-valent disiloxane and an isolable silaformamide-borane complex with considerable silicon-oxygen double-bond character. Angew Chem Int Ed Engl (2007) 0.80
Bis(silylenyl)- and bis(germylenyl)-substituted ferrocenes: synthesis, structure, and catalytic applications of bidentate silicon(II)-cobalt complexes. Angew Chem Int Ed Engl (2012) 0.79
Lithium-promoted hydrogenation of carbon dioxide to formates by heterobimetallic hydridozinc alkoxide clusters. Chem Commun (Camb) (2008) 0.79
Steering S-H and N-H bond activation by a stable n-heterocyclic silylene: different addition of H(2)S, NH(3), and organoamines on a silicon(II) ligand versus its Si(II)-->Ni(CO)(3) complex. J Am Chem Soc (2010) 0.79
Facile access to silicon-functionalized bis-silylene titanium(II) complexes. Chemistry (2012) 0.79
Iridium-catalyzed regioselective silylation of aromatic and benzylic C-H bonds directed by a secondary amine. Angew Chem Int Ed Engl (2014) 0.79
Consecutive insertion of a silylene into the P4 tetrahedron: facile access to strained SiP4 and Si2P4 cage compounds. Angew Chem Int Ed Engl (2007) 0.79
An isolable silanoic ester by oxygenation of a stable silylene. J Am Chem Soc (2007) 0.79
Cobalt-manganese-based spinels as multifunctional materials that unify catalytic water oxidation and oxygen reduction reactions. ChemSusChem (2014) 0.79
A fragile zwitterionic phosphasilene as a transfer agent of the elusive parent phosphinidene (:PH). J Am Chem Soc (2013) 0.79
Unprecedented silicon(II)→calcium complexes with N-heterocyclic silylenes. Dalton Trans (2015) 0.78
Copper-catalyzed oxidative dehydrogenative carboxylation of unactivated alkanes to allylic esters via alkenes. J Am Chem Soc (2014) 0.78
A donor-stabilized zwitterionic "half-parent" phosphasilene and its unusual reactivity towards small molecules. Chemistry (2014) 0.78
Chemical vapor synthesis of size-selected zinc oxide nanoparticles. Small (2005) 0.78
Synthesis, structure, and reactivity of a pyridine-stabilized germanone. Chemistry (2011) 0.78
Synthesis and unexpected coordination of a silicon(II)-based SiCSi pincerlike arene to palladium. Angew Chem Int Ed Engl (2012) 0.78
An isolable bis-silylene oxide ("disilylenoxane") and its metal coordination. J Am Chem Soc (2010) 0.78
An ylide-like phosphasilene and striking formation of a 4π-electron, resonance-stabilized 2,4-disila-1,3-diphosphacyclobutadiene. J Am Chem Soc (2011) 0.78
A series of isolable silanoic thio-, seleno-, and telluroesters (LSi(=X)OR) with donor-supported Si=X double bonds (L = beta-diketiminate; X = S, Se, Te). Chem Asian J (2008) 0.77
Synthesis of mixed silylene-carbene chelate ligands from N-heterocyclic silylcarbenes mediated by nickel. Angew Chem Int Ed Engl (2014) 0.77
Using nickel manganese oxide catalysts for efficient water oxidation. Chem Commun (Camb) (2015) 0.77
Unprecedented alkylzinc-magnesium alkoxide clusters as suitable organometallic precursors for magnesium-containing ZnO nanoparticles. Chemistry (2011) 0.77
Molecular encoding at the nanoscale: from complex cubes to bimetallic oxides. Angew Chem Int Ed Engl (2005) 0.77
Dioxygenase-like reactivity of an isolable superoxo-nickel(II) complex. Chemistry (2010) 0.77
Aromatic ylide-stabilized carbocyclic silylene. Angew Chem Int Ed Engl (2011) 0.76
Formation of N-heterocyclic, donor-stabilized borenium ions. Chem Commun (Camb) (2011) 0.76
