Published in Angew Chem Int Ed Engl on October 27, 2011
Aerobic copper-catalyzed organic reactions. Chem Rev (2013) 1.54
High-valent organometallic copper and palladium in catalysis. Nature (2012) 1.46
Overcoming the "oxidant problem": strategies to use O2 as the oxidant in organometallic C-H oxidation reactions catalyzed by Pd (and Cu). Acc Chem Res (2012) 1.25
Forming all-carbon quaternary stereogenic centres in acyclic systems from alkynes. Nature (2012) 1.07
A Highly Selective Vanadium Catalyst for Benzylic C-H Oxidation. Chem Sci (2012) 1.07
Metal-free α-amination of secondary amines: computational and experimental evidence for azaquinone methide and azomethine ylide intermediates. J Org Chem (2013) 1.02
Copper-promoted sulfenylation of sp2 C-H bonds. J Am Chem Soc (2012) 1.01
Redox-neutral copper(II) carboxylate catalyzed α-alkynylation of amines. Angew Chem Int Ed Engl (2013) 1.01
Double-fold C-H oxygenation of arenes using PyrDipSi: a general and efficient traceless/modifiable silicon-tethered directing group. J Am Chem Soc (2012) 0.99
Cobalt-catalyzed, aminoquinoline-directed C(sp²)-H bond alkenylation by alkynes. Angew Chem Int Ed Engl (2014) 0.93
Copper-catalyzed recycling of halogen activating groups via 1,3-halogen migration. J Am Chem Soc (2012) 0.92
Redox-neutral α-oxygenation of amines: reaction development and elucidation of the mechanism. J Am Chem Soc (2014) 0.91
N-Acyloxyphthalimides as nitrogen radical precursors in the visible light photocatalyzed room temperature C-H amination of arenes and heteroarenes. J Am Chem Soc (2014) 0.91
Redox-neutral α-arylation of amines. Org Lett (2013) 0.90
Copper-catalyzed etherification of arene C-H bonds. Org Lett (2013) 0.88
Redox-neutral α,β-difunctionalization of cyclic amines. Angew Chem Int Ed Engl (2014) 0.87
Alkenyl carbonyl derivatives in enantioselective redox relay Heck reactions: accessing α,β-unsaturated systems. J Am Chem Soc (2015) 0.87
Facile Access to Ring-Fused Aminals via Direct α-Amination of Secondary Amines with ortho-Aminobenzaldehydes. Synthesis of Vasicine, Deoxyvasicine, Deoxyvasicinone, Mackinazolinone and Ruteacarpine. Synthesis (Stuttg) (2013) 0.87
Copper-catalyzed regioselective ortho C-H cyanation of vinylarenes. Angew Chem Int Ed Engl (2014) 0.87
The redox-Mannich reaction. Org Lett (2014) 0.85
Copper-catalyzed oxytrifluoromethylation of unactivated alkenes. J Am Chem Soc (2012) 0.84
Selective copper(II) acetate and potassium iodide catalyzed oxidation of aminals to dihydroquinazoline and quinazolinone alkaloids. Beilstein J Org Chem (2013) 0.83
Mechanistic studies of copper(I)-catalyzed 1,3-halogen migration. J Am Chem Soc (2015) 0.81
C-H bond halogenation catalyzed or mediated by copper: an overview. Beilstein J Org Chem (2015) 0.81
Cu-catalyzed direct amidation of aromatic C-H bonds: an access to arylamines. J Org Chem (2014) 0.80
Isolation of a 2-hydroxytetrahydrofuran complex from copper-promoted hydroxylation of THF. Inorg Chem (2013) 0.80
Purinyl N1-directed aromatic C-H oxidation in 6-arylpurines and 6-arylpurine nucleosides. J Org Chem (2013) 0.80
Palladium-catalyzed dual C-H or N-H functionalization of unfunctionalized indole derivatives with alkenes and arenes. Beilstein J Org Chem (2012) 0.79
Access to a Cu(II)-O-Cu(II) motif: spectroscopic properties, solution structure, and reactivity. J Am Chem Soc (2013) 0.79
Stereodefined trisubstituted enolates as a unique entry to all-carbon quaternary stereogenic centers in acyclic systems. Nat Protoc (2013) 0.79
