Published in J Am Chem Soc on September 18, 2008
Bioorthogonal chemistry: fishing for selectivity in a sea of functionality. Angew Chem Int Ed Engl (2009) 8.15
Tetrazine-based cycloadditions: application to pretargeted live cell imaging. Bioconjug Chem (2008) 3.93
Cu-free click cycloaddition reactions in chemical biology. Chem Soc Rev (2010) 3.89
Fast and sensitive pretargeted labeling of cancer cells through a tetrazine/trans-cyclooctene cycloaddition. Angew Chem Int Ed Engl (2009) 3.63
Bioorthogonal turn-on probes for imaging small molecules inside living cells. Angew Chem Int Ed Engl (2010) 2.57
Bioorthogonal chemistry amplifies nanoparticle binding and enhances the sensitivity of cell detection. Nat Nanotechnol (2010) 2.49
Genetically encoded norbornene directs site-specific cellular protein labelling via a rapid bioorthogonal reaction. Nat Chem (2012) 2.37
Biomedical applications of tetrazine cycloadditions. Acc Chem Res (2011) 2.10
Genetic Encoding of bicyclononynes and trans-cyclooctenes for site-specific protein labeling in vitro and in live mammalian cells via rapid fluorogenic Diels-Alder reactions. J Am Chem Soc (2012) 2.03
Dextran-coated iron oxide nanoparticles: a versatile platform for targeted molecular imaging, molecular diagnostics, and therapy. Acc Chem Res (2011) 1.93
Design and synthesis of highly reactive dienophiles for the tetrazine-trans-cyclooctene ligation. J Am Chem Soc (2011) 1.90
Selective labeling of living cells by a photo-triggered click reaction. J Am Chem Soc (2009) 1.89
Labeling live cells by copper-catalyzed alkyne--azide click chemistry. Bioconjug Chem (2010) 1.86
Optimized orthogonal translation of unnatural amino acids enables spontaneous protein double-labelling and FRET. Nat Chem (2014) 1.82
Development of a bioorthogonal and highly efficient conjugation method for quantum dots using tetrazine-norbornene cycloaddition. J Am Chem Soc (2010) 1.80
Synthesis and evaluation of a series of 1,2,4,5-tetrazines for bioorthogonal conjugation. Bioconjug Chem (2011) 1.78
Proteome labeling and protein identification in specific tissues and at specific developmental stages in an animal. Nat Biotechnol (2014) 1.77
Reactive polymer enables efficient in vivo bioorthogonal chemistry. Proc Natl Acad Sci U S A (2012) 1.74
Designer proteins: applications of genetic code expansion in cell biology. Nat Rev Mol Cell Biol (2012) 1.72
Chemical reporters for biological discovery. Nat Chem Biol (2013) 1.69
Tetrazine-trans-cyclooctene ligation for the rapid construction of 18F labeled probes. Chem Commun (Camb) (2010) 1.69
Genetically encoded tetrazine amino acid directs rapid site-specific in vivo bioorthogonal ligation with trans-cyclooctenes. J Am Chem Soc (2012) 1.67
Fast alkene functionalization in vivo by Photoclick chemistry: HOMO lifting of nitrile imine dipoles. Angew Chem Int Ed Engl (2009) 1.62
Diels-Alder cycloaddition for fluorophore targeting to specific proteins inside living cells. J Am Chem Soc (2012) 1.62
Advances in Bioconjugation. Curr Org Chem (2010) 1.60
Bioorthogonal chemistry: recent progress and future directions. Chem Commun (Camb) (2010) 1.58
Live-cell imaging of cyclopropene tags with fluorogenic tetrazine cycloadditions. Angew Chem Int Ed Engl (2012) 1.55
A pretargeted PET imaging strategy based on bioorthogonal Diels-Alder click chemistry. J Nucl Med (2013) 1.52
Synthesis and in vivo imaging of a 18F-labeled PARP1 inhibitor using a chemically orthogonal scavenger-assisted high-performance method. Angew Chem Int Ed Engl (2011) 1.47
Modular strategy for the construction of radiometalated antibodies for positron emission tomography based on inverse electron demand Diels-Alder click chemistry. Bioconjug Chem (2011) 1.45