Main group chemistry: Breaking the limits with silylenes. Nat Chem (2012) 0.76
The striking stabilization of Ni0(eta6-arene) complexes by an ylide-like silylene ligand. Angew Chem Int Ed Engl (2009) 0.76
From a paramagnetic, mononuclear supersulfidonickel(II) complex to a diamagnetic dimer with a four-sulfur two-electron bond. J Am Chem Soc (2008) 0.76
Synthesis and unexpected reactivity of germyliumylidene hydride [:GeH]+ stabilized by a bis(N-heterocyclic carbene)borate ligand. J Am Chem Soc (2014) 0.75
A cyclic silylone ("siladicarbene") with an electron-rich silicon(0) atom. Angew Chem Int Ed Engl (2013) 0.75
Taming the germyliumylidene [CIGe:]+ and germathionium [CIGe=S]+ ions by donor-acceptor stabilization using 1,8-bis(tributylphosphazenyl)naphthalene. Chem Commun (Camb) (2012) 0.75
A cyclic germadicarbene ("germylone") from germyliumylidene. J Am Chem Soc (2013) 0.75
The elusive silyliumylidene [ClSi:]+ and silathionium [ClSi=S]+ cations stabilized by bis(iminophosphorane) chelate ligand. Angew Chem Int Ed Engl (2012) 0.75
Consecutive fragmentations of the cubane-like zinc cluster [CH3Zn(O-i-C3H7)]4 upon electron ionization. Phys Chem Chem Phys (2005) 0.75
Silicon analogues of carboxylic acids: synthesis of isolable silanoic acids by donor-acceptor stabilization. Angew Chem Int Ed Engl (2010) 0.75
A heterobimetallic approach to stabilize the elusive disulfur radical trianion ("subsulfide") S2(·3-). Chemistry (2012) 0.75
Striking reactivity of ylide-like germylene toward terminal alkynes: [4+2] cycloaddition versus C-H bond activation. Chem Commun (Camb) (2008) 0.75
Facile and efficient reduction of ketones in the presence of zinc catalysts modified by phenol ligands. Chem Asian J (2010) 0.75
Heterotermetallic indium lithium halostannates: low-temperature single-source precursors for tin-rich indium tin oxides and their application for thin-film transistors. Chemistry (2012) 0.75
Synthesis and tunable reactivity of N-heterocyclic germylene. Chem Asian J (2012) 0.75
An unsymmetric substituted digermylene with a Ge(I)-Ge(I) bond and synthesis of a germylene-stannylene with a Ge(I)-Sn(I) bond. Chem Commun (Camb) (2009) 0.75
Germanium(IV) chloride at 193 K. Acta Crystallogr C (2002) 0.75
Versatile reactivity of a zwitterionic isolable silylene toward ketones: silicon-mediated, regio- and stereoselective C-H activation. Chemistry (2009) 0.75
From elusive thio- and selenosilanoic acids to copper(I) complexes with intermolecular Si=E → Cu-O-Si coordination modes (E = S, Se). Chem Commun (Camb) (2013) 0.75
From bis(silylene) and bis(germylene) pincer-type nickel(II) complexes to isolable intermediates of the nickel-catalyzed Sonogashira cross-coupling reaction. J Am Chem Soc (2013) 0.75
Versatile conversion of N-heterocyclic silylene to silyl metal compounds by insertion of divalent silicon into metal-carbon and metal-hydrogen bonds. Chemistry (2012) 0.75
Chemical tricks to stabilize silanones and their heavier homologues with E=O bonds (E=Si-Pb): from elusive species to isolable building blocks. Angew Chem Int Ed Engl (2013) 0.75
Activation of C-H bonds mediated by Mo[triple bond]Mo moieties in heterobimetallic Zn/O/Mo clusters. Dalton Trans (2009) 0.75
Bis-N-heterocyclic carbene (NHC) stabilized η6-arene iron(0) complexes: synthesis, structure, reactivity, and catalytic activity. J Am Chem Soc (2013) 0.75