Reactivity of (Dicarboxamide)M(II)-OH (M = Cu, Ni) Complexes: Reaction with Acetonitrile to Yield M(II)-Cyanomethides. Eur J Inorg Chem (2013) 0.79
Quinone-Catalyzed Selective Oxidation of Organic Molecules. Angew Chem Int Ed Engl (2015) 0.78
[CuO](+) and [CuOH](2+) complexes: intermediates in oxidation catalysis? Acc Chem Res (2015) 0.78
Vanadium-Catalyzed C(sp(3))-H Fluorination Reactions. Org Chem Front (2014) 0.78
Kinetic and Spectroscopic Studies of Aerobic Copper(II)-Catalyzed Methoxylation of Arylboronic Esters and Insights into Aryl Transmetalation to Copper(II). Organometallics (2012) 0.78
Synthesis of Indole-2-carboxylate Derivatives via Palladium-Catalyzed Aerobic Amination of Aryl C-H Bonds. Org Lett (2016) 0.78
Chemistry. Copper's contribution to amination catalysis. Science (2013) 0.76
Room temperature copper(II)-catalyzed oxidative cyclization of enamides to 2,5-disubstituted oxazoles via vinylic C-H functionalization. J Org Chem (2012) 0.76
Perturbing the Copper(III)-Hydroxide Unit through Ligand Structural Variation. J Am Chem Soc (2015) 0.76
Probing Cu(I) in homogeneous catalysis using high-energy-resolution fluorescence-detected X-ray absorption spectroscopy. Chem Commun (Camb) (2015) 0.76
Manganese-catalyzed allylation via sequential C-H and C-C/C-Het bond activation. Chem Sci (2017) 0.75
Chemoselective Oxidation of Benzyl, Amino, and Propargyl Alcohols to Aldehydes and Ketones under Mild Reaction Conditions. ChemistryOpen (2014) 0.75
Ligand-Mediated and Copper-Catalyzed C(sp(3))-H Bond Functionalization of Aryl Ketones with Sodium Sulfinates under Mild Conditions. Sci Rep (2015) 0.75
A bioinspired catalytic aerobic oxidative C-H functionalization of primary aliphatic amines: synthesis of 1,2-disubstituted benzimidazoles. Chemistry (2015) 0.75
Copper-catalyzed aerobic oxidative coupling: From ketone and diamine to pyrazine. Sci Adv (2015) 0.75
The facile construction of the phthalazin-1(2H)-one scaffold via copper-mediated C-H(sp(2))/C-H(sp) coupling under mild conditions. Beilstein J Org Chem (2015) 0.75
A chlorine-free protocol for processing germanium. Sci Adv (2017) 0.75
Sterically directed nitronate complexes of 2,6-di-tert-butyl-4-nitrophenoxide with Cu(ii) and Zn(ii) and their H-atom transfer reactivity. Dalton Trans (2017) 0.75
Nickel or phenanthroline mediated intramolecular arylation of sp3 C-H bonds using aryl halides. Org Lett (2013) 0.75
[1+1+1] Cyclotrimerization for the Synthesis of Cyclopropanes. Angew Chem Int Ed Engl (2016) 0.75
Dual C-H functionalization of N-aryl amines: synthesis of polycyclic amines via an oxidative Povarov approach. Org Lett (2014) 0.75
Synthesis of antiviral tetrahydrocarbazole derivatives by photochemical and acid-catalyzed C-H functionalization via intermediate peroxides (CHIPS). J Vis Exp (2014) 0.75
Merging Visible Light Photoredox Catalysis with Metal Catalyzed C-H Activations: On the Role of Oxygen and Superoxide Ions as Oxidants. Acc Chem Res (2016) 0.75
An automated method to find reaction mechanisms and solve the kinetics in organometallic catalysis. Chem Sci (2017) 0.75
Copper-catalyzed oxidative C(sp(3))-H/C(sp(2))-H cross-coupling en route to carbocyclic rings. Chem Sci (2017) 0.75
Reactivity of a stable copper-dioxygen complex. Chem Commun (Camb) (2017) 0.75
Mimicry of antimicrobial host-defense peptides by random copolymers. J Am Chem Soc (2007) 2.12
