1
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Synthesis of a stable compound with fivefold bonding between two chromium(I) centers.
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Science
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1.96
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2
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Methylene-bridged glycoluril dimers: synthetic methods.
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J Org Chem
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2002
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1.96
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3
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Reversible reactions of ethylene with distannynes under ambient conditions.
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Science
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1.46
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4
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Potent s-cis-locked bithiazole correctors of DeltaF508 cystic fibrosis transmembrane conductance regulator cellular processing for cystic fibrosis therapy.
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J Med Chem
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2008
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1.29
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5
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Synthesis and relaxometric studies of a dendrimer-based pH-responsive MRI contrast agent.
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Chemistry
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1.28
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6
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Isolation of a stable, acyclic, two-coordinate silylene.
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J Am Chem Soc
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7
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Interpenetrating As20 fullerene and Ni12 icosahedra in the onion-skin [As@Ni12@As20]3- ion.
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Science
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2003
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1.16
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Stannous chloride in alcohol: a one-pot conversion of 2-nitro-N-arylbenzamides to 2,3-dihydro-1H-quinazoline-4-ones.
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J Org Chem
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1.15
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Regarding the stability of d(0) monocyclopentadienyl zirconium acetamidinate complexes bearing alkyl substituents with beta-hydrogens.
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J Am Chem Soc
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2002
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1.13
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10
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An oxazolo[3,2-b]indazole route to 1H-indazolones.
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Org Lett
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1.12
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11
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Magnetic properties and negative colossal magnetoresistance of the rare earth Zintl phase EuIn2As2.
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Inorg Chem
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1.09
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12
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Pyrazolylthiazole as DeltaF508-cystic fibrosis transmembrane conductance regulator correctors with improved hydrophilicity compared to bithiazoles.
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J Med Chem
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2010
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1.04
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13
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Ion channel formation from a calix[4]arene amide that binds HCl.
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J Am Chem Soc
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14
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Titanium-catalyzed stereoselective synthesis of spirooxindole oxazolines.
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Org Lett
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1.01
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15
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Catalytic asymmetric synthesis of substituted 3-hydroxy-2-oxindoles.
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Angew Chem Int Ed Engl
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2010
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1.00
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Synthesis of (-)-viriditoxin: a 6,6'-binaphthopyran-2-one that targets the bacterial cell division protein FtsZ.
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Angew Chem Int Ed Engl
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2011
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0.98
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Profiling base excision repair glycosylases with synthesized transition state analogs.
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Bioorg Med Chem Lett
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18
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Fluoride-selective host based on anion-pi interactions, ion pairing, and hydrogen bonding: synthesis and fluoride-ion sandwich complex.
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Angew Chem Int Ed Engl
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2007
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Diastereoselective formation of glycoluril dimers: isomerization mechanism and implications for cucurbit[n]uril synthesis.
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J Am Chem Soc
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2002
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0.97
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20
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Molecular clips form isostructural dimeric aggregates from benzene to water.
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J Am Chem Soc
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A one-pot-three-step route to triazolotriazepinoindazolones from oxazolino-2H-indazoles.
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Org Lett
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22
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Lipophilic G-quadruplexes are self-assembled ion pair receptors, and the bound anion modulates the kinetic stability of these complexes.
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J Am Chem Soc
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Facile activation of dihydrogen by an unsaturated heavier main group compound.
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J Am Chem Soc
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Intramolecular cycloaddition of azomethine ylides in the preparation of pyrrolidino[2',3':3,4]pyrrolidino[1,2- a]benzimidazoles.
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Org Lett
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Stereocontrol in asymmetric γ-lactam syntheses from imines and cyanosuccinic anhydrides.
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A new synthetic route to (North)-methanocarba nucleosides designed as A3 adenosine receptor agonists.
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Synthesis of a γ-lactam library via formal cycloaddition of imines and substituted succinic anhydrides.
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ACS Comb Sci
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Heterocycle-heterocycle strategies: (2-nitrophenyl)isoxazole precursors to 4-aminoquinolines, 1H-indoles, and quinolin-4(1H)-ones.
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Angew Chem Int Ed Engl
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Diazocinones: synthesis and conformational analysis.
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Oxatriquinane and oxatriquinacene: extraordinary oxonium ions.
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Proc Natl Acad Sci U S A
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Efficient syntheses of the unknown quinolino[2,3-c]cinnolines; synthesis of neocryptolepines.
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Org Lett
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One-step synthesis of complex nitrogen heterocycles from imines and alkyl-substituted maleic anhydrides.
