Published in Angew Chem Int Ed Engl on July 26, 2010
Synthesis of cyclic enones via direct palladium-catalyzed aerobic dehydrogenation of ketones. J Am Chem Soc (2011) 1.39
Intramolecular Pd(II)-catalyzed aerobic oxidative amination of alkenes: synthesis of six-membered N-heterocycles. Org Lett (2012) 0.91
Vicinal diamination of alkenes under Rh-catalysis. J Am Chem Soc (2014) 0.90
Enantioselective Dehydrogenative Heck Arylations of Trisubstituted Alkenes with Indoles to Construct Quaternary Stereocenters. J Am Chem Soc (2015) 0.89
Alkenyl carbonyl derivatives in enantioselective redox relay Heck reactions: accessing α,β-unsaturated systems. J Am Chem Soc (2015) 0.87
Characterization of DMSO coordination to palladium(II) in solution and insights into the aerobic oxidation catalyst, Pd(DMSO)2(TFA)2. Inorg Chem (2012) 0.86
Catalyst-controlled C-O versus C-N allylic functionalization of terminal olefins. J Am Chem Soc (2013) 0.83
Synthesis of vicinal aminoalcohols by stereoselective aza-Wacker cyclizations: access to (-)-acosamine by redox relay. Angew Chem Int Ed Engl (2013) 0.83
Asymmetric Palladium-Catalyzed Alkene Carboamination Reactions for the Synthesis of Cyclic Sulfamides. Chemistry (2016) 0.79
Stereoselective synthesis of cis-2,5-disubstituted pyrrolidines via Wacker-type aerobic oxidative cyclization of alkenes with tert-butanesulfinamide nucleophiles. Org Lett (2012) 0.77
In situ tether formation from amines and alcohols enabling highly selective Tsuji-Trost allylation and olefin functionalization. Chem Sci (2016) 0.75
Intramolecular Radical Aziridination of Allylic Sulfamoyl Azides by Cobalt(II)-Based Metalloradical Catalysis: Effective Construction of Strained Heterobicyclic Structures. Angew Chem Int Ed Engl (2016) 0.75
Intramolecular 1,5-C(sp(3))-H Radical Amination via Co(II)-Based Metalloradical Catalysis for Five-Membered Cyclic Sulfamides. Chem Sci (2016) 0.75
Palladium oxidase catalysis: selective oxidation of organic chemicals by direct dioxygen-coupled turnover. Angew Chem Int Ed Engl (2004) 3.00
Vicinal diamino functionalities as privileged structural elements in biologically active compounds and exploitation of their synthetic chemistry. Chem Biol Drug Des (2006) 2.22
Palladium(II)-catalyzed intramolecular diamination of unfunctionalized alkenes. J Am Chem Soc (2005) 2.04
Serial ligand catalysis: a highly selective allylic C-H oxidation. J Am Chem Soc (2005) 1.89
A sulfoxide-promoted, catalytic method for the regioselective synthesis of allylic acetates from monosubstituted olefins via C-H oxidation. J Am Chem Soc (2004) 1.75
Pd(II)-catalyzed intermolecular 1,2-diamination of conjugated dienes. J Am Chem Soc (2005) 1.71
Catalytic and highly regioselective cross-coupling of aromatic C-H substrates. J Am Chem Soc (2007) 1.63
Catalytic asymmetric allylic and homoallylic diamination of terminal olefins via formal C-H activation. J Am Chem Soc (2008) 1.59
Oxidative cyclizations in a nonpolar solvent using molecular oxygen and studies on the stereochemistry of oxypalladation. J Am Chem Soc (2005) 1.55
Copper(II) carboxylate promoted intramolecular diamination of terminal alkenes: improved reaction conditions and expanded substrate scope. Org Lett (2007) 1.49
A Pd(0)-catalyzed diamination of terminal olefins at allylic and homoallylic carbons via formal C-H activation under solvent-free conditions. J Am Chem Soc (2007) 1.48