Palladium(II)-catalyzed alkene functionalization via nucleopalladation: stereochemical pathways and enantioselective catalytic applications. Chem Rev (2011) 1.76
Highly regioselective Pd-catalyzed intermolecular aminoacetoxylation of alkenes and evidence for cis-aminopalladation and S(N)2 C-O bond formation. J Am Chem Soc (2006) 1.69
Highly practical copper(I)/TEMPO catalyst system for chemoselective aerobic oxidation of primary alcohols. J Am Chem Soc (2011) 1.64
Synthesis of pyrrolidines via palladium(II)-catalyzed aerobic oxidative carboamination of butyl vinyl ether and styrenes with allyl tosylamides. Org Lett (2006) 1.50
Copper-catalyzed aerobic oxidative amidation of terminal alkynes: efficient synthesis of ynamides. J Am Chem Soc (2008) 1.48
Palladium-catalyzed aerobic oxidative amination of alkenes: development of intra- and intermolecular aza-Wacker reactions. Inorg Chem (2007) 1.43
Carbon-nitrogen bond formation involving well-defined aryl-copper(III) complexes. J Am Chem Soc (2008) 1.40
Synthesis of cyclic enones via direct palladium-catalyzed aerobic dehydrogenation of ketones. J Am Chem Soc (2011) 1.39
Copper-catalyzed aerobic oxidative functionalization of an arene C-H bond: evidence for an aryl-copper(III) intermediate. J Am Chem Soc (2010) 1.38
Dual mechanism of bacterial lethality for a cationic sequence-random copolymer that mimics host-defense antimicrobial peptides. J Mol Biol (2008) 1.37
Mechanistic study of copper-catalyzed aerobic oxidative coupling of arylboronic esters and methanol: insights into an organometallic oxidase reaction. J Am Chem Soc (2009) 1.34
Mechanism of Pd(OAc)2/DMSO-catalyzed aerobic alcohol oxidation: mass-transfer-limitation effects and catalyst decomposition pathways. J Am Chem Soc (2006) 1.33
Efficient intramolecular oxidative amination of olefins through direct dioxygen-coupled palladium catalysis. Angew Chem Int Ed Engl (2002) 1.32
Two-faced reactivity of alkenes: cis- versus trans-aminopalladation in aerobic Pd-catalyzed intramolecular aza-Wacker reactions. J Am Chem Soc (2007) 1.31
Development of Safe and Scalable Continuous-Flow Methods for Palladium-Catalyzed Aerobic Oxidation Reactions. Green Chem (2010) 1.29
Allylic C-H acetoxylation with a 4,5-diazafluorenone-ligated palladium catalyst: a ligand-based strategy to achieve aerobic catalytic turnover. J Am Chem Soc (2010) 1.29
Structure-activity relationships among random nylon-3 copolymers that mimic antibacterial host-defense peptides. J Am Chem Soc (2009) 1.26
Overcoming the "oxidant problem": strategies to use O2 as the oxidant in organometallic C-H oxidation reactions catalyzed by Pd (and Cu). Acc Chem Res (2012) 1.25
Palladium-catalyzed aerobic dehydrogenation of substituted cyclohexanones to phenols. Science (2011) 1.24
Enantioselective Pd(II)-catalyzed aerobic oxidative amidation of alkenes and insights into the role of electronic asymmetry in pyridine-oxazoline ligands. Org Lett (2011) 1.23
Aerobic oxidative amination of unactivated alkenes catalyzed by palladium. J Am Chem Soc (2005) 1.22
Ligand-modulated palladium oxidation catalysis: mechanistic insights into aerobic alcohol oxidation with the Pd(OAc)(2)/pyridine catalyst system. Org Lett (2002) 1.20
Mechanistic characterization of aerobic alcohol oxidation catalyzed by Pd(OAc)(2)/pyridine including identification of the catalyst resting state and the origin of nonlinear [catalyst] dependence. J Am Chem Soc (2004) 1.19
Chemoselective metal-free aerobic alcohol oxidation in lignin. J Am Chem Soc (2013) 1.18