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Org Lett
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Four psychrotolerant species with high chemical diversity consistently producing cycloaspeptide A, Penicillium jamesonlandense sp. nov., Penicillium ribium sp. nov., Penicillium soppii and Penicillium lanosum.
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Direct displacement of alkoxy groups of vinylogous esters by Grignard reagents.
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J Org Chem
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37
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Regulating supramolecular function in membranes: calixarenes that enable or inhibit transmembrane Cl- transport.
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Design and synthesis of propeller-shaped dispiroisoxazolinopiperidinochromanones.
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J Comb Chem
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Cucurbit[n]uril analogues: synthetic and mechanistic studies.
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J Org Chem
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Two-coordinate, homoleptic manganese(II) primary terphenyl amido complexes: the effects of secondary coordination on geometry and Lewis base complexation.
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Dalton Trans
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41
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Parallel Synthesis of bis-heterocyclic isoxazolylmethyl- and isoxazolinylmethylpyrazoles.
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J Comb Chem
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Catalytic Alkene Cyclization Reactions for the Stereoselective Synthesis of Complex "Terpenoid-like" Heterocycles.
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Dispersion force stabilized two-coordinate transition metal-amido complexes of the -N(SiMe3)Dipp (Dipp = C6H3-2,6-Pr(i)2) ligand: structural, spectroscopic, magnetic, and computational studies.
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Inorg Chem
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Reactions of the heavier group 14 element alkyne analogues Ar'EEAr' (Ar' = C6H3-2,6(C6H3-2,6-Pri2)2; E = Ge, Sn) with unsaturated molecules: probing the character of the EE multiple bonds.
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Cucurbit[n]uril analogues.
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Selective nucleophilic chemistry in the synthesis of 5-carbamoyl-3-sulfanylmethylisoxazole-4-carboxylic acids.
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J Comb Chem
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Asymmetric catalysis: resin-bound hydroxyprolylthreonine derivatives in enamine-mediated reactions.
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Angew Chem Int Ed Engl
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2008
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0.83
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48
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Direct spectroscopic observation of large quenching of first-order orbital angular momentum with bending in monomeric, two-coordinate Fe(II) primary amido complexes and the profound magnetic effects of the absence of Jahn- and Renner-Teller distortions in rigorously linear coordination.
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J Am Chem Soc
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2009
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Designed self-assembly of molecular necklaces using host-stabilized charge-transfer interactions.
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J Am Chem Soc
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2004
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"Matched/mismatched" diastereomeric dirhodium(II) carboxamidate catalyst pairs. Structure-selectivity correlations in diazo decomposition and hetero-Diels-Alder reactions.
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Azatriquinane as a platform for tripodal metal complexes and calixiform scaffolds.
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Very large changes in bond length and bond angle in a heavy group 14 element alkyne analogue by modification of a remote ligand substituent.
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Addition of H2 to distannynes under ambient conditions.
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Addition of hydrogen or ammonia to a low-valent group 13 metal species at 25 degrees C and 1 atmosphere.
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Angew Chem Int Ed Engl
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Synthesis, structure, and magnetic and electrochemical properties of quasi-linear and linear iron(I), cobalt(I), and nickel(I) amido complexes.
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A pirouette on a metallofullerene sphere: interconversion of isomers of N-tritylpyrrolidino I(h) Sc3N@C80.
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An unsymmetric oxo/imido-bridged germanium-centered singlet diradicaloid.
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Quinoxalino[2,3-c]cinnolines and their 5-N-oxide: alkoxylation of methyl-substituted quinoxalino[2,3-c]cinnolines to acetals and orthoesters.
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Multicomponent macrocyclization reactions (MCMRs) employing highly reactive acyl ketene and nitrile oxide intermediates.
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Linear and nonlinear two-coordinate vanadium complexes: synthesis, characterization, and magnetic properties of V(II) amides.
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A germanium isocyanide complex featuring (n → π*) back-bonding and its conversion to a hydride/cyanide product via C-H bond activation under mild conditions.
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Reaction of a sterically encumbered iron(I) aryl/arene with organoazides: formation of an iron(V) bis(imide).
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Synthesis, structure, and dynamic properties of [Ni2Sn17]4-.
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Synthesis and characterization of the homologous M-M bonded series Ar'MMAr' (M = Zn, Cd, or Hg; Ar' = C6H3-2,6-(C6H3-2,6-Pr(i)2)2) and related arylmetal halides and hydride species.
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2007
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Polymorphs and aurophilic interactions in colorless crystals of Au2(μ-1,2 bis-(diphenylarsino)ethane)X2, (X = Cl, Br, I).
