Published in Angew Chem Int Ed Engl on January 01, 2007
Reactive intermediates in oxygenation reactions with mononuclear nonheme iron catalysts. Angew Chem Int Ed Engl (2009) 0.88
Structural and spectroscopic characterization of metastable thiolate-ligated manganese(III)-alkylperoxo species. J Am Chem Soc (2011) 0.84
Mono- and binuclear non-heme iron chemistry from a theoretical perspective. J Biol Inorg Chem (2016) 0.82
X-ray absorption spectroscopy and reactivity of thiolate-ligated Fe(III)-OOR complexes. Inorg Chem (2010) 0.82
Reactivities of Fe(IV) complexes with oxo, hydroxo, and alkylperoxo ligands: an experimental and computational study. Inorg Chem (2009) 0.81
Differences and comparisons of the properties and reactivities of iron(III)-hydroperoxo complexes with saturated coordination sphere. Chemistry (2014) 0.79
Crystallographic and spectroscopic characterization of a nonheme Fe(IV)-O complex. Science (2003) 3.40
A highly selective fluorescent chemosensor for Pb2+. J Am Chem Soc (2005) 2.33
Nonheme FeIVO complexes that can oxidize the C-H bonds of cyclohexane at room temperature. J Am Chem Soc (2004) 2.26
Axial ligand tuning of a nonheme iron(IV)-oxo unit for hydrogen atom abstraction. Proc Natl Acad Sci U S A (2007) 1.70
Crystal structure of a metal ion-bound oxoiron(IV) complex and implications for biological electron transfer. Nat Chem (2010) 1.58
A highly active zinc catalyst for the controlled polymerization of lactide. J Am Chem Soc (2003) 1.57
A low-spin ruthenium(IV)-oxo complex: does the spin state have an impact on the reactivity? Angew Chem Int Ed Engl (2010) 1.48
A thiolate-ligated nonheme oxoiron(IV) complex relevant to cytochrome P450. Science (2005) 1.45
Structural insights into nonheme alkylperoxoiron(III) and oxoiron(IV) intermediates by X-ray absorption spectroscopy. J Am Chem Soc (2004) 1.45
An FeIV=O complex of a tetradentate tripodal nonheme ligand. Proc Natl Acad Sci U S A (2003) 1.44
Structure and reactivity of a mononuclear non-haem iron(III)-peroxo complex. Nature (2011) 1.40
Axial ligand effects on the geometric and electronic structures of nonheme oxoiron(IV) complexes. J Am Chem Soc (2008) 1.32
[Mn(tmc)(O2)]+: a side-on peroxido manganese(III) complex bearing a non-heme ligand. Angew Chem Int Ed Engl (2007) 1.29
Catalytic mechanism of dopamine beta-monooxygenase mediated by Cu(III)-oxo. Inorg Chem (2006) 1.29
Synthesis, characterization, and reactivities of manganese(V)-oxo porphyrin complexes. J Am Chem Soc (2007) 1.25
Geometric and electronic structure and reactivity of a mononuclear "side-on" nickel(III)-peroxo complex. Nat Chem (2009) 1.19
Metal ion-coupled electron transfer of a nonheme oxoiron(IV) complex: remarkable enhancement of electron-transfer rates by Sc3+. J Am Chem Soc (2010) 1.16
Mononuclear metal-O2 complexes bearing macrocyclic N-tetramethylated cyclam ligands. Acc Chem Res (2012) 1.15
A two-state reactivity rationale for counterintuitive axial ligand effects on the C-H activation reactivity of nonheme FeIV=O oxidants. Chemistry (2008) 1.14
Mechanistic insight into alcohol oxidation by high-valent iron-oxo complexes of heme and nonheme ligands. Angew Chem Int Ed Engl (2005) 1.11
Axial ligand substituted nonheme FeIV=O complexes: observation of near-UV LMCT bands and Fe=O Raman vibrations. J Am Chem Soc (2005) 1.11
