Molybdenum-based complexes with two aryloxides and a pentafluoroimido ligand: catalysts for efficient Z-selective synthesis of a macrocyclic trisubstituted alkene by ring-closing metathesis.

Synthesis of Z-(pinacolato)allylboron and Z-(pinacolato)alkenylboron compounds through stereoselective catalytic cross-metathesis. J Am Chem Soc (2013) 1.21

Evolution of catalytic stereoselective olefin metathesis: from ancillary transformation to purveyor of stereochemical identity. J Org Chem (2014) 1.02

Synthesis of High Oxidation State Molybdenum Imido Heteroatom-Substituted Alkylidene Complexes. Organometallics (2013) 0.89

Catalyst-controlled stereoselective olefin metathesis as a principal strategy in multistep synthesis design: a concise route to (+)-neopeltolide. Angew Chem Int Ed Engl (2014) 0.86

Preparation of macrocyclic Z-enoates and (E,Z)- or (Z,E)-dienoates through catalytic stereoselective ring-closing metathesis. J Am Chem Soc (2014) 0.82

Ru-Based Z-Selective Metathesis Catalysts with Modified Cyclometalated Carbene Ligands. Chem Sci (2014) 0.81

Contemporary Strategies for the Synthesis of Tetrahydropyran Derivatives: Application to Total Synthesis of Neopeltolide, a Marine Macrolide Natural Product. Mar Drugs (2016) 0.75

Investigations into Ruthenium Metathesis Catalysts with Six-Membered Chelating NHC Ligands: Relationship between Catalyst Structure and Stereoselectivity. Organometallics (2013) 0.75

Metathesis reactions in total synthesis. Angew Chem Int Ed Engl (2005) 3.56

Highly efficient molybdenum-based catalysts for enantioselective alkene metathesis. Nature (2008) 3.36

The remarkable metal-catalysed olefin metathesis reaction. Nature (2007) 3.23

Catalytic Z-selective olefin cross-metathesis for natural product synthesis. Nature (2011) 2.89

Highly Z- and enantioselective ring-opening/cross-metathesis reactions catalyzed by stereogenic-at-Mo adamantylimido complexes. J Am Chem Soc (2009) 2.17

Macrocyclization by ring-closing metathesis in the total synthesis of natural products: reaction conditions and limitations. Angew Chem Int Ed Engl (2006) 2.10

Design and stereoselective preparation of a new class of chiral olefin metathesis catalysts and application to enantioselective synthesis of quebrachamine: catalyst development inspired by natural product synthesis. J Am Chem Soc (2009) 1.77

Synthesis of monoalkoxide monopyrrolyl complexes Mo(NR)(CHR')(OR'')(pyrrolyl): enyne metathesis with high oxidation state catalysts. J Am Chem Soc (2007) 1.63

Synthesis of macrocyclic natural products by catalyst-controlled stereoselective ring-closing metathesis. Nature (2011) 1.50

Understanding d(0)-olefin metathesis catalysts: which metal, which ligands? J Am Chem Soc (2007) 1.48

On the remarkable antitumor properties of fludelone: how we got there. Angew Chem Int Ed Engl (2005) 1.28

Enol ethers as substrates for efficient Z- and enantioselective ring-opening/cross-metathesis reactions promoted by stereogenic-at-Mo complexes: utility in chemical synthesis and mechanistic attributes. J Am Chem Soc (2012) 1.23

Total synthesis of dolabelide D. J Am Chem Soc (2006) 1.22

The chemistry and biology of epothilones--the wheel keeps turning. ChemMedChem (2007) 1.21

Alkyne metathesis. Chem Commun (Camb) (2005) 1.13

Evolution of a total synthesis of (-)-kendomycin exploiting a Petasis-Ferrier rearrangement/ring-closing olefin metathesis strategy. J Am Chem Soc (2006) 1.05

Synthesis of a C(1)-C(14)-containing fragment of callipeltoside A. Org Lett (1999) 1.01

Control of olefin geometry in macrocyclic ring-closing metathesis using a removable silyl group. J Am Chem Soc (2011) 0.98

Shutting down secondary reaction pathways: the essential role of the pyrrolyl ligand in improving silica supported d(0)-ML4 alkene metathesis catalysts from DFT calculations. J Am Chem Soc (2010) 0.96

Total synthesis of floresolide B and Delta(6,7)-Z-floresolide B. Chem Commun (Camb) (2006) 0.89

Solid-phase based total synthesis of Jasplakinolide by ring-closing metathesis. Chem Commun (Camb) (2009) 0.84

Application of a metathesis reaction in the synthesis of sterically congested medium-sized rings. A direct ring closing versus a double bond migration-ring closing process. Org Biomol Chem (2011) 0.81