syn-1,2-Amino alcohols via diastereoselective allylic C-H amination. J Am Chem Soc (2007) 1.47
Twofold C-H functionalization: palladium-catalyzed ortho arylation of anilides. Org Lett (2008) 1.46
Palladium(II)-Catalyzed Intramolecular Aminocarbonylation of endo-Carbamates under Wacker-Type Conditions. J Org Chem (1997) 1.44
Exploring the nickel-catalyzed oxidation of alkenes: a diamination by sulfamide transfer. Angew Chem Int Ed Engl (2007) 1.42
Palladium(II)-Catalyzed Cyclization of Olefinic Tosylamides. J Org Chem (1996) 1.41
Mechanism of Pd(OAc)2/DMSO-catalyzed aerobic alcohol oxidation: mass-transfer-limitation effects and catalyst decomposition pathways. J Am Chem Soc (2006) 1.33
Efficient intramolecular oxidative amination of olefins through direct dioxygen-coupled palladium catalysis. Angew Chem Int Ed Engl (2002) 1.32
Transition-metal-catalyzed diamination of olefins. Angew Chem Int Ed Engl (2009) 1.30
Stereoselective synthesis of imidazolidin-2-ones via Pd-catalyzed alkene carboamination. Scope and limitations. Tetrahedron (2008) 1.26
A new synthesis of imidazolidin-2-ones via Pd-catalyzed carboamination of N-allylureas. Org Lett (2006) 1.23
Palladium-catalyzed diamination of unactivated alkenes using N-fluorobenzenesulfonimide as source of electrophilic nitrogen. Org Lett (2009) 1.23
Cu(I)-catalyzed asymmetric diamination of conjugated dienes. Org Lett (2008) 1.19
Catalytic C-H amination for the preparation of substituted 1,2-diamines. J Am Chem Soc (2008) 1.15
Synthetic and mechanistic studies on Pd(0)-catalyzed diamination of conjugated dienes. J Am Chem Soc (2010) 1.14
Chemistry. Palladium-catalyzed oxidation of organic chemicals with O2. Science (2005) 1.12
Mechanistic study of alcohol oxidation by the Pd(OAc)(2)/O(2)/DMSO catalyst system and implications for the development of improved aerobic oxidation catalysts. J Am Chem Soc (2002) 1.11
A palladium-catalyzed dehydrogenative diamination of terminal olefins. Angew Chem Int Ed Engl (2008) 1.07
A convenient palladium-catalyzed aerobic oxidation of alcohols at room temperature. Chem Commun (Camb) (2002) 1.03
Asymmetric synthesis of alpha-branched allylic amines by the Rh(I)-catalyzed addition of alkenyltrifluoroborates to N-tert-butanesulfinyl aldimines. J Am Chem Soc (2009) 0.99
Asymmetric synthesis of diamine derivatives via sequential palladium and rhodium catalysis. J Am Chem Soc (2009) 0.94
Synthesis of (+)-CP-99,994 via Pd(0)-catalyzed asymmetric allylic and homoallylic C-H Diamination of terminal olefin. J Org Chem (2009) 0.83
Mimicry of antimicrobial host-defense peptides by random copolymers. J Am Chem Soc (2007) 2.12
Copper-catalyzed aerobic oxidative C-H functionalizations: trends and mechanistic insights. Angew Chem Int Ed Engl (2011) 1.79
Palladium(II)-catalyzed alkene functionalization via nucleopalladation: stereochemical pathways and enantioselective catalytic applications. Chem Rev (2011) 1.76
Highly regioselective Pd-catalyzed intermolecular aminoacetoxylation of alkenes and evidence for cis-aminopalladation and S(N)2 C-O bond formation. J Am Chem Soc (2006) 1.69
Highly practical copper(I)/TEMPO catalyst system for chemoselective aerobic oxidation of primary alcohols. J Am Chem Soc (2011) 1.64
