Published in J Am Chem Soc on May 05, 2010
Mononuclear metal-O2 complexes bearing macrocyclic N-tetramethylated cyclam ligands. Acc Chem Res (2012) 1.15
Synthesis, structural, and spectroscopic characterization and reactivities of mononuclear cobalt(III)-peroxo complexes. J Am Chem Soc (2010) 1.01
Chromium(IV)-peroxo complex formation and its nitric oxide dioxygenase reactivity. J Am Chem Soc (2012) 0.92
Mononuclear nickel(II)-superoxo and nickel(III)-peroxo complexes bearing a common macrocyclic TMC ligand. Chem Sci (2013) 0.87
XAS and DFT investigation of mononuclear cobalt(III) peroxo complexes: electronic control of the geometric structure in CoO2 versus NiO2 systems. Inorg Chem (2010) 0.85
Reactions of a chromium(III)-superoxo complex and nitric oxide that lead to the formation of chromium(IV)-oxo and chromium(III)-nitrito complexes. J Am Chem Soc (2013) 0.85
Characterization of a paramagnetic mononuclear nonheme iron-superoxo complex. J Am Chem Soc (2014) 0.82
Ligand-sensitive but not ligand-diagnostic: evaluating Cr valence-to-core X-ray emission spectroscopy as a probe of inner-sphere coordination. Inorg Chem (2014) 0.81
Efficient C-H Bond Activations via O2 Cleavage by a Dianionic Cobalt(II) Complex. Chem Sci (2014) 0.80
Activation of Dioxygen by Iron and Manganese Complexes: A Heme and Nonheme Perspective. J Am Chem Soc (2016) 0.78
Synthesis, characterization, and reactivity of cobalt(III)-oxygen complexes bearing a macrocyclic N-tetramethylated cyclam ligand. Chemistry (2013) 0.78
Crystallographic and spectroscopic characterization and reactivities of a mononuclear non-haem iron(III)-superoxo complex. Nat Commun (2014) 0.78
Characterization of a heterobimetallic nonheme Fe(III)-O-Cr(III) species formed by O2 activation. Chem Commun (Camb) (2015) 0.77
Photocatalytic Oxygenation of Substrates by Dioxygen with Protonated Manganese(III) Corrolazine. Inorg Chem (2016) 0.77
Mechanism of the Swern oxidation: significant deviations from transition state theory. J Org Chem (2010) 0.75
Crystallographic and spectroscopic characterization of a nonheme Fe(IV)-O complex. Science (2003) 3.40
A highly selective fluorescent chemosensor for Pb2+. J Am Chem Soc (2005) 2.33
Nonheme FeIVO complexes that can oxidize the C-H bonds of cyclohexane at room temperature. J Am Chem Soc (2004) 2.26
Axial ligand tuning of a nonheme iron(IV)-oxo unit for hydrogen atom abstraction. Proc Natl Acad Sci U S A (2007) 1.70
Crystal structure of a metal ion-bound oxoiron(IV) complex and implications for biological electron transfer. Nat Chem (2010) 1.58
A highly active zinc catalyst for the controlled polymerization of lactide. J Am Chem Soc (2003) 1.57
A thiolate-ligated nonheme oxoiron(IV) complex relevant to cytochrome P450. Science (2005) 1.45
Structural insights into nonheme alkylperoxoiron(III) and oxoiron(IV) intermediates by X-ray absorption spectroscopy. J Am Chem Soc (2004) 1.45
An FeIV=O complex of a tetradentate tripodal nonheme ligand. Proc Natl Acad Sci U S A (2003) 1.44
Structure and reactivity of a mononuclear non-haem iron(III)-peroxo complex. Nature (2011) 1.40
Axial ligand effects on the geometric and electronic structures of nonheme oxoiron(IV) complexes. J Am Chem Soc (2008) 1.32
[Mn(tmc)(O2)]+: a side-on peroxido manganese(III) complex bearing a non-heme ligand. Angew Chem Int Ed Engl (2007) 1.29
Synthesis, characterization, and reactivities of manganese(V)-oxo porphyrin complexes. J Am Chem Soc (2007) 1.25
Geometric and electronic structure and reactivity of a mononuclear "side-on" nickel(III)-peroxo complex. Nat Chem (2009) 1.19
Metal ion-coupled electron transfer of a nonheme oxoiron(IV) complex: remarkable enhancement of electron-transfer rates by Sc3+. J Am Chem Soc (2010) 1.16
Mononuclear metal-O2 complexes bearing macrocyclic N-tetramethylated cyclam ligands. Acc Chem Res (2012) 1.15