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Thermochemistry of paddle wheel MOFs: Cu-HKUST-1 and Zn-HKUST-1.
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Tandem glycosyl iodide glycosylation and regioselective enzymatic acylation affords 6-O-tetradecanoyl-α-d-cholesterylglycosides.
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Room-temperature reaction of carbon monoxide with a stable diarylgermylene.
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Metal-metal interactions in thallium(I)/platinum(II) compounds involving a chelating dicarbene and various auxiliary ligands.
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Stereoselective synthesis of γ-lactams from imines and cyanosuccinic anhydrides.
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Distinctly different reactivities of two similar polyoxoniobates with hydrogen peroxide.
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Reaction of hydrogen or ammonia with unsaturated germanium or tin molecules under ambient conditions: oxidative addition versus arene elimination.
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Electrocatalytic hydrogen evolution from water by a series of iron carbonyl clusters.
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Two-coordinate, quasi-two-coordinate, and distorted three coordinate, T-shaped chromium(II) amido complexes: unusual effects of coordination geometry on the lowering of ground state magnetic moments.
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Reaction of a germylene, stannylene, or plumbylene with trimethylaluminum and trimethylgallium: insertion into Al-C or ga-C bonds, a reversible metal-carbon insertion equilibrium, and a new route to diplumbenes.
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A reversible polymorphic phase change which affects the luminescence and aurophilic interactions in the gold (I) cluster complex, [mu3-S(AuCNC7H13)3](SbF6).
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Synthesis, structural, and magnetic characterization of linear and bent geometry cobalt(II) and nickel(II) amido complexes: evidence of very large spin-orbit coupling effects in rigorously linear coordinated Co2+.
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A new titanoniobate ion-completing the series [Nb10O28]6-, [TiNb9O28]7- and [Ti2Nb8O28]8-.
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The sodium ions inside a lipophilic G-quadruplex channel as probed by solid-state (23)Na NMR.
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The [Ti12Nb6O44]10- ion--a new type of polyoxometalate structure.
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[Ni5Sb17]4- transition-metal Zintl ion complex: crossing the Zintl border in molecular intermetalloid clusters.
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Cluster growth and fragmentation in the highly fluxional platinum derivatives of Sn9 4-: synthesis, characterization, and solution dynamics of Pt2@Sn17 4- and Pt@Sn9H 3-.
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Synthesis and characterization of the titanium bisamide Ti{N(H)Ar(iPr6)}2 (Ar(iPr6) = C6H3-2,6-(C6H2-2,4,6-(i)Pr3)2 and its TiCl{N(H)Ar(iPr6)}2 precursor: Ti(II) → Ti(IV) cyclization.
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A fused [3.3.0]-neoglycoside lactone derived from glucuronic acid.
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Synthesis of substituted chromanones: an organocatalytic aldol/oxa-Michael reaction.
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N-H and N=C bond formation via germanium(III) diradicaloid intermediates and C-S bond cleavage in reactions of the digermyne Ar'GeGeAr' (Ar' = C6H3-2,6-(C6H3-2,6-Pr(i)2)2) with azides.
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High-resolution 39K NMR spectroscopy of bio-organic solids.
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Stable plumbylene dichalcogenolate monomers with large differences in their interligand angles and the synthesis and characterization of a monothiolato Pb(II) bromide and lithium trithiolato plumbate.
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Spin-state crossover with structural changes in a cobalt(II) organometallic species: low-coordinate, first row, heteroleptic amido transition metal aryls. Synthesis and characterization of Ar'MN(H)Ar# (M = Mn, Fe, Co) (Ar' = C6H3-2,6-(C6H3-2,6-iPr2)2, Ar# = C6H3-2,6-(C6H2-2,4,6-Me3)2).
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Variation in crystallization conditions allows the isolation of trimeric as well as dimeric and monomeric forms of [(alkyl isocyanide)4RhI]+.
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Blue or green glowing crystals of the cation [Au{C(NHMe)2}2]+. Structural effects of anions, hydrogen bonding, and solvate molecules on the luminescence of a two-coordinate gold(I) carbene complex.
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126
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Synthesis, structural characterization, and spectroscopy of the cadmium-cadmium bonded molecular species Ar'CdCdAr' (Ar' = C6H3-2,6-(C6H3-2,6-Pri2)2).