Striking reactivity of a stable, zwitterionic silylene towards substituted diazomethanes, azides, and isocyanides. Chemistry (2009) 0.75
Addition of [(eta(5)-C(5)Me(5))IrH(4)] to a zwitterionic silylene: stepwise formation of iridium(V)-silyl and iridium(III)-silylene complexes. Dalton Trans (2010) 0.75
Facile metalation of silicon and germanium analogues of thiocarboxylic acids with a manganese(II) hydride precursor. Chemistry (2012) 0.75
Synthesis and rearrangement of stable NHC-->silylene adducts and their unique reactivity towards cyclohexylisocyanide. Chem Asian J (2010) 0.75
Twice silicon-induced C-H activation and tautomerisation of a beta-diketiminato ligand and formation of new types of N-heterocyclic silanes. Dalton Trans (2008) 0.75
One-pot synthesis of lithium alkylzinc alkoxo heterocubanes with a LiZn3O4 core as suitable organometallic precursors for Li-containing ZnO nanocrystals. Dalton Trans (2009) 0.75
Side-on coordination of a P-P bond in heterobinuclear tetraphosphorus complexes with a [Si(mu,eta(2:2)-P(4))Ni] core and nickel(I) centers. Inorg Chem (2009) 0.75
Hydrosilylation of alkynes by Ni(CO)3-stabilized silicon(II) hydride. Angew Chem Int Ed Engl (2011) 0.75
A zwitterionic silylene as reactive intermediate and its unusual dimerization to an N-heterobicyclic disilane. Chem Asian J (2009) 0.75
Parent heavy methylenes: chemical tricks to access isolable complexes of elusive H2E: species (E=Ge and Sn). Angew Chem Int Ed Engl (2011) 0.75
Diketiminate silicon(II) and related NHSi ligands generated in the coordination sphere of nickel(0). J Am Chem Soc (2009) 0.75
Dichotomic reactivity of a stable silylene toward terminal alkynes: facile C-H bond insertion versus autocatalytic formation of silacycloprop-3-ene. Angew Chem Int Ed Engl (2008) 0.75
A new type of heteroleptic complex of divalent lead and synthesis of the P-plumbyleniophosphasilene, R2Si=P-Pb(L): (L = beta-diketiminate). Chem Commun (Camb) (2007) 0.75
Facile dissociation of [(LNi(II))2E2] dichalcogenides: evidence for [LNi(II)E2] superselenides and supertellurides in solution. Angew Chem Int Ed Engl (2009) 0.75
A cyclopentadienide analogue containing divalent germanium and a heavy cyclobutadiene-like dianion with an unusual Ge4 core. J Am Chem Soc (2008) 0.75
A neutral, monomeric germanium(I) radical. J Am Chem Soc (2011) 0.75
Coordination of a Si[double bond, length as m-dash]O subunit to metals: complexes of donor-stabilized silanone featuring a terminal Si[double bond, length as m-dash]O→M coordination (M = Zn, Al). Dalton Trans (2010) 0.75
From a stable silanone complex to isolable, donor-supported silicoxonium halides [LSi(dmap)=O-SiMe3](+)X-. Chemistry (2011) 0.75
Activation of ammonia by a Si=O double bond and formation of a unique pair of sila-hemiaminal and silanoic amide tautomers. J Am Chem Soc (2010) 0.75
Raman and photoluminescence spectroscopic detection of surface-bound Li(+)O2(-) defect sites in Li-doped ZnO nanocrystals derived from molecular precursors. Chemphyschem (2011) 0.75
Electron-rich N-heterocyclic silylene (NHSi)-iron complexes: synthesis, structures, and catalytic ability of an isolable hydridosilylene-iron complex. J Am Chem Soc (2013) 0.75
First preparation of nanocrystalline zinc silicate by chemical vapor synthesis using an organometallic single-source precursor. Chemistry (2004) 0.75