A two-state reactivity rationale for counterintuitive axial ligand effects on the C-H activation reactivity of nonheme FeIV=O oxidants. Chemistry (2008) 1.14
Mechanistic insight into alcohol oxidation by high-valent iron-oxo complexes of heme and nonheme ligands. Angew Chem Int Ed Engl (2005) 1.11
Mononuclear nonheme ferric-peroxo complex in aldehyde deformylation. Chem Commun (Camb) (2005) 1.11
Axial ligand substituted nonheme FeIV=O complexes: observation of near-UV LMCT bands and Fe=O Raman vibrations. J Am Chem Soc (2005) 1.11
Photofunctional triplet excited states of cyclometalated Ir(III) complexes: beyond electroluminescence. Chem Soc Rev (2012) 1.10
Dioxygen activation by a non-heme iron(II) complex: formation of an iron(IV)-oxo complex via C-H activation by a putative iron(III)-superoxo species. J Am Chem Soc (2010) 1.10
Fundamental electron-transfer properties of non-heme oxoiron(IV) complexes. J Am Chem Soc (2007) 1.09
A mononuclear non-heme manganese(IV)-oxo complex binding redox-inactive metal ions. J Am Chem Soc (2013) 1.09
Nonheme oxoiron(IV) complexes of tris(2-pyridylmethyl)amine with cis-monoanionic ligands. Inorg Chem (2006) 1.04
Accelerated cerebral ischemic injury by activated macrophages/microglia after lipopolysaccharide microinjection into rat corpus callosum. Glia (2005) 1.04
Dioxygen activation and catalytic aerobic oxidation by a mononuclear nonheme iron(II) complex. J Am Chem Soc (2005) 1.04
Structural characterization and remarkable axial ligand effect on the nucleophilic reactivity of a nonheme manganese(III)-peroxo complex. Angew Chem Int Ed Engl (2009) 1.04
Oxoiron(IV) porphyrin pi-cation radical complexes with a chameleon behavior in cytochrome P450 model reactions. J Biol Inorg Chem (2005) 1.04
Oxygen-atom transfer between mononuclear nonheme iron(IV)-oxo and iron(II) complexes. Angew Chem Int Ed Engl (2006) 1.02
Synthesis, structural, and spectroscopic characterization and reactivities of mononuclear cobalt(III)-peroxo complexes. J Am Chem Soc (2010) 1.01
Identification of an "end-on" nickel-superoxo adduct, [Ni(tmc)(O2)]+. J Am Chem Soc (2006) 1.00
Dioxygen activation by mononuclear nonheme iron(II) complexes generates iron-oxygen intermediates in the presence of an NADH analogue and proton. J Am Chem Soc (2009) 1.00
Reactivities of mononuclear non-heme iron intermediates including evidence that iron(III)-hydroperoxo species is a sluggish oxidant. J Am Chem Soc (2006) 0.99
Enhanced reactivities of iron(IV)-oxo porphyrin pi-cation radicals in oxygenation reactions by electron-donating axial ligands. Chemistry (2009) 0.97
Fluorescent zinc sensor with minimized proton-induced interferences: photophysical mechanism for fluorescence turn-on response and detection of endogenous free zinc ions. Inorg Chem (2012) 0.97
[Fe(IV)═O(TBC)(CH3CN)]2+: comparative reactivity of iron(IV)-oxo species with constrained equatorial cyclam ligation. J Am Chem Soc (2012) 0.96
Metal ion effect on the switch of mechanism from direct oxygen transfer to metal ion-coupled electron transfer in the sulfoxidation of thioanisoles by a non-heme iron(IV)-oxo complex. J Am Chem Soc (2011) 0.96
Status of reactive non-heme metal-oxygen intermediates in chemical and enzymatic reactions. J Am Chem Soc (2014) 0.95
Enhanced electron-transfer reactivity of nonheme manganese(IV)-oxo complexes by binding scandium ions. J Am Chem Soc (2013) 0.94
Hydrogen-atom abstraction reactions by manganese(V)- and manganese(IV)-oxo porphyrin complexes in aqueous solution. Chemistry (2009) 0.93
Phosphorescent sensor for robust quantification of copper(II) ion. J Am Chem Soc (2011) 0.93
Comparison of high-spin and low-spin nonheme Fe(III)-OOH complexes in O-O bond homolysis and H-atom abstraction reactivities. J Am Chem Soc (2013) 0.92