Synthesis of pyrrolidines via palladium(II)-catalyzed aerobic oxidative carboamination of butyl vinyl ether and styrenes with allyl tosylamides. Org Lett (2006) 1.50
Copper-catalyzed aerobic oxidative amidation of terminal alkynes: efficient synthesis of ynamides. J Am Chem Soc (2008) 1.48
Palladium-catalyzed aerobic oxidative amination of alkenes: development of intra- and intermolecular aza-Wacker reactions. Inorg Chem (2007) 1.43
Carbon-nitrogen bond formation involving well-defined aryl-copper(III) complexes. J Am Chem Soc (2008) 1.40
Synthesis of cyclic enones via direct palladium-catalyzed aerobic dehydrogenation of ketones. J Am Chem Soc (2011) 1.39
Copper-catalyzed aerobic oxidative functionalization of an arene C-H bond: evidence for an aryl-copper(III) intermediate. J Am Chem Soc (2010) 1.38
Dual mechanism of bacterial lethality for a cationic sequence-random copolymer that mimics host-defense antimicrobial peptides. J Mol Biol (2008) 1.37
Mechanistic study of copper-catalyzed aerobic oxidative coupling of arylboronic esters and methanol: insights into an organometallic oxidase reaction. J Am Chem Soc (2009) 1.34
Mechanism of Pd(OAc)2/DMSO-catalyzed aerobic alcohol oxidation: mass-transfer-limitation effects and catalyst decomposition pathways. J Am Chem Soc (2006) 1.33
Efficient intramolecular oxidative amination of olefins through direct dioxygen-coupled palladium catalysis. Angew Chem Int Ed Engl (2002) 1.32
Two-faced reactivity of alkenes: cis- versus trans-aminopalladation in aerobic Pd-catalyzed intramolecular aza-Wacker reactions. J Am Chem Soc (2007) 1.31
Allylic C-H acetoxylation with a 4,5-diazafluorenone-ligated palladium catalyst: a ligand-based strategy to achieve aerobic catalytic turnover. J Am Chem Soc (2010) 1.29
Development of Safe and Scalable Continuous-Flow Methods for Palladium-Catalyzed Aerobic Oxidation Reactions. Green Chem (2010) 1.29
Structure-activity relationships among random nylon-3 copolymers that mimic antibacterial host-defense peptides. J Am Chem Soc (2009) 1.26
Overcoming the "oxidant problem": strategies to use O2 as the oxidant in organometallic C-H oxidation reactions catalyzed by Pd (and Cu). Acc Chem Res (2012) 1.25
Palladium-catalyzed aerobic dehydrogenation of substituted cyclohexanones to phenols. Science (2011) 1.24
Enantioselective Pd(II)-catalyzed aerobic oxidative amidation of alkenes and insights into the role of electronic asymmetry in pyridine-oxazoline ligands. Org Lett (2011) 1.23
Aerobic oxidative amination of unactivated alkenes catalyzed by palladium. J Am Chem Soc (2005) 1.22
Ligand-modulated palladium oxidation catalysis: mechanistic insights into aerobic alcohol oxidation with the Pd(OAc)(2)/pyridine catalyst system. Org Lett (2002) 1.20
Mechanistic characterization of aerobic alcohol oxidation catalyzed by Pd(OAc)(2)/pyridine including identification of the catalyst resting state and the origin of nonlinear [catalyst] dependence. J Am Chem Soc (2004) 1.19
Chemoselective metal-free aerobic alcohol oxidation in lignin. J Am Chem Soc (2013) 1.18
Access to poly-beta-peptides with functionalized side chains and end groups via controlled ring-opening polymerization of beta-lactams. J Am Chem Soc (2009) 1.17
Regioselective copper-catalyzed chlorination and bromination of arenes with O(2) as the oxidant. Chem Commun (Camb) (2009) 1.14