Bringing chemistry to life. Nat Methods (2011) 1.45
Bioorthogonal reaction pairs enable simultaneous, selective, multi-target imaging. Angew Chem Int Ed Engl (2011) 1.40
Click chemistry in complex mixtures: bioorthogonal bioconjugation. Chem Biol (2014) 1.40
Tetrazine-trans-cyclooctene ligation for the rapid construction of integrin αvβ₃ targeted PET tracer based on a cyclic RGD peptide. Bioorg Med Chem Lett (2011) 1.36
Cancer nanotheranostics: improving imaging and therapy by targeted delivery across biological barriers. Adv Mater (2011) 1.33
Designing degradable hydrogels for orthogonal control of cell microenvironments. Chem Soc Rev (2013) 1.30
A metabolic alkene reporter for spatiotemporally controlled imaging of newly synthesized proteins in Mammalian cells. ACS Chem Biol (2010) 1.27
trans-Cyclooctene--a stable, voracious dienophile for bioorthogonal labeling. Curr Opin Chem Biol (2013) 1.25
The growing impact of bioorthogonal click chemistry on the development of radiopharmaceuticals. J Nucl Med (2013) 1.22
Noninvasive imaging of immune responses. Proc Natl Acad Sci U S A (2015) 1.20
Bioorthogonal chemistry: strategies and recent developments. Chem Commun (Camb) (2013) 1.19
Metal-catalyzed one-pot synthesis of tetrazines directly from aliphatic nitriles and hydrazine. Angew Chem Int Ed Engl (2012) 1.19
Enzymatic labeling of proteins: techniques and approaches. Bioconjug Chem (2013) 1.18
Bioorthogonal imaging of aurora kinase A in live cells. Angew Chem Int Ed Engl (2012) 1.14
Protein conjugation with genetically encoded unnatural amino acids. Curr Opin Chem Biol (2013) 1.14
Pyrrolysyl-tRNA synthetase: an ordinary enzyme but an outstanding genetic code expansion tool. Biochim Biophys Acta (2014) 1.13
Copper-free Sonogashira cross-coupling for functionalization of alkyne-encoded proteins in aqueous medium and in bacterial cells. J Am Chem Soc (2011) 1.08
Thiacycloalkynes for copper-free click chemistry. Angew Chem Int Ed Engl (2012) 1.08
Fluorescent live-cell imaging of metabolically incorporated unnatural cyclopropene-mannosamine derivatives. Chembiochem (2013) 1.08
π-Clamp-mediated cysteine conjugation. Nat Chem (2015) 1.06
Specific pathogen detection using bioorthogonal chemistry and diagnostic magnetic resonance. Bioconjug Chem (2011) 1.06
(18)F-labeled-bioorthogonal liposomes for in vivo targeting. Bioconjug Chem (2013) 1.05
Chemoenzymatic reversible immobilization and labeling of proteins without prior purification. J Am Chem Soc (2012) 1.05
Bioorthogonal Click Chemistry: An Indispensable Tool to Create Multifaceted Cell Culture Scaffolds. ACS Macro Lett (2012) 1.02
Efficient 18F labeling of cysteine-containing peptides and proteins using tetrazine-trans-cyclooctene ligation. Mol Imaging (2013) 1.01
Expanding room for tetrazine ligations in the in vivo chemistry toolbox. Curr Opin Chem Biol (2013) 1.01
Conformationally Strained trans-Cyclooctene with Improved Stability and Excellent Reactivity in Tetrazine Ligation. Chem Sci (2014) 0.99
Super-resolution imaging of the Golgi in live cells with a bioorthogonal ceramide probe. Angew Chem Int Ed Engl (2014) 0.98
Enzymatic "click" ligation: selective cysteine modification in polypeptides enabled by promiscuous glutathione S-transferase. Angew Chem Int Ed Engl (2013) 0.98
Fluorine-18 radiochemistry, labeling strategies and synthetic routes. Bioconjug Chem (2014) 0.98
Bioorthogonal cyclization-mediated in situ self-assembly of small-molecule probes for imaging caspase activity in vivo. Nat Chem (2014) 0.98
Concerted, rapid, quantitative, and site-specific dual labeling of proteins. J Am Chem Soc (2014) 0.97
The inverse electron demand Diels-Alder click reaction in radiochemistry. J Labelled Comp Radiopharm (2013) 0.96