Mononuclear nonheme ferric-peroxo complex in aldehyde deformylation. Chem Commun (Camb) (2005) 1.11
An "end-on" chromium(III)-superoxo complex: crystallographic and spectroscopic characterization and reactivity in C-H bond activation of hydrocarbons. J Am Chem Soc (2010) 1.11
Photofunctional triplet excited states of cyclometalated Ir(III) complexes: beyond electroluminescence. Chem Soc Rev (2012) 1.10
Dioxygen activation by a non-heme iron(II) complex: formation of an iron(IV)-oxo complex via C-H activation by a putative iron(III)-superoxo species. J Am Chem Soc (2010) 1.10
Fundamental electron-transfer properties of non-heme oxoiron(IV) complexes. J Am Chem Soc (2007) 1.09
A mononuclear non-heme manganese(IV)-oxo complex binding redox-inactive metal ions. J Am Chem Soc (2013) 1.09
Comparison of the reactivity of bis(mu-oxo)Cu(II)Cu(III) and Cu(III)Cu(III) species to methane. Inorg Chem (2009) 1.09
A theoretical study on the mechanism of camphor hydroxylation by compound I of cytochrome p450. J Am Chem Soc (2003) 1.08
Nonheme oxoiron(IV) complexes of tris(2-pyridylmethyl)amine with cis-monoanionic ligands. Inorg Chem (2006) 1.04
Accelerated cerebral ischemic injury by activated macrophages/microglia after lipopolysaccharide microinjection into rat corpus callosum. Glia (2005) 1.04
Dioxygen activation and catalytic aerobic oxidation by a mononuclear nonheme iron(II) complex. J Am Chem Soc (2005) 1.04
Structural characterization and remarkable axial ligand effect on the nucleophilic reactivity of a nonheme manganese(III)-peroxo complex. Angew Chem Int Ed Engl (2009) 1.04
Oxoiron(IV) porphyrin pi-cation radical complexes with a chameleon behavior in cytochrome P450 model reactions. J Biol Inorg Chem (2005) 1.04
Oxygen-atom transfer between mononuclear nonheme iron(IV)-oxo and iron(II) complexes. Angew Chem Int Ed Engl (2006) 1.02
Synthesis, structural, and spectroscopic characterization and reactivities of mononuclear cobalt(III)-peroxo complexes. J Am Chem Soc (2010) 1.01
Computational exploration of the catalytic mechanism of dopamine beta-monooxygenase: modeling of its mononuclear copper active sites. Inorg Chem (2005) 1.00
Identification of an "end-on" nickel-superoxo adduct, [Ni(tmc)(O2)]+. J Am Chem Soc (2006) 1.00
Dioxygen activation by mononuclear nonheme iron(II) complexes generates iron-oxygen intermediates in the presence of an NADH analogue and proton. J Am Chem Soc (2009) 1.00
Reactivities of mononuclear non-heme iron intermediates including evidence that iron(III)-hydroperoxo species is a sluggish oxidant. J Am Chem Soc (2006) 0.99
Enhanced reactivities of iron(IV)-oxo porphyrin pi-cation radicals in oxygenation reactions by electron-donating axial ligands. Chemistry (2009) 0.97
Fluorescent zinc sensor with minimized proton-induced interferences: photophysical mechanism for fluorescence turn-on response and detection of endogenous free zinc ions. Inorg Chem (2012) 0.97
[Fe(IV)═O(TBC)(CH3CN)]2+: comparative reactivity of iron(IV)-oxo species with constrained equatorial cyclam ligation. J Am Chem Soc (2012) 0.96
Metal ion effect on the switch of mechanism from direct oxygen transfer to metal ion-coupled electron transfer in the sulfoxidation of thioanisoles by a non-heme iron(IV)-oxo complex. J Am Chem Soc (2011) 0.96
Iron-catalysed transformation of molecular dinitrogen into silylamine under ambient conditions. Nat Commun (2012) 0.96