Catalytic antibody route to the naturally occurring epothilones: total synthesis of epothilones A-F. Chemistry (2001) 0.81

Total synthesis of the terpenoid buddledone A: 11-membered ring-closing metathesis. Org Lett (2012) 0.79

Catalytic reduction of dinitrogen to ammonia at a single molybdenum center. Science (2003) 4.28

Molybdenum and tungsten imido alkylidene complexes as efficient olefin-metathesis catalysts. Angew Chem Int Ed Engl (2003) 4.01

Highly efficient molybdenum-based catalysts for enantioselective alkene metathesis. Nature (2008) 3.36

Catalytic Z-selective olefin cross-metathesis for natural product synthesis. Nature (2011) 2.89

Highly Z- and enantioselective ring-opening/cross-metathesis reactions catalyzed by stereogenic-at-Mo adamantylimido complexes. J Am Chem Soc (2009) 2.17

Enantioselective silyl protection of alcohols catalysed by an amino-acid-based small molecule. Nature (2006) 2.16

Highly Z-selective metathesis homocoupling of terminal olefins. J Am Chem Soc (2009) 2.01

Dipyrrolyl precursors to bisalkoxide molybdenum olefin metathesis catalysts. J Am Chem Soc (2006) 1.94

Z-selective olefin metathesis processes catalyzed by a molybdenum hexaisopropylterphenoxide monopyrrolide complex. J Am Chem Soc (2009) 1.83

A readily available chiral Ag-based N-heterocyclic carbene complex for use in efficient and highly enantioselective Ru-catalyzed olefin metathesis and Cu-catalyzed allylic alkylation reactions. J Am Chem Soc (2005) 1.78

Design and stereoselective preparation of a new class of chiral olefin metathesis catalysts and application to enantioselective synthesis of quebrachamine: catalyst development inspired by natural product synthesis. J Am Chem Soc (2009) 1.77

All-carbon quaternary stereogenic centers by enantioselective cu-catalyzed conjugate additions promoted by a chiral N-heterocyclic carbene. Angew Chem Int Ed Engl (2007) 1.76

Efficient boron-copper additions to aryl-substituted alkenes promoted by NHC-based catalysts. enantioselective Cu-catalyzed hydroboration reactions. J Am Chem Soc (2009) 1.74

Studies relevant to catalytic reduction of dinitrogen to ammonia by molybdenum triamidoamine complexes. Inorg Chem (2005) 1.69

Synthesis of monoalkoxide monopyrrolyl complexes Mo(NR)(CHR')(OR'')(pyrrolyl): enyne metathesis with high oxidation state catalysts. J Am Chem Soc (2007) 1.63

Chiral Ru-based complexes for asymmetric olefin metathesis: enhancement of catalyst activity through steric and electronic modifications. J Am Chem Soc (2003) 1.60

Enantioselective synthesis of all-carbon quaternary stereogenic centers by catalytic asymmetric conjugate additions of alkyl and aryl aluminum reagents to five-, six-, and seven-membered-ring beta-substituted cyclic enones. Angew Chem Int Ed Engl (2008) 1.59

Vicinal diboronates in high enantiomeric purity through tandem site-selective NHC-Cu-catalyzed boron-copper additions to terminal alkynes. J Am Chem Soc (2009) 1.51

Synthesis of macrocyclic natural products by catalyst-controlled stereoselective ring-closing metathesis. Nature (2011) 1.50

Highly site- and enantioselective Cu-catalyzed allylic alkylation reactions with easily accessible vinylaluminum reagents. J Am Chem Soc (2007) 1.48

Reduction of dinitrogen to ammonia at a well-protected reaction site in a molybdenum triamidoamine complex. J Am Chem Soc (2002) 1.47

Enantioselective synthesis of allylboronates bearing a tertiary or quaternary B-substituted stereogenic carbon by NHC-Cu-catalyzed substitution reactions. J Am Chem Soc (2010) 1.44

Cu-catalyzed asymmetric allylic alkylations of aromatic and aliphatic phosphates with alkylzinc reagents. An effective method for enantioselective synthesis of tertiary and quaternary carbons. J Am Chem Soc (2004) 1.44

Chiral N-heterocyclic carbenes in natural product synthesis: application of Ru-catalyzed asymmetric ring-opening/cross-metathesis and Cu-catalyzed allylic alkylation to total synthesis of baconipyrone C. Angew Chem Int Ed Engl (2007) 1.43

Enantioselective synthesis of cyclic amides and amines through mo-catalyzed asymmetric ring-closing metathesis. J Am Chem Soc (2005) 1.42

A practical method for enantioselective synthesis of all-carbon quaternary stereogenic centers through NHC-Cu-catalyzed conjugate additions of alkyl- and arylzinc reagents to beta-substituted cyclic enones. J Am Chem Soc (2006) 1.40