Access to poly-beta-peptides with functionalized side chains and end groups via controlled ring-opening polymerization of beta-lactams. J Am Chem Soc (2009) 1.17
Regioselective copper-catalyzed chlorination and bromination of arenes with O(2) as the oxidant. Chem Commun (Camb) (2009) 1.14
Mechanistic study of alcohol oxidation by the Pd(OAc)(2)/O(2)/DMSO catalyst system and implications for the development of improved aerobic oxidation catalysts. J Am Chem Soc (2002) 1.11
Aerobic Oxidative Coupling of o-Xylene: Discovery of 2-Fluoropyridine as a Ligand to Support Selective Pd-Catalyzed C-H Functionalization. Adv Synth Catal (2010) 1.10
Enantioselective hydroformylation of N-vinyl carboxamides, allyl carbamates, and allyl ethers using chiral diazaphospholane ligands. J Am Chem Soc (2010) 1.09
Practical aerobic oxidations of alcohols and amines with homogeneous copper/TEMPO and related catalyst systems. Angew Chem Int Ed Engl (2014) 1.09
Reaction of molecular oxygen with a Pd(II)-hydride to produce a Pd(II)-hydroperoxide: experimental evidence for an HX-reductive-elimination pathway. J Am Chem Soc (2008) 1.08
Unexpected roles of molecular sieves in palladium-catalyzed aerobic alcohol oxidation. J Org Chem (2006) 1.08
Catalytic transamidation reactions compatible with tertiary amide metathesis under ambient conditions. J Am Chem Soc (2009) 1.06
"Inverse-electron-demand" ligand substitution: experimental and computational insights into olefin exchange at palladium(0). J Am Chem Soc (2004) 1.04
Reversible alkene insertion into the Pd-N bond of Pd(II)-sulfonamidates and implications for catalytic amidation reactions. J Am Chem Soc (2011) 1.03
Mechanistic study of asymmetric oxidative biaryl coupling: evidence for self-processing of the copper catalyst to achieve control of oxidase vs oxygenase activity. J Am Chem Soc (2008) 1.03
Reconciling the stereochemical course of nucleopalladation with the development of enantioselective wacker-type cyclizations. Angew Chem Int Ed Engl (2012) 1.03
Mechanism of Pd(OAc)2/pyridine catalyst reoxidation by O2: influence of labile monodentate ligands and identification of a biomimetic mechanism for O2 activation. Chemistry (2009) 1.02
Catalytic transamidation under moderate conditions. J Am Chem Soc (2003) 1.01
Highly stable redox-active molecular layers by covalent grafting to conductive diamond. J Am Chem Soc (2011) 1.01
Copper(I)/ABNO-catalyzed aerobic alcohol oxidation: alleviating steric and electronic constraints of Cu/TEMPO catalyst systems. J Am Chem Soc (2013) 1.00
Modular synthesis of 1,2-diamine derivatives by palladium-catalyzed aerobic oxidative cyclization of allylic sulfamides. Angew Chem Int Ed Engl (2010) 1.00
Direct Aerobic α, β-Dehydrogenation of Aldehydes and Ketones with a Pd(TFA)(2)/4,5-Diazafluorenone Catalyst(). Chem Sci (2011) 0.98
Mechanism of copper(I)/TEMPO-catalyzed aerobic alcohol oxidation. J Am Chem Soc (2013) 0.97
Formation of enamides via palladium(II)-catalyzed vinyl transfer from vinyl ethers to nitrogen nucleophiles. Org Lett (2004) 0.97
Mechanistic studies of Wacker-type intramolecular aerobic oxidative amination of alkenes catalyzed by Pd(OAc)2/pyridine. J Org Chem (2011) 0.97
Catalyst-controlled regioselectivity in the synthesis of branched conjugated dienes via aerobic oxidative Heck reactions. J Am Chem Soc (2012) 0.96
Catalytic metathesis of simple secondary amides. Angew Chem Int Ed Engl (2007) 0.96