Status of reactive non-heme metal-oxygen intermediates in chemical and enzymatic reactions. J Am Chem Soc (2014) 0.95
Enhanced electron-transfer reactivity of nonheme manganese(IV)-oxo complexes by binding scandium ions. J Am Chem Soc (2013) 0.94
Hydrogen-atom abstraction reactions by manganese(V)- and manganese(IV)-oxo porphyrin complexes in aqueous solution. Chemistry (2009) 0.93
Phosphorescent sensor for robust quantification of copper(II) ion. J Am Chem Soc (2011) 0.93
Does Cob(II)alamin act as a conductor in coenzyme B12 dependent mutases? Angew Chem Int Ed Engl (2007) 0.93
Comparison of high-spin and low-spin nonheme Fe(III)-OOH complexes in O-O bond homolysis and H-atom abstraction reactivities. J Am Chem Soc (2013) 0.92
Chromium(IV)-peroxo complex formation and its nitric oxide dioxygenase reactivity. J Am Chem Soc (2012) 0.92
Direct evidence for oxygen-atom exchange between nonheme oxoiron(IV) complexes and isotopically labeled water. Angew Chem Int Ed Engl (2004) 0.92
Manganese displacement from Zinpyr-1 allows zinc detection by fluorescence microscopy and magnetic resonance imaging. Chem Commun (Camb) (2010) 0.92
Ruthenium-catalyzed selective and efficient oxygenation of hydrocarbons with water as an oxygen source. Angew Chem Int Ed Engl (2008) 0.91
Catalytic formation of ammonia from molecular dinitrogen by use of dinitrogen-bridged dimolybdenum-dinitrogen complexes bearing PNP-pincer ligands: remarkable effect of substituent at PNP-pincer ligand. J Am Chem Soc (2014) 0.91
Scandium ion-enhanced oxidative dimerization and N-demethylation of N,N-dimethylanilines by a non-heme iron(IV)-oxo complex. Inorg Chem (2011) 0.91
Combined experimental and theoretical study on aromatic hydroxylation by mononuclear nonheme iron(IV)-oxo complexes. Inorg Chem (2007) 0.90
Self-hydroxylation of perbenzoic acids at a nonheme iron(II) center. Chem Commun (Camb) (2005) 0.90
Reversible O-O bond cleavage and formation between Mn(IV)-peroxo and Mn(V)-oxo corroles. J Am Chem Soc (2010) 0.89
Brønsted acid-promoted C-H bond cleavage via electron transfer from toluene derivatives to a protonated nonheme iron(IV)-oxo complex with no kinetic isotope effect. J Am Chem Soc (2013) 0.89
Evidence for an alternative to the oxygen rebound mechanism in C-H bond activation by non-heme Fe(IV)O complexes. J Am Chem Soc (2012) 0.89
Formation, stability, and reactivity of a mononuclear nonheme oxoiron(IV) complex in aqueous solution. Chem Commun (Camb) (2005) 0.88
Molybdenum-catalyzed transformation of molecular dinitrogen into silylamine: experimental and DFT study on the remarkable role of ferrocenyldiphosphine ligands. J Am Chem Soc (2011) 0.88
Electron-transfer reduction of dinuclear copper peroxo and bis-μ-oxo complexes leading to the catalytic four-electron reduction of dioxygen to water. Chemistry (2012) 0.88
Quantum transport effects in nanosized graphite sheets. Chemphyschem (2002) 0.88
Reactivity of a cobalt(III)-peroxo complex in oxidative nucleophilic reactions. J Inorg Biochem (2008) 0.88
Theoretical measurements of conductance in an (AT)12 DNA molecule. Chemphyschem (2003) 0.88
Reactive intermediates in oxygenation reactions with mononuclear nonheme iron catalysts. Angew Chem Int Ed Engl (2009) 0.88
Ligand topology effect on the reactivity of a mononuclear nonheme iron(IV)-oxo complex in oxygenation reactions. J Am Chem Soc (2011) 0.88