Mechanistic study of alcohol oxidation by the Pd(OAc)(2)/O(2)/DMSO catalyst system and implications for the development of improved aerobic oxidation catalysts. J Am Chem Soc (2002) 1.11
Aerobic Oxidative Coupling of o-Xylene: Discovery of 2-Fluoropyridine as a Ligand to Support Selective Pd-Catalyzed C-H Functionalization. Adv Synth Catal (2010) 1.10
Enantioselective hydroformylation of N-vinyl carboxamides, allyl carbamates, and allyl ethers using chiral diazaphospholane ligands. J Am Chem Soc (2010) 1.09
Practical aerobic oxidations of alcohols and amines with homogeneous copper/TEMPO and related catalyst systems. Angew Chem Int Ed Engl (2014) 1.09
Reaction of molecular oxygen with a Pd(II)-hydride to produce a Pd(II)-hydroperoxide: experimental evidence for an HX-reductive-elimination pathway. J Am Chem Soc (2008) 1.08
Unexpected roles of molecular sieves in palladium-catalyzed aerobic alcohol oxidation. J Org Chem (2006) 1.08
Catalytic transamidation reactions compatible with tertiary amide metathesis under ambient conditions. J Am Chem Soc (2009) 1.06
"Inverse-electron-demand" ligand substitution: experimental and computational insights into olefin exchange at palladium(0). J Am Chem Soc (2004) 1.04
Mechanistic study of asymmetric oxidative biaryl coupling: evidence for self-processing of the copper catalyst to achieve control of oxidase vs oxygenase activity. J Am Chem Soc (2008) 1.03
Reversible alkene insertion into the Pd-N bond of Pd(II)-sulfonamidates and implications for catalytic amidation reactions. J Am Chem Soc (2011) 1.03
Reconciling the stereochemical course of nucleopalladation with the development of enantioselective wacker-type cyclizations. Angew Chem Int Ed Engl (2012) 1.03
Mechanism of Pd(OAc)2/pyridine catalyst reoxidation by O2: influence of labile monodentate ligands and identification of a biomimetic mechanism for O2 activation. Chemistry (2009) 1.02
Catalytic transamidation under moderate conditions. J Am Chem Soc (2003) 1.01
Highly stable redox-active molecular layers by covalent grafting to conductive diamond. J Am Chem Soc (2011) 1.01
Copper(I)/ABNO-catalyzed aerobic alcohol oxidation: alleviating steric and electronic constraints of Cu/TEMPO catalyst systems. J Am Chem Soc (2013) 1.00
Direct Aerobic α, β-Dehydrogenation of Aldehydes and Ketones with a Pd(TFA)(2)/4,5-Diazafluorenone Catalyst(). Chem Sci (2011) 0.98
Mechanism of copper(I)/TEMPO-catalyzed aerobic alcohol oxidation. J Am Chem Soc (2013) 0.97
Mechanistic studies of Wacker-type intramolecular aerobic oxidative amination of alkenes catalyzed by Pd(OAc)2/pyridine. J Org Chem (2011) 0.97
Formation of enamides via palladium(II)-catalyzed vinyl transfer from vinyl ethers to nitrogen nucleophiles. Org Lett (2004) 0.97
Catalyst-controlled regioselectivity in the synthesis of branched conjugated dienes via aerobic oxidative Heck reactions. J Am Chem Soc (2012) 0.96
Catalytic metathesis of simple secondary amides. Angew Chem Int Ed Engl (2007) 0.96
Regiocontrolled aerobic oxidative coupling of indoles and benzene using Pd catalysts with 4,5-diazafluorene ligands. Chem Commun (Camb) (2011) 0.95
Aerobic oxidative Heck/dehydrogenation reactions of cyclohexenones: efficient access to meta-substituted phenols. Angew Chem Int Ed Engl (2013) 0.93
Characterization of peroxo and hydroperoxo intermediates in the aerobic oxidation of N-heterocyclic-carbene-coordinated palladium(0). J Am Chem Soc (2004) 0.93