Regiocontrolled aerobic oxidative coupling of indoles and benzene using Pd catalysts with 4,5-diazafluorene ligands. Chem Commun (Camb) (2011) 0.95
Aerobic oxidative Heck/dehydrogenation reactions of cyclohexenones: efficient access to meta-substituted phenols. Angew Chem Int Ed Engl (2013) 0.93
Mechanistic studies of Wacker-type amidocyclization of alkenes catalyzed by (IMes)Pd(TFA)2(H2O): kinetic and stereochemical implications of proton transfer. J Org Chem (2012) 0.93
Characterization of peroxo and hydroperoxo intermediates in the aerobic oxidation of N-heterocyclic-carbene-coordinated palladium(0). J Am Chem Soc (2004) 0.93
PdII complexes possessing a seven-membered N-heterocyclic carbene ligand. Angew Chem Int Ed Engl (2005) 0.93
Pd-catalyzed Semmler-Wolff reactions for the conversion of substituted cyclohexenone oximes to primary anilines. J Am Chem Soc (2013) 0.93
Nylon-3 copolymers that generate cell-adhesive surfaces identified by library screening. J Am Chem Soc (2009) 0.92
Mechanism of alcohol oxidation mediated by copper(II) and nitroxyl radicals. J Am Chem Soc (2014) 0.92
Observation and mechanistic study of facile C-O bond formation between a well-defined aryl-copper(III) complex and oxygen nucleophiles. Chemistry (2011) 0.91
Biophysical mimicry of lung surfactant protein B by random nylon-3 copolymers. J Am Chem Soc (2010) 0.91
Intramolecular Pd(II)-catalyzed aerobic oxidative amination of alkenes: synthesis of six-membered N-heterocycles. Org Lett (2012) 0.91
Palladium-catalyzed intermolecular aminoacetoxylation of alkenes and the influence of PhI(OAc)2 on aminopalladation stereoselectivity. J Org Chem (2013) 0.90
Aerobic intramolecular oxidative amination of alkenes catalyzed by NHC-coordinated palladium complexes. Org Lett (2006) 0.89
Dioxygen-coupled oxidative amination of styrene. J Am Chem Soc (2003) 0.89
Palladium-catalyzed oxidative amination of alkenes: improved catalyst reoxidation enables the use of alkene as the limiting reagent. Org Lett (2007) 0.89
Electrochemical water oxidation with cobalt-based electrocatalysts from pH 0-14: the thermodynamic basis for catalyst structure, stability, and activity. J Am Chem Soc (2011) 0.88
Effects of side chain configuration and backbone spacing on the gene delivery properties of lysine-derived cationic polymers. Bioconjug Chem (2005) 0.88
Copper(I)/TEMPO-catalyzed aerobic oxidation of primary alcohols to aldehydes with ambient air. Nat Protoc (2012) 0.88
Aerobic dehydrogenation of cyclohexanone to phenol catalyzed by Pd(TFA)2/2-dimethylaminopyridine: evidence for the role of Pd nanoparticles. J Am Chem Soc (2013) 0.88
Insertion of molecular oxygen into a palladium-hydride bond: computational evidence for two nearly isoenergetic pathways. J Am Chem Soc (2007) 0.88
Chemoselective organocatalytic aerobic oxidation of primary amines to secondary imines. Org Lett (2012) 0.87
Reaction of O2 with [(-)-sparteine]Pd(H)Cl: evidence for an intramolecular [H-L]+ "reductive elimination" pathway. J Am Chem Soc (2011) 0.87
C-terminal functionalization of nylon-3 polymers: effects of C-terminal groups on antibacterial and hemolytic activities. Biomacromolecules (2011) 0.87
Synthesis of Pd Complexes Bearing an Enantiomerically-Resolved Seven-Membered N-Heterocyclic Carbene Ligands and Initial Studies of their Use in Asymmetric Wacker-Type Oxidative Cyclization Reactions. Tetrahedron (2009) 0.87
Cooperative electrocatalytic alcohol oxidation with electron-proton-transfer mediators. Nature (2016) 0.86