Manganese displacement from Zinpyr-1 allows zinc detection by fluorescence microscopy and magnetic resonance imaging. Chem Commun (Camb) (2010) 0.92
Direct evidence for oxygen-atom exchange between nonheme oxoiron(IV) complexes and isotopically labeled water. Angew Chem Int Ed Engl (2004) 0.92
Chromium(IV)-peroxo complex formation and its nitric oxide dioxygenase reactivity. J Am Chem Soc (2012) 0.92
Scandium ion-enhanced oxidative dimerization and N-demethylation of N,N-dimethylanilines by a non-heme iron(IV)-oxo complex. Inorg Chem (2011) 0.91
Self-hydroxylation of perbenzoic acids at a nonheme iron(II) center. Chem Commun (Camb) (2005) 0.90
Combined experimental and theoretical study on aromatic hydroxylation by mononuclear nonheme iron(IV)-oxo complexes. Inorg Chem (2007) 0.90
Brønsted acid-promoted C-H bond cleavage via electron transfer from toluene derivatives to a protonated nonheme iron(IV)-oxo complex with no kinetic isotope effect. J Am Chem Soc (2013) 0.89
Reversible O-O bond cleavage and formation between Mn(IV)-peroxo and Mn(V)-oxo corroles. J Am Chem Soc (2010) 0.89
Evidence for an alternative to the oxygen rebound mechanism in C-H bond activation by non-heme Fe(IV)O complexes. J Am Chem Soc (2012) 0.89
Reactivity of a cobalt(III)-peroxo complex in oxidative nucleophilic reactions. J Inorg Biochem (2008) 0.88
Formation, stability, and reactivity of a mononuclear nonheme oxoiron(IV) complex in aqueous solution. Chem Commun (Camb) (2005) 0.88
Reactive intermediates in oxygenation reactions with mononuclear nonheme iron catalysts. Angew Chem Int Ed Engl (2009) 0.88
Electron-transfer reduction of dinuclear copper peroxo and bis-μ-oxo complexes leading to the catalytic four-electron reduction of dioxygen to water. Chemistry (2012) 0.88
Ligand topology effect on the reactivity of a mononuclear nonheme iron(IV)-oxo complex in oxygenation reactions. J Am Chem Soc (2011) 0.88
A biomimetic ferric hydroperoxo porphyrin intermediate. Angew Chem Int Ed Engl (2010) 0.87
Proton-promoted oxygen atom transfer vs proton-coupled electron transfer of a non-heme iron(IV)-oxo complex. J Am Chem Soc (2012) 0.87
Experiment and theory reveal the fundamental difference between two-state and single-state reactivity patterns in nonheme Fe(IV)=O versus Ru(IV)=O oxidants. Angew Chem Int Ed Engl (2008) 0.87
Mononuclear nickel(II)-superoxo and nickel(III)-peroxo complexes bearing a common macrocyclic TMC ligand. Chem Sci (2013) 0.87
Nonheme iron(II) complexes of macrocyclic ligands in the generation of oxoiron(IV) complexes and the catalytic epoxidation of olefins. J Inorg Biochem (2006) 0.87
Contrasting effects of axial ligands on electron-transfer versus proton-coupled electron-transfer reactions of nonheme oxoiron(IV) complexes. Chemistry (2010) 0.87
Mechanistic insights into hydride-transfer and electron-transfer reactions by a manganese(IV)-oxo porphyrin complex. J Am Chem Soc (2009) 0.86
A chromium(III)-superoxo complex in oxygen atom transfer reactions as a chemical model of cysteine dioxygenase. J Am Chem Soc (2012) 0.86
Reactions of a chromium(III)-superoxo complex and nitric oxide that lead to the formation of chromium(IV)-oxo and chromium(III)-nitrito complexes. J Am Chem Soc (2013) 0.85
Direct evidence for an iron(IV)-oxo porphyrin pi-cation radical as an active oxidant in catalytic oxygenation reactions. Chem Commun (Camb) (2008) 0.85
Phosphorescent sensor for biological mobile zinc. J Am Chem Soc (2011) 0.85
Hydrogen atom abstraction and hydride transfer reactions by iron(IV)-oxo porphyrins. Angew Chem Int Ed Engl (2008) 0.85
XAS and DFT investigation of mononuclear cobalt(III) peroxo complexes: electronic control of the geometric structure in CoO2 versus NiO2 systems. Inorg Chem (2010) 0.85
Unified view of oxidative C-H bond cleavage and sulfoxidation by a nonheme iron(IV)-oxo complex via Lewis acid-promoted electron transfer. Inorg Chem (2014) 0.84