Mechanistic studies of Wacker-type amidocyclization of alkenes catalyzed by (IMes)Pd(TFA)2(H2O): kinetic and stereochemical implications of proton transfer. J Org Chem (2012) 0.93
Pd-catalyzed Semmler-Wolff reactions for the conversion of substituted cyclohexenone oximes to primary anilines. J Am Chem Soc (2013) 0.93
PdII complexes possessing a seven-membered N-heterocyclic carbene ligand. Angew Chem Int Ed Engl (2005) 0.93
Nylon-3 copolymers that generate cell-adhesive surfaces identified by library screening. J Am Chem Soc (2009) 0.92
Mechanism of alcohol oxidation mediated by copper(II) and nitroxyl radicals. J Am Chem Soc (2014) 0.92
Observation and mechanistic study of facile C-O bond formation between a well-defined aryl-copper(III) complex and oxygen nucleophiles. Chemistry (2011) 0.91
Biophysical mimicry of lung surfactant protein B by random nylon-3 copolymers. J Am Chem Soc (2010) 0.91
Intramolecular Pd(II)-catalyzed aerobic oxidative amination of alkenes: synthesis of six-membered N-heterocycles. Org Lett (2012) 0.91
Palladium-catalyzed intermolecular aminoacetoxylation of alkenes and the influence of PhI(OAc)2 on aminopalladation stereoselectivity. J Org Chem (2013) 0.90
Palladium-catalyzed oxidative amination of alkenes: improved catalyst reoxidation enables the use of alkene as the limiting reagent. Org Lett (2007) 0.89
Dioxygen-coupled oxidative amination of styrene. J Am Chem Soc (2003) 0.89
Aerobic intramolecular oxidative amination of alkenes catalyzed by NHC-coordinated palladium complexes. Org Lett (2006) 0.89
Electrochemical water oxidation with cobalt-based electrocatalysts from pH 0-14: the thermodynamic basis for catalyst structure, stability, and activity. J Am Chem Soc (2011) 0.88
Copper(I)/TEMPO-catalyzed aerobic oxidation of primary alcohols to aldehydes with ambient air. Nat Protoc (2012) 0.88
Insertion of molecular oxygen into a palladium-hydride bond: computational evidence for two nearly isoenergetic pathways. J Am Chem Soc (2007) 0.88
Aerobic dehydrogenation of cyclohexanone to phenol catalyzed by Pd(TFA)2/2-dimethylaminopyridine: evidence for the role of Pd nanoparticles. J Am Chem Soc (2013) 0.88
Effects of side chain configuration and backbone spacing on the gene delivery properties of lysine-derived cationic polymers. Bioconjug Chem (2005) 0.88
Chemoselective organocatalytic aerobic oxidation of primary amines to secondary imines. Org Lett (2012) 0.87
C-terminal functionalization of nylon-3 polymers: effects of C-terminal groups on antibacterial and hemolytic activities. Biomacromolecules (2011) 0.87
Synthesis of Pd Complexes Bearing an Enantiomerically-Resolved Seven-Membered N-Heterocyclic Carbene Ligands and Initial Studies of their Use in Asymmetric Wacker-Type Oxidative Cyclization Reactions. Tetrahedron (2009) 0.87
Reaction of O2 with [(-)-sparteine]Pd(H)Cl: evidence for an intramolecular [H-L]+ "reductive elimination" pathway. J Am Chem Soc (2011) 0.87
Cooperative electrocatalytic alcohol oxidation with electron-proton-transfer mediators. Nature (2016) 0.86
Characterization of DMSO coordination to palladium(II) in solution and insights into the aerobic oxidation catalyst, Pd(DMSO)2(TFA)2. Inorg Chem (2012) 0.86