Characterization of DMSO coordination to palladium(II) in solution and insights into the aerobic oxidation catalyst, Pd(DMSO)2(TFA)2. Inorg Chem (2012) 0.86
Steric modulation of chiral biaryl diamines via Pd-catalyzed directed C-H arylation. J Org Chem (2009) 0.85
Synthesis of beta-lactams bearing functionalized side chains from a readily available precursor. Org Lett (2008) 0.85
Reaction of molecular oxygen with a PdII- hydride to produce a PdII-hydroperoxide: acid catalysis and implications for Pd-catalyzed aerobic oxidation reactions. Angew Chem Int Ed Engl (2006) 0.85
Benzoquinone-promoted reaction of O2 with a Pd(II)-hydride. J Am Chem Soc (2011) 0.85
Brønsted base-modulated regioselectivity in the aerobic oxidative amination of styrene catalyzed by palladium. J Am Chem Soc (2005) 0.84
Divergence between organometallic and single-electron-transfer mechanisms in copper(II)-mediated aerobic C-H oxidation. J Am Chem Soc (2013) 0.84
Copper-catalyzed hydroalkylation of terminal alkynes. J Am Chem Soc (2015) 0.84
Cu/Nitroxyl Catalyzed Aerobic Oxidation of Primary Amines into Nitriles at Room Temperature. ACS Catal (2013) 0.84
Modular Synthesis of 1,2-Diamine Derivatives via Palladium-Catalyzed Aerobic Oxidative Cyclization of Allylic Sulfamides. Angew Chem Int Ed Engl (2010) 0.83
Molecular mechanism of acid-triggered aryl-halide reductive elimination in well-defined aryl-Cu(III)-halide species. Dalton Trans (2010) 0.83
Synthesis of vicinal aminoalcohols by stereoselective aza-Wacker cyclizations: access to (-)-acosamine by redox relay. Angew Chem Int Ed Engl (2013) 0.83
Mechanistic analysis of trans C-N reductive elimination from a square-planar macrocyclic aryl-copper(III) complex. Dalton Trans (2011) 0.83
Reaction of molecular oxygen with an NHC-coordinated Pd0 complex: computational insights and experimental implications. Angew Chem Int Ed Engl (2007) 0.83
Functionally Diverse Nylon-3 Copolymers from Readily Accessible β-Lactams. ACS Macro Lett (2012) 0.83
Pd-catalyzed aerobic oxidative coupling of arenes: evidence for transmetalation between two Pd(II)-aryl intermediates. J Am Chem Soc (2014) 0.82
Electronic structural comparison of the reactions of dioxygen and alkenes with nitrogen-chelated palladium(0). Inorg Chem (2010) 0.82
Fluoride-modulated cobalt catalysts for electrochemical oxidation of water under non-alkaline conditions. ChemSusChem (2010) 0.82
Bioinspired aerobic oxidation of secondary amines and nitrogen heterocycles with a bifunctional quinone catalyst. J Am Chem Soc (2013) 0.81
Aerobic dehydrogenation of cyclohexanone to cyclohexenone catalyzed by Pd(DMSO)2(TFA)2: evidence for ligand-controlled chemoselectivity. J Am Chem Soc (2013) 0.81
Modular o-quinone catalyst system for dehydrogenation of tetrahydroquinolines under ambient conditions. J Am Chem Soc (2014) 0.81
Insights into the spin-forbidden reaction between L2Pd0 and molecular oxygen. J Am Chem Soc (2004) 0.80
Synthesis and isolation of a stable, axially-chiral seven-membered N-heterocyclic carbene. Dalton Trans (2009) 0.78
Copper(II)-mediated oxidative cyclization of enamides to oxazoles. Org Biomol Chem (2012) 0.78
Kinetic and Spectroscopic Studies of Aerobic Copper(II)-Catalyzed Methoxylation of Arylboronic Esters and Insights into Aryl Transmetalation to Copper(II). Organometallics (2012) 0.78
Modular synthesis of alkyne-substituted ruthenium polypyridyl complexes suitable for "click" coupling. Inorg Chem (2013) 0.78