Published in Science on January 29, 2010
A stable germanone as the first isolated heavy ketone with a terminal oxygen atom. Nat Chem (2012) 0.96
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Dispersion-Energy-Driven Wagner-Meerwein Rearrangements in Oligosilanes. J Am Chem Soc (2016) 0.76
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Putting pressure on aromaticity along with in situ experimental electron density of a molecular crystal. Nat Commun (2016) 0.75
Isolation and Versatile Derivatization of an Unsaturated Anionic Silicon Cluster (Siliconoid). Angew Chem Int Ed Engl (2016) 0.75
The stable pentamethylcyclopentadienyl cation remains unknown. Angew Chem Int Ed Engl (2002) 66.09
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One molecule, two atoms, three views, four bonds? Angew Chem Int Ed Engl (2013) 1.95
Iron and cobalt ethylene polymerization catalysts: variations on the central donor. Inorg Chem (2003) 1.95
Enhancement of the chemical semantic web through the use of InChI identifiers. Org Biomol Chem (2005) 1.77
Representation and use of chemistry in the global electronic age. Org Biomol Chem (2004) 1.65
Quadruple bonding in C2 and analogous eight-valence electron species. Nat Chem (2012) 1.62
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Chemical Markup, XML and the World-Wide Web. 8. Polymer Markup Language. J Chem Inf Model (2008) 1.51
SPECTRa: the deposition and validation of primary chemistry research data in digital repositories. J Chem Inf Model (2008) 1.48
A computational evaluation of the evidence for the synthesis of 1,3-dimethylcyclobutadiene in the solid state and aqueous solution. Chemistry (2013) 1.39
Chemical markup, XML, and the World Wide Web. 5. Applications of chemical metadata in RSS aggregators. J Chem Inf Comput Sci (2004) 1.37
Framework materials assembled from magnesium carboxylate building units. Dalton Trans (2007) 1.23
Four-coordinate iron complexes bearing alpha-diimine ligands: efficient catalysts for atom transfer radical polymerisation (ATRP). Chem Commun (Camb) (2002) 1.21
Dinuclear zinc complexes using pentadentate phenolate ligands. Inorg Chem (2008) 1.18
Chemistry in bioinformatics. BMC Bioinformatics (2005) 1.18
The vicinal difluoro motif: The synthesis and conformation of erythro- and threo- diastereoisomers of 1,2-difluorodiphenylethanes, 2,3-difluorosuccinic acids and their derivatives. Beilstein J Org Chem (2006) 1.17
Synthesis and structures of bimetallic and polymeric zinc coordination compounds supported by salicylaldiminato and anilido-aldimine ligands. Dalton Trans (2006) 1.17
Digital processing with a three-state molecular switch. J Org Chem (2003) 1.14
Titanium-salen complexes as initiators for the ring opening polymerisation of rac-lactide. Dalton Trans (2006) 1.13
Non-heme iron(II) complexes containing tripodal tetradentate nitrogen ligands and their application in alkane oxidation catalysis. Inorg Chem (2005) 1.11
CML: Evolution and design. J Cheminform (2011) 1.10
Digital data repositories in chemistry and their integration with journals and electronic notebooks. J Chem Inf Model (2014) 1.05
2,1,3-Benzothiadiazole-5,6-dicarboxylic imide--a versatile building block for additive- and annealing-free processing of organic solar cells with efficiencies exceeding 8%. Adv Mater (2014) 1.02
The use of imidazolium-2-dithiocarboxylates in the formation of gold(I) complexes and gold nanoparticles. Inorg Chem (2010) 0.99
On the determination of the stereochemistry of semisynthetic natural product analogues using chiroptical spectroscopy: desulfurization of epidithiodioxopiperazine fungal metabolites. Chemistry (2011) 0.98
Dramatic effect of heteroatom backbone substituents on the ethylene polymerization behavior of bis(imino)pyridine iron catalysts. Inorg Chem (2004) 0.97
Multimetallic complexes of group 10 and 11 metals based on polydentate dithiocarbamate ligands. Dalton Trans (2011) 0.93
A study in mauve: unveiling Perkin's dye in historic samples. Chemistry (2008) 0.92