Steric modulation of chiral biaryl diamines via Pd-catalyzed directed C-H arylation. J Org Chem (2009) 0.85
Benzoquinone-promoted reaction of O2 with a Pd(II)-hydride. J Am Chem Soc (2011) 0.85
Reaction of molecular oxygen with a PdII- hydride to produce a PdII-hydroperoxide: acid catalysis and implications for Pd-catalyzed aerobic oxidation reactions. Angew Chem Int Ed Engl (2006) 0.85
Synthesis of beta-lactams bearing functionalized side chains from a readily available precursor. Org Lett (2008) 0.85
Brønsted base-modulated regioselectivity in the aerobic oxidative amination of styrene catalyzed by palladium. J Am Chem Soc (2005) 0.84
Cu/Nitroxyl Catalyzed Aerobic Oxidation of Primary Amines into Nitriles at Room Temperature. ACS Catal (2013) 0.84
Divergence between organometallic and single-electron-transfer mechanisms in copper(II)-mediated aerobic C-H oxidation. J Am Chem Soc (2013) 0.84
Modular Synthesis of 1,2-Diamine Derivatives via Palladium-Catalyzed Aerobic Oxidative Cyclization of Allylic Sulfamides. Angew Chem Int Ed Engl (2010) 0.83
Synthesis of vicinal aminoalcohols by stereoselective aza-Wacker cyclizations: access to (-)-acosamine by redox relay. Angew Chem Int Ed Engl (2013) 0.83
Molecular mechanism of acid-triggered aryl-halide reductive elimination in well-defined aryl-Cu(III)-halide species. Dalton Trans (2010) 0.83
Mechanistic analysis of trans C-N reductive elimination from a square-planar macrocyclic aryl-copper(III) complex. Dalton Trans (2011) 0.83
Reaction of molecular oxygen with an NHC-coordinated Pd0 complex: computational insights and experimental implications. Angew Chem Int Ed Engl (2007) 0.83
Functionally Diverse Nylon-3 Copolymers from Readily Accessible β-Lactams. ACS Macro Lett (2012) 0.83
Electronic structural comparison of the reactions of dioxygen and alkenes with nitrogen-chelated palladium(0). Inorg Chem (2010) 0.82
Fluoride-modulated cobalt catalysts for electrochemical oxidation of water under non-alkaline conditions. ChemSusChem (2010) 0.82
Pd-catalyzed aerobic oxidative coupling of arenes: evidence for transmetalation between two Pd(II)-aryl intermediates. J Am Chem Soc (2014) 0.82
Bioinspired aerobic oxidation of secondary amines and nitrogen heterocycles with a bifunctional quinone catalyst. J Am Chem Soc (2013) 0.81
Aerobic dehydrogenation of cyclohexanone to cyclohexenone catalyzed by Pd(DMSO)2(TFA)2: evidence for ligand-controlled chemoselectivity. J Am Chem Soc (2013) 0.81
Modular o-quinone catalyst system for dehydrogenation of tetrahydroquinolines under ambient conditions. J Am Chem Soc (2014) 0.81
Insights into the spin-forbidden reaction between L2Pd0 and molecular oxygen. J Am Chem Soc (2004) 0.80
Modular synthesis of alkyne-substituted ruthenium polypyridyl complexes suitable for "click" coupling. Inorg Chem (2013) 0.78
Kinetic and Spectroscopic Studies of Aerobic Copper(II)-Catalyzed Methoxylation of Arylboronic Esters and Insights into Aryl Transmetalation to Copper(II). Organometallics (2012) 0.78
Synthesis and isolation of a stable, axially-chiral seven-membered N-heterocyclic carbene. Dalton Trans (2009) 0.78
Copper(II)-mediated oxidative cyclization of enamides to oxazoles. Org Biomol Chem (2012) 0.78
Development of an O2-sensitive fluorescence-quenching assay for the combinatorial discovery of electrocatalysts for water oxidation. Angew Chem Int Ed Engl (2012) 0.77