A biomimetic ferric hydroperoxo porphyrin intermediate. Angew Chem Int Ed Engl (2010) 0.87
Mononuclear nickel(II)-superoxo and nickel(III)-peroxo complexes bearing a common macrocyclic TMC ligand. Chem Sci (2013) 0.87
Experiment and theory reveal the fundamental difference between two-state and single-state reactivity patterns in nonheme Fe(IV)=O versus Ru(IV)=O oxidants. Angew Chem Int Ed Engl (2008) 0.87
Proton-promoted oxygen atom transfer vs proton-coupled electron transfer of a non-heme iron(IV)-oxo complex. J Am Chem Soc (2012) 0.87
Nonheme iron(II) complexes of macrocyclic ligands in the generation of oxoiron(IV) complexes and the catalytic epoxidation of olefins. J Inorg Biochem (2006) 0.87
Contrasting effects of axial ligands on electron-transfer versus proton-coupled electron-transfer reactions of nonheme oxoiron(IV) complexes. Chemistry (2010) 0.87
A chromium(III)-superoxo complex in oxygen atom transfer reactions as a chemical model of cysteine dioxygenase. J Am Chem Soc (2012) 0.86
Mechanistic insights into hydride-transfer and electron-transfer reactions by a manganese(IV)-oxo porphyrin complex. J Am Chem Soc (2009) 0.86
Hydrogen atom abstraction and hydride transfer reactions by iron(IV)-oxo porphyrins. Angew Chem Int Ed Engl (2008) 0.85
Reactions of a chromium(III)-superoxo complex and nitric oxide that lead to the formation of chromium(IV)-oxo and chromium(III)-nitrito complexes. J Am Chem Soc (2013) 0.85
Phosphorescent sensor for biological mobile zinc. J Am Chem Soc (2011) 0.85
Direct evidence for an iron(IV)-oxo porphyrin pi-cation radical as an active oxidant in catalytic oxygenation reactions. Chem Commun (Camb) (2008) 0.85
XAS and DFT investigation of mononuclear cobalt(III) peroxo complexes: electronic control of the geometric structure in CoO2 versus NiO2 systems. Inorg Chem (2010) 0.85
Unified view of oxidative C-H bond cleavage and sulfoxidation by a nonheme iron(IV)-oxo complex via Lewis acid-promoted electron transfer. Inorg Chem (2014) 0.84
High-valent manganese(v)-oxo porphyrin complexes in hydride transfer reactions. Chem Commun (Camb) (2008) 0.84
A highly reactive mononuclear non-heme manganese(IV)-oxo complex that can activate the strong C-H bonds of alkanes. J Am Chem Soc (2011) 0.84
Quantum chemical approach to the mechanism for the biological conversion of tyrosine to dopaquinone. J Am Chem Soc (2008) 0.84
A mononuclear non-heme high-spin iron(III)-hydroperoxo complex as an active oxidant in sulfoxidation reactions. J Am Chem Soc (2013) 0.84
Factors that control catalytic two- versus four-electron reduction of dioxygen by copper complexes. J Am Chem Soc (2012) 0.84
High conversion of olefins to cis-diols by non-heme iron catalysts and H2O2. Chem Commun (Camb) (2002) 0.84
Water as an oxygen source in the generation of mononuclear nonheme iron(IV) oxo complexes. Angew Chem Int Ed Engl (2009) 0.84
Sulfur versus iron oxidation in an iron-thiolate model complex. J Am Chem Soc (2010) 0.84
Oxidative N-dealkylation reactions by oxoiron(IV) complexes of nonheme and heme ligands. Inorg Chem (2007) 0.83
Facile N-H bond cleavage of ammonia by an iridium complex bearing a noninnocent PNP-pincer type phosphaalkene ligand. J Am Chem Soc (2013) 0.83
Naphthalene and anthracene complexes sandwiched by two {(Cp*)Fe(I)} fragments: strong electronic coupling between the Fe(I) centers. Chem Asian J (2012) 0.83