Silver-catalyzed formal inverse electron-demand Diels-Alder reaction of 1,2-diazines and siloxy alkynes. J Am Chem Soc (2012) 0.96
Imaging beyond the proteome. Chem Commun (Camb) (2012) 0.95
Inverse electron demand Diels-Alder reactions of 1,2,3-triazines: pronounced substituent effects on reactivity and cycloaddition scope. J Am Chem Soc (2011) 0.95
Design strategies for bioorthogonal smart probes. Org Biomol Chem (2014) 0.95
Strained cycloalkynes as new protein sulfenic acid traps. J Am Chem Soc (2014) 0.94
Proline editing: a general and practical approach to the synthesis of functionally and structurally diverse peptides. Analysis of steric versus stereoelectronic effects of 4-substituted prolines on conformation within peptides. J Am Chem Soc (2013) 0.94
Fast hydrazone reactants: electronic and acid/base effects strongly influence rate at biological pH. J Am Chem Soc (2013) 0.94
Imaging cell surface glycosylation in vivo using "double click" chemistry. Bioconjug Chem (2013) 0.94
Real-time single-molecule electronic DNA sequencing by synthesis using polymer-tagged nucleotides on a nanopore array. Proc Natl Acad Sci U S A (2016) 0.93
Scope of the inverse electron demand Diels-Alder reactions of 1,2,3-triazine. Org Lett (2011) 0.93
Multicolor live-cell chemical imaging by isotopically edited alkyne vibrational palette. J Am Chem Soc (2014) 0.92
Optimization of a Pretargeted Strategy for the PET Imaging of Colorectal Carcinoma via the Modulation of Radioligand Pharmacokinetics. Mol Pharm (2015) 0.91
Rapid oligonucleotide-templated fluorogenic tetrazine ligations. Nucleic Acids Res (2013) 0.90
Facile and stabile linkages through tyrosine: bioconjugation strategies with the tyrosine-click reaction. Bioconjug Chem (2013) 0.90
Rapid cross-metathesis for reversible protein modifications via chemical access to Se-allyl-selenocysteine in proteins. J Am Chem Soc (2013) 0.90
Synthesis and reactivity comparisons of 1-methyl-3-substituted cyclopropene mini-tags for tetrazine bioorthogonal reactions. Chemistry (2014) 0.90
On-chip bioorthogonal chemistry enables immobilization of in situ modified nanoparticles and small molecules for label-free monitoring of protein binding and reaction kinetics. Lab Chip (2012) 0.89
Meter-long multiblock copolymer microfibers via interfacial bioorthogonal polymerization. Adv Mater (2015) 0.89
Haptoglobin Preserves Vascular Nitric Oxide Signaling during Hemolysis. Am J Respir Crit Care Med (2016) 0.88
Genetically encoded unstrained olefins for live cell labeling with tetrazine dyes. Chem Commun (Camb) (2014) 0.88
A biocompatible in vivo ligation reaction and its application for noninvasive bioluminescent imaging of protease activity in living mice. ACS Chem Biol (2013) 0.88
Total Synthesis of Hyacinthacine A2: Stereocontrolled 5-aza-cyclooctene Photoisomerization and Transannular Hydroamination with Planar-to-Point Chirality Transfer. Chem Sci (2011) 0.88
Selective labeling of polypeptides using protein farnesyltransferase via rapid oxime ligation. Chem Commun (Camb) (2010) 0.88
Storable arylpalladium(II) reagents for alkene labeling in aqueous media. J Am Chem Soc (2011) 0.88
Extension of the PNA world by functionalized PNA monomers eligible candidates for inverse Diels Alder Click Chemistry. Int J Med Sci (2010) 0.88
Interfacial Bioorthogonal Cross-Linking. ACS Macro Lett (2014) 0.88
Bioorthogonal chemistry: implications for pretargeted nuclear (PET/SPECT) imaging and therapy. Am J Nucl Med Mol Imaging (2014) 0.88
Peptide/protein stapling and unstapling: introduction of s-tetrazine, photochemical release, and regeneration of the peptide/protein. J Am Chem Soc (2015) 0.87
