57Fe ENDOR spectroscopy and 'electron inventory' analysis of the nitrogenase E4 intermediate suggest the metal-ion core of FeMo-cofactor cycles through only one redox couple.

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Published in J Am Chem Soc on October 07, 2011

Authors

Peter E Doan1, Joshua Telser, Brett M Barney, Robert Y Igarashi, Dennis R Dean, Lance C Seefeldt, Brian M Hoffman

Author Affiliations

1: Department of Chemistry, Northwestern University, Evanston, Illinois 60208, USA.

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