Mechanism for catechol ring-cleavage by non-heme iron extradiol dioxygenases. J Am Chem Soc (2004) 1.39

The significance of degenerate processes to enantioselective olefin metathesis reactions promoted by stereogenic-at-Mo complexes. J Am Chem Soc (2009) 1.37

Simple organic molecules as catalysts for enantioselective synthesis of amines and alcohols. Nature (2013) 1.34

Site- and enantioselective formation of allene-bearing tertiary or quaternary carbon stereogenic centers through NHC-Cu-catalyzed allylic substitution. J Am Chem Soc (2012) 1.33

Enantioselective total synthesis of clavirolide C. Applications of Cu-catalyzed asymmetric conjugate additions and Ru-catalyzed ring-closing metathesis. J Am Chem Soc (2008) 1.33

Fundamental studies of tungsten alkylidene imido monoalkoxidepyrrolide complexes. J Am Chem Soc (2009) 1.33

Efficient enantioselective synthesis of functionalized tetrahydropyrans by Ru-catalyzed asymmetric ring-opening metathesis/cross-metathesis (AROM/CM). J Am Chem Soc (2004) 1.32

Comparison of Ru- and Mo-based chiral olefin metathesis catalysts. Complementarity in asymmetric ring-opening/cross-metathesis reactions of oxa- and azabicycles. Org Lett (2007) 1.32

Bidentate NHC-based chiral ligands for efficient Cu-catalyzed enantioselective allylic alkylations: structure and activity of an air-stable chiral Cu complex. J Am Chem Soc (2004) 1.32

Efficient and practical Ag-catalyzed cycloadditions between arylimines and the Danishefsky diene. J Am Chem Soc (2003) 1.30

Tyrosine gated electron transfer is key to the toxic mechanism of Alzheimer's disease beta-amyloid. FASEB J (2004) 1.29

Molybdenum triamidoamine complexes that contain hexa-tert-butylterphenyl, hexamethylterphenyl, or p-bromohexaisopropylterphenyl substituents. An examination of some catalyst variations for the catalytic reduction of dinitrogen. J Am Chem Soc (2004) 1.28

Efficient C-B bond formation promoted by N-heterocyclic carbenes: synthesis of tertiary and quaternary B-substituted carbons through metal-free catalytic boron conjugate additions to cyclic and acyclic alpha,beta-unsaturated carbonyls. J Am Chem Soc (2009) 1.28

Surface versus molecular siloxy ligands in well-defined olefin metathesis catalysts: [{(RO)3SiO}Mo(=NAr)(=CHtBu)(CH2tBu)]. Angew Chem Int Ed Engl (2006) 1.26

Inversion of configuration at the metal in diastereomeric imido alkylidene monoaryloxide monopyrrolide complexes of molybdenum. J Am Chem Soc (2009) 1.26

Synthesis and reactions of molybdenum triamidoamine complexes containing hexaisopropylterphenyl substituents. Inorg Chem (2003) 1.25

Formation of {[HIPTN(3)N]Mo(III)H}(-) by heterolytic cleavage of H(2) as established by EPR and ENDOR spectroscopy. Inorg Chem (2010) 1.25

Monodentate non-C(2)-symmetric chiral N-heterocyclic carbene complexes for enantioselective synthesis. Cu-catalyzed conjugate additions of aryl- and alkenylsilylfluorides to cyclic enones. J Org Chem (2009) 1.24

Enol ethers as substrates for efficient Z- and enantioselective ring-opening/cross-metathesis reactions promoted by stereogenic-at-Mo complexes: utility in chemical synthesis and mechanistic attributes. J Am Chem Soc (2012) 1.23

Room Temperature Z-Selective Homocoupling of α Olefins by Tungsten Catalysts. Organometallics (2011) 1.22

Enantioselective synthesis of medium-ring heterocycles, tertiary ethers, and tertiary alcohols by Mo-catalyzed ring-closing metathesis. J Am Chem Soc (2002) 1.22

Alpha-selective Ni-catalyzed hydroalumination of aryl- and alkyl-substituted terminal alkynes: practical syntheses of internal vinyl aluminums, halides, or boronates. J Am Chem Soc (2010) 1.22

Alkylidene and metalacyclic complexes of tungsten that contain a chiral biphenoxide ligand. synthesis, asymmetric ring-closing metathesis, and mechanistic investigations. J Am Chem Soc (2003) 1.21

Synthesis of Z-(pinacolato)allylboron and Z-(pinacolato)alkenylboron compounds through stereoselective catalytic cross-metathesis. J Am Chem Soc (2013) 1.21