Design of spiro[2.3]hex-1-ene, a genetically encodable double-strained alkene for superfast photoclick chemistry. J Am Chem Soc (2014) 0.87
Two rapid catalyst-free click reactions for in vivo protein labeling of genetically encoded strained alkene/alkyne functionalities. Bioconjug Chem (2014) 0.86
Monoalkoxy BODIPYs--a fluorophore class for bioimaging. Bioconjug Chem (2014) 0.86
Application of strain-promoted azide-alkyne cycloaddition and tetrazine ligation to targeted Fc-drug conjugates. Bioconjug Chem (2012) 0.86
The use of (18)F-2-fluorodeoxyglucose (FDG) to label antibody fragments for immuno-PET of pancreatic cancer. ACS Cent Sci (2015) 0.86
Chemically modified antibodies as diagnostic imaging agents. Curr Opin Chem Biol (2010) 0.85
A bioorthogonal quadricyclane ligation. J Am Chem Soc (2011) 0.85
Metabolic glycan imaging by isonitrile-tetrazine click chemistry. Chembiochem (2013) 0.84
Noninvasive brain cancer imaging with a bispecific antibody fragment, generated via click chemistry. Proc Natl Acad Sci U S A (2015) 0.84
Click Chemistry: Diverse Chemical Function from a Few Good Reactions. Angew Chem Int Ed Engl (2001) 19.25
Copper-free click chemistry for dynamic in vivo imaging. Proc Natl Acad Sci U S A (2007) 8.50
A strain-promoted [3 + 2] azide-alkyne cycloaddition for covalent modification of biomolecules in living systems. J Am Chem Soc (2004) 7.51
Visualizing metabolically labeled glycoconjugates of living cells by copper-free and fast huisgen cycloadditions. Angew Chem Int Ed Engl (2008) 5.90
Site-specific labeling of proteins with small molecules in live cells. Curr Opin Biotechnol (2005) 4.39
Second-generation difluorinated cyclooctynes for copper-free click chemistry. J Am Chem Soc (2008) 3.65
A photoinducible 1,3-dipolar cycloaddition reaction for rapid, selective modification of tetrazole-containing proteins. Angew Chem Int Ed Engl (2008) 2.72
Selective functionalization of a genetically encoded alkene-containing protein via "photoclick chemistry" in bacterial cells. J Am Chem Soc (2008) 2.33
Mechanistic investigation of the staudinger ligation. J Am Chem Soc (2005) 2.19
The Staudinger ligation-a gift to chemical biology. Angew Chem Int Ed Engl (2004) 2.18
Differential reactivity of the functional sulfhydryl groups of cysteine-32 and cysteine-35 present in the reduced form of thioredoxin from Escherichia coli. J Biol Chem (1980) 2.15
Using electroactive substrates to pattern the attachment of two different cell populations. Proc Natl Acad Sci U S A (2001) 2.09
A photochemical synthesis of functionalized trans-cyclooctenes driven by metal complexation. J Am Chem Soc (2008) 1.90
A hydrophilic azacyclooctyne for Cu-free click chemistry. Org Lett (2008) 1.84
Regio- and chemoselective covalent immobilization of proteins through unnatural amino acids. J Am Chem Soc (2006) 1.60
Reaction mechanism and kinetics of the traceless Staudinger ligation. J Am Chem Soc (2006) 1.52
Site-specific, covalent attachment of proteins to a solid surface. Bioconjug Chem (2006) 1.46
Transition metal catalyzed methods for site-selective protein modification. Curr Opin Chem Biol (2006) 1.38
Mechanism of thio acid/azide amidation. J Am Chem Soc (2006) 1.21
Manipulating proteins with chemistry: a cross-section of chemical biology. Trends Biochem Sci (2005) 1.16
Protein-cross-linked polymeric materials through site-selective bioconjugation. Angew Chem Int Ed Engl (2008) 1.14
Diels-Alder ligation and surface immobilization of proteins. Angew Chem Int Ed Engl (2005) 1.10
Inhibition of human neutrophil elastase with peptidyl electrophilic ketones. 2. Orally active PG-Val-Pro-Val pentafluoroethyl ketones. J Med Chem (1994) 1.01
Novel method for the covalent immobilization of oligonucleotides via Diels-Alder bioconjugation. Nucleosides Nucleotides Nucleic Acids (2003) 0.99