Factors that control catalytic two- versus four-electron reduction of dioxygen by copper complexes. J Am Chem Soc (2012) 0.84
Water as an oxygen source in the generation of mononuclear nonheme iron(IV) oxo complexes. Angew Chem Int Ed Engl (2009) 0.84
Sulfur versus iron oxidation in an iron-thiolate model complex. J Am Chem Soc (2010) 0.84
Experimental and theoretical evidence for nonheme iron(III) alkylperoxo species as sluggish oxidants in oxygenation reactions. Angew Chem Int Ed Engl (2007) 0.84
A mononuclear non-heme high-spin iron(III)-hydroperoxo complex as an active oxidant in sulfoxidation reactions. J Am Chem Soc (2013) 0.84
High conversion of olefins to cis-diols by non-heme iron catalysts and H2O2. Chem Commun (Camb) (2002) 0.84
High-valent manganese(v)-oxo porphyrin complexes in hydride transfer reactions. Chem Commun (Camb) (2008) 0.84
A highly reactive mononuclear non-heme manganese(IV)-oxo complex that can activate the strong C-H bonds of alkanes. J Am Chem Soc (2011) 0.84
Oxidative N-dealkylation reactions by oxoiron(IV) complexes of nonheme and heme ligands. Inorg Chem (2007) 0.83
Highly reactive nonheme iron(III) iodosylarene complexes in alkane hydroxylation and sulfoxidation reactions. Angew Chem Int Ed Engl (2014) 0.83
Water oxidation catalysis with nonheme iron complexes under acidic and basic conditions: homogeneous or heterogeneous? Inorg Chem (2013) 0.83
Temperature-independent catalytic two-electron reduction of dioxygen by ferrocenes with a copper(II) tris[2-(2-pyridyl)ethyl]amine catalyst in the presence of perchloric acid. J Am Chem Soc (2013) 0.83
Catalytic four-electron reduction of O2 via rate-determining proton-coupled electron transfer to a dinuclear cobalt-μ-1,2-peroxo complex. J Am Chem Soc (2012) 0.83
Reactivity comparison of high-valent iron(IV)-oxo complexes bearing N-tetramethylated cyclam ligands with different ring size. Dalton Trans (2013) 0.82
How axial ligands control the reactivity of high-valent iron(IV)-oxo porphyrin pi-cation radicals in alkane hydroxylation: a computational study. J Inorg Biochem (2006) 0.82
A highly efficient non-heme manganese complex in oxygenation reactions. Chem Commun (Camb) (2007) 0.81
Spectroscopic and computational characterization of CuII-OOR (R = H or cumyl) complexes bearing a Me6-tren ligand. Dalton Trans (2011) 0.81
Photocatalytic generation of a non-heme oxoiron(IV) complex with water as an oxygen source. J Am Chem Soc (2011) 0.81
Manganese substituted Compound I of cytochrome P450 biomimetics: a comparative reactivity study of Mn(V)-oxo versus Mn(IV)-oxo species. Arch Biochem Biophys (2011) 0.80
The axial ligand effect on aliphatic and aromatic hydroxylation by non-heme iron(IV)-oxo biomimetic complexes. Chem Asian J (2010) 0.80
Water as an oxygen source: synthesis, characterization, and reactivity studies of a mononuclear nonheme manganese(IV) oxo complex. Angew Chem Int Ed Engl (2010) 0.80
Nonheme iron-oxo and -superoxo reactivities: O2 binding and spin inversion probability matter. Chem Commun (Camb) (2012) 0.80
Highly efficient photocatalytic oxygenation reactions using water as an oxygen source. Nat Chem (2010) 0.80
Parallel mechanistic studies on the counterion effect of manganese salen and porphyrin complexes on olefin epoxidation by iodosylarenes. J Inorg Biochem (2005) 0.80
Enantioselective recognition of 1,2-amino alcohols by reversible formation of imines with resonance-assisted hydrogen bonds. Org Lett (2005) 0.80
How does the axial ligand of cytochrome P450 biomimetics influence the regioselectivity of aliphatic versus aromatic hydroxylation? Chemistry (2009) 0.79
Mononuclear manganese-peroxo and bis(μ-oxo)dimanganese complexes bearing a common N-methylated macrocyclic ligand. Chemistry (2013) 0.79