Endo-selective enyne ring-closing metathesis promoted by stereogenic-at-Mo monoalkoxide and monoaryloxide complexes. Efficient synthesis of cyclic dienes not accessible through reactions with Ru carbenes. J Am Chem Soc (2009) 1.21

Diphenylamido Precursors to Bisalkoxide Molybdenum Olefin Metathesis Catalysts. Organometallics (2006) 1.21

Enantioselective synthesis of homoallylic amines through reactions of (pinacolato)allylborons with aryl-, heteroaryl-, alkyl-, or alkene-substituted aldimines catalyzed by chiral C1-symmetric NHC-Cu complexes. J Am Chem Soc (2011) 1.21

Enantioselective synthesis of boron-substituted quaternary carbons by NHC-Cu-catalyzed boronate conjugate additions to unsaturated carboxylic esters, ketones, or thioesters. J Am Chem Soc (2010) 1.20

Isolation of pure disubstituted E olefins through Mo-catalyzed Z-selective ethenolysis of stereoisomeric mixtures. J Am Chem Soc (2011) 1.20

Kinetic resolution of 1,2-diols through highly site- and enantioselective catalytic silylation. Angew Chem Int Ed Engl (2007) 1.19

Experimental and theoretical EPR study of Jahn-Teller-active [HIPTN(3)N]MoL complexes (L = N(2), CO, NH(3)). J Am Chem Soc (2010) 1.17

Enhancement of enantioselectivity by THF in asymmetric mo-catalyzed olefin metathesis. Catalytic enantioselective synthesis of cyclic tertiary ethers and spirocycles. J Am Chem Soc (2002) 1.17

A recyclable chiral Ru catalyst for enantioselective olefin metathesis. Efficient catalytic asymmetric ring-opening/cross metathesis in air. J Am Chem Soc (2002) 1.16

Enantioselective conjugate silyl additions to cyclic and acyclic unsaturated carbonyls catalyzed by Cu complexes of chiral N-heterocyclic carbenes. J Am Chem Soc (2010) 1.16

Highly selective methods for synthesis of internal (α-) vinylboronates through efficient NHC-Cu-catalyzed hydroboration of terminal alkynes. Utility in chemical synthesis and mechanistic basis for selectivity. J Am Chem Soc (2011) 1.16

Stereogenic-at-metal Zn- and Al-based N-heterocyclic carbene (NHC) complexes as bifunctional catalysts in Cu-free enantioselective allylic alkylations. J Am Chem Soc (2009) 1.15

Barrier to enantiomerization of unstabilized, chelated, and dipole-stabilized 2-lithiopyrrolidines. J Am Chem Soc (2005) 1.15

Cu-catalyzed chemoselective preparation of 2-(pinacolato)boron-substituted allylcopper complexes and their in situ site-, diastereo-, and enantioselective additions to aldehydes and ketones. Angew Chem Int Ed Engl (2013) 1.15

Efficient and selective formation of macrocyclic disubstituted Z alkenes by ring-closing metathesis (RCM) reactions catalyzed by Mo- or W-based monoaryloxide pyrrolide (MAP) complexes: applications to total syntheses of epilachnene, yuzu lactone, ambrettolide, epothilone C, and nakadomarin A. Chemistry (2013) 1.14

Enantioselective synthesis of nitroalkanes bearing all-carbon quaternary stereogenic centers through Cu-catalyzed asymmetric conjugate additions. J Am Chem Soc (2005) 1.14

Synthesis of cis,syndiotactic ROMP polymers containing alternating enantiomers. J Am Chem Soc (2011) 1.14

Total synthesis of anti-HIV agent chloropeptin I. J Am Chem Soc (2003) 1.11

Efficient catalytic enantioselective synthesis of unsaturated amines: preparation of small- and medium-ring cyclic amines through mo-catalyzed asymmetric ring-closing metathesis in the absence of solvent. J Am Chem Soc (2002) 1.10

Lewis base activation of grignard reagents with N-heterocyclic carbenes. Cu-free catalytic enantioselective additions to gamma-chloro-alpha,beta-unsaturated esters. J Am Chem Soc (2006) 1.10

Ethenolysis reactions catalyzed by imido alkylidene monoaryloxide monopyrrolide (MAP) complexes of molybdenum. J Am Chem Soc (2009) 1.09

Catalytic enantioselective alkylations of tetrasubstituted olefins. Synthesis of all-carbon quaternary stereogenic centers through Cu-catalyzed asymmetric conjugate additions of alkylzinc reagents to enones. J Am Chem Soc (2005) 1.09

Catalytic reduction of dinitrogen to ammonia at a single molybdenum center. Proc Natl Acad Sci U S A (2006) 1.08

NHC-Cu-catalyzed protoboration of monosubstituted allenes. Ligand-controlled site selectivity, application to synthesis and mechanism. Org Lett (2013) 1.08