Synthesis of N-(beta-D-glucopyranosyl) monoamides of dicarboxylic acids as potential inhibitors of glycogen phosphorylase. Carbohydr Res (2006) 0.93
Genetic Encoding of bicyclononynes and trans-cyclooctenes for site-specific protein labeling in vitro and in live mammalian cells via rapid fluorogenic Diels-Alder reactions. J Am Chem Soc (2012) 2.03
A photochemical synthesis of functionalized trans-cyclooctenes driven by metal complexation. J Am Chem Soc (2008) 1.90
Design and synthesis of highly reactive dienophiles for the tetrazine-trans-cyclooctene ligation. J Am Chem Soc (2011) 1.90
Tetrazine-trans-cyclooctene ligation for the rapid construction of 18F labeled probes. Chem Commun (Camb) (2010) 1.69
Genetically encoded tetrazine amino acid directs rapid site-specific in vivo bioorthogonal ligation with trans-cyclooctenes. J Am Chem Soc (2012) 1.67
Diels-Alder cycloaddition for fluorophore targeting to specific proteins inside living cells. J Am Chem Soc (2012) 1.62
Chemical characterization of the smallest S-nitrosothiol, HSNO; cellular cross-talk of H2S and S-nitrosothiols. J Am Chem Soc (2012) 1.46
Tetrazine-trans-cyclooctene ligation for the rapid construction of integrin αvβ₃ targeted PET tracer based on a cyclic RGD peptide. Bioorg Med Chem Lett (2011) 1.36
Rh-catalyzed intermolecular reactions of alkynes with alpha-diazoesters that possess beta-hydrogens: ligand-based control over divergent pathways. J Am Chem Soc (2007) 1.28
trans-Cyclooctene--a stable, voracious dienophile for bioorthogonal labeling. Curr Opin Chem Biol (2013) 1.25
Development and evaluation of 18F-TTCO-Cys40-Exendin-4: a PET probe for imaging transplanted islets. J Nucl Med (2013) 1.19
Chiral crown conformation of Rh(2)(S-PTTL)(4): enantioselective cyclopropanation with alpha-alkyl-alpha-diazoesters. J Am Chem Soc (2009) 1.19
Rh-catalyzed intermolecular cyclopropanation with alpha-alkyl-alpha-diazoesters: catalyst-dependent chemo- and diastereoselectivity. Org Lett (2008) 1.15
Synthesis of stable derivatives of cycloprop-2-ene carboxylic acid. J Org Chem (2008) 1.11
Rh-catalyzed formation of dioxolanes from alpha-alkyl diazoesters: diastereoselective cycloadditions of carbonyl ylides with selectivity over beta-hydride elimination. J Org Chem (2008) 1.04
Efficient 18F labeling of cysteine-containing peptides and proteins using tetrazine-trans-cyclooctene ligation. Mol Imaging (2013) 1.01
Rhodium(II)-catalyzed enantioselective C-H functionalization of indoles. J Am Chem Soc (2011) 1.00
Enantioselective, facially selective carbomagnesation of cyclopropenes. J Am Chem Soc (2006) 1.00
Unusually reactive and selective carbonyl ylides for three-component cycloaddition reactions. J Am Chem Soc (2009) 0.97
A copper-catalyzed method for the facially selective addition of grignard reagents to cyclopropenes. J Am Chem Soc (2002) 0.97
A reactivity/affinity switch for parallel kinetic resolution: alpha-amino acid quasienantiomers and the resolution of cyclopropene carboxylic acids. J Am Chem Soc (2004) 0.96
Synthesis of cyclopropene alpha-amino acids via enantioselective desymmetrization. Org Lett (2006) 0.94
Meter-long multiblock copolymer microfibers via interfacial bioorthogonal polymerization. Adv Mater (2015) 0.89
Diastereoselective synthesis of methylenecyclopropanes from chiral cyclopropene derivatives. Angew Chem Int Ed Engl (2006) 0.89
Total Synthesis of Hyacinthacine A2: Stereocontrolled 5-aza-cyclooctene Photoisomerization and Transannular Hydroamination with Planar-to-Point Chirality Transfer. Chem Sci (2011) 0.88
Facially selective and regioselective carbometalation of cyclopropenes by aryl Grignard reagents. J Org Chem (2007) 0.88