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J Am Chem Soc
|
2006
|
0.75
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127
|
Synthesis and characterization of diametrically substituted tetra-O-n-butylcalix[4]arene ligands and their chelated complexes of titanium, molybdenum, and palladium.
|
Inorg Chem
|
2002
|
0.75
|
128
|
Synthesis and structural characterization of a series of dimeric metal(II) imido complexes {M(mu-NAr(#))}2 [M = Ge, Sn, Pb; Ar(#) = C6H3-2,6-(C6H2-2,4,6-Me3)2] and the related monomeric primary amido derivatives M{N(H)Ar(#)}2 (M = Ge, Sn, Pb): spectroscopic manifestations of secondary metal-ligand interactions.
|
Inorg Chem
|
2010
|
0.75
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129
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Cyclometalated products of [(COE)(2)RhCl](2) and 1,3-(RSCH(2))(2)C(6)H(4) (R = (t)Bu, (i)Pr) Are Dimeric. Synthesis, molecular structures, and solution dynamics of [mu-ClRh(H)(RSCH(2))(2)C(6)H(3)-2,6](2).
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Inorg Chem
|
2002
|
0.75
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130
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Reduction of terphenyl Co(II) halide derivatives in the presence of arenes: insertion of Co(I) into a C-F bond.
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Inorg Chem
|
2012
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0.75
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131
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Simple routes to bulky silyl-substituted acetylide ligands and examples of V(III), Fe(II), and Mn(II) complexes.
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Chem Commun (Camb)
|
2011
|
0.75
|
132
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Crystallographic and computational studies of luminescent, binuclear gold(I) complexes, Au(I)2(Ph2P(CH2)nPPh2)2I2 (n = 3-6).
|
Inorg Chem
|
2013
|
0.75
|
133
|
Dispersion forces and counterintuitive steric effects in main group molecules: heavier group 14 (Si-Pb) dichalcogenolate carbene analogues with sub-90° interligand bond angles.
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J Am Chem Soc
|
2013
|
0.75
|
134
|
Synthesis and characterization of the M(II) (M = Ge, Sn, or Pb) phosphinidene dimers {M(μ-PAr')}2 (Ar' = C6H3-2,6-(C6H3-2,6-Pr(i)2)2).
|
Inorg Chem
|
2010
|
0.75
|
135
|
Three chiral vinyldioxazaborocanes.
|
Acta Crystallogr C
|
2006
|
0.75
|
136
|
Synthesis and characterization of the metal(I) dimers [Ar'MMAr']: comparisons with quintuple-bonded [Ar'CrCrAr'].
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Angew Chem Int Ed Engl
|
2008
|
0.75
|
137
|
Synthesis and reactivity of dimethyl platinum(IV) hydrides in water.
|
J Am Chem Soc
|
2004
|
0.75
|
138
|
C-H activation of cycloalkenes by dimetallynes (M = Ge, Sn) under ambient conditions.
|
J Am Chem Soc
|
2011
|
0.75
|
139
|
Reversible complexation of ethylene by a silylene under ambient conditions.
|
J Am Chem Soc
|
2014
|
0.75
|
140
|
Reversible and irreversible higher-order cycloaddition reactions of polyolefins with a multiple-bonded heavier group 13 alkene analogue: contrasting the behavior of systems with π-π, π-π*, and π-n+ frontier molecular orbital symmetry.
|
J Am Chem Soc
|
2012
|
0.75
|
141
|
Living Ziegler-Natta polymerization by early transition metals: synthesis and evaluation of cationic zirconium alkyl complexes bearing beta-hydrogens as models for propagating centers.
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J Am Chem Soc
|
2006
|
0.75
|
142
|
Activation of olefins with low-valent gallium compounds under ambient conditions.
|
Chem Commun (Camb)
|
2011
|
0.75
|
143
|
Synthesis and characterization of two of the three isomers of a germanium-substituted bicyclo[2.2.0]hexane diradicaloid: stretching the Ge-Ge bond.
|
Angew Chem Int Ed Engl
|
2010
|
0.75
|
144
|
Interplay of supramolecular organization, metallophilic interactions, phase changes, and luminescence in four polymorphs of IrI(CO)2(OC(CH3)CHC(CH3)N(p-tol)).
|
Inorg Chem
|
2008
|
0.75
|
145
|
Reduction of terphenyl iron(II) or cobalt(II) halides in the presence of trimethylphosphine: an unusual triple dehydrogenation of an alkyl group.
|
Dalton Trans
|
2009
|
0.75
|
146
|
Mechanistic study of stepwise methylisocyanide coupling and C-H activation mediated by a low-valent main group molecule.
|
J Am Chem Soc
|
2013
|
0.75
|
147
|
Three-dimensional nets from star-shaped hexakis(arylthio)triphenylene molecules and silver(I) salts.
|
Inorg Chem
|
2006
|
0.75
|