Towards photocatalytic alkane oxidation: the insertion of dioxygen into a platinum(II)-methyl bond. Angew Chem Int Ed Engl (2009) 0.92
SemanticEye: a semantic web application to rationalize and enhance chemical electronic publishing. J Chem Inf Model (2006) 0.92
Rationalization and prediction of solution enantiomeric excess in ternary phase systems. Angew Chem Int Ed Engl (2006) 0.92
Phosphide delivery to a cyclotrisilene. Angew Chem Int Ed Engl (2014) 0.91
Gold(I) complexes bearing mixed-donor ligands derived from N-heterocyclic carbenes. Dalton Trans (2011) 0.91
Chromogenic oxazines for cyanide detection. J Org Chem (2006) 0.91
Di- and tri-zinc catalysts for the low-pressure copolymerization of CO2 and cyclohexene oxide. Inorg Chem (2009) 0.91
Suitanes. Angew Chem Int Ed Engl (2006) 0.90
A computational investigation of the structure of polythiocyanogen. Dalton Trans (2008) 0.90
Nondegenerate pi-donor/pi-acceptor [2]catenanes containing proton-ionizable 1H-1,2,4-triazole subunits: synthesis and spontaneous resolution. Chemistry (2007) 0.90
Stable cyclic silenes from reaction of disilenides with carboxylic acid chlorides. Angew Chem Int Ed Engl (2007) 0.90
Discovery and optimization of new chromium catalysts for ethylene oligomerization and polymerization aided by high-throughput screening. J Am Chem Soc (2005) 0.90
A simple, short, and flexible synthesis of viridiofungin derivatives. J Org Chem (2006) 0.89
Bromoiodinanes with an I(III)-Br bond: preparation, X-ray crystallography and reactivity as electrophilic brominating agents. Chem Commun (Camb) (2006) 0.89
Communication and re-use of chemical information in bioscience. BMC Bioinformatics (2005) 0.89
Bypassing a highly unstable frustrated Lewis pair: dihydrogen cleavage by a thermally robust silylium-phosphine adduct. Chem Commun (Camb) (2014) 0.89
Emergence of solution-phase homochirality via crystal engineering of amino acids. J Am Chem Soc (2007) 0.88
Zirconocene dichloride catalyzed hydrodefluorination of C(sp 2)-F bonds. Angew Chem Int Ed Engl (2012) 0.88
Highly convergent three component benzyne coupling: the total synthesis of ent-clavilactone B. J Am Chem Soc (2006) 0.88
The surprisingly beneficial effect of soft donors on the performance of early transition metal olefin polymerisation catalysts. Chem Commun (Camb) (2004) 0.88
Stereocontrolled lactide polymerisation determined by the nuclearity of the yttrium initiator. Chem Commun (Camb) (2009) 0.87
Study of ligand substituent effects on the rate and stereoselectivity of lactide polymerization using aluminum salen-type initiators. Proc Natl Acad Sci U S A (2006) 0.87
Defining the mechanism of action and enzymatic selectivity of psammaplin A against its epigenetic targets. J Med Chem (2012) 0.87
Crocker, not Armit and Robinson, begat the six aromatic electrons. Chem Rev (2005) 0.87
Remarkable stereocontrol in the polymerization of racemic lactide using aluminum initiators supported by tetradentate aminophenoxide ligands. J Am Chem Soc (2004) 0.87
Synthetic, structural, mechanistic, and computational studies on single-site beta-diketiminate tin(II) initiators for the polymerization of rac-lactide. J Am Chem Soc (2006) 0.86
Novel unsymmetrical P/O substituted ferrocene ligands and the first structurally characterised hydroxyferrocene derivative. Dalton Trans (2004) 0.86
Porphyrazines as molecular scaffolds: flexible syntheses of novel multimetallic complexes. Inorg Chem (2006) 0.86
Structural reassignment of obtusallenes V, VI, and VII by GIAO-based density functional prediction. J Nat Prod (2008) 0.86
Successful computational modeling of isobornyl chloride ion-pair mechanisms. J Org Chem (2010) 0.86
Synthesis of iron(II), manganese(II) cobalt(II) and ruthenium(II) complexes containing tridentate nitrogen ligands and their application in the catalytic oxidation of alkanes. Dalton Trans (2005) 0.85
Synthesis of novel thieno[3,2-b]thienobis(silolothiophene) based low bandgap polymers for organic photovoltaics. Chem Commun (Camb) (2012) 0.85
Novel H2 activation by a tris[3,5-bis(trifluoromethyl)phenyl]borane frustrated Lewis pair. Dalton Trans (2012) 0.85