Diastereoselective intermolecular Pauson-Khand reactions of chiral cyclopropenes. Org Lett (2005) 0.88
Rh-catalyzed intermolecular reactions of cyclic α-diazocarbonyl compounds with selectivity over tertiary C-H bond migration. J Am Chem Soc (2012) 0.87
Directed carbozincation reactions of cyclopropene derivatives. J Am Chem Soc (2009) 0.87
Dianion approach to chiral cyclopropene carboxylic acids. Org Lett (2004) 0.86
Studies on the stability of cycloprop-2-ene carboxylate dianions and reactions with electrophiles. J Org Chem (2008) 0.86
Rh(2)(S-PTTL)(3)TPA-A Mixed Ligand Dirhodium(II) Catalyst for Enantioselective Reactions of α-Alkyl-α-Diazoesters. Chem Sci (2012) 0.85
Synthesis and characterization of Pt(IV) fluorescein conjugates to investigate Pt(IV) intracellular transformations. Bioconjug Chem (2013) 0.83
Enantioselective synthesis of cyclobutanes via sequential Rh-catalyzed bicyclobutanation/Cu-catalyzed homoconjugate addition. J Am Chem Soc (2013) 0.83
The chiral crown conformation in paddlewheel complexes. Chem Commun (Camb) (2010) 0.82
Enantioselective synthesis of (-)-pentalenene. Org Lett (2007) 0.81
Facially selective Cu-catalyzed carbozincation of cyclopropenes using arylzinc reagents formed by sequential I/Mg/Zn exchange. J Org Chem (2012) 0.81
Abiotic metallofoldamers as electrochemically responsive molecules. J Am Chem Soc (2005) 0.81
Copper-catalyzed synthesis of 2,4-disubstituted allenoates from α-diazoesters. Org Lett (2011) 0.81
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Stereospecific synthesis of alkylidenecyclopropanes via sequential cyclopropene carbomagnesation/1,3-carbon shift. J Org Chem (2010) 0.78
The Curtius rearrangement of cyclopropyl and cyclopropenoyl azides. A combined theoretical and experimental mechanistic study. J Org Chem (2008) 0.78
Supramolecular metal displacement allows on-fluorescence analysis of manganese(II) in living cells. Chem Commun (Camb) (2012) 0.78
Minimalist end groups for control of absolute helicity in salen- and salophen-based metallofoldamers. Org Lett (2010) 0.78
Co-complexes derived from alkene insertion to alkyne-dicobaltpentacarbonyl complexes: insight into the regioselectivity of pauson-khand reactions of cyclopropenes. J Org Chem (2008) 0.77
trans-Cyclohexane-1,2-diamine is a weak director of absolute helicity in chiral nickel-salen complexes. J Am Chem Soc (2007) 0.77
In situ activation of a doxorubicin prodrug using imaging-capable nanoparticles. Chem Commun (Camb) (2016) 0.76
Anticancer drug delivery systems: N4-acyl poly(ethyleneglycol) prodrugs of ara-C. I. Efficacy in solid tumors. J Control Release (2002) 0.76
Control of absolute helicity in single-stranded abiotic metallofoldamers. J Am Chem Soc (2006) 0.76
Interplay between the diamine structure and absolute helicity in Ni-salen metallofoldamers. Chem Commun (Camb) (2011) 0.76
A helicene-containing foldamer displaying highly solvent-dependent CD spectra. Org Lett (2004) 0.76
Asymmetric synthesis of cis-2,5-disubstituted pyrrolidine, the core scaffold of β3-AR agonists. Org Lett (2013) 0.76
Selective syntheses of Δ(α,β) and Δ(β,γ) butenolides from allylic cyclopropenecarboxylates via tandem ring expansion/[3,3]-sigmatropic rearrangements. Org Lett (2013) 0.75
Functionalized Cyclopropenes and Methylenecyclopropenes from Dianions of 3-Hydroxymethylcyclopropenes. Synthesis (Stuttg) (2012) 0.75
Chiral cyclopropenyl ketones: reactive and selective Diels-Alder dienophiles. J Org Chem (2013) 0.75
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Two-dimensional scaffolds for the parallel alignment of rod-shaped conjugated molecules. J Org Chem (2007) 0.75
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