NHC-stabilized silagermenylidene: a heavier analogue of vinylidene. Angew Chem Int Ed Engl (2013) 0.85
NHC-coordinated silagermenylidene functionalized in allylic position and its behaviour as a ligand. Dalton Trans (2014) 0.84
Unified route to the palmarumycin and preussomerin natural products. Enantioselective synthesis of (-)-preussomerin G. J Org Chem (2002) 0.84
N-heterocyclic carbene coordinated neutral and cationic heavier cyclopropylidenes. Angew Chem Int Ed Engl (2014) 0.83
Design of highly active iron-based catalysts for atom transfer radical polymerization: tridentate salicylaldiminato ligands affording near ideal Nernstian behavior. J Am Chem Soc (2003) 0.83
Elucidating the mechanism of the asymmetric aza-Michael reaction. Chemistry (2007) 0.83
Reversible base coordination to a disilene. Angew Chem Int Ed Engl (2012) 0.83
Methylene-bridged bis(imidazoline)-derived 2-oxopyrimidinium salts as catalysts for asymmetric Michael reactions. Angew Chem Int Ed Engl (2013) 0.82
A biosynthetically-inspired synthesis of the tetrahydrofuran core of obtusallenes II and IV. Org Lett (2007) 0.82
The functionalisation of ruthenium(II) and osmium(II) alkenyl complexes with amine- and alkoxy-terminated dithiocarbamates. Dalton Trans (2010) 0.82
Constrained beta-proline analogues in organocatalytic aldol reactions: the influence of acid geometry. J Org Chem (2009) 0.82
Tri(pyridylmethyl)phosphine: the elusive congener of TPA shows surprisingly different coordination behavior. Inorg Chem (2013) 0.82
Coordination chemistry with phosphine and phosphine oxide-substituted hydroxyferrocenes. Dalton Trans (2010) 0.82
Syntheses of trisila analogues of allyl chlorides and their transformations to chlorocyclotrisilanes, cyclotrisilanides, and a trisilaindane. J Am Chem Soc (2008) 0.82
A global resource for computational chemistry. J Mol Model (2005) 0.82
Claisen rearrangements of equilibrating allylic azides. Org Biomol Chem (2011) 0.82
The generation and trapping of enantiopure bromonium ions. Chem Commun (Camb) (2009) 0.82
Synthesis of two novel dinuclear palladium(I) complexes and studies of their catalytic activity in amination reactions. Chem Commun (Camb) (2004) 0.81
Arylazopyrazoles: azoheteroarene photoswitches offering quantitative isomerization and long thermal half-lives. J Am Chem Soc (2014) 0.81
Silver-catalysed enantioselective addition of O-H and N-H bonds to allenes: a new model for stereoselectivity based on noncovalent interactions. Chemistry (2012) 0.81
A computational analysis of the ring-opening polymerization of rac-lactide initiated by single-site beta-diketiminate metal complexes: defining the mechanistic pathway and the origin of stereocontrol. J Am Chem Soc (2005) 0.81
Studies towards the synthesis of halomon: asymmetric hexafunctionalisation of myrcene. Chem Commun (Camb) (2014) 0.81
Intramolecular bromonium ion assisted epoxide ring-opening: capture of the oxonium ion with an added external nucleophile. J Org Chem (2010) 0.81
Synthesis of diverse macrocyclic peptidomimetics utilizing ring-closing metathesis and solid-phase synthesis. J Org Chem (2004) 0.81
In vitro DNA scission activity of heterometallocenes. Dalton Trans (2007) 0.81
Ligand topology variations and the importance of ligand field strength in non-heme iron catalyzed oxidations of alkanes. Inorg Chem (2007) 0.80
Correlation of metal spin state with catalytic reactivity: polymerizations mediated by alpha-diimine-iron complexes. Angew Chem Int Ed Engl (2006) 0.80
Synthesis, characterization, and reactivity of ruthenium hydride complexes of N-centered triphosphine ligands. Inorg Chem (2014) 0.80
Studies on the total synthesis of lactonamycin: synthesis of the CDEF ring system. J Org Chem (2006) 0.80
A T-shaped platinum(II) boryl complex as the precursor to a platinum compound with a base-stabilized borylene ligand. Angew Chem Int Ed Engl (2005) 0.80
Contraction and expansion of the silicon scaffold of stable Si6R6 isomers. J Am Chem Soc (2012) 0.80
Fast and stable photochromic oxazines. J Org Chem